CN107033280A - Drilling fluid both sexes heat and salinity tolerance fluid loss additive and preparation method - Google Patents
Drilling fluid both sexes heat and salinity tolerance fluid loss additive and preparation method Download PDFInfo
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- CN107033280A CN107033280A CN201710127078.3A CN201710127078A CN107033280A CN 107033280 A CN107033280 A CN 107033280A CN 201710127078 A CN201710127078 A CN 201710127078A CN 107033280 A CN107033280 A CN 107033280A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/52—Amides or imides
- C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F220/56—Acrylamide; Methacrylamide
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/02—Well-drilling compositions
- C09K8/03—Specific additives for general use in well-drilling compositions
- C09K8/035—Organic additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/02—Well-drilling compositions
- C09K8/04—Aqueous well-drilling compositions
- C09K8/14—Clay-containing compositions
- C09K8/18—Clay-containing compositions characterised by the organic compounds
- C09K8/22—Synthetic organic compounds
- C09K8/24—Polymers
Abstract
The invention discloses a kind of drilling fluid both sexes heat and salinity tolerance fluid loss additive and preparation method, it is made up of the raw material of following certain part by weight:Acrylamide, olefin sulfonic acid or AOS, acrylic acid, cationic monomer, rigid unitary, sodium hydroxide, potassium hydroxide, dispersant, deionized water, molecular weight regulator, initiator;Preparation method:Acrylamide, acrylic acid, olefin sulfonic acid or AOS, cationic monomer, rigid unitary and deionized water are added in the reactor, solution ph is adjusted after dissolving, reactor is transferred to after adding dispersant, logical nitrogen deoxygenation adds initiator initiation polymerization, and reaction takes out jelly after terminating and dries, pulverizes and sieves.Filtrate reducer for drilling fluid molecular weight of the present invention is controllable;The drilling condition of complexity is adapted to, can be used in horizontal well, high temperature deep well, saline bed;The residual list of filtrate reducer for drilling fluid is low;It is good with other oil field chemical compatibilities;Preparation method is simple;Cost is relatively low, beneficial to popularization.
Description
Technical field
The present invention relates to a kind of drilling fluid both sexes heat and salinity tolerance fluid loss additive and preparation method, belong to oilfield chemistry drilling well
Liquid inorganic agent field.
Background technology
It will be percolated when drilling fluid flows through permeable formation under stress in drilling process, cause the filtrate of drilling fluid to be invaded
Enter stratum, this process is commonly referred to as " dehydration ".If not controlling dehydration, the reduction of liquid phase volume will increase cement slurry density,
Thickening time, the former design requirement of rheology sexual deviation, substantial amounts of liquid, which flows into stratum, makes cement mortar become to be difficult to pump, and to stratum
Different degrees of injury is caused, filtrate invaded formation can not only cause shale hydration to expand, hole instability is caused when serious
With various down hole problems.Fluid loss additive is generally added in drilling fluid, the rheological characteristic of drilling fluid can be improved, by well
Low-permeability, flexible, thin and compact filter cake are formed on wall, the filter loss of drilling fluid is reduced as far as possible.
As oil-gas exploration and development develops to deep formation, bore the stratum met and become increasingly complex, property of drilling fluid is wanted
Ask harsher, the control of rheological characteristic and filter loss has turned into restriction drilling liquid technology particularly under high density drilling fluid hot conditions
The principal element of development.Under the high temperature conditions, the effect partial of existing additive for drilling fluid or completely lose, if in saliferous
Under the conditions of, such case can be more serious.Therefore, the need for the ultra-deep well drilling, domestic and international expert and scientific research personnel are in anti-height
Carry out a series of research work in terms of warm additive for drilling fluid, but these researchs focus primarily upon the polymerization object space of vinyl monomer
Face, and due to the limitation of group on the molecular structure and molecule of such polymer, in control drilling fluid high-temperature high pressure filter loss
Aspect goes back Shortcomings.
For this it is contemplated that a kind of new fluid loss additive of exploitation solves asking for high temperature and high pre ssure filtration in the prior art
Topic.
The content of the invention
The purpose of the present invention is dropped aiming at the defect that prior art is present there is provided a kind of drilling fluid with both sexes heat and salinity tolerance
Fluid loss agents and preparation method.
Its technical scheme is:A kind of drilling fluid both sexes heat and salinity tolerance fluid loss additive and preparation method, the drilling fluid use two
Property heat and salinity tolerance fluid loss additive is made up of the raw material of following parts by weight:280-340 parts of acrylamide, olefin sulfonic acid or alkenyl sulphur
20-70 parts of hydrochlorate, 20-55 parts of acrylic acid, 20-50 parts of cationic monomer, 8-20 parts of rigid unitary, sodium hydroxide 5-35
Part, 5-35 parts of potassium hydroxide, 0.5-2 parts of dispersant, 420-640 parts of deionized water, molecular weight regulator 0.001-0.05
Part, 0.001-0.5 part of initiator;Its preparation method is:Acrylamide, acrylic acid, olefin sulfonic acid or alkene are added in the reactor
It is molten with sodium hydroxide or potassium hydroxide regulation after base sulfonate, cationic monomer, rigid unitary and deionized water, fully dissolving
Liquid pH value, pH value is adjusted between 7.5-7.7, then adds dispersant, is transferred to after being sufficiently mixed in reactor, leads to nitrogen
40-80min of deoxygenation, adds initiator and triggers polymerization at 14-16 DEG C, and adjust products molecule by molecular weight regulator
Amount, so as to obtain the product of suitable molecular weight, reaction takes out jelly after terminating, by polymer prills and carry out drying dry,
Pulverize and sieve and produce the product.
Wherein, the olefin sulfonic acid or AOS are 2- acrylamide-2-methyl propane sulfonics, vinyl sulfonic acid, alkene
One or more in propyl sulfonic acid, methylpropene sodium sulfonate.
During the cationic monomer is dimethyl diallyl ammonium chloride, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride
It is one or more.
The rigid unitary is the one or more in NVP or N- benzyl-3-pyrrolidones.
The dispersant is the one or more in empgen BB or lauroylamidopropyl betaine.
The molecular weight regulator is the one or more in isopropanol, sodium formate.
The initiation system for triggering polymerization is composite initiation system, including azo-initiator and Redox Initiator
Agent;The azo-initiator is the NSC 18620 dihydrochloride of azo two, ABVN, azodiisobutyronitrile and 4,4 '-idol
One or more in nitrogen pair, 4- cyanopentanoic acids;Redox initiator is benzoyl peroxide, isopropyl benzene hydroperoxide, mistake
Any two kinds in potassium sulfate, sodium formaldehyde sulfoxylate, ferrous sulfate, sodium hydrogensulfite.
The pH value is adjusted using sodium hydroxide and potassium hydroxide, and sodium hydroxide and potassium hydroxide addition are to rub
You compare 1:1.5.
The dry temperature of the drying is 60-90 DEG C;It is described to pulverize and sieve to cross 20-50 mesh sieves after crushing.
Had the characteristics that compared with fluid loss additive of the invention with existing oilfield drilling:
(1)The filtrate reducer for drilling fluid molecular weight of the present invention is controllable, molecular weight ranges 20 ~ 6,000,000;
(2)Products obtained therefrom of the present invention makes fluid loss additive have very by introducing quaternary ammonium group and rigid radical in molecular side chain
Good heat and salinity tolerance performance, rigid radical can make fluid loss additive finer and close and abundant in the hydration shell that clay surface is formed, can
Calcium, the intrusion of magnesium ion are effectively hindered, so as to strengthen the ability that its salt resistance is invaded, calcium is invaded.Quaternary ammonium group carries positive charge, energy simultaneously
Occurs electrostatic adsorption with clay surface, so that fluid loss additive occurs stronger suction-operated with clay surface and reached anti-
Temperature, anticalcium effect.The more complicated drilling condition of the product adaptation, can be used in horizontal well, high temperature deep well, saline bed;
(3)K is introduced in the filtrate reducer for drilling fluid of the present invention+Ion, greatly reduces drilling fluid to the borehole wall and the wound on stratum
Evil, certain antiexpanding action is played to the clay mineral of stratum near wellbore zone;
(4)The residual list of filtrate reducer for drilling fluid of the present invention is low;
(5)The filtrate reducer for drilling fluid and other oil field chemical compatibilities of the present invention is good;
(6)Operating method step of the present invention is simple, and operating procedure is easy, easily controllable, and monomer is easy to get, the raw material of fluid loss additive into
This is relatively low, beneficial to popularization and application.
Embodiment
A kind of drilling fluid both sexes heat and salinity tolerance fluid loss additive and preparation method, the drilling fluid is dropped with both sexes heat and salinity tolerance to be filtered
Agent is lost to be made up of the raw material of following parts by weight:280-340 parts of acrylamide, olefin sulfonic acid or 20-70 parts of AOS, third
20-55 parts of olefin(e) acid, 20-50 parts of cationic monomer, 8-20 parts of rigid unitary, 5-35 parts of sodium hydroxide, potassium hydroxide 5-35
Part, 0.5-2 parts of dispersant, 420-640 parts of deionized water, 0.001-0.05 part of molecular weight regulator, initiator 0.001-
0.5 part;Its preparation method is:Acrylamide, acrylic acid, olefin sulfonic acid or AOS, cation are added in the reactor
After monomer, rigid unitary and deionized water, fully dissolving, solution ph is adjusted with sodium hydroxide or potassium hydroxide, pH value is adjusted
Save between 7.5-7.7, then to add dispersant, be transferred in reactor after being sufficiently mixed, lead to nitrogen 40-80min of deoxygenation, plus
Enter initiator and trigger polymerization at 14-16 DEG C, and molecular weight product is adjusted by molecular weight regulator, so as to properly be divided
The product of son amount, reaction takes out jelly after terminating, and by polymer prills and carries out drying and dries, pulverizes and sieves and produce the production
Product.
Wherein, the olefin sulfonic acid or AOS are 2- acrylamide-2-methyl propane sulfonics, vinyl sulfonic acid, alkene
One or more in propyl sulfonic acid, methylpropene sodium sulfonate.
During the cationic monomer is dimethyl diallyl ammonium chloride, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride
It is one or more.
The rigid unitary is the one or more in NVP or N- benzyl-3-pyrrolidones.
The dispersant is the one or more in empgen BB or lauroylamidopropyl betaine.
The molecular weight regulator is the one or more in isopropanol, sodium formate.
The initiation system for triggering polymerization is composite initiation system, including azo-initiator and Redox Initiator
Agent;The azo-initiator is the NSC 18620 dihydrochloride of azo two, ABVN, azodiisobutyronitrile and 4,4 '-idol
One or more in nitrogen pair, 4- cyanopentanoic acids;Redox initiator is benzoyl peroxide, isopropyl benzene hydroperoxide, mistake
Any two kinds in potassium sulfate, sodium formaldehyde sulfoxylate, ferrous sulfate, sodium hydrogensulfite.
The pH value is adjusted using sodium hydroxide and potassium hydroxide, and sodium hydroxide and potassium hydroxide addition are to rub
You compare 1:1.5.
The dry temperature of the drying is 60-90 DEG C;It is described to pulverize and sieve to cross 20-50 mesh sieves after crushing.
Embodiment 1:
Parts by weight of raw materials is:Acrylamide 280,2- acrylamide-2-methyl propane sulfonics 56, acrylic acid 28, the allyl of dimethyl two
Ammonium chloride 42, NVP 14, deionized water 546, sodium hydroxide 10.55, potassium hydroxide 22.14, dodecane
Base glycine betaine 1.5, azodiisobutyronitrile 0.3, potassium peroxydisulfate 0.012, sodium hydrogensulfite 0.008.
Specifically preparation process is:
(1)Acrylamide, 2- acrylamide-2-methyl propane sulfonics, acrylic acid, the allyl of dimethyl two are sequentially added in mixing kettle
After ammonium chloride, NVP and deionized water, fully dissolving, with sodium hydroxide or potassium hydroxide and acrylic acid
And 2- acrylamide-2-methyl propane sulfonics, and solution ph is adjusted, pH value is adjusted between 7.5-7.7,12 are added
Alkyl betaine, is sufficiently mixed;
(2)Logical nitrogen deoxygenation 60min, adds initiator and polymerize at 14 ~ 16 DEG C;
(3)Reaction takes out jelly after terminating, and blob of viscose is granulated, micelle is placed in baking oven and is dried in 70 DEG C;
(4)Dry micelle crushing is taken out after 2h and produces the product, molecular weight product is 4,160,000, and filtrate reducing effect is shown in Table 2.
Embodiment 2:
Parts by weight of raw materials is:Acrylamide 300,2- acrylamide-2-methyl propane sulfonics 60, acrylic acid 32, the allyl of dimethyl two
Ammonium chloride 45, N- benzyl-3-pyrrolidones 15, deionized water 511, sodium hydroxide 11.7, potassium hydroxide 24.66, dodecane
Base glycine betaine 1, azodiisobutyronitrile 0.5, potassium peroxydisulfate 0.02, sodium hydrogensulfite 0.01.
Specifically preparation process is:
(1)Acrylamide, 2- acrylamide-2-methyl propane sulfonics, acrylic acid, the allyl of dimethyl two are sequentially added in mixing kettle
After ammonium chloride, N- benzyl-3-pyrrolidones, fully deionized water, dissolving, with sodium hydroxide or potassium hydroxide and acrylic acid
And 2- acrylamide-2-methyl propane sulfonics, and solution ph is adjusted, pH value is adjusted between 7.5 ~ 7.7, dodecane is added
Base glycine betaine, is sufficiently mixed.
(2)Logical nitrogen deoxygenation 60min, adds initiator and polymerize at 14 ~ 16 DEG C;
(3)Reaction takes out jelly after terminating, and blob of viscose is granulated, micelle is placed in baking oven and is dried in 70 DEG C;
(4)Dry micelle crushing is taken out after 2h and produces the product, molecular weight product is 2,310,000, and filtrate reducing effect is shown in Table 2.
Embodiment 3:
Parts by weight of raw materials is:Acrylamide 330,2- acrylamide-2-methyl propane sulfonics 66, methylpropene sodium sulfonate 0.5, propylene
Acid 35, dimethyl diallyl ammonium chloride 49.5, NVP 16.5, deionized water 462, sodium hydroxide 12.87,
Potassium hydroxide 27.03, lauroylamidopropyl betaine 1.5, azodiisobutyronitrile 0.4, potassium peroxydisulfate 0.035, sodium hydrogensulfite
0.015。
Specifically preparation process is:
(1)Acrylamide, 2- acrylamide-2-methyl propane sulfonics, methylpropene sodium sulfonate, propylene are sequentially added in mixing kettle
After acid, dimethyl diallyl ammonium chloride, NVP, fully deionized water, dissolving, with sodium hydroxide or hydrogen-oxygen
Change in potassium and acrylic acid and 2- acrylamide-2-methyl propane sulfonics, and adjust solution ph, by pH value be adjusted to 7.5 ~ 7.7 it
Between, lauroylamidopropyl betaine is added, is sufficiently mixed.
(2)Logical nitrogen deoxygenation 60min, adds initiator and polymerize at 14 ~ 16 DEG C;
(3)Reaction takes out jelly after terminating, and blob of viscose is granulated, micelle is placed in baking oven and is dried in 70 DEG C;
(4)Dry micelle crushing is taken out after 2h and produces the product, molecular weight product is 670,000, and filtrate reducing effect is shown in Table 2.
Henchnmrk test is carried out with both sexes heat and salinity tolerance fluid loss additive to the drilling fluid that is prepared according to present example:
The evaluation method given according to SY/T 5660-95 evaluates performance of the fluid loss additive in compound salt-water basic slurry, is combined salt solution
The configuration of base slurry:The proportions of 45.0g sodium chloride, 5.0g anhydrous calcium chlorides and 13.0g magnesium chlorides are added by every liter of distilled water
Compound salt solution, makes after its dissolving, and adding 400mL in high-speed stirred cup is combined salt solution, 90.0g calcium bentonites and the anhydrous carbon of 5.4g
Sour sodium high-speed stirred 20min, at least stops twice, to scrape the clay of adhesion on the wall therebetween.Insulating box is put into, at 25 DEG C
24h is conserved at ± 3 DEG C.High-speed stirred 5min, its apparent viscosity, modeling are determined at 25 DEG C ± 3 DEG C by SY/T 5621 regulation again
Property viscosity and filter loss.Base slurry performance indications should meet the regulation requirement of table 1, otherwise can be by increasing and decreasing bentonite and Carbon Dioxide
The dosage of sodium, until reaching requirement.
The drilling fluid experimental performance index of table 1
Filter pressing loss is determined in compound salt-water basic slurry normal temperature:The compound salt-water basic slurry 400mL prepared is taken, is stirred on high speed agitator
10min is mixed, the fluid loss additive sample is added in compound salt-water basic slurry high-speed stirred by 2.8g simultaneously, it is dispersed in base slurry
In, insulating box is put into, 24h is conserved at 25 DEG C ± 3 DEG C.High-speed stirred 5min after taking-up, it is determined by SY/T 5621 regulation
Apparent viscosity, plastic viscosity and filter loss.
Middle filter pressing loss after 220 DEG C of heat rolling 16h of compound salt-water basic slurry is determined:The compound salt-water basic slurry 400mL prepared is taken,
10min is stirred on high speed agitator, the fluid loss additive sample is added in compound salt-water basic slurry high-speed stirred by 2.8g simultaneously, is made
It is dispersed in base slurry, and at 220 ± 3 DEG C after heat rolling 16h, high-speed stirred 5min determines its apparent viscosity, plastic viscosity
And filter loss.
The fluid loss additive of table 2 influences relation table to compound salt-water basic slurry rheology and filtration property
Project | Apparent viscosity mpas | Plastic viscosity mpas | Filter loss mL |
Compound salt-water basic slurry(25℃) | 4.7 | 2.5 | 57 |
Add the fluid loss agents of 0.7% example 1 in base slurry(25℃) | 33.5 | 19 | 6.1 |
Add the fluid loss agents of 0.7% example 1 in base slurry(220℃) | 29 | 17 | 9.8 |
Add the fluid loss agents of 0.7% example 2 in base slurry(25℃) | 31 | 18 | 6.7 |
Add the fluid loss agents of 0.7% example 2 in base slurry(220℃) | 27 | 15 | 8.9 |
Add the fluid loss agents of 0.7% example 3 in base slurry(25℃) | 26.5 | 16 | 7.8 |
Add the fluid loss agents of 0.7% example 3 in base slurry(220℃) | 23 | 14 | 8.4 |
Claims (9)
1. drilling fluid both sexes heat and salinity tolerance fluid loss additive and preparation method, it is characterised in that:The drilling fluid is anti-with both sexes temperature resistance
Salt fluid loss additive is made up of the raw material of following parts by weight:280-340 parts of acrylamide, olefin sulfonic acid or AOS 20-
70 parts, 20-55 parts of acrylic acid, 20-50 parts of cationic monomer, 8-20 parts of rigid unitary, 5-35 parts of sodium hydroxide, hydroxide
5-35 parts of potassium, 0.5-2 parts of dispersant, 420-640 parts of deionized water, 0.001-0.05 part of molecular weight regulator, initiator
0.001-0.5 part;Its preparation method is:Add in the reactor acrylamide, acrylic acid, olefin sulfonic acid or AOS,
After cationic monomer, rigid unitary and deionized water, fully dissolving, solution ph is adjusted with sodium hydroxide or potassium hydroxide, will
PH value is adjusted between 7.5-7.7, then adds dispersant, is transferred to after being sufficiently mixed in reactor, and logical nitrogen deoxygenation 40-
80min, adds initiator and triggers polymerization at 14-16 DEG C, and adjusts molecular weight product by molecular weight regulator, so that
To the product of suitable molecular weight, reaction takes out jelly after terminating, and by polymer prills and carries out drying and dries, pulverizes and sieves i.e.
Obtain the product.
2. drilling fluid according to claim 1 both sexes heat and salinity tolerance fluid loss additive and preparation method, it is characterised in that:Institute
It is 2- acrylamide-2-methyl propane sulfonics, vinyl sulfonic acid, allyl sulphonic acid, methyl-prop to state olefin sulfonic acid or AOS
One or more in alkene sodium sulfonate.
3. drilling fluid according to claim 1 both sexes heat and salinity tolerance fluid loss additive and preparation method, it is characterised in that:Institute
It is one kind or many in dimethyl diallyl ammonium chloride, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride to state cationic monomer
Kind.
4. drilling fluid according to claim 1 both sexes heat and salinity tolerance fluid loss additive and preparation method, it is characterised in that:Institute
It is the one or more in NVP or N- benzyl-3-pyrrolidones to state rigid unitary.
5. drilling fluid according to claim 1 both sexes heat and salinity tolerance fluid loss additive and preparation method, it is characterised in that:Institute
It is the one or more in empgen BB or lauroylamidopropyl betaine to state dispersant.
6. drilling fluid according to claim 1 both sexes heat and salinity tolerance fluid loss additive and preparation method, it is characterised in that:Institute
It is the one or more in isopropanol, sodium formate to state molecular weight regulator.
7. drilling fluid according to claim 1 both sexes heat and salinity tolerance fluid loss additive and preparation method, it is characterised in that:Institute
State and trigger the initiation system of polymerization for composite initiation system, including azo-initiator and redox initiator;The azo
Class initiator is that the NSC 18620 dihydrochloride of azo two, ABVN, azodiisobutyronitrile and 4,4 '-azo be double, 4- cyano group
One or more in valeric acid;Redox initiator be benzoyl peroxide, isopropyl benzene hydroperoxide, potassium peroxydisulfate, hang it is white
Any two kinds in block, ferrous sulfate, sodium hydrogensulfite.
8. drilling fluid according to claim 1 both sexes heat and salinity tolerance fluid loss additive and preparation method, it is characterised in that:Institute
Stating pH value is adjusted using sodium hydroxide and potassium hydroxide, and sodium hydroxide and potassium hydroxide addition are mol ratio 1:1.5.
9. drilling fluid according to claim 1 both sexes heat and salinity tolerance fluid loss additive and preparation method, it is characterised in that:Institute
It is 60-90 DEG C to state the dry temperature of drying;It is described to pulverize and sieve to cross 20-50 mesh sieves after crushing.
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