CN107032557A - A kind of method that modified clay aids in the high fouling Produced Water In Oil-gas Fields, Ngi of microbiological treatment - Google Patents
A kind of method that modified clay aids in the high fouling Produced Water In Oil-gas Fields, Ngi of microbiological treatment Download PDFInfo
- Publication number
- CN107032557A CN107032557A CN201710214238.8A CN201710214238A CN107032557A CN 107032557 A CN107032557 A CN 107032557A CN 201710214238 A CN201710214238 A CN 201710214238A CN 107032557 A CN107032557 A CN 107032557A
- Authority
- CN
- China
- Prior art keywords
- oil
- water
- high fouling
- modified clay
- ngi
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/288—Treatment of water, waste water, or sewage by sorption using composite sorbents, e.g. coated, impregnated, multi-layered
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5236—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
- C02F1/56—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/66—Treatment of water, waste water, or sewage by neutralisation; pH adjustment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/10—Nature of the water, waste water, sewage or sludge to be treated from quarries or from mining activities
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/02—Aerobic processes
- C02F3/12—Activated sludge processes
- C02F3/1205—Particular type of activated sludge processes
- C02F3/1226—Particular type of activated sludge processes comprising an absorbent material suspended in the mixed liquor
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
Abstract
The invention discloses a kind of method that modified clay aids in the high fouling Produced Water In Oil-gas Fields, Ngi of microbiological treatment, high fouling oil field extracted water and certain density modified clay are pre-mixed after certain time in mixing pit, the dirt class material such as calcium sulfate, calcium carbonate in high fouling recovered water is deposited on modified surface of clay under the suction-operated of modified surface of clay polysaccharose substance or protein；Thereafter the water outlet in mixing pit is imported in microbial reaction pond, carries out the processing of sewage to the degradation of Organic substance in water using microorganism；The water outlet of microbial reaction pond is by filtering, re-injection oil reservoir；This method has been effectively promoted dirt in modified clay particle surface deposition, and then dirt is reduced in antimicrobial surface deposition, it ensure that microbial method handles the stable operation of high fouling oil extraction-generated waste water technique, efficient degradation of the microorganism to oil extraction-generated waste water is promoted, is deposited for the removal and elimination dirt for solving high fouling oil extraction-generated waste water dirt in antimicrobial surface and is influenceed microbial method to handle high fouling oil recovery treatment efficiency and technical support and feasible program are provided.
Description
Technical field
The invention belongs to Produced Water In Oil-gas Fields, Ngi processing and reuse technology field, and in particular to a kind of modified clay aids in micro- life
The method of the high fouling Produced Water In Oil-gas Fields, Ngi of thing processing.
Background technology
At present, the Produced Liquid moisture content being had enter into China's oil-gas field development in waterflood stage, producing well is up to more
More than 80%, and oil field produces substantial amounts of water in need as injection water, the recovered water after processing is optimal injection water water source.
Generally, oil field extracted water salt content high (most of even as high as 290000mg/L between 20000-120000mg/L, having),
Ca2+And SO4 2-Ion concentration is high, often contains a certain amount of HCO in sewage in addition3 -、CO3 2-, therefore sewage fouling belongs to generally existing
As the even strong fouling water having.
Produced water treatment has at present：At Physical, chemical method, physical-chemical process, microorganism treatment etc., wherein microorganism
Reason technology has that the dirty Organic substance in water ability of mild condition, degraded is strong, the feature of stable effluent quality, and therefore, this method turns into
One of method of oil recovery treatment very advantageous.In microbiological treatment technology, obtain dominant degradation bacteria and improve its degraded
Performance is the key of the technology.By effort for many years, activated sludge process, biomembrance process and stabilization pond method etc. have been formd many
Processing method and technique are planted, wherein with activated sludge process using more.
Although biological method processing oil extraction-generated waste water is technically feasible, it is related to microbiological treatment oil extraction-generated waste water and also deposits
In many problems.Such as meeting fouling, sewage fouling meeting because of interionic reaction after the poor multilayer oil extraction-generated waste water mixing of compatibility
Microorganism and extraneous Exchange of material and energy are influenceed, and is suppressed the microorganism in biological treatment system, microorganism is caused
Sewage treatment process treatment effeciency, which declines, even paralyses.
Therefore, need to solve because the high fouling of oil extraction-generated waste water causes dirt in micro- life during microbiological treatment oil extraction-generated waste water
Thing surface deposit and cause micro-organism treatment process bad stability, or even paralysis deficiency the problems such as, in order to avoid influence microorganism
To the efficient degradation of dirty Organic substance in water.
The content of the invention
To solve problems of the prior art, the invention provides a kind of modified clay auxiliary microbiological treatment height knot
The method of dirty Produced Water In Oil-gas Fields, Ngi, modified clay stain eliminating technology link is added in microbiological treatment leading portion, can promote dirt in modification
Clay particle surface is deposited, and then reduces dirt in antimicrobial surface deposition, it is ensured that the high fouling oil extraction-generated waste water of microbial method processing
The stable operation of technique, promotes efficient degradation of the microorganism to oil extraction-generated waste water, this method is simple and easy to apply, and cost is relatively low, and two
Secondary pollution is few.
To achieve the above object, the invention discloses following technical scheme：A kind of modified clay auxiliary microbiological treatment is high
The method of fouling Produced Water In Oil-gas Fields, Ngi, this method comprises the following steps：
Step one：The high fouling recovered water of oil gas field that oily-water seperating equipment is isolated is pumped in mixing pit, by modification
Clay is added in mixing pit and is pre-mixed with high fouling recovered water, forms mixed liquor a；
Step 2：After mixed liquor a is sufficiently mixed, the dirty class material in high fouling recovered water is in modified clay surface modification
Under the suction-operated of thing polar groups, modified surface of clay is deposited on, mixed liquor b is formed；
Step 3：Mixed liquor b is imported in microbial reaction pond, the organic matter in mixed liquor b carried out using microorganism
Mixed liquor c is formed after degradation treatment；
Step 4：Mixed liquor c is filtered, water after filter reinjection into reservoir, continuation is used as oilfield injection water.
Being added in step one also into mixing pit has pH value regulator, flocculant and flocculation aid；PH value regulator is used to adjust
Mixed liquor a pH value is saved 6~8；PH value regulator is sodium hydroxide or sodium hydroxide and calcium oxide according to mass ratio 2:1 system
Standby compound, flocculant is PAC, and flocculation aid is PAM.
The amount of scale buildup being used in rate-determining steps two in every liter of mixed liquor b of the modification clay added in step one is not higher than
50mg。
Modification clay particle fineness in the step one is higher than 100 mesh, and water content is less than 5%, in the high fouling extraction of 1L
50mg~100mg is added in water and is modified clay.
Mixed liquor a incorporation time is at least 20min in the step 2.
Microbial reaction pond in the step 3 is aerobic reaction tank.
Filter in the step 4 uses film filter, or quartz filter blooming filter, or quartz sand mistake
Filter adds walnut shell filter plus modified fiber ball filter.
Modification clay in the step one is the montmorillonite after the concentrated sulfuric acid acidification of mass concentration 10%, dry
It is dry, be crushed to more than 100 mesh after, mixed at room temperature to adsorption saturation with polysaccharose substance or protein solution, through filtering,
Dry, crush obtained.
The polysaccharose substance is for chitosan and containing hydroxyl or amino polysaccharide derivates, and the protein is glycoprotein
And containing hydroxyl or amino protein derivatives, the polysaccharose substance or protein are with intercalation and adsorption two ways
It is supported on montmorillonite surface.
The load capacity of the polysaccharose substance or protein on montmorillonite surface is：1g montmorillonite area loads 50mg~
247mg polysaccharose substances or protein.
Compared with prior art, the present invention at least has the advantages that：
The present invention is carrying out degradation treatment using microorganism to oil gas field oil-containing extraction Organic substance in water, and processing is thorough, into
This is low, on the basis of the advantages of secondary pollution is few, adds modified clay stain eliminating technology link in microbiological treatment leading portion, can promote
Dirt is deposited in modified clay particle surface, and then, it is ensured that the reduction dirt of the high fouling oil extraction-generated waste water technique of microbial method processing exists
Antimicrobial surface deposits stable operation, promotes efficient degradation of the microorganism to oil extraction-generated waste water, and then avoid because dirt is micro-
Biological surface deposition causes microbial degradation speed to decline, or even situations such as paralysis, handling process is simple and easy to apply, and cost is relatively low,
And secondary pollution is few.
Polysaccharide and protein-modified adsorption by clay descalling technique and the high fouling oil recovery treatment technique phase of microbiological treatment
With reference to invention deposited in antimicrobial surface for solving the removal of high fouling oil extraction-generated waste water dirt and eliminating dirt and influence micro- life
The high fouling oil recovery treatment efficiency of thing method processing provides technical support and feasible program, and polysaccharose substance and protein conduct
Sorbent-loaded is in montmorillonite surface and intercalation so that the structure of the modification clay is more stablized, to the dirt in oil extraction-generated waste water
With quick, thoroughly adsorption effect, so as to optimize stain eliminating technology link to a certain extent, improve whole processing technology and enter
Journey.
Microbial reaction pond uses aerobic reaction tank, provides good aerobic environment for the degradation process of microorganism, can have
Degradation efficiency of the effect promotion microorganism to organic matter in oil extraction-generated waste water.
The present invention, for adsorbing the suspension in recovered water, forms settling of floccus also by adding flocculant and flocculation aid
In bottom, the suspension in recovered water is removed in advance, and make to be modified absorption of the clay to dirt is not influenceed by Suspended Matter in Water, and
Mixed liquor is adjusted to neutral environment by adding pH adjusting agent, is beneficial to the absorption of structure in mixed liquor；Moreover, in neutral ring
Under border, microorganism is more obvious to the degradation effect of organic harmful substance in recovered water.
The Produced Water In Oil-gas Fields, Ngi after modified adsorption by clay and microbiological treatment is filtered in the present invention, filter is adopted
With film filter, either quartz filter+film filter or quartz filter+walnut shell filter+modified fiber ball
Filter, these three filters can be achieved to produce thorough, the quick high efficiency filter effect of sewage, further optimization after processing
Handling process, being later stage supernatant as reinjected water injection stratum, there is provided good aquatic environment.
Brief description of the drawings
Fig. 1 handles the technological process of the high fouling oil extraction-generated waste water of oil gas field for the present invention.
Embodiment
The present invention will be further described with specific embodiment below in conjunction with the accompanying drawings.
In the present invention, the general principle of the modified clay auxiliary high fouling Produced Water In Oil-gas Fields, Ngi of microbiological treatment is：By changing
Property clay in be supported on being tied containing hydroxyl, the polysaccharide of amino polar group or protein and its derivative to height in montmorillonite
Under the dirt class material suction-operated such as calcium sulfate, calcium carbonate in dirty recovered water, it is set to be deposited on modified surface of clay, and then reduce
Dirt promotes efficient degradation of the microorganism to oil extraction-generated waste water, it is to avoid because dirt is in antimicrobial surface in antimicrobial surface deposition
Deposition causes microbial degradation speed to decline, or even situations such as paralysis, handling process is simple and easy to apply, and cost is relatively low, and secondary dirt
Dye is few.
As shown in figure 1, the invention discloses a kind of modified clay auxiliary high fouling Produced Water In Oil-gas Fields, Ngi of microbiological treatment
Method, this method includes following steps：
1) modified clay is added：The high fouling recovered water of oil gas field isolated from oily-water seperating equipment is pumped to mixing pit
In, a certain amount of modified clay is added in mixing pit and is pre-mixed with high fouling recovered water, mixed liquor a is formed；It is modified viscous
The addition of soil is not higher than 50mg as standard using the amount of scale buildup in every liter of mixed liquor in controlling；
2) mixed precipitation is pre-processed：After mixed liquor a is sufficiently mixed (incorporation time is at least 20min), high fouling extraction
The dirt class material such as calcium sulfate, calcium carbonate in water is under the suction-operated of modified clay surface modification thing polar groups, deposition
In modified surface of clay, mixed liquor b is formed；
3) the mixed liquor b in mixing pit is imported in microbial reaction pond, the degraded using microorganism to Organic substance in water
Effect carries out the processing of sewage, the preferred aerobic reaction tank in microbial reaction pond formed in mixed liquor c, this step；
4) the mixed liquor c in step 3 after microbiological treatment is filtered, water after filter reinjection into reservoir, continues to make
Used for oilfield injection water；Filter in this step uses film filter, or quartz filter blooming filter, or quartz
Sand filter adds walnut shell filter plus modified fiber ball filter.
The modification clay particle fineness used in the processing procedure of the present invention is higher than 100 mesh, and water content is less than 5%, prepares
Method is montmorillonite after the concentrated sulfuric acid acidification of mass concentration 10%, after drying, being crushed to more than 100 mesh, and many
Glucide or protein solution are mixed to adsorption saturation at room temperature, are made through filtering, dry, crushing；It is preferred that, polysaccharide
Class material is for chitosan and containing hydroxyl or amino polysaccharide derivates, and protein is glycoprotein and contains hydroxyl or amino egg
White matter derivative, polysaccharose substance or protein are supported on montmorillonite surface, and polysaccharide with intercalation and adsorption two ways
The load capacity of class material or protein on montmorillonite surface is：1g montmorillonites area load 50mg~247mg polysaccharose substances or
Protein.
It is exemplified below three and the high fouling oil extraction-generated waste water from different oil extraction in oil field factories is handled using processing method of the present invention
Embodiment.
Embodiment 1：
It is water -- natural oil removing -- to extend the multi-purpose station oil-containing sewage treatment technique flow of oil field Wuqi County oil recovery factory's stone million
Air supporting -- biochemistry pool -- filtering -- water outlet, biochemistry pool import sewage amount of scale buildup is 180-260mg/L, and oil content is 10-15mg/L,
Suspension content is 5-10mg/L, during normal operation, and biochemistry pool outlet amount of scale buildup is 30-50mg/L, and oil content is≤1mg/L,
Suspension content 5-10mg/L, after filtering water outlet reaches reinjected water water quality requirement.But, three months run times, dirt is in life
Changing pond microbe granular surface deposition causes microbe treatment system to collapse, and the fouling of filtration system filtrate is serious, and dirty type is with carbon
Based on sour calcium.After measured, biochemistry pool outlet amount of scale buildup is 60-100mg/L, and oil content is 15-25mg/L, suspension content 12-
20mg/L。
Modified clay+mixed precipitation pretreatment is added before flotation tank, pre-treatment medicaments are chitin modified clay, pH value
Conditioning agent (sodium hydroxide), flocculant (PAC), flocculation aid (PAM), chemical feeding quantity is respectively 50mg/L, 80mg/L, 40mg/L,
0.5mg/L, medicine-adding order is followed successively by chitin modified clay, pH value regulator (sodium hydroxide), flocculant (PAC), flocculation aid
(PAM), biochemistry pool import amount of scale buildup is changed into 15-25mg/L after pretreatment, and biochemistry pool antimicrobial surface does not find scale forming matter, mistake
Filter surface does not also find scale forming matter, and 1 year, the operation of sewage disposal system was stable.
Embodiment 2：
Extend the series of strata recovered water of oil field apricot river length 2, calcium ion content isSulfate ion content Growing 6 series of strata recovered water calcium ion contents isSulfate ion contentLong 2 series of strata recovered waters are mixed with long 6 series of strata recovered waters by 9 ︰ 1, and 72h amount of scale buildups are 4478.25mg/L.Using
Pseudomonad handles the mixed sample, crude oil addition 4%, strain addition 2%, mixing speed 200r/min, 37 DEG C of temperature,
PH value is 7.5, degradation time 7 days, because dirt is in the coalescence of pseudomonad surface, deposition, cause pseudomonad and external substance with
Energy exchange approach is obstructed, and oil degradation rate is by blank (simulation water：Change calcium ion in long by 2, long 6 layers of water into content of the same race
Sodium ion, remaining ion concentration is constant) 53.45% drop to 17.52%.Mix fouling water to pre-process by modified clay, in advance
Treatment agent is respectively chitin modified clay, pH value regulator (sodium hydroxide), flocculant (PAC), flocculation aid (PAM), plus
Dose is respectively 100mg/L, 30mg/L, 50mg/L, 1mg/L, and medicine-adding order is followed successively by chitin modified clay, pH value regulator
(sodium hydroxide), flocculant (PAC), flocculation aid (PAM), mixing water 72h amount of scale buildups are 45mg/L after pretreatment, using false unit cell
Bacterium handles the mixed sample, under equal conditions, and oil degradation rate is 60.78%.
Case 3：
Extending the series of strata recovered water calcium ion content of oil field apricot river length 2 isSulfate ion content Growing 6 series of strata recovered water calcium ion contents isSulfate ion contentLong 2 series of strata recovered waters are mixed with long 6 series of strata recovered waters in the ratios of 9 ︰, 1 to 1 ︰ 9, and 72h amount of scale buildups are 275mg/L
To between 4478.25mg/L.The mixed sample, crude oil addition 4%, strain addition 2%, stirring speed are handled with pseudomonad
Spend 200r/min, 37 DEG C of temperature, pH value is 7.5, degradation time 7 days, oil degradation rate be 15.75 to 22.86 between.It is not year-on-year
Example mixing fouling water is by modified clay pretreatment, and pre-treatment medicaments are respectively chitin modified clay, pH value regulator (hydrogen-oxygen
Change sodium with calcium oxide according to mass ratio 2:1 compound prepared), flocculant (PAC), flocculation aid (PAM), chemical feeding quantity is respectively
80mg/L, 30mg/L, 50mg/L, 1mg/L, medicine-adding order be followed successively by chitin modified clay, pH value regulator (sodium hydroxide),
Flocculant (PAC), flocculation aid (PAM), mixing water 72h amount of scale buildups are 30mg/L after pretreatment, and handling this using pseudomonad mixes
Heshui sample, under equal conditions, oil degradation rate are 67.34%.
Find out from embodiment, the addition of modified clay causes the amount of scale buildup in biochemistry pool substantially to reduce, to a certain extent
Dirt is prevented in the deposition of antimicrobial surface, and then promotes degradation rate of the microorganism to recovered water Crude Oil, degradation rate from
20% or so brings up to nearly 70%, and effect is obvious.
Claims (10)
1. a kind of method that modified clay aids in the high fouling Produced Water In Oil-gas Fields, Ngi of microbiological treatment, it is characterised in that this method bag
Include following steps：
Step one：The high fouling recovered water of oil gas field that oily-water seperating equipment is isolated is pumped in mixing pit, by modified clay
It is pre-mixed added in mixing pit with high fouling recovered water, forms mixed liquor a；
Step 2：After mixed liquor a is sufficiently mixed, the dirty class material in high fouling recovered water is in modified clay surface modification thing
Under the suction-operated of polar group, modified surface of clay is deposited on, mixed liquor b is formed；
Step 3：Mixed liquor b is imported in microbial reaction pond, the organic matter in mixed liquor b degraded using microorganism
Mixed liquor c is formed after processing；
Step 4：Mixed liquor c is filtered, water after filter reinjection into reservoir, continuation is used as oilfield injection water.
2. the method that a kind of modified clay according to claim 1 aids in the high fouling Produced Water In Oil-gas Fields, Ngi of microbiological treatment,
Characterized in that, being added in step one also into mixing pit has pH value regulator, flocculant and flocculation aid；PH value regulator is used for
Mixed liquor a pH value is adjusted 6~8；PH value regulator is sodium hydroxide or sodium hydroxide and calcium oxide according to mass ratio 2:1
The compound of preparation, flocculant is PAC, and flocculation aid is PAM.
3. the method that a kind of modified clay according to claim 1 aids in the high fouling Produced Water In Oil-gas Fields, Ngi of microbiological treatment,
Characterized in that, the amount of scale buildup being used in rate-determining steps two in every liter of mixed liquor b of the modification clay added in step one is not high
In 50mg.
4. the method that a kind of modified clay according to claim 1 aids in the high fouling Produced Water In Oil-gas Fields, Ngi of microbiological treatment,
Characterized in that, the modification clay particle fineness in the step one is higher than 100 mesh, water content is less than 5%, adopted in the high foulings of 1L
50mg~100mg is added in water outlet and is modified clay.
5. the method that a kind of modified clay according to claim 1 aids in the high fouling Produced Water In Oil-gas Fields, Ngi of microbiological treatment,
Characterized in that, mixed liquor a incorporation time is at least 20min in the step 2.
6. the method that a kind of modified clay according to claim 1 aids in the high fouling Produced Water In Oil-gas Fields, Ngi of microbiological treatment,
Characterized in that, the microbial reaction pond in the step 3 is aerobic reaction tank.
7. the method that a kind of modified clay according to claim 1 aids in the high fouling Produced Water In Oil-gas Fields, Ngi of microbiological treatment,
Characterized in that, the filter in the step 4 uses film filter, or quartz filter blooming filter, or quartz sand
Filter adds walnut shell filter plus modified fiber ball filter.
8. the method that a kind of modified clay according to claim 1 aids in the high fouling Produced Water In Oil-gas Fields, Ngi of microbiological treatment,
Characterized in that, the modification clay in the step one is the montmorillonite after the concentrated sulfuric acid acidification of mass concentration 10%,
After drying, being crushed to more than 100 mesh, mix to adsorption saturation, pass through at room temperature with polysaccharose substance or protein solution
Filtering, dry, crushing are made.
9. the method that a kind of modified clay according to claim 8 aids in the high fouling Produced Water In Oil-gas Fields, Ngi of microbiological treatment,
Characterized in that, the polysaccharose substance is for chitosan and containing hydroxyl or amino polysaccharide derivates, the protein is sugar
Albumen and containing hydroxyl or amino protein derivatives, the polysaccharose substance or protein are with two kinds of intercalation and adsorption
Mode is supported on montmorillonite surface.
10. the method that a kind of modified clay according to claim 9 aids in the high fouling Produced Water In Oil-gas Fields, Ngi of microbiological treatment,
Characterized in that, the load capacity of the polysaccharose substance or protein on montmorillonite surface is：1g montmorillonite area loads 50mg
~247mg polysaccharose substances or protein.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710214238.8A CN107032557A (en) | 2017-04-01 | 2017-04-01 | A kind of method that modified clay aids in the high fouling Produced Water In Oil-gas Fields, Ngi of microbiological treatment |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710214238.8A CN107032557A (en) | 2017-04-01 | 2017-04-01 | A kind of method that modified clay aids in the high fouling Produced Water In Oil-gas Fields, Ngi of microbiological treatment |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107032557A true CN107032557A (en) | 2017-08-11 |
Family
ID=59533992
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710214238.8A Pending CN107032557A (en) | 2017-04-01 | 2017-04-01 | A kind of method that modified clay aids in the high fouling Produced Water In Oil-gas Fields, Ngi of microbiological treatment |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107032557A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110127900A (en) * | 2019-05-29 | 2019-08-16 | 西安长庆科技工程有限责任公司 | A kind of oil field produced water treatment facilities of premix fouling and method |
| CN115010276A (en) * | 2021-03-05 | 2022-09-06 | 中国石油化工股份有限公司 | Anti-scaling method for oilfield produced water |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2174246A (en) * | 1937-05-26 | 1939-09-26 | Standard Oil Dev Co | Method for producing wax modifying agents |
| JPS5277446A (en) * | 1975-12-24 | 1977-06-29 | Nippon Chemical Ind | Method of treating chromium hydroxide contained sludge |
| CN101613136A (en) * | 2008-06-02 | 2009-12-30 | 世界矿物公司 | Be used to prevent and reduce the method that fouling forms |
| CN102992524A (en) * | 2012-04-23 | 2013-03-27 | 北京矿冶研究总院 | Treatment method of fracturing flow-back fluid |
| CN203256067U (en) * | 2013-04-23 | 2013-10-30 | 北京中联动力技术有限责任公司 | Automatic-control oil-field wastewater treatment system |
| CN103601348A (en) * | 2013-12-10 | 2014-02-26 | 达州军华油田工程服务有限公司 | Advanced treatment process for gas field produced water |
| CN103819032A (en) * | 2014-03-24 | 2014-05-28 | 潍坊力德电器有限公司 | Advanced treatment recovery device for oily sewage |
| CN203845899U (en) * | 2014-03-24 | 2014-09-24 | 潍坊力德电器有限公司 | Oily sewage advanced treatment recycling device |
| CN104108822A (en) * | 2014-06-25 | 2014-10-22 | 苏州帝瀚环保科技有限公司 | Waste emulsified oil low-temperature separation system |
-
2017
- 2017-04-01 CN CN201710214238.8A patent/CN107032557A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2174246A (en) * | 1937-05-26 | 1939-09-26 | Standard Oil Dev Co | Method for producing wax modifying agents |
| JPS5277446A (en) * | 1975-12-24 | 1977-06-29 | Nippon Chemical Ind | Method of treating chromium hydroxide contained sludge |
| CN101613136A (en) * | 2008-06-02 | 2009-12-30 | 世界矿物公司 | Be used to prevent and reduce the method that fouling forms |
| CN102992524A (en) * | 2012-04-23 | 2013-03-27 | 北京矿冶研究总院 | Treatment method of fracturing flow-back fluid |
| CN203256067U (en) * | 2013-04-23 | 2013-10-30 | 北京中联动力技术有限责任公司 | Automatic-control oil-field wastewater treatment system |
| CN103601348A (en) * | 2013-12-10 | 2014-02-26 | 达州军华油田工程服务有限公司 | Advanced treatment process for gas field produced water |
| CN103819032A (en) * | 2014-03-24 | 2014-05-28 | 潍坊力德电器有限公司 | Advanced treatment recovery device for oily sewage |
| CN203845899U (en) * | 2014-03-24 | 2014-09-24 | 潍坊力德电器有限公司 | Oily sewage advanced treatment recycling device |
| CN104108822A (en) * | 2014-06-25 | 2014-10-22 | 苏州帝瀚环保科技有限公司 | Waste emulsified oil low-temperature separation system |
Non-Patent Citations (1)
| Title |
|---|
| 张蕾: "硫酸钙在改性粘土颗粒表面的沉积性质研究", 《中国学位论文全文数据库》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110127900A (en) * | 2019-05-29 | 2019-08-16 | 西安长庆科技工程有限责任公司 | A kind of oil field produced water treatment facilities of premix fouling and method |
| CN110127900B (en) * | 2019-05-29 | 2024-03-19 | 西安长庆科技工程有限责任公司 | Device and method for treating produced water of premixed scaling oil field |
| CN115010276A (en) * | 2021-03-05 | 2022-09-06 | 中国石油化工股份有限公司 | Anti-scaling method for oilfield produced water |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US7384573B2 (en) | Compositions for wastewater treatment | |
| CN106277589A (en) | A kind of system and method utilizing ferrum carbon Fenton pretreatment UBF A/O to process waste water from dyestuff | |
| CN105254012B (en) | A kind of method of rapidly cultivating aerobic particle sludge | |
| CN107352752A (en) | The method for improving the removal of sludge in activated sludge waste water treatment process and keeping discharge quality | |
| CN208471815U (en) | A kind of high-concentration sewage treatment system of AO technique and Fenton system support | |
| CN106348523A (en) | Method for treating waste water from food industry | |
| CN102876574B (en) | Method for preparing oil-removing microbial inoculum and method for treating oil field sewage by using oil-removing microbial inoculum | |
| CN104649519A (en) | Sewage treatment device and method by combining bio-ferric process and anaerobic MBR method | |
| CN106673255A (en) | Wastewater treatment method and wastewater treatment device | |
| CN106277597A (en) | The processing method of the higher fatty acid waste water of food industry | |
| CN106277614B (en) | A kind of processing method of reuse condensed oil sewage | |
| CN105668890A (en) | Treatment method of refractory organic wastewater | |
| CN107032557A (en) | A kind of method that modified clay aids in the high fouling Produced Water In Oil-gas Fields, Ngi of microbiological treatment | |
| CN103739172B (en) | Water circulating and reusing method for industrial parks | |
| CN104649515A (en) | Treatment process method and device for high-salinity and high-ammonia-nitrogen rare-earth production wastewater | |
| CN107540161A (en) | High pure and ultra-fine modified calcium carbonate produces the processing method and processing system of waste water | |
| CN108726773A (en) | A kind of chemical wastewater treatment technique | |
| CN102229458A (en) | Emulsion-containing waste water treatment method in automobile industry | |
| CN101671091B (en) | Processing method for produced water for ultra-low permeable oil field reinjection | |
| CN107512830A (en) | A kind of cigar mill's process for comprehensively treating sewage | |
| CN204417290U (en) | A kind of high salinity height ammonia nitrogen Rare Earth Production wastewater treatment equipment | |
| CN108069570B (en) | Method for removing carbon, nitrogen and phosphorus in aquaculture wastewater | |
| CN108409025A (en) | A kind of ternary composite driving oil field recovered water materialization-biochemistry combined treatment process | |
| CN104386880B (en) | A kind of processing method of soybean protein sewage | |
| CN208617524U (en) | Modified refuse transfer station percolate and membranous system concentrate deep purifying device |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |