CN107030264B - A kind of super austenitic stainless steel double roll strip casting rolling production process - Google Patents

A kind of super austenitic stainless steel double roll strip casting rolling production process Download PDF

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Publication number
CN107030264B
CN107030264B CN201710288311.6A CN201710288311A CN107030264B CN 107030264 B CN107030264 B CN 107030264B CN 201710288311 A CN201710288311 A CN 201710288311A CN 107030264 B CN107030264 B CN 107030264B
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strip
rolling
austenitic stainless
stainless steel
molten steel
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CN107030264A (en
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刘国平
杨作宏
宋治屏
陈兴润
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Jiuquan Iron and Steel Group Co Ltd
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Jiuquan Iron and Steel Group Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/001Continuous casting of metals, i.e. casting in indefinite lengths of specific alloys
    • B22D11/002Stainless steels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/46Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling metal immediately subsequent to continuous casting
    • B21B1/463Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling metal immediately subsequent to continuous casting in a continuous process, i.e. the cast not being cut before rolling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B3/00Rolling materials of special alloys so far as the composition of the alloy requires or permits special rolling methods or sequences ; Rolling of aluminium, copper, zinc or other non-ferrous metals
    • B21B3/02Rolling special iron alloys, e.g. stainless steel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/06Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars
    • B22D11/0622Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars formed by two casting wheels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/06Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars
    • B22D11/0637Accessories therefor
    • B22D11/0697Accessories therefor for casting in a protected atmosphere

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Continuous Casting (AREA)

Abstract

The present invention relates to a kind of super austenitic stainless steel double roll strip casting rolling production process, include the following steps: that the molten steel of (1) ingredient qualification is hoisted to bale panoramic tables;(2) molten steel is injected into tundish;(3) double-roller rolling;(4) made-up belt hot rolling;(5) strip cooling and excision end to end;(6) strip coiling.The present invention directly produces super austenitic stainless steel strip by double-roller rolling, simplifies hot-rolled process, the crack of surface layer and delamination splitting of super austenitic stainless steel when avoiding prior art hot rolling.It is combined by double-roller rolling and hot rolling, realizes the production of 1.0-3.5mm thin gauge, qualified raw material is provided for subsequent cold-rolling process, reduce energy consumption while shortening production procedure.

Description

A kind of super austenitic stainless steel double roll strip casting rolling production process
Technical field
The invention belongs to thin-belt casting rolling production metallurgy field of engineering technology, and in particular to a kind of super austenitic stainless steel is double Roll strip casting rolling production process.
Background technique
The metallographic structure of super austenitic stainless steel is the fully austenitic structure with face-centred cubic structure, is a kind of low-carbon High-alloy steel, since the addition of the alloying elements such as Gao Ge, molybdenum, nickel, copper has this kind of steel, intensity is high, hardness is big, impact flexibility Well, the strong and excellent corrosion resistance of good welding performance, high temperature creep-resisting ability.The particularization of super austenitic stainless steel Study point, tissue and performance are widely used this kind of steel in every field, especially in many harsh work condition environments In, such as paper pulp and paper-making industry, pharmaceuticals industry, chemical fertilizer industry and sea field.But due to the conjunction of super austenitic stainless steel Golden component content is higher, especially Mo, Cr, makes to be easy carbide precipitate, chromium nitride and some intermetallics in stainless steel Object, as σ phase, chi phase, Laves are equal.Especially when the use of temperature being 600~1000 DEG C, the second phase is easier from stainless It is precipitated in steel.If amount of precipitation reaches certain value, these interphases can reduce the mechanical property and corrosion resistance of material, thus Influence the service performance of material.
During prior art produces super austenitic stainless steel, since the high alloy content of super austenitic stainless steel causes Make such steel manufacturing process require become very high, increase production difficulty, be prone in the hot rolling delamination splitting and Crack of surface layer etc., this is greatly lowered product quality and lumber recovery.Further, since super austenitic stainless steel intensity is high, heat 5mm or more think gauge can only be produced by rolling, and seriously affect the popularization and application of super austenitic stainless steel.
Summary of the invention
The technical problem to be solved by the present invention is to provide a kind of super Ovshinsky aiming at the problems existing in the prior art Body stainless steel double roll strip casting rolling production process.
Technical problem to solve of the invention adopts the following technical scheme that
A kind of super austenitic stainless steel double roll strip casting rolling production process, the specific steps are as follows:
(1) molten steel of ingredient qualification is hoisted to bale panoramic tables: not by the super austenitic after the refining of LF ladle refining furnace Rust steel molten steel is hoisted to bale panoramic tables, calm 15-25min;
(2) molten steel is injected into tundish: tundish blowing argon gas 10-20min, which drives out of, passes through long nozzle for steel after air in packet Water is injected into tundish from ladle, and degree of superheat control is added on 20 DEG C -40 DEG C, molten steel to be mingled with for keeping the temperature and adsorbing Tundish covering flux;;
(3) double-roller rolling: molten steel is injected in twin-roll cast-rolling mill by submersed nozzle, and slab speed is 80-120 m/ Min, casting roller gap is adjustable between 1.5-4.5mm, and the gaseous mixture of argon gas or argon gas and hydrogen is used during MOLTEN STEEL FLOW Body is protected, and for molten steel in Casting Roller in process of setting, cooling rate control range is 300-700 DEG C/s;
(4) made-up belt hot rolling: roll casting sheet protects gas in the mixed gas protected lower carry out hot rolling of argon gas or argon gas and hydrogen Body pressure 0.3-0.5MPa, made-up belt are sent to hot-rolling mill through pinch roller and carry out constant-tension rolling, and mill speed range is 100-150 M/min, wherein the control of made-up belt hot-rolled temperature is 1050-1200 DEG C, and steel strip thickness control range is 1.2- after made-up belt hot rolling 3.6mm;
(5) strip cooling and excision end to end
Strip after hot rolling is cooling, is sent to cutter through pinch roller and carries out the excision of strip end to end;
(6) strip coiling
Strip after excision end to end is sent to coiling machine through pinch roller and carries out strip coiling, obtains finished product thin strip steel coil.
Protective gas pressure is 0.3-0.5MPa in the step (3).
The volume ratio of argon gas and hydrogen is 3: 1 in the step (3).
Protective gas pressure is 0.3-0.5MPa in the step (4).
The volume ratio of argon gas and hydrogen is 3: 1 in the step (4).
Strip in the step (5) after hot rolling is cooled to 600-650 DEG C through cooling facility for laminar flow.
Double-roll type thin-belt casting rolling technology is metallurgical cutting edge technology, has realized industrial application in carbon steel production.We are according to double It the characteristics of roll-type thin-belt casting rolling technique, is introduced into the production of super purified austenitic stainless steel, by reasonable matching thickness, pours The key process parameters such as temperature, teeming speed, cooling rate are cast, the qualified super austenitic stainless steel of high quality, low cost is realized The production of product.The invention has the benefit that (1) directly produces super austenitic stainless steel strip by double-roller rolling, Simplify hot-rolled process, the crack of surface layer and delamination splitting of super austenitic stainless steel when avoiding prior art hot rolling.(2) by double Roller casting and hot rolling combine, and realize the production of 1.2-3.6mm thin gauge, and qualified raw material is provided for subsequent cold-rolling process, Energy consumption is reduced while shortening production procedure.(3) casting and course of hot rolling whole process are using the mixed of argon gas or argon gas and hydrogen Gas shield is closed, Molten Steel Cleanliness is high, and scale on surface is thin, is conducive to improve product surface quality and subsequent pickling cost Reduction, the raising of production efficiency.
Detailed description of the invention
Fig. 1 is super austenitic stainless steel thin-belt casting rolling production procedure schematic diagram of the present invention.
Specific embodiment
In conjunction with specific embodiments, the present invention is described in further detail, but embodiments of the present invention are not limited to This.
Embodiment 1
A kind of thickness 1.2mm, steel grade 904L super austenitic stainless steel double roll strip casting rolling production process include following step It is rapid:
(1) molten steel of ingredient qualification is hoisted to bale panoramic tables: not by the super austenitic after the refining of LF ladle refining furnace Rust steel molten steel is hoisted to bale panoramic tables, calm 20min;
(2) molten steel is injected into tundish: tundish blowing argon gas 15min drive out of in packet after air by long nozzle by molten steel from Ladle is injected into tundish, and the degree of superheat is controlled at 30 DEG C, is added above molten steel for keeping the temperature and adsorbing the intermediate cladding being mingled with Lid agent;
(3) double-roller rolling: molten steel is injected into twin-roll cast-rolling mill by submersed nozzle, and slab speed is 120m/min, It is 1.5mm that Casting Roller, which presets roll gap, uses argon gas to be protected during MOLTEN STEEL FLOW, protective gas pressure 0.5Mpa, casting The made-up belt obtained afterwards is with a thickness of 1.5mm.For molten steel in Casting Roller in process of setting, cooling rate control range is 700 DEG C/s;
(4) made-up belt hot rolling: roll casting sheet carries out hot rolling under protection of argon gas, and protective gas pressure 0.5Mpa, made-up belt is through pressing from both sides Send roller be sent to hot-rolling mill carry out constant-tension rolling, 150 m/min of mill speed, 1200 DEG C of made-up belt hot-rolled temperature, after made-up belt hot rolling Steel strip thickness is 1.2mm;
(5) strip cooling and excision end to end
When the strip that temperature is 950 DEG C after hot rolling is cooled to 650 DEG C through cooling facility for laminar flow, then shearing is sent to through pinch roller Machine carries out the excision of strip end to end;
(6) strip coiling
Strip after excision end to end is sent to coiling machine through pinch roller and carries out strip coiling, obtains finished product thin strip steel coil.
Embodiment 2
A kind of thickness 1.8mm, steel grade 904L super austenitic stainless steel double roll strip casting rolling production process include following step It is rapid:
(1) molten steel of ingredient qualification is hoisted to bale panoramic tables: not by the super austenitic after the refining of LF ladle refining furnace Rust steel molten steel is hoisted to bale panoramic tables, calm 20min;
(2) molten steel is injected into tundish: tundish blowing argon gas 15min drive out of in packet after air by long nozzle by molten steel from Ladle is injected into tundish, and the degree of superheat is controlled at 30 DEG C, is added above molten steel for keeping the temperature and adsorbing the intermediate cladding being mingled with Lid agent;
(3) double-roller rolling: molten steel is injected into twin-roll cast-rolling mill by submersed nozzle, and slab speed is 100m/min, It is 2.5mm that Casting Roller, which presets roll gap, uses the mixed gas of argon gas and hydrogen to be protected during MOLTEN STEEL FLOW, wherein argon gas Volume ratio with hydrogen is 3: 1, and protective gas pressure 0.3MPa, the made-up belt obtained after casting is with a thickness of 2.5mm, and molten steel is in casting In roller in process of setting, cooling rate control range is 500 DEG C/s;
(4) made-up belt hot rolling: roll casting sheet is in the mixed gas protected lower carry out hot rolling of argon gas and hydrogen, wherein argon gas and hydrogen The volume ratio of gas is 3: 1, protective gas pressure 0.3MPa.Made-up belt is sent to hot-rolling mill through pinch roller and carries out constant-tension rolling, rolling 139 m/min of speed, 1100 DEG C of made-up belt hot-rolled temperature, steel strip thickness is 1.8mm after made-up belt hot rolling;
(5) strip cooling and excision end to end
When the strip that temperature is 910 DEG C after hot rolling is cooled to 620 DEG C through cooling facility for laminar flow, then shearing is sent to through pinch roller Machine carries out the excision of strip end to end;
(6) strip coiling
Strip after excision end to end is sent to coiling machine through pinch roller and carries out strip coiling, obtains finished product thin strip steel coil.
Embodiment 3
A kind of thickness 3.6mm, steel grade 904L super austenitic stainless steel double roll strip casting rolling production process include following step It is rapid:
(1) molten steel of ingredient qualification is hoisted to bale panoramic tables: not by the super austenitic after the refining of LF ladle refining furnace Rust steel molten steel is hoisted to bale panoramic tables, calm 20min;
(2) molten steel is injected into tundish: tundish blowing argon gas 15min drive out of in packet after air by long nozzle by molten steel from Ladle is injected into tundish, and the degree of superheat is controlled at 30 DEG C, is added above molten steel for keeping the temperature and adsorbing the intermediate cladding being mingled with Lid agent;
(3) double-roller rolling: molten steel is injected into twin-roll cast-rolling mill by submersed nozzle, and slab speed is 80m/min, casting It is 4.5mm that roll, which presets roll gap,.Argon gas is used to be protected during MOLTEN STEEL FLOW, protective gas pressure 0.5MPa, after casting Obtained made-up belt is with a thickness of 4.5mm, and for molten steel in Casting Roller in process of setting, cooling rate is 300 DEG C/s;
(4) made-up belt hot rolling: roll casting sheet carries out hot rolling, protective gas pressure 0.5MPa under protection of argon gas.Made-up belt is through pressing from both sides Send roller be sent to hot-rolling mill carry out constant-tension rolling, 100 m/min of mill speed, 1050 DEG C of made-up belt hot-rolled temperature, after made-up belt hot rolling Steel strip thickness is 3.6mm;
(5) strip cooling and excision end to end
When the strip that temperature is 900 DEG C after hot rolling is cooled to 600 DEG C through cooling facility for laminar flow, then shearing is sent to through pinch roller Machine carries out the excision of strip end to end;
(6) strip coiling
Strip after excision end to end is sent to coiling machine through pinch roller and carries out strip coiling, obtains finished product thin strip steel coil.

Claims (5)

1. a kind of super austenitic stainless steel double roll strip casting rolling production process, it is characterised in that specific step is as follows:
(1) molten steel of ingredient qualification is hoisted to bale panoramic tables: by the super austenitic stainless steel after the refining of LF ladle refining furnace Molten steel is hoisted to bale panoramic tables, calm 15-25min;
(2) molten steel is injected into tundish: tundish blowing argon gas 10-20min drive out of in packet after air by long nozzle by molten steel from Ladle is injected into tundish, and degree of superheat control is added on 20 DEG C -40 DEG C, molten steel for keeping the temperature and adsorbing the centre being mingled with Covering agent;
(3) double-roller rolling: molten steel is injected in twin-roll cast-rolling mill by submersed nozzle, and slab speed is 80-120 m/min, casting Roller gap is adjustable between 1.5-4.5mm, and the mixed gas of argon gas or argon gas and hydrogen is used to carry out during MOLTEN STEEL FLOW Protection, for molten steel in Casting Roller in process of setting, cooling rate control range is 300-700 DEG C/s;
(4) made-up belt hot rolling: mixed gas protected lower carry out hot rolling of the roll casting sheet in argon gas or argon gas and hydrogen, protective gas pressure Power 0.3-0.5MPa, made-up belt are sent to hot-rolling mill through pinch roller and carry out constant-tension rolling, and mill speed range is 100-150 m/ Min, wherein the control of made-up belt hot-rolled temperature is 1050-1200 DEG C, and steel strip thickness control range is 1.2-3.6mm after made-up belt hot rolling;
(5) strip cooling and excision end to end
Strip after hot rolling is cooling, is sent to cutter through pinch roller and carries out the excision of strip end to end;
(6) strip coiling
Strip after excision end to end is sent to coiling machine through pinch roller and carries out strip coiling, obtains finished product thin strip steel coil.
2. a kind of super austenitic stainless steel double roll strip casting rolling production process according to claim 1, it is characterised in that: Protective gas pressure is 0.3-0.5MPa in the step (3).
3. a kind of super austenitic stainless steel double roll strip casting rolling production process according to claim 2, it is characterised in that: The volume ratio of argon gas and hydrogen is 3: 1 in the step (3).
4. a kind of super austenitic stainless steel double roll strip casting rolling production process according to claim 3, it is characterised in that: The volume ratio of argon gas and hydrogen is 3: 1 in the step (4).
5. a kind of super austenitic stainless steel double roll strip casting rolling production process according to claim 3 or 4, feature exist In: the strip in the step (5) after hot rolling is cooled to 600-650 DEG C through cooling facility for laminar flow.
CN201710288311.6A 2017-04-27 2017-04-27 A kind of super austenitic stainless steel double roll strip casting rolling production process Active CN107030264B (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108611565B (en) * 2018-05-25 2019-12-06 江苏集萃冶金技术研究院有限公司 Method for preparing high-strength low-alloy steel by twin-roll thin strip casting and aging process
CN108359909B (en) * 2018-05-25 2020-01-03 江苏集萃冶金技术研究院有限公司 Method for preparing high-strength and high-toughness martensitic steel through thin strip casting and rolling and aging process
CN111389914B (en) * 2020-03-02 2022-03-25 北京鼎新时代科技有限公司 Production method of super austenite 904L stainless steel plate strip

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CN103305770A (en) * 2012-03-14 2013-09-18 宝山钢铁股份有限公司 Method for manufacturing 550MPa-level high-strength atmospheric corrosion resistant steel strip through strip continuous casting
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CN104722586A (en) * 2013-12-24 2015-06-24 Posco公司 Method of manufacturing thin martensitic stainless steel sheet using strip caster with twin rolls and thin martensitic stainless steel sheet manufactured by the same
CN105543711A (en) * 2015-12-22 2016-05-04 东北大学 Cast-rolling method for restraining Cr element and Mo element of super-austenitic stainless steel from center segregation
CN105714212A (en) * 2014-12-22 2016-06-29 Posco公司 Twin-roll strip caster, method for manufacturing thin duplex stainless steel sheet using the same and thin duplex stainless steel sheet

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CN1182801A (en) * 1996-10-15 1998-05-27 阿维达·谢菲尔德公司 Method for manufacturing stainless steel band
CN1351528A (en) * 1999-04-22 2002-05-29 于西纳公司 Method for continuously casting between two rolls austenitic stainless steel strips with excellent surface quality and resulting strips
CN102039309A (en) * 2009-10-23 2011-05-04 宝山钢铁股份有限公司 Twin-roller double-strip composite-structured thin strip continuous casting and rolling method
CN104105805A (en) * 2011-12-28 2014-10-15 Posco公司 High strength austenitic stainless steel, and preparation method thereof
CN103305770A (en) * 2012-03-14 2013-09-18 宝山钢铁股份有限公司 Method for manufacturing 550MPa-level high-strength atmospheric corrosion resistant steel strip through strip continuous casting
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