CN107029551A - One kind is based on TiO2The device of nano pipe photochemical catalyst degraded VOCs gases - Google Patents

One kind is based on TiO2The device of nano pipe photochemical catalyst degraded VOCs gases Download PDF

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Publication number
CN107029551A
CN107029551A CN201710436894.2A CN201710436894A CN107029551A CN 107029551 A CN107029551 A CN 107029551A CN 201710436894 A CN201710436894 A CN 201710436894A CN 107029551 A CN107029551 A CN 107029551A
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CN
China
Prior art keywords
tio
photochemical catalyst
nano pipe
degraded
vocs gases
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710436894.2A
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Chinese (zh)
Inventor
王丽娟
史超
朱阳阳
王德新
孙沛东
佟万璐
孙丽晶
尹丽
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Changchun University of Technology
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Changchun University of Technology
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Filing date
Publication date
Application filed by Changchun University of Technology filed Critical Changchun University of Technology
Priority to CN201710436894.2A priority Critical patent/CN107029551A/en
Publication of CN107029551A publication Critical patent/CN107029551A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8678Removing components of undefined structure
    • B01D53/8687Organic components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8696Controlling the catalytic process
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20707Titanium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/80Type of catalytic reaction
    • B01D2255/802Photocatalytic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s

Abstract

TiO is based on the present invention relates to one kind2The device of nano pipe photochemical catalyst degraded VOCs gases, takes periodic duty:By closed degraded storehouse(3)Interior TiO2Four times-Adsorption Concentration of photocatalytic degradation area(10)Four times-Adsorption Concentration of zeolite adsorption area(10)Zeolite desorption concentration is considered as a cycle, circular flow.Utilize pressure transducer(6)With VOCs sensors(7)Closed degraded storehouse is detected respectively(3)Internal pressure and the concentration of degraded VOCs gases, pass through PLC(8)Intelligent control blower fan(9), heater(11), ventilating fan(12)With one-way flow pipe(13)Switch, periodic duty can improve the utilization rate of device, fully degraded.

Description

One kind is based on TiO2The device of nano pipe photochemical catalyst degraded VOCs gases
Technical field
The present invention is a kind of based on TiO2The device of nano pipe photochemical catalyst degraded VOCs gases, belongs to air purifying process neck Domain.
Background technology
VOCs (volatile organic compounds) volatile organic matter, is often referred to readily volatilized at normal temperatures Organic matter.More typical has benzene,toluene,xylene, ethylbenzene, styrene, formaldehyde, ketone etc..VOCs is a class to human body and ring The harmful gas in border, and originate and its extensive, for example, industrial waste gas, vehicle exhaust, indoor hardware fitting, photochemical fog etc.. And the method for main processing VOCs gases is absorption at present, such as runner type is adsorbed, cylinder type absorption etc., but this method can not It is inherently eliminated VOCs gases.
Therefore, processing degraded VOCs gases are an important at present efforts at environmental protection.Urged using titania nanotube light Changing degraded VOCs gases has its superiority, can generate CO2Deng inorganic matter, it can greatly reduce the danger to environment and human body Evil.
The content of the invention
The present invention devises a kind of based on TiO2The device of nano pipe photochemical catalyst degraded VOCs gases, to solve above-mentioned background The problem of being mentioned in technology.Device includes:Fibrous filter net(1), air-introduced machine(2), closed degraded storehouse(3), load TiO2Nanometer The dividing plate of pipe(4), UV-LED lamps(5), pressure transducer(6), VOCs sensors(7), PLC(8), blower fan (9), Adsorption Concentration area(10), heater(11), ventilating fan(12), one-way flow pipe(13).
As a kind of preferred scheme, the present apparatus takes periodic duty:By " closed degraded storehouse(3)Interior TiO2Light is urged Change four times-Adsorption Concentration of degraded area(10)Four times-Adsorption Concentration of zeolite adsorption area(10)Zeolite desorption concentration " is considered as a week Phase, circular flow can improve the utilization rate of device.
It is used as a kind of preferred scheme, TiO2Nano tube supported dividing plate internally(4)Positive and negative, and closed degraded storehouse (3)Inner surface, while in closed degraded storehouse(3)Four UV-LED lamps of interior installation(5), so as to utilize the TiO of large area2 Nanotube and plentiful illumination are fully degraded VOCs gases.
It is used as a kind of preferred scheme, pressure transducer(6)With PLC(8)Connection, storehouse internal pressure it is powerful in During 0.3 ~ 0.5 MPa of given threshold, air-introduced machine is closed(2)Switch, stop air inlet.
As a kind of preferred scheme, using PLC(8)Control device, intelligent control reduces manpower.
Brief description of the drawings
Fig. 1:Based on TiO2The device of nano pipe photochemical catalyst degraded VOCs gases.
Fig. 2:Load TiO2The dividing plate of nanotube.
Fig. 3:Load TiO2The degraded storehouse inner surface of nanotube.
Specific implementation method
VOCs gases pass through fibrous filter net(1)The impurity such as dust in air are filtered out, air-introduced machine is then sent through(2), via list Enter closed degraded storehouse to flow duct(3), in VOCs enters to put in storage, it is attached to TiO2On nanotube, in UV-LED lamps(5)Irradiation Under, TiO2Electron hole pair is produced inside nanotube, redox reaction occurs for the VOCs gases for being attached to surface, generates CO2Deng Inorganic matter, now, by pressure transducer(5)Internal pressure is detected, when pressure values are more than 0.5 MPa of given threshold, can be compiled by PLC Range controller(8)Control air-introduced machine(2)Switch, stop air inlet.By VOCs sensors(7)Detect now closed degraded storehouse(3) The concentration of interior VOCs gases, is set to initial value, closed degraded storehouse(3)The concentration of interior VOCs gases reaches the 20% of initial concentration When, PLC(8)To control blower fan(9)Switch, gas is sent to Adsorption Concentration area via blast pipe(10), The 20%VOCs not being degraded is by zeolite adsorption, CO2By Adsorption Concentration area(10)And ventilating fan(12)Discharge, so circulates four After secondary, PLC(8)Control heater(11)Open, ventilating fan(12)Close, one-way flow pipe(13)Open, 200 DEG C of heating, the VOCs after desorption concentration passes through one-way flow pipe(13)Into closed degraded storehouse(3), by VOCs sensors(7) When detecting VOCs concentration for 0 ppm, PLC(8)Blower fan is controlled again(9)Open, one-way flow pipe(13)Close, Gas passes through ventilating fan(12)Manpower, fully intelligent control, degraded are saved in discharge, such a cycle, circular flow.

Claims (7)

1. one kind is based on TiO2The device of nano pipe photochemical catalyst degraded VOCs gases, it is characterised in that:Apparatus is by fiber filter Net(1), air-introduced machine(2), closed degraded storehouse(3), load TiO2The dividing plate of nanotube(4), UV-LED lamps(5), pressure transducer (6), VOCs detectors(7), PLC(8), blower fan(9), Adsorption Concentration area(10), heater(11), ventilating fan (12), one-way flow pipe(13)Composition.
2. it is according to claim 1 a kind of based on TiO2The device of nano pipe photochemical catalyst degraded VOCs gases, its feature exists In:Fibrous filter net(1)The high density net being made of ultra-fine fibre glass, is existed to the filter efficiency not less than 0.3 μm of particle More than 99.995%.
3. it is according to claim 1 a kind of based on TiO2The device of nano pipe photochemical catalyst degraded VOCs gases, its feature exists In:TiO2Nanotube is tubular structure, and diameter is not less than 15 nm, it is allowed to which VOCs gases flow through, and pipe range is 10 μm ~ 15 μm.
4. it is according to claim 1 a kind of based on TiO2The device of nano pipe photochemical catalyst degraded VOCs gases, its feature exists In:VOCs detectors(7)Detection range is 0 ~ 2000 ppm, and the ppm of resolution ratio 0.1, accuracy of detection is not more than 3%.
5. it is according to claim 1 a kind of based on TiO2The device of nano pipe photochemical catalyst degraded VOCs gases, its feature exists In:PLC(8)Large scale integrated circuit is contained in inside, can be by the intake and exhaust of presetting apparatus, can High, the strong antijamming capability by property.
6. it is according to claim 1 a kind of based on TiO2The device of nano pipe photochemical catalyst degraded VOCs gases, its feature exists In:Adsorption Concentration area(10)Selection zeolite is the hole of uniform size and passage inside Adsorption Concentration material, zeolite crystal, body Product accounts for more than the 50% of zeolite volume, can adsorb larger molecular organicses, it is allowed to which micro-molecular gas flows through.
7. it is according to claim 1 a kind of based on TiO2The device of nano pipe photochemical catalyst degraded VOCs gases, its feature exists In:Heater(11)Range of temperature is 190 DEG C ~ 220 DEG C.
CN201710436894.2A 2017-06-12 2017-06-12 One kind is based on TiO2The device of nano pipe photochemical catalyst degraded VOCs gases Pending CN107029551A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710436894.2A CN107029551A (en) 2017-06-12 2017-06-12 One kind is based on TiO2The device of nano pipe photochemical catalyst degraded VOCs gases

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710436894.2A CN107029551A (en) 2017-06-12 2017-06-12 One kind is based on TiO2The device of nano pipe photochemical catalyst degraded VOCs gases

Publications (1)

Publication Number Publication Date
CN107029551A true CN107029551A (en) 2017-08-11

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Country Status (1)

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CN (1) CN107029551A (en)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201482379U (en) * 2009-08-18 2010-05-26 深圳市鼎和环保科技有限公司 High-efficiency combined type foul smell and VOC waste gas treatment device
CN202237744U (en) * 2011-08-12 2012-05-30 宁波大学 Integral organic waste gas purifying device for active carbon beds and low-temperature plasmas
CN204017627U (en) * 2014-08-25 2014-12-17 上海安居乐环保科技有限公司 A kind of equipment for treating industrial waste gas of ultraviolet light regenerated carbon
CN205461750U (en) * 2016-03-09 2016-08-17 石伟 Device of optoelectronic integration oxidation treatment waste gas
CN106492605A (en) * 2016-11-22 2017-03-15 徐亚军 A kind of multi-stage combination, the Treatment process of circular treatment volatile organic compoundses
CN106621702A (en) * 2017-03-23 2017-05-10 合肥工业大学 Organic exhaust gas concentration treatment device

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201482379U (en) * 2009-08-18 2010-05-26 深圳市鼎和环保科技有限公司 High-efficiency combined type foul smell and VOC waste gas treatment device
CN202237744U (en) * 2011-08-12 2012-05-30 宁波大学 Integral organic waste gas purifying device for active carbon beds and low-temperature plasmas
CN204017627U (en) * 2014-08-25 2014-12-17 上海安居乐环保科技有限公司 A kind of equipment for treating industrial waste gas of ultraviolet light regenerated carbon
CN205461750U (en) * 2016-03-09 2016-08-17 石伟 Device of optoelectronic integration oxidation treatment waste gas
CN106492605A (en) * 2016-11-22 2017-03-15 徐亚军 A kind of multi-stage combination, the Treatment process of circular treatment volatile organic compoundses
CN106621702A (en) * 2017-03-23 2017-05-10 合肥工业大学 Organic exhaust gas concentration treatment device

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Application publication date: 20170811