CN107029530A - A kind of container-type additive solution dosing system for flue gas demercuration - Google Patents

A kind of container-type additive solution dosing system for flue gas demercuration Download PDF

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Publication number
CN107029530A
CN107029530A CN201710282685.7A CN201710282685A CN107029530A CN 107029530 A CN107029530 A CN 107029530A CN 201710282685 A CN201710282685 A CN 201710282685A CN 107029530 A CN107029530 A CN 107029530A
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CN
China
Prior art keywords
additive
dosing system
solution
electric control
control gear
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Pending
Application number
CN201710282685.7A
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Chinese (zh)
Inventor
许昌日
王语桐
郝向宇
程俊峰
张开元
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Beijing SPC Environment Protection Tech Co Ltd
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Beijing SPC Environment Protection Tech Co Ltd
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Priority to CN201710282685.7A priority Critical patent/CN107029530A/en
Publication of CN107029530A publication Critical patent/CN107029530A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/64Heavy metals or compounds thereof, e.g. mercury
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/346Controlling the process
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/79Injecting reactants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/60Heavy metals or heavy metal compounds
    • B01D2257/602Mercury or mercury compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treating Waste Gases (AREA)

Abstract

A kind of container-type additive solution dosing system for flue gas demercuration, including:Additive solution stocking system, dosing system, rinse-system, electric control gear and associated pipe, it is characterised in that:Described additive solution stocking system is made up of at least one additive delivery pump, additive storage tank and delivery pipe, and the import of additive solution stocking system connects external additive solution, outlet connection dosing system;Described dosing system puts into point by measuring pump by the pipeline communication additive that feeds intake;The rinse-system provides system flush water, and the said equipment is arranged in container by electric control gear control, the said equipment and associated pipe connection;Apparatus of the present invention can be moved flexibly, energy rapid deployment to different fume treatments scene.Its small investment, take up an area small, be swift in response, conveniently moving, automaticity it is high, energy-conservation environmental protection again.

Description

A kind of container-type additive solution dosing system for flue gas demercuration
Technical field
The invention belongs to a kind of collection for flue gas demercuration in energy-conserving and environment-protective field, particularly Air Pollution Control field Vanning formula additive solution dosing system.
Background technology
With expanding economy, consumption of the society to coal, oil equal energy source constantly aggravates, and the burning of these fuel is utilized Many atmosphere pollutions such as SOx, NOx, dust, mercury can be produced, wherein mercury is connect as heavy metal contaminants by breathing, skin The modes such as tactile, diet enter after human body, cause various nervous systems, disease of cardiovascular system, and great danger is produced to health Evil.
The oxidative absorption technology of mercury turns into the high efficiency technical of flue gas Mercury vacancy, and the technology is each by being added in flue gas Class additive, strengthens Hg0To Hg in flue gas2+Conversion, recycle Hg2+ ease of solubility pass through the wash mill handle such as desulfurizing tower Mercury is removed from flue gas.
Research shows that the content of mercury is 0.1~5.5 μ g/g in raw coal, and average mercury content is 0.22 μ g/g, therefore, coal-fired The mode of flue gas demercuration mainly have burning before demercuration, burning in demercuration and burning after three kinds of demercuration.Due to demercuration and combustion before burning The technology of demercuration is limited to the removal ability of mercury in fire coal in burning, therefore demercuration technology is still topmost controlling soil moist after burning. Mercury in coal-fired flue-gas is main with gaseous elemental mercury (Hg0), gaseous state divalent ion mercury (Hg2+) and particle mercury (Hgp) three kinds of shapes Formula is present, wherein, gaseous elemental mercury (Hg0) account for the 30%~80% of flue gas total mercury content.Elemental Mercury (Hg0) water insoluble, and Volatility is extremely strong, and dedusting or desulphurization plant are difficult capture, and almost all is discharged into the atmosphere;And divalent ion mercury (Hg2+) readily soluble Yu Shui, is also easily adsorbed by the particulate matter in flue gas, so divalent ion mercury (Hg2+) easily separated by cleaner;Particle mercury (Hgp) also easily separated by cleaner.At present, domestic and international flue gas demercuration technology mainly uses charcoal absorption or oxidant pair Coal-fired flue-gas carries out demercuration after burning, and operating cost is of a relatively high.
One of traditional method of flue gas demercuration in coal-burning power plant is the oxidative absorption technology using mercury, and the technology is newly-increased cigarette Qi exhaustion mercury facility, all kinds of catalyst or oxidant are added into flue gas, strengthen Hg0To Hg in flue gas2+Conversion, recycle de- Sulphur device removes mercury from flue gas.And newly-increased flue gas demercuration facility is present that floor space is big, mobile inconvenient, utilization rate is not high Etc. defect.
The content of the invention
The technical scheme that the present invention takes is a kind of container-type additive solution dosing system for flue gas demercuration, bag Include additive solution stocking system, additive dosing system, rinse-system, container, electric control gear;
The additive solution stocking system, additive dosing system, rinse-system, electric control gear are all arranged on container In;The discharging opening of additive solution stocking system is connected with the charging aperture of additive dosing system, and the rinse-system leads to respectively Technique water pipe and wash tub pipe connection additive solution stocking system and additive dosing system are crossed, the electric control gear passes through electricity Signal controls the said equipment.
Further, the additive solution stocking system can be received described electric control gear control signal by least one Additive delivery pump, additive storage tank and delivery pipe constitute, the additive delivery pump discharging opening passes through delivery pipe and addition Agent storage tank is connected, and additive delivery pump, which is imported and exported to set, can receive the motor-operated control valve of described electric control gear control signal.
Further, the additive storage tank is provided with agitator, overflow pipe and transmittable signal to the electric control gear Liquid level gauge.
Further, the agitator is arranged inside additive storage tank, and the overflow pipe is arranged at liquid level gauge Additive storage tank outer wall.
Further, described electric control gear control signal can be received by being provided with the pipeline of the additive dosing system Measuring pump, transmittable signal give flowmeter, safety valve, counterbalance valve, damper, pressure gauge and the additive of the electric control gear Commissioning pipe, the flowmeter, safety valve, counterbalance valve, damper, pressure gauge are arranged on additive commissioning pipe, the measuring pump Import connects the bottom of additive storage tank.
Further, the rinse-system includes water tank, and water tank sets rinse-system liquid level gauge, water tank and technique Water pipe, wash tub pipe connection.
Further, it is provided with ventilative window on described container side wall.
Further, described electric control gear includes distribution box, PLC control cabinet, the MCC control cabinets being sequentially connected electrically.
Further, described distribution control box is used to provide distribution.
Further, described PLC control cabinet is used for the signal control of package unit and automatically controlled.
Further, described MCC control cabinets are that automatic or manual starts the control device closed.
A kind of container-type additive solution dosing system for flue gas demercuration of the invention, it can not increase fire coal Under conditions of power-plant flue gas treatment facility, with container-type additive solution dosing system, power-plant flue gas demercuration energy is effectively improved Power, reduces smoke mercury emission concentration.The system is applied to various demercuration additive solutions, simultaneously because the apparatus module is matched somebody with somebody Put, be equally applicable to the flue gas demercuration of the industries such as metal smelt, cement, chemical industry, petroleum refining.It pacifies with traditional construction on the spot Dress technique is compared, small with small investment, occupation of land, and be swift in response fast, conveniently moving, automaticity are high, and environmental protection etc. is excellent again for energy-conservation Point.
Brief description of the drawings
Fig. 1 is structure schematic top plan view of the invention
Fig. 2 is structure front-view schematic diagram of the invention
Figure elements explanation
1st, additive solution stocking system, 101, additive delivery pump, 102, additive storage tank, 103, delivery pipe, 104, Motor-operated control valve, 105, agitator, 106, overflow pipe, 107, liquid level gauge;
2nd, additive dosing system, 201, measuring pump, 202, flowmeter, 203, safety valve, 204, counterbalance valve, 205, damping Device, 206, pressure gauge, 207, additive commissioning pipe;
3rd, rinse-system, 301, water tank, 302, rinse-system liquid level gauge, 303, technique water pipe, 304, wash tub pipe, 305th, delivery pipe;
4th, container;
5th, electric control gear, 501, distribution box, 502, PLC control cabinet, 503, MCC control cabinets.
Embodiment
Embodiment
A kind of container-type additive solution dosing system for flue gas demercuration, as depicted in figs. 1 and 2, including addition Agent solution stocking system 1, additive dosing system 2, rinse-system 3, container 4, electric control gear 5 and associated pipe.Described Additive solution stocking system 1, additive dosing system 2, rinse-system 3 are by electric control gear control, the said equipment and correlation Pipeline connection is arranged in container 4.
Described additive solution stocking system 1 is by least one additive delivery pump 101, additive storage tank 102 and defeated Pipe 103 is sent to constitute, the import of additive solution stocking system 1 connects external additive solution, outlet connection additive dosing system 2;Described additive delivery pump 101 is imported and exported to be connected with external additive and additive storage tank 102 respectively by delivery pipe 103 Connect, additive delivery pump 101 imports and exports the motor-operated control valve 104 for setting and being controlled by electric control gear 5, and external additive is by adding Plus agent delivery pump 101 is pumped into additive storage tank 102 and stored, the additive storage tank 102 sets agitator 105, overflow Liquid level in pipe 106 and liquid level gauge 107, wherein liquid level gauge 107 detection additive storage tank 102, adds toward additive storage tank 102 and adds Plus during agent, it is defeated that the liquid level signal of liquid level gauge 107 is transferred to feedback signal control motor-operated control valve 104 and additive after electric control gear 5 Pump 101 is sent, and unnecessary additive is discharged by overflow pipe 106, controls the additive in additive storage tank 102 to add with this Amount and safety levels.
Described additive dosing system 2 is by measuring pump 201, flowmeter 202, safety valve 203, counterbalance valve 204, damper 205th, pressure gauge 206 and additive commissioning pipe 207 and associated pipe etc. are constituted, and are wherein installed with additive commissioning pipe 207 Flowmeter 202, safety valve 203, counterbalance valve 204, damper 205, pressure gauge 206 etc., their effect are to ensure commissioning pipe 207 Interior pressure stability, maintains the constant basis conveying of measuring pump 201, and additive commissioning pipe 207 is used to additive be added to flue gas The toss area of demercuration system.The import of measuring pump 201 connects additive storage tank 102, and additive is delivered to addition by measuring pump 102 Agent puts into point, controls the additive dosage of measuring pump 201 when adding additive in real time by flowmeter 202 and electric control gear 5,
Described rinse-system 3 is made up of water tank 301 and respective line, and water tank sets rinse-system liquid level gauge 302 Liquid level is controlled, while technique water pipe 303 is the water filling of water tank 301, wash tub pipe 304 is used for the flushing of system, and flushing water passes through Delivery pipe 305 is rejected to outside system.
Described container 4 is provided with least two transoms, and is provided with least one and is connected with electric control gear 5 There is provided ventilation in container and illumination for air-conditioning and illuminating lamp.
Described electric control gear 5 includes:Distribution box 501, PLC control cabinet 502, MCC control cabinets 503, described matching somebody with somebody is automatically controlled Case 501 processed is to provide distribution for the illumination of equipment, air-conditioning and container;Described PLC control cabinet 502 is used for the signal of package unit Control and automatically control;Described MCC control cabinets 503 are that automatic or manual starts the specific equipment such as closing agitator tank, pump, valve The control of operation.
The additive reserves situation of the Real-time Feedback additive storage tank 102 of liquid level gauge 107 is to electric control gear 5, when liquid level gauge 107 When the liquid level of feedback is less than minimum level value set in advance, electric control gear 5 sends additive fluid infusion signal, opens additive defeated Pump 101 and motor-operated control valve 104 are sent, when the liquid level that liquid level gauge 107 feeds back reaches optimal liquid level value set in advance, automatically controlled dress Put 5 and send stopping fluid infusion signal, close additive delivery pump 101 and motor-operated control valve 104;
When electric control gear 5, which receives additive, adds order, measuring pump 201, counterbalance valve 204, damper 205 are opened, and By pressure gauge 206 and the detecting system pressure value of flowmeter 202 and flow value, electric control gear 5 is adjusted according to the flow signal of feedback The dosage of measuring pump 201 is saved, makes it consistent with required dosage.When flow, pressure oscillation occur in system, counterbalance valve 204 provide the pressure differential between system and betting, and damper 205 absorbs the flow peak between measuring pump 201 and counterbalance valve 204 Unnecessary additive returns to additive storage tank 102 in value, the off-loadable pipeline of safety valve 203, reduces whole pipe-line system and is flowed Speed and the impact of pressure oscillation.
It is automatically controlled when the level value that rinse-system liquid level gauge 302 feeds back to electric control gear 5 is less than default minimum level value Device 5 sends moisturizing order, motor-operated control valve water filling into water tank 301 on technique water pipe 303 is opened, when level value reaches During default optimal liquid level value, electric control gear 5 sends stopping moisturizing order, and the motor-operated control valve closed on technique water pipe 303;
When electric control gear 5 receives flush command, the motor-operated control valve opened on wash tub pipe 304 enters to whole system water filling Row is rinsed, while the level value of the feedback of detection rinse-system liquid level gauge 302 in real time, when level value reaches the default liquid of flush command During place value, electric control gear sends stopping flush command, and the motor-operated control valve closed on wash tub pipe 304.
The present invention is in use, technological process is as follows:
The additive that outside transport comes is defeated by additive solution by additive delivery pipe 103 and additive delivery pump 101 It is sent to the measuring pump 201 in additive storage tank 102, the liquid outlet connection additive dosing system 2 of additive storage tank 102, addition Additive in agent storage tank 102 is added to additive by additive commissioning pipe 207 after the accurate measurement of measuring pump 201 The toss area of flue gas mercury removal system.During additive is added, safety valve 203, the counterbalance valve installed on additive commissioning pipe 207 204th, the part such as damper 205, pressure gauge 206 maintains the stabilization of loine pressure, it is ensured that the constant basis conveying of additive.Work as system Flushing of pipeline is needed, during discharge pipe Liquid Residue, the control rinse-system 3 of electric control gear 5 provides a system to flushing water, and flushing is finished Flushing water is rejected to outside system by delivery pipe 305 afterwards.
When carrying out flue gas demercuration, additive dosage exists related to exhaust gas volumn, gas mercury concentration and required demercuration efficiency Relation, when external additive dosage signal is transferred to electric control gear 5, control signal passes to measuring pump 201 after analysis Dosage is controlled, and combines the implementation feedback dosage of flowmeter 202.When the additive in additive storage tank 102 is not enough, pass through Additive delivery pump 101 is from external complement additive.
The effect of invention:
Using bromine demercuration additive solution, additive concentration is 25%, and exhaust gas volumn is 1,000,000 Nm3/h, gas mercury concentration For 7.6~9.5 μ g/Nm3,
Gas mercury concentration μ g/Nm3 Additive dosage L/h Demercuration efficiency %
9.5 80 89
8.7 45 81
8.3 58 84
7.6 66 86
For flue gas mercury removal system due in flue gas the Hg contents order of magnitude it is relatively low, the scale of required control device is relatively passed Small many of the equipment such as the desulphurization and denitration of system, beneficial to being designed to container-type integrated control system, container-type pollutant removing The advantage of system be in engineering it can not only shorten the set-up time of pollution control system and flexible arrangement, convenient transportation, Operation is simple to operate, easily realize centralized Control and maintenance, thus in terms of the pollutant catabolic gene of following small scale with it is traditional Great advantage is had for construction mounting process.
The present invention is by the storage of demercuration additive, added and rinse-system, is integrally loaded into container, and use standard Change design, from various common apparatus, instrument, electrical equipment etc., be easy for installation and maintenance, control is simple, can be achieved to add certainly Dynamic control.The system can be applicable adding for a variety of demercuration additive solutions, with good broad spectrum activity.In addition, the system has The features such as having high small investment, flexibility, saving occupation of land, conveniently moving, has broad application prospects.The system connects external add Plus after agent, power supply, technique water pipe, discharging tube, the pipeline that feeds intake, you can use.
Under conditions of coal-fired plant flue gas treatment facility is not increased, added with container-type additive solution additive and be System, effectively improves power-plant flue gas demercuration ability, reduces smoke mercury emission concentration.It is molten that the system is applied to various demercuration additives Liquid, simultaneously because the apparatus moduleization configures, be equally applicable to the flue gas of the industries such as metal smelt, cement, chemical industry, petroleum refining Demercuration.

Claims (11)

1. a kind of container-type additive solution dosing system for flue gas demercuration, it is characterised in that:Including additive solution Stocking system (1), additive dosing system (2), rinse-system (3), container (4), electric control gear (5);
The additive solution stocking system (1), additive dosing system (2), rinse-system (3), electric control gear (5) are all installed In container (4);The discharging opening of additive solution stocking system (1) is connected with the charging aperture of additive dosing system (2), institute State rinse-system (3) respectively by technique water pipe (303) and wash tub pipe (304) connect additive solution stocking system (1) and Additive dosing system (2), the electric control gear (5) controls the said equipment by electric signal.
2. solution dosing system according to claim 1, it is characterised in that the additive solution stocking system (1) by At least one additive delivery pump (101) that can receive described electric control gear (5) control signal, additive storage tank (102) and Delivery pipe (103) is constituted, and additive delivery pump (101) discharging opening is connected by delivery pipe (103) and additive storage tank (102) Connect, additive delivery pump (101), which is imported and exported to set, can receive the motor-operated control valve of described electric control gear (5) control signal (104)。
3. solution dosing system according to claim 2, it is characterised in that the additive storage tank (102), which is provided with, stirs Mix the liquid level gauge (107) of device (105), overflow pipe (106) and transmittable signal to the electric control gear (5).
4. solution dosing system according to claim 3, it is characterised in that the agitator (105), which is arranged at, to be added Plus agent storage tank (102) is internal, the overflow pipe (106) is arranged at additive storage tank (102) outer wall with liquid level gauge (107).
5. solution dosing system according to claim 1, it is characterised in that the pipeline of the additive dosing system (2) On be provided with the measuring pump (201) that can receive described electric control gear (5) control signal, transmittable signal to the electric control gear (5) flowmeter (202), safety valve (203), counterbalance valve (204), damper (205), pressure gauge (206) and additive feeds intake Manage (207), the flowmeter (202), safety valve (203), counterbalance valve (204), damper (205), pressure gauge (206) are arranged on On additive commissioning pipe (207), the bottom of measuring pump (201) the import connection additive storage tank (102).
6. solution dosing system according to claim 1, it is characterised in that the rinse-system (3) includes water tank (301), water tank (301) sets rinse-system liquid level gauge (302), water tank (301) and technique water pipe (303), wash tub pipe (304) connect.
7. solution dosing system according to claim 1, it is characterised in that be provided with described container (4) side wall Ventilative window.
8. solution dosing system according to claim 1, it is characterised in that described electric control gear (5) includes electric successively Distribution box (501), PLC control cabinet (502), the MCC control cabinets (503) of connection.
9. solution dosing system according to claim 6, it is characterised in that described distribution control box (501) is used to carry For distribution.
10. solution dosing system according to claim 6, it is characterised in that described PLC control cabinet (502) is used for whole The signal of covering device is controlled and automatically controlled.
11. solution dosing system according to claim 6, it is characterised in that described MCC control cabinets (503) are automatic Or manually boot the control device of closing.
CN201710282685.7A 2017-04-26 2017-04-26 A kind of container-type additive solution dosing system for flue gas demercuration Pending CN107029530A (en)

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Cited By (3)

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Publication number Priority date Publication date Assignee Title
CN110511801A (en) * 2019-09-17 2019-11-29 青岛华友恒新能源材料技术研究院有限公司 A kind of natural gas mercury-removing agent chemicals dosing plant
CN110694540A (en) * 2019-10-30 2020-01-17 广州无一物联网科技有限公司 Intelligent additive master batch batching system and control method thereof
CN113064455A (en) * 2021-03-23 2021-07-02 魏桥纺织股份有限公司 Full-automatic accurate control system of foaming agent

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CN102241423A (en) * 2011-06-10 2011-11-16 北京市市政工程设计研究总院 Mobile container type integrated powder dissolving and adding device
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110511801A (en) * 2019-09-17 2019-11-29 青岛华友恒新能源材料技术研究院有限公司 A kind of natural gas mercury-removing agent chemicals dosing plant
CN110694540A (en) * 2019-10-30 2020-01-17 广州无一物联网科技有限公司 Intelligent additive master batch batching system and control method thereof
CN113064455A (en) * 2021-03-23 2021-07-02 魏桥纺织股份有限公司 Full-automatic accurate control system of foaming agent

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