CN107022287A - A kind of fluorinated hydrophobic minute surface nano paint and preparation method thereof - Google Patents
A kind of fluorinated hydrophobic minute surface nano paint and preparation method thereof Download PDFInfo
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- CN107022287A CN107022287A CN201710429049.2A CN201710429049A CN107022287A CN 107022287 A CN107022287 A CN 107022287A CN 201710429049 A CN201710429049 A CN 201710429049A CN 107022287 A CN107022287 A CN 107022287A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D169/00—Coating compositions based on polycarbonates; Coating compositions based on derivatives of polycarbonates
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/28—Nitrogen-containing compounds
- C08K2003/282—Binary compounds of nitrogen with aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention discloses a kind of fluorinated hydrophobic minute surface nano paint, it is made up of the raw material of following weight parts：90 95% sulfuric acid 57, acetone 60 70,2 butyl cellosolves 23, trimethylene carbonate 80 90, trihydroxy ethylamine oleate soap 13, pyromellitic acid anhydride 24, hydrophobic dispersion liquid 16 20, terpinol 23,8 oxyquinolines 0.8 1, diaminodiphenyl ether 0.6 1, diisopropyl ethanolamine 12, stabilizer 23, polyglyceryl fatty acid ester 23, ammonium fluozirconate 10 12, aluminium nitride 35.
Description
Technical field
The invention belongs to paint field, and in particular to a kind of fluorinated hydrophobic minute surface nano paint and preparation method thereof.
Background technology
The functional coating that LOW-E glass on the market mainly plays heat-blocking action at present is silver layer.Silver has infrared anti-well
Penetrate performance, but silver with air contact with processing when easily aoxidize, the silver oxide generated after oxidation is opaque, and adhesive force it is low,
Heat-insulated narrow range, complex process, it reduce LOW-E stability, glass and effective light transmission effect, therefore will at least be plated two layers two
If silica carrys out mating protection with dried layer other materials, it does not allow it to oxidize away or reduce as far as possible its influence to translucency；
With the promotion and application such as the development of electronics industry, particularly smart mobile phone, large screen television, Intelligent flat computer, this
Nowadays a little products come into global huge numbers of families and numerous companies.But after the popularization of various touch screen technologies,
These products are used due to high-frequency, the display surface of product is easy to dirty, scratch and rotten by some chemical solvents
Erosion, therefore it is very necessary to improve waterproof, antifouling, anti-chemical reagent, raising wearability of these products etc., at present in electronics
In terms of the protection of product display screen, the method that many people use pad pasting, but this method effect is general, and very by limitation,
Particularly giant-screen telecomputer, outdoor ATM machines, building glass curtain wall, the side such as large-sized smart mobile phone, vehicle glass
Face, can not be applied.For such situation, develop a kind of glass of each side excellent combination property, electronic product and show
Show that device protective coating is just very necessary；
At present on the market for being carried out with waterproof, the excellent coating for having no effect on the transparent performance of product of antifouling, anti-wear performance
It is many to attempt, and have developed the coating of all kinds of coatings protections, due to the low-surface-energy of fluoro-containing coating, heat-resisting, chemical resistance, from
The performances such as lubricity, weatherability, therefore how fluorine is incorporated into coating surface and just seems especially important.
The content of the invention
It is an object of the invention to for coating water-proof in the prior art, antifouling, anti-wear performance is poor the problem of there is provided one
Plant fluorinated hydrophobic minute surface nano paint and preparation method thereof.
To achieve the above object, the present invention uses following technical scheme：
A kind of fluorinated hydrophobic minute surface nano paint, it is made up of the raw material of following weight parts：
90-95% sulfuric acid 5-7, acetone 60-70, butoxy ethanol 2-3, trimethylene carbonate 80-90, triethanolamine oil
Sour soap 1-3, pyromellitic acid anhydride 2-4, hydrophobic dispersion liquid 16-20, terpinol 2-3,8-hydroxyquinoline 0.8-1, diaminourea two
Phenylate 0.6-1, diisopropyl ethanolamine 1-2, stabilizer 2-3, polyglyceryl fatty acid ester 2-3, ammonium fluozirconate 10-12, aluminium nitride
3-5。
Described stabilizer is one kind in barium stearate, zinc stearate, calcium stearate.
Described catalyst is stannous octoate.
What described hydrophobic dispersion liquid was made up of the raw material of following weight parts：
1H, 1H, 2H, 2H- perfluoro decyl triethoxysilane 3-4, butanethiol tin 1-2, lauryl dimethyl amine oxide 0.4-
1st, castor oil acid 2-3, polyoxyethylene oleic acid ester 0.1-0.2.
A kind of fluorinated hydrophobic minute surface nano paint, the preparation method of described hydrophobic dispersion liquid, comprises the following steps：
（1）Lauryl dimethyl amine oxide is taken, in the deionized water for being added to 20-30 times of its weight, is stirred, amine is obtained and disperses
Liquid；
（2）Castor oil acid is taken, in the absolute ethyl alcohol for being added to 2.8-4 times of its weight, is stirred, rise temperature is 70-75 DEG C,
Butanethiol tin is added, insulated and stirred 30-40 minutes adds polyoxyethylene oleic acid ester, stirs to normal temperature, obtain ester solution；
（3）Above-mentioned ester solution, the mixing of amine dispersion liquid are taken, stirs, adds 1H, 1H, 2H, 2H- perfluoro decyl triethoxysilicanes
Alkane, it is ultrasonic 10-20 minutes, produce the hydrophobic dispersion liquid.
A kind of preparation method of fluorinated hydrophobic minute surface nano paint, comprises the following steps：
（1）Pyromellitic acid anhydride is taken, in the deionized water for being added to 16-20 times of its weight, is stirred, fluorine zirconic acid is added
Ammonium, rise temperature is 70-80 DEG C, and insulated and stirred 1-2 hours after above-mentioned 90-95% sulfuric acid, completion of dropping are added dropwise, acid zirconium is obtained
Solution；
（2）Aluminium nitride is taken, in the deionized water for being added to 10-13 times of its weight, diaminodiphenyl ether is added, it is ultrasonic 4-7 minutes,
Obtain aluminium nitride dispersion liquid；
（3）Above-mentioned acid zirconium solution, the mixing of aluminium nitride dispersion liquid are taken, stirs, filters, precipitation is washed, 80-90 DEG C of vacuum
Lower dry 1-2 hours, normal temperature is cooled to, carboxylated filler is obtained；
（4）8-hydroxyquinoline is taken, in the absolute ethyl alcohol for being added to 4-7 times of its weight, is stirred, triethanolamine oleate is added
Soap, insulated and stirred 10-20 minutes at 60-70 DEG C, obtains alcohol dispersion liquid；
（5）Above-mentioned carboxylated filler is taken, is added in alcohol dispersion liquid, stirs, polyglyceryl fatty acid ester is added, stirring is equal
It is even, obtain ester dispersion liquid；
（6）Trimethylene carbonate, the mixing of ester dispersion liquid are taken, is added in acetone, stirs, be sent in reactor, plus
Enter catalyst, be passed through nitrogen, regulation temperature of reaction kettle is 35-40 DEG C, insulation reaction 2-3 hour, add butoxy ethanol, surely
Determine agent, stirring to normal temperature, discharging is mixed with remaining each raw material, ultrasonic 20-30 minutes, dehydration produces the fluorinated hydrophobic minute surface
Nano paint.
Advantages of the present invention：
In the hydrophobic dispersion liquid that the present invention is added, using castor oil acid, absolute ethyl alcohol as raw material, it is stabilization to add butanethiol tin
Agent, obtained esterified material is distributed in the aqueous solution of lauryl dimethyl amine oxide, and passes through 1H, 1H, 2H, the 2H- perfluor last of the ten Heavenly stems
Ethyl triethoxy silicane alkane processing, obtained hydrophobic dispersion liquid can effectively improve the hydrophobic performance of finished product film；
The present invention by acidification, then mixes with aluminium nitride dispersion liquid using ammonium fluozirconate as raw material, obtains carboxylated and fill out
Material, it can improve the hardness and abrasion resistance of finished product film coated surface；
The present invention mixes esterification with carboxylated filler, and pass through polyglycereol fat using the alcohol dispersion liquid of 8-hydroxyquinoline as raw material
Acid esters disperses, and can effectively improve dispersiveness of the filler between carboxylate, improves the stability_intensity of film；
The present invention also introduces 8-hydroxyquinoline, trihydroxy ethylamine oleate soap during esterification, effectively improves each raw material
Compatibility, improve the caking property intensity of film and base material, improve peel strength；
The present invention, using the ester dispersion liquid containing filler as solvent, enters using trimethylene carbonate as monomer under catalyst action
Row polymerization, improves compatibility of the filler between polymer, improves the combination property of finished product coating；
The coating of the present invention has splendid soil resistance, ultra-thin membrane coat, excellent slickness, resistance to acids and bases and salt fog resistance,
It is super-hydrophobic, the characteristic such as hardness height.Water contact angle can reach 115 °, and hydrophobicity is strong, and case hardness can reach 8H-9H, and the product can
Lipophobic hydrophobic is improved for surface, the surface of low-friction coefficient with durable reduction fingerprint, can be created, table easy to clean is created
Face, makes surface have good wearability.
Embodiment
Embodiment 1
A kind of fluorinated hydrophobic minute surface nano paint, it is made up of the raw material of following weight parts：
95% sulfuric acid 7, acetone 70, butoxy ethanol 3, trimethylene carbonate 90, trihydroxy ethylamine oleate soap 3, equal benzene tetramethyl
Acid dianhydride 2-4, hydrophobic dispersion liquid 20, terpinol 3,8-hydroxyquinoline 1, diaminodiphenyl ether 1, diisopropyl ethanolamine 2, stably
Agent 3, polyglyceryl fatty acid ester 3, ammonium fluozirconate 12, aluminium nitride 5.
Described stabilizer is calcium stearate.
Described catalyst is stannous octoate.
What described hydrophobic dispersion liquid was made up of the raw material of following weight parts：
1H, 1H, 2H, 2H- perfluoro decyl triethoxysilane 4, butanethiol tin 2, lauryl dimethyl amine oxide 1, castor oil
Acid 3, polyoxyethylene oleic acid ester 0.2.
The preparation method of described hydrophobic dispersion liquid, comprises the following steps：
（1）Lauryl dimethyl amine oxide is taken, in the deionized water for being added to 30 times of its weight, stirs, obtains amine dispersion liquid；
（2）Castor oil acid is taken, in the absolute ethyl alcohol for being added to 4 times of its weight, is stirred, rise temperature is 75 DEG C, adds fourth
Base tin mercaptides, insulated and stirred 40 minutes adds polyoxyethylene oleic acid ester, stirs to normal temperature, obtains ester solution；
（3）Above-mentioned ester solution, the mixing of amine dispersion liquid are taken, stirs, adds 1H, 1H, 2H, 2H- perfluoro decyl triethoxysilicanes
Alkane, ultrasound 20 minutes, produces the hydrophobic dispersion liquid.
A kind of preparation method of fluorinated hydrophobic minute surface nano paint, comprises the following steps：
（1）Pyromellitic acid anhydride is taken, in the deionized water for being added to 20 times of its weight, is stirred, ammonium fluozirconate is added, risen
High-temperature is 80 DEG C, and insulated and stirred 2 hours after above-mentioned 95% sulfuric acid, completion of dropping are added dropwise, acid zirconium solution is obtained；
（2）Aluminium nitride is taken, in the deionized water for being added to 13 times of its weight, diaminodiphenyl ether is added, it is ultrasonic 4-7 minutes, obtain
Aluminium nitride dispersion liquid；
（3）Above-mentioned acid zirconium solution, the mixing of aluminium nitride dispersion liquid are taken, stirs, filters, precipitation is washed, at 90 DEG C of vacuum
Dry 2 hours, be cooled to normal temperature, obtain carboxylated filler；
（4）8-hydroxyquinoline is taken, in the absolute ethyl alcohol for being added to 7 times of its weight, is stirred, trihydroxy ethylamine oleate soap is added,
Insulated and stirred 20 minutes at 70 DEG C, obtain alcohol dispersion liquid；
（5）Above-mentioned carboxylated filler is taken, is added in alcohol dispersion liquid, stirs, polyglyceryl fatty acid ester is added, stirring is equal
It is even, obtain ester dispersion liquid；
（6）Trimethylene carbonate, the mixing of ester dispersion liquid are taken, is added in acetone, stirs, be sent in reactor, plus
Enter catalyst, be passed through nitrogen, regulation temperature of reaction kettle is 340 DEG C, insulation reaction 3 hours, add butoxy ethanol, stably
Agent, stirring to normal temperature, discharging is mixed with remaining each raw material, ultrasound 30 minutes, dehydration, produces the fluorinated hydrophobic minute surface nanometer
Coating.
Embodiment 2
A kind of fluorinated hydrophobic minute surface nano paint, it is made up of the raw material of following weight parts：
90% sulfuric acid 5, acetone 60, butoxy ethanol 2, trimethylene carbonate 80, trihydroxy ethylamine oleate soap 1, equal benzene tetramethyl
It is acid dianhydride 2, hydrophobic dispersion liquid 16, terpinol 2,8-hydroxyquinoline 0.8, diaminodiphenyl ether 0.6, diisopropyl ethanolamine 1, steady
Determine agent 2, polyglyceryl fatty acid ester 2, ammonium fluozirconate 10, aluminium nitride 3.
Described stabilizer is barium stearate.
Described catalyst is stannous octoate.
What described hydrophobic dispersion liquid was made up of the raw material of following weight parts：
1H, 1H, 2H, 2H- perfluoro decyl triethoxysilane 3, butanethiol tin 1, lauryl dimethyl amine oxide 0.4, castor-oil plant
Oleic acid 2, polyoxyethylene oleic acid ester 0.1.
The preparation method of described hydrophobic dispersion liquid, comprises the following steps：
（1）Lauryl dimethyl amine oxide is taken, in the deionized water for being added to 20 times of its weight, stirs, obtains amine dispersion liquid；
（2）Castor oil acid is taken, in the absolute ethyl alcohol for being added to 2.8 times of its weight, is stirred, rise temperature is 70 DEG C, is added
Butanethiol tin, insulated and stirred 30 minutes adds polyoxyethylene oleic acid ester, stirs to normal temperature, obtains ester solution；
（3）Above-mentioned ester solution, the mixing of amine dispersion liquid are taken, stirs, adds 1H, 1H, 2H, 2H- perfluoro decyl triethoxysilicanes
Alkane, ultrasound 10 minutes, produces the hydrophobic dispersion liquid.
A kind of preparation method of fluorinated hydrophobic minute surface nano paint, comprises the following steps：
（1）Pyromellitic acid anhydride is taken, in the deionized water for being added to 16 times of its weight, is stirred, ammonium fluozirconate is added, risen
High-temperature is 70 DEG C, and insulated and stirred 1 hour after above-mentioned 90% sulfuric acid, completion of dropping is added dropwise, acid zirconium solution is obtained；
（2）Aluminium nitride is taken, in the deionized water for being added to 10 times of its weight, diaminodiphenyl ether is added, it is ultrasonic 4-7 minutes, obtain
Aluminium nitride dispersion liquid；
（3）Above-mentioned acid zirconium solution, the mixing of aluminium nitride dispersion liquid are taken, stirs, filters, precipitation is washed, at 80 DEG C of vacuum
Dry 1 hour, be cooled to normal temperature, obtain carboxylated filler；
（4）8-hydroxyquinoline is taken, in the absolute ethyl alcohol for being added to 4 times of its weight, is stirred, trihydroxy ethylamine oleate soap is added,
Insulated and stirred 10 minutes at 60 DEG C, obtain alcohol dispersion liquid；
（5）Above-mentioned carboxylated filler is taken, is added in alcohol dispersion liquid, stirs, polyglyceryl fatty acid ester is added, stirring is equal
It is even, obtain ester dispersion liquid；
（6）Trimethylene carbonate, the mixing of ester dispersion liquid are taken, is added in acetone, stirs, be sent in reactor, plus
Enter catalyst, be passed through nitrogen, regulation temperature of reaction kettle is 35 DEG C, and insulation reaction 2 hours adds butoxy ethanol, stabilizer,
Stirring to normal temperature, discharging is mixed with remaining each raw material, ultrasound 20 minutes, dehydration, is produced the fluorinated hydrophobic minute surface nanometer and is applied
Material.
Performance test：
The coating of the present invention：
Originate water contact angle：115-120 degree；
It is wear-resisting, steel wool #0000,10N, 2000 time, 1cm2：With water contact angle 106-110 degree after mill；
Traditional mirror coating：
Originate water contact angle：40-50 degree；
It is wear-resisting, steel wool #0000,10N, 2000 time, 1cm2：Surface coating is destroyed after mill；
As can be seen that the coating of the present invention has higher abrasion resistance, hydrophobic properties of the surface.
Claims (6)
1. a kind of fluorinated hydrophobic minute surface nano paint, it is characterised in that it is made up of the raw material of following weight parts：
90-95% sulfuric acid 5-7, acetone 60-70, butoxy ethanol 2-3, trimethylene carbonate 80-90, triethanolamine oil
Sour soap 1-3, pyromellitic acid anhydride 2-4, hydrophobic dispersion liquid 16-20, terpinol 2-3,8-hydroxyquinoline 0.8-1, diaminourea two
Phenylate 0.6-1, diisopropyl ethanolamine 1-2, stabilizer 2-3, polyglyceryl fatty acid ester 2-3, ammonium fluozirconate 10-12, aluminium nitride
3-5。
2. a kind of fluorinated hydrophobic minute surface nano paint according to claim 1, it is characterised in that described stabilizer is hard
One kind in resin acid barium, zinc stearate, calcium stearate.
3. a kind of fluorinated hydrophobic minute surface nano paint according to claim 1, it is characterised in that described catalyst is pungent
Sour stannous.
4. a kind of fluorinated hydrophobic minute surface nano paint according to claim 1, it is characterised in that described hydrophobic dispersion liquid
It is made up of the raw material of following weight parts：
1H, 1H, 2H, 2H- perfluoro decyl triethoxysilane 3-4, butanethiol tin 1-2, lauryl dimethyl amine oxide 0.4-
1st, castor oil acid 2-3, polyoxyethylene oleic acid ester 0.1-0.2.
5. a kind of fluorinated hydrophobic minute surface nano paint according to claim 1,4, it is characterised in that described is hydrophobic scattered
The preparation method of liquid, comprises the following steps：
（1）Lauryl dimethyl amine oxide is taken, in the deionized water for being added to 20-30 times of its weight, is stirred, amine is obtained and disperses
Liquid；
（2）Castor oil acid is taken, in the absolute ethyl alcohol for being added to 2.8-4 times of its weight, is stirred, rise temperature is 70-75 DEG C,
Butanethiol tin is added, insulated and stirred 30-40 minutes adds polyoxyethylene oleic acid ester, stirs to normal temperature, obtain ester solution；
（3）Above-mentioned ester solution, the mixing of amine dispersion liquid are taken, stirs, adds 1H, 1H, 2H, 2H- perfluoro decyl triethoxysilicanes
Alkane, it is ultrasonic 10-20 minutes, produce the hydrophobic dispersion liquid.
6. a kind of preparation method of fluorinated hydrophobic minute surface nano paint as described in claim 1-5, it is characterised in that including with
Lower step：
（1）Pyromellitic acid anhydride is taken, in the deionized water for being added to 16-20 times of its weight, is stirred, fluorine zirconic acid is added
Ammonium, rise temperature is 70-80 DEG C, and insulated and stirred 1-2 hours after above-mentioned 90-95% sulfuric acid, completion of dropping are added dropwise, acid zirconium is obtained
Solution；
（2）Aluminium nitride is taken, in the deionized water for being added to 10-13 times of its weight, diaminodiphenyl ether is added, it is ultrasonic 4-7 minutes,
Obtain aluminium nitride dispersion liquid；
（3）Above-mentioned acid zirconium solution, the mixing of aluminium nitride dispersion liquid are taken, stirs, filters, precipitation is washed, 80-90 DEG C of vacuum
Lower dry 1-2 hours, normal temperature is cooled to, carboxylated filler is obtained；
（4）8-hydroxyquinoline is taken, in the absolute ethyl alcohol for being added to 4-7 times of its weight, is stirred, triethanolamine oleate is added
Soap, insulated and stirred 10-20 minutes at 60-70 DEG C, obtains alcohol dispersion liquid；
（5）Above-mentioned carboxylated filler is taken, is added in alcohol dispersion liquid, stirs, polyglyceryl fatty acid ester is added, stirring is equal
It is even, obtain ester dispersion liquid；
（6）Trimethylene carbonate, the mixing of ester dispersion liquid are taken, is added in acetone, stirs, be sent in reactor, plus
Enter catalyst, be passed through nitrogen, regulation temperature of reaction kettle is 35-40 DEG C, insulation reaction 2-3 hour, add butoxy ethanol, surely
Determine agent, stirring to normal temperature, discharging is mixed with remaining each raw material, ultrasonic 20-30 minutes, dehydration produces the fluorinated hydrophobic minute surface
Nano paint.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201710429049.2A CN107022287A (en) | 2017-06-08 | 2017-06-08 | A kind of fluorinated hydrophobic minute surface nano paint and preparation method thereof |
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| CN201710429049.2A CN107022287A (en) | 2017-06-08 | 2017-06-08 | A kind of fluorinated hydrophobic minute surface nano paint and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109575682A (en) * | 2018-12-28 | 2019-04-05 | 张展清 | A kind of IML ink of resistance to red ink and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103509422A (en) * | 2012-06-29 | 2014-01-15 | 3M创新有限公司 | Hydrophobic and oleophobic coating composition |
-
2017
- 2017-06-08 CN CN201710429049.2A patent/CN107022287A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103509422A (en) * | 2012-06-29 | 2014-01-15 | 3M创新有限公司 | Hydrophobic and oleophobic coating composition |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109575682A (en) * | 2018-12-28 | 2019-04-05 | 张展清 | A kind of IML ink of resistance to red ink and preparation method thereof |
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Application publication date: 20170808 |