CN107011844A - A kind of special adhesive of corrugated paper - Google Patents
A kind of special adhesive of corrugated paper Download PDFInfo
- Publication number
- CN107011844A CN107011844A CN201710217450.XA CN201710217450A CN107011844A CN 107011844 A CN107011844 A CN 107011844A CN 201710217450 A CN201710217450 A CN 201710217450A CN 107011844 A CN107011844 A CN 107011844A
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- CN
- China
- Prior art keywords
- parts
- farina
- corrugated paper
- weight
- special adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Paper (AREA)
Abstract
The invention discloses a kind of special adhesive of corrugated paper, its raw material includes by weight：50~80 parts of base material, 4~6 parts of curing agent, 10~16 parts of filler, 4~12 parts of alcohol soluble protein, 6~10 parts of nbr carboxyl terminal, poly- 0.7~1.5 part of decanedioic acid propylene glycol ester, 6~8 parts of chlorinated paraffin, 30~40 parts of expoxy propane glycerin ether.The special adhesive of corrugated paper proposed by the present invention, makes have higher peel strength between the composite bed of corrugated paper, while making the surface of corrugated paper has preferable water proofing property and ageing resistance, is difficult degumming, can extend the service life of corrugated paper, reduce its production cost.
Description
Technical field
The present invention relates to adhesive technical field, more particularly to a kind of special adhesive of corrugated paper.
Background technology
In all kinds of packagings of industrial products, packaging material turns into the main flow of packing business with corrugated paper, due to its weight
Gently, it is foldable, and cost is low, environmental protection, specification is easily changed, and can carry out high-quality printing, and can be used as after recovery can be again
Production-goods source, thus it is more and more wider using scope.But existing corrugated paper adhesive is present that moisture protection is poor, glue is stablized in itself
Property difference the problem of, the corrugated paper being bonded with it, easily occur after being moistened degumming, panel paper and corrugating media separation feelings
Condition, so as to cause corrugated case to disintegrate.
The content of the invention
The technical problem existed based on background technology, the present invention is proposed a kind of special adhesive of corrugated paper, makes corrugated paper
Composite bed between there is higher peel strength, while making the surface of corrugated paper has preferable water proofing property and ageing resistance,
Degumming is difficult, the service life of corrugated paper can be extended, its production cost is reduced.
A kind of special adhesive of corrugated paper proposed by the present invention, its raw material includes by weight：50~80 parts of base material, solidification
4~6 parts of agent, 10~16 parts of filler, 4~12 parts of alcohol soluble protein, 6~10 parts of nbr carboxyl terminal, poly- decanedioic acid propane diols
0.7~1.5 part of ester, 6~8 parts of chlorinated paraffin, 30~40 parts of expoxy propane glycerin ether.
Preferably, base material includes by weight：20~25 parts of bisphenol-s epoxy resin, tricyanic epoxy resin 10~
20 parts, 15~20 parts of farina compound.
Preferably, curing agent includes by weight：6~8 parts of AEEA, 3~5 parts of a cyanoethyl ethylenediamine, second
1~3 part of alkenyl triamine.
Preferably, filler includes by weight：6~12 parts of sepiolite powder, 8~16 parts of zeolite powder.
Preferably, farina compound is prepared using following technique：Sericite is heated up drying, polyamide wax is added
Stirring, is down to room temperature, crushes, and adds ethanol solution and stirs, adds sodium trimetaphosphate, monoxone and stir, then
Add farina to be well mixed, regulation system pH value is 8~8.8, heating stirring, application of vacuum is crushed, is dried to obtain horse
Bell sweet potato starch compound.
Preferably, farina compound is prepared using following technique：12~18 parts of sericites are heated up by weight
Dry, add 4~8 parts of polyamide wax stirrings, be down to room temperature, crush, it is that 30~40wt% ethanol is molten to add 85~95 parts of concentration
Liquid stirs, and adds 4~8 parts of sodium trimetaphosphates, 1~3 part of monoxone and stirs, is subsequently added into 20~30 portions of potatos
Starch is well mixed, and regulation system pH value is 8~8.8, and heating stirring, application of vacuum is crushed, and is dried to obtain farina and is answered
Compound.
Preferably, farina compound is prepared using following technique：12~18 parts of sericites are heated up by weight
To 115~125 DEG C of dry 7~10h, add 4~8 parts of polyamide waxes and stir 4~8h, whipping temp is 110~120 DEG C, stirring
Speed is 1000~1200r/min, is down to room temperature, is crushed, and adds 85~95 parts of concentration and is stirred for 30~40wt% ethanol solutions
Uniformly, 4~8 parts of sodium trimetaphosphates, 1~3 part of monoxone are added to stir, 20~30 parts of farinas is subsequently added into and mixes
Close uniform, regulation system pH value is 8~8.8, be warming up to 60~68 DEG C of 25~45min of stirring, 125~150 DEG C of applications of vacuum 15
~20min, crushes, is dried to obtain farina compound.
The present invention is used as main body using farina compound and bisphenol-s epoxy resin, tricyanic epoxy resin
Material, zeolite powder, sepiolite powder are added using AEEA, a cyanoethyl ethylenediamine, vinyl triamine as curing system
As filler, stable jelly can be formed, even if at relatively high temperatures, viscosity intensity is also high, and good waterproof performance, is difficult
Degumming.
In farina compound, sericite is hydrophilic and oleophobic after pretreatment, through polyamide wax coating modification, high
The polar group of polyamide wax is combined with sericite surface hydroxyl after temperature shearing, and not only mobility is fabulous, and and farina
Compatibility it is good, through sodium trimetaphosphate, monoxone crosslinking etherificate after, carry out vacuum high-temperature processing, formed space net structure, point
Mutually wind and run through between subchain, enable that farina compound is not only wear-resisting, anti acid alkali performance is excellent, and adhesive property
It is extremely excellent.
The present invention is using sepiolite powder, zeolite powder and farina compound complex role, in expoxy propane glycerin ether
In the presence of, good dispersion is flowed, makes the wellability of the present invention good, smears uniform, even if at high temperature, toughness is also fabulous, is resisted
Peeling effect is good, and storage time is extremely long.
The present invention is applied in corrugated paper, makes have higher peel strength between the composite bed of corrugated paper, while making watt
The surface of stupefied paper has preferable water proofing property and ageing resistance, can extend the service life of corrugated paper, reduces its production cost.
Embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of special adhesive of corrugated paper proposed by the present invention, its raw material includes by weight：50 parts of base material, curing agent 6
Part, 10 parts of filler, 12 parts of alcohol soluble protein, 6 parts of nbr carboxyl terminal, poly- 1.5 parts of decanedioic acid propylene glycol ester, chlorinated paraffin 6
Part, 40 parts of expoxy propane glycerin ether.
Embodiment 2
A kind of special adhesive of corrugated paper proposed by the present invention, its raw material includes by weight：80 parts of base material, curing agent 4
Part, 16 parts of filler, 4 parts of alcohol soluble protein, 10 parts of nbr carboxyl terminal, poly- 0.7 part of decanedioic acid propylene glycol ester, chlorinated paraffin 8
Part, 30 parts of expoxy propane glycerin ether.
Base material includes by weight：20 parts of bisphenol-s epoxy resin, 20 parts of tricyanic epoxy resin, farina
15 parts of compound.
Curing agent includes by weight：8 parts of AEEA, 3 parts of a cyanoethyl ethylenediamine, 3 parts of vinyl triamine.
Filler includes by weight：6 parts of sepiolite powder, 16 parts of zeolite powder.
Farina compound is prepared using following technique：Sericite is heated up drying, polyamide wax stirring, drop is added
To room temperature, crush, add ethanol solution and stir, add sodium trimetaphosphate, monoxone and stir, be subsequently added into Ma Ling
Sweet potato starch is well mixed, and regulation system pH value is 8~8.8, and heating stirring, application of vacuum is crushed, is dried to obtain farina
Compound.
Embodiment 3
A kind of special adhesive of corrugated paper proposed by the present invention, its raw material includes by weight：60 parts of base material, curing agent
5.5 parts, 12 parts of filler, 10 parts of alcohol soluble protein, 7 parts of nbr carboxyl terminal, poly- 1.3 parts of decanedioic acid propylene glycol ester, chlorination stone
6.5 parts of wax, 38 parts of expoxy propane glycerin ether.
Base material includes by weight：25 parts of bisphenol-s epoxy resin, 10 parts of tricyanic epoxy resin, farina
20 parts of compound.
Curing agent includes by weight：6 parts of AEEA, 5 parts of a cyanoethyl ethylenediamine, 1 part of vinyl triamine.
Filler includes by weight：12 parts of sepiolite powder, 8 parts of zeolite powder.
Farina compound is prepared using following technique：By weight by 15 parts of sericites heating dryings, 6 parts are added
Polyamide wax is stirred, and is down to room temperature, is crushed, and it is that 35wt% ethanol solutions stir to add 90 parts of concentration, add 6 part three it is inclined
Sodium phosphate, 2 parts of monoxones stir, and are subsequently added into 25 parts of farinas and are well mixed, and regulation system pH value is 8~8.8,
Heating stirring, application of vacuum is crushed, is dried to obtain farina compound.
Embodiment 4
A kind of special adhesive of corrugated paper proposed by the present invention, its raw material includes by weight：70 parts of base material, curing agent
4.5 parts, 14 parts of filler, 8 parts of alcohol soluble protein, 9 parts of nbr carboxyl terminal, poly- 1 part of decanedioic acid propylene glycol ester, chlorinated paraffin
7.8 parts, 32 parts of expoxy propane glycerin ether.
Base material includes by weight：22 parts of bisphenol-s epoxy resin, 16 parts of tricyanic epoxy resin, farina
16 parts of compound.
Curing agent includes by weight：7.5 parts of AEEA, 3.5 parts of a cyanoethyl ethylenediamine, vinyl triamine
2.5 part.
Filler includes by weight：8 parts of sepiolite powder, 14 parts of zeolite powder.
Farina compound is prepared using following technique：12 parts of sericites are warming up to 125 DEG C of dryings by weight
7h, adds 8 parts of polyamide wax stirring 4h, whipping temp is 120 DEG C, and mixing speed is 1000r/min, is down to room temperature, is crushed, plus
Enter 95 parts of concentration to stir for 30wt% ethanol solutions, add 8 parts of sodium trimetaphosphates, 1 part of monoxone and stir, then
Add 30 parts of farinas to be well mixed, regulation system pH value is 8~8.8, be warming up to 60 DEG C of stirring 45min, 125 DEG C of vacuum
20min is handled, crushes, is dried to obtain farina compound.
Embodiment 5
A kind of special adhesive of corrugated paper proposed by the present invention, its raw material includes by weight：65 parts of base material, curing agent 5
Part, 13 parts of filler, 9 parts of alcohol soluble protein, 8 parts of nbr carboxyl terminal, poly- 1.2 parts of decanedioic acid propylene glycol ester, chlorinated paraffin 7
Part, 35 parts of expoxy propane glycerin ether.
Base material includes by weight：24 parts of bisphenol-s epoxy resin, 12 parts of tricyanic epoxy resin, farina
18 parts of compound.
Curing agent includes by weight：6.5 parts of AEEA, 4.5 parts of a cyanoethyl ethylenediamine, vinyl triamine
1.5 part.
Filler includes by weight：10 parts of sepiolite powder, 10 parts of zeolite powder.
Farina compound is prepared using following technique：18 parts of sericites are warming up to 115 DEG C of dryings by weight
10h, adds 4 parts of polyamide wax stirring 8h, whipping temp is 110 DEG C, and mixing speed is 1200r/min, is down to room temperature, is crushed,
It is that 40wt% ethanol solutions stir to add 85 parts of concentration, adds 4 parts of sodium trimetaphosphates, 3 parts of monoxones and stirs, connects
20 parts of farinas of addition to be well mixed, regulation system pH value is 8~8.8, be warming up to 68 DEG C of stirring 25min, 150 DEG C true
15min is managed in vacancy, is crushed, is dried to obtain farina compound.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (7)
1. a kind of special adhesive of corrugated paper, it is characterised in that its raw material includes by weight：50~80 parts of base material, curing agent 4
~6 parts, 10~16 parts of filler, 4~12 parts of alcohol soluble protein, 6~10 parts of nbr carboxyl terminal, poly- decanedioic acid propylene glycol ester
0.7~1.5 part, 6~8 parts of chlorinated paraffin, 30~40 parts of expoxy propane glycerin ether.
2. the special adhesive of corrugated paper according to claim 1, it is characterised in that base material includes by weight：Bisphenol S type ring
20~25 parts of oxygen tree fat, 10~20 parts of tricyanic epoxy resin, 15~20 parts of farina compound.
3. the special adhesive of corrugated paper according to claim 1 or claim 2, it is characterised in that curing agent includes by weight：Hydroxyl second
6~8 parts of base ethylenediamine, 3~5 parts of a cyanoethyl ethylenediamine, 1~3 part of vinyl triamine.
4. according to the special adhesive of any one of the claim 1-3 corrugated papers, it is characterised in that filler is wrapped by weight
Include：6~12 parts of sepiolite powder, 8~16 parts of zeolite powder.
5. according to the special adhesive of any one of the claim 1-4 corrugated papers, it is characterised in that farina compound is adopted
Prepared with following technique：Sericite is heated up drying, polyamide wax stirring is added, is down to room temperature, crush, ethanol solution is added and stirs
Mix uniform, add sodium trimetaphosphate, monoxone and stir, be subsequently added into farina and be well mixed, regulation system pH
It is worth for 8~8.8, heating stirring, application of vacuum is crushed, is dried to obtain farina compound.
6. according to the special adhesive of any one of the claim 1-5 corrugated papers, it is characterised in that farina compound is adopted
Prepared with following technique：By weight by 12~18 parts of sericites heating dryings, 4~8 parts of polyamide waxes stirrings are added, room is down to
Temperature, is crushed, and it is that 30~40wt% ethanol solutions stir to add 85~95 parts of concentration, adds 4~8 parts of sodium trimetaphosphates, 1
~3 parts of monoxones stir, and are subsequently added into 20~30 parts of farinas and are well mixed, and regulation system pH value is 8~8.8,
Heating stirring, application of vacuum is crushed, is dried to obtain farina compound.
7. according to the special adhesive of any one of the claim 1-6 corrugated papers, it is characterised in that farina compound is adopted
Prepared with following technique：12~18 parts of sericites are warming up to 115~125 DEG C of dry 7~10h by weight, 4~8 parts are added
Polyamide wax stirs 4~8h, and whipping temp is 110~120 DEG C, and mixing speed is 1000~1200r/min, is down to room temperature, powder
Broken, it is that 30~40wt% ethanol solutions stir to add 85~95 parts of concentration, add 4~8 parts of sodium trimetaphosphates, 1~3 part
Monoxone stirs, and is subsequently added into 20~30 parts of farinas and is well mixed, regulation system pH value is 8~8.8, is warming up to
60~68 DEG C of stirrings 25~45min, 125~150 DEG C of 15~20min of application of vacuum, are crushed, and are dried to obtain farina and are combined
Thing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710217450.XA CN107011844A (en) | 2017-04-05 | 2017-04-05 | A kind of special adhesive of corrugated paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710217450.XA CN107011844A (en) | 2017-04-05 | 2017-04-05 | A kind of special adhesive of corrugated paper |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107011844A true CN107011844A (en) | 2017-08-04 |
Family
ID=59445889
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710217450.XA Pending CN107011844A (en) | 2017-04-05 | 2017-04-05 | A kind of special adhesive of corrugated paper |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107011844A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1310751A (en) * | 1998-07-23 | 2001-08-29 | 马铃薯及衍生产品合作销售生产阿韦贝公司 | Adhesive composition |
| CN103232823A (en) * | 2013-04-07 | 2013-08-07 | 青阳县华鼎包装有限公司 | Package-use adhesive comprising nano-grade sepiolite, and preparation method thereof |
| CN106318301A (en) * | 2016-08-20 | 2017-01-11 | 界首市鑫旺彩印研发中心 | Degradable environment-friendly adhesive for packaging boxes |
-
2017
- 2017-04-05 CN CN201710217450.XA patent/CN107011844A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1310751A (en) * | 1998-07-23 | 2001-08-29 | 马铃薯及衍生产品合作销售生产阿韦贝公司 | Adhesive composition |
| US6596860B1 (en) * | 1998-07-23 | 2003-07-22 | Cooperatieve Verkoop-En Productievereniging Van Aardappelmeel En Derivaten Avebe B.A. | Adhesive composition |
| CN103232823A (en) * | 2013-04-07 | 2013-08-07 | 青阳县华鼎包装有限公司 | Package-use adhesive comprising nano-grade sepiolite, and preparation method thereof |
| CN106318301A (en) * | 2016-08-20 | 2017-01-11 | 界首市鑫旺彩印研发中心 | Degradable environment-friendly adhesive for packaging boxes |
Non-Patent Citations (5)
| Title |
|---|
| 何小维: "《碳水化合物功能材料》", 31 January 2007, 中国轻工业出版社 * |
| 冯启明: "《非金属矿产加工与开发利用》", 30 December 2010, 地质出版社 * |
| 张向宇: "《胶接与胶补》", 31 March 1979, 湖南科学技术出版社 * |
| 徐峰 王惠明: "《建筑涂料》", 31 August 2007, 中国建筑工业出版社 * |
| 黄锐: "《塑料工程手册（上册）》", 30 April 2000, 机械工业出版社 * |
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Application publication date: 20170804 |