CN107010808A - A kind of method for handling domestic sludge - Google Patents

A kind of method for handling domestic sludge Download PDF

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Publication number
CN107010808A
CN107010808A CN201710311579.7A CN201710311579A CN107010808A CN 107010808 A CN107010808 A CN 107010808A CN 201710311579 A CN201710311579 A CN 201710311579A CN 107010808 A CN107010808 A CN 107010808A
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China
Prior art keywords
domestic sludge
mixture
temperature
handling
carried out
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CN201710311579.7A
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Chinese (zh)
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CN107010808B (en
Inventor
李苏卿
李文东
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Li Suqing
Li Wendong
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Zhangjiagang Best Ecology Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/10Treatment of sludge; Devices therefor by pyrolysis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/004Sludge detoxification
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/121Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/121Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering
    • C02F11/122Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering using filter presses
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/14Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/02Agglomerated materials, e.g. artificial aggregates
    • C04B18/027Lightweight materials
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/60Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Water Supply & Treatment (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Civil Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Structural Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Treatment Of Sludge (AREA)

Abstract

The invention discloses a kind of method for handling domestic sludge, high-temperature retorting carbonization and high temperature glazing are carried out after to domestic sludge deep dehydration, after it is mixed with auxiliary material, the ceramic product available for sale has been made.The ceramic product can be used for configuration construction timber concrete, realizes harmless treatment and the recycling of domestic sludge, turns waste into wealth.

Description

A kind of method for handling domestic sludge
Technical field
The present invention relates to a kind of method for handling domestic sludge.
Background technology
With the high speed development of social economy, the amount of domestic sludge also cumulative year after year.It is existing to be used to handle domestic sludge Method be generally Sludge landfill technology, sludge composting technology and sludge incineration technology.Dehydration rate of these three technologies to sludge Only up to 60% or so, sludge incineration technology can cause secondary pollution, and the impervious barrier used in Sludge landfill technology is water Mud, underground water pollution can be caused after cement ruptures.
Meanwhile, these three technologies can discharge toxic gas and waste residue, and the recovery of utilization and heavy metal to resource is almost It is zero, extra economic benefit will not be produced substantially, i.e., can not accomplish innoxious, the recycling treatment to domestic sludge.
The content of the invention
It is an object of the invention to provide a kind of method for handling domestic sludge, accomplish to the harmless of domestic sludge Change, recycling treatment.
To reach above-mentioned purpose, the technical solution adopted by the present invention is:
A kind of method for handling domestic sludge, comprises the following steps:
(1)Stirring dehydration:Domestic sludge and dehydrating agent are mixed into stirring, made by the dehydrating agent micro- in the domestic sludge Biological cell wall is ruptured, and the domestic sludge is dehydrated;
(2)Extruding filtering:Domestic sludge extruding after dehydration is filtered into solid-like;
(3)High-frequency microwave detoxifies:The domestic sludge of solid-like is carried out disinfection sterilization by microwave, generation is had into poison gas Body exports and collects processing;
(4)Coagulation dispensing:Auxiliary material formation mixture is added into the domestic sludge after disinfection;
(5)High-temperature retorting is carbonized:High-temperature retorting carbonization is carried out to the mixture, carbon molecules net is made into, by the domestic sludge In heavy metal particles be solidificated in the carbon molecules net, formed carbonized mixture;
(6)High temperature glazing:High temperature glazing is carried out to the carbonized mixture, the carbonized mixture is wrapped up by glaze layer, is formed Haydite.
Preferably, in the step(3)Before, the domestic sludge of solid-like is crushed into powdering.
Preferably, in the step(4)Afterwards, the mixture is squeezed into graininess.
Preferably, in the step(6)Afterwards, concrete is configured by aggregate of the haydite.
Preferably, in the step(3)In, pass sequentially through the life of infrared ray, microwave, ultraviolet to solid-like dirty Mud carries out disinfection sterilization.
Preferably, in the step(5)In, high-temperature retorting carbonization, the carbon are carried out to the mixture by the kiln that is carbonized Feed direction of the temperature along the mixture changed in kiln gradually rises, the temperature in the carbonization kiln 300 DEG C -600 DEG C it Between.
Preferably, in the step(6)In, high temperature coloured glaze glazing, institute are carried out to the carbonized mixture by glaze kiln The temperature in glaze kiln is stated between 1100 DEG C -1300 DEG C.
Preferably, in the step(3)In, by the toxic gas by being collected processing again after heavy grey room.
Preferably, in the step(4)In, the auxiliary material includes silica, alundum (Al2O3), di-iron trioxide.
Due to the utilization of above-mentioned technical proposal, the present invention has following advantages compared with prior art:A kind of use of the invention In the method for processing domestic sludge, after to domestic sludge deep dehydration, high-temperature retorting carbon is carried out after it is mixed with auxiliary material Change and high temperature glazing, the ceramic product available for sale has been made.The ceramic product can be used for configuration construction timber concrete, real Harmless treatment and the recycling of domestic sludge are showed, have turned waste into wealth.
Embodiment
Technical scheme is further elaborated with reference to specific embodiment.
A kind of method for handling domestic sludge, comprises the following steps:
(1)Stirring dehydration:Domestic sludge and dehydrating agent are put into stirring pool and mix stirring, is made by dehydrating agent in domestic sludge Microorganism wall rupture, to domestic sludge carry out deep dehydration;
(2)Extruding filtering:Domestic sludge and water after dehydration is passed through in filter press together, by setting the pressure in filter press Parameter, solid-like is filtered into by domestic sludge extruding;In the present embodiment, by the filter press, three points of domestic sludge decrement is made Two, reach the purpose of deep dehydration, dewatered sludge;After the step is to the dehydration of domestic sludge, its moisture content as little as 45% with Under, detoxification.Sterilization rate reaches more than 70%;Domestic sludge is pressed into by filter cake by filter press;
(3)Domestic sludge is crushed by powdering and/or small bulk by cake breaker;
(4)High-frequency microwave detoxifies:The domestic sludge after broken is carried out disinfection sterilization by microwave, the toxic gas of generation is led Go out and collect processing;Infrared ray, microwave, ultraviolet is passed sequentially through to carry out disinfection to the domestic sludge after broken sterilization;The step Principle be according to infrared ray, microwave, ultraviolet disinfection characteristic, using high-frequency microwave converter technique, to domestic sludge Organic molecule carry out chain rupture formula decomposition, short molecular chain is become by long chain, thus change its organic molecule structure and Chemical property, departs from toxic gas, reaches the purpose of disinfection, and its sterilization effect is more than 90%;
(5)Poison gas processing:Toxic gas is subjected to ash fall by heavy grey room, toxic gas is sent into again recycled afterwards Handled in equipment;The recycling equipment includes acid & alkali liquid scrubbing tower, and processing method includes plasma, activated carbon, light and touched The technologies such as matchmaker;
(6)Coagulation dispensing:Auxiliary material formation mixture is added into the domestic sludge after disinfection;In the present embodiment, this is auxiliary Material includes silica, alundum (Al2O3), di-iron trioxide;
(7)The mixture is squeezed into graininess by specification size as required;
(8)High-temperature retorting is carbonized:High-temperature retorting carbonization is carried out to mixture, makes granular mixture expanded, is made into carbon molecules Net, the heavy metal particles in domestic sludge are solidificated in carbon molecules net, form carbonized mixture;Heavy metal particles after solidification It will not again escape and pollute;In the present embodiment, high-temperature retorting carbonization, the carbon are carried out to granular mixture by the kiln that is carbonized The temperature changed in kiln gradually rises along the feed direction of granular mixture, and the temperature of the carbonization kiln feed end is 300 DEG C, the carbon The temperature for changing kiln discharge end is 600 DEG C;
(9)High temperature glazing:High temperature glazing is carried out to carbonized mixture, carbonized mixture is wrapped up by glaze layer, haydite is formed;Pass through Glaze layer wraps up carbonized mixture, completely eliminated organic contamination, heavy metal particles is not escaped again, has reached permanent cured heavy The purpose of metallic particles;In the present embodiment, carbonized mixture is carried out in high temperature coloured glaze glazing, the glaze kiln by glaze kiln Temperature between 1100 DEG C -1300 DEG C;By carrying out high temperature coloured glaze glazing to carbonized mixture, carbonized particles are not only increased Hardness, while protecting carbon molecules net;And water imbibition is reduced, heat-insulating property is improved;Haydite is exported from glaze kiln When, its temperature is at 800 DEG C or so;By in step(6)Middle addition silica, adds the hardness of haydite;By in step (6)Middle addition alundum (Al2O3) and di-iron trioxide, improve the anti-corrosive properties of haydite;
(10)Light aggregate concrete is configured by aggregate of the haydite, water used herein can use step(2)In obtained dirt Water, realizes the zero-emission of waste water;Using building block and the shaping mechanism of concrete foaming technique into lightweight concrete building block and self-insurance Warm concrete compound block;Harmless treatment and the recycling of domestic sludge are realized, is turned waste into wealth.
Haydite prepared by the present embodiment method, its bulk density is 730kg/m3;Its cylindrical compress strength is 6.0Mpa;Per hour Water absorption rate is only 5%;Coefficient of softing is 0.9;Grain type coefficient is 1.6.
The above embodiments merely illustrate the technical concept and features of the present invention, and its object is to allow person skilled in the art Scholar can understand present disclosure and be carried out, and it is not intended to limit the scope of the present invention, all according to the present invention The equivalent change or modification that Spirit Essence is made, should all cover within the scope of the present invention.

Claims (9)

1. a kind of method for handling domestic sludge, it is characterised in that:Comprise the following steps:
(1)Stirring dehydration:Domestic sludge and dehydrating agent are mixed into stirring, made by the dehydrating agent micro- in the domestic sludge Biological cell wall is ruptured, and the domestic sludge is dehydrated;
(2)Extruding filtering:Domestic sludge extruding after dehydration is filtered into solid-like;
(3)High-frequency microwave detoxifies:The domestic sludge of solid-like is carried out disinfection sterilization by microwave, generation is had into poison gas Body exports and collects processing;
(4)Coagulation dispensing:Auxiliary material formation mixture is added into the domestic sludge after disinfection;
(5)High-temperature retorting is carbonized:High-temperature retorting carbonization is carried out to the mixture, carbon molecules net is made into, by the domestic sludge In heavy metal particles be solidificated in the carbon molecules net, formed carbonized mixture;
(6)High temperature glazing:High temperature glazing is carried out to the carbonized mixture, the carbonized mixture is wrapped up by glaze layer, is formed Haydite.
2. a kind of method for handling domestic sludge according to claim 1, it is characterised in that:In the step(3) Before, the domestic sludge of solid-like is crushed into powdering.
3. a kind of method for handling domestic sludge according to claim 1, it is characterised in that:In the step(4) Afterwards, the mixture is squeezed into graininess.
4. a kind of method for handling domestic sludge according to claim 1, it is characterised in that:In the step(6) Afterwards, concrete is configured by aggregate of the haydite.
5. a kind of method for handling domestic sludge according to claim 1, it is characterised in that:In the step(3) In, pass sequentially through infrared ray, microwave, ultraviolet and the domestic sludge of solid-like is carried out disinfection sterilization.
6. a kind of method for handling domestic sludge according to claim 1, it is characterised in that:In the step(5) In, temperature the sending along the mixture in high-temperature retorting carbonization, the carbonization kiln is carried out to the mixture by the kiln that is carbonized Material direction gradually rises, and the temperature in the carbonization kiln is between 300 DEG C -600 DEG C.
7. a kind of method for handling domestic sludge according to claim 1, it is characterised in that:In the step(6) In, high temperature coloured glaze glazing is carried out to the carbonized mixture by glaze kiln, the temperature in the glaze kiln is at 1100 DEG C -1300 Between DEG C.
8. a kind of method for handling domestic sludge according to claim 1, it is characterised in that:In the step(3) In, by the toxic gas by being collected processing again after heavy grey room.
9. a kind of method for handling domestic sludge according to claim 1, it is characterised in that:In the step(4) In, the auxiliary material includes silica, alundum (Al2O3), di-iron trioxide.
CN201710311579.7A 2017-05-05 2017-05-05 Method for treating domestic sludge Active CN107010808B (en)

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CN107010808B CN107010808B (en) 2020-08-04

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109485232A (en) * 2018-12-12 2019-03-19 河南力诚环保科技有限公司 A kind of medicament for deeply dehydrating sludge, method and device
CN114835470A (en) * 2022-04-08 2022-08-02 广州市净水有限公司 Method for preparing ceramic artware by utilizing dried sludge
CN115707674A (en) * 2022-11-02 2023-02-21 中建能源管理(辽宁)有限公司 Method for treating domestic sludge by fermenting ultrahigh-temperature aerobic microorganisms

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101792247A (en) * 2010-03-19 2010-08-04 杭州新源环境工程有限公司 Sludge treatment method capable of combining powerful dehydration with low-temperature mummification
CN102491731A (en) * 2011-12-08 2012-06-13 复旦大学 Preparation method of biological ceramsite
CN102875003A (en) * 2012-11-05 2013-01-16 天津城市建设学院 Integrated technology of thermal decomposing, dry distilling and gasifying sludge and preparing of ceramsite

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101792247A (en) * 2010-03-19 2010-08-04 杭州新源环境工程有限公司 Sludge treatment method capable of combining powerful dehydration with low-temperature mummification
CN102491731A (en) * 2011-12-08 2012-06-13 复旦大学 Preparation method of biological ceramsite
CN102875003A (en) * 2012-11-05 2013-01-16 天津城市建设学院 Integrated technology of thermal decomposing, dry distilling and gasifying sludge and preparing of ceramsite

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
段光复: "《电镀废水处理及回用技术手册》", 30 June 2016 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109485232A (en) * 2018-12-12 2019-03-19 河南力诚环保科技有限公司 A kind of medicament for deeply dehydrating sludge, method and device
CN114835470A (en) * 2022-04-08 2022-08-02 广州市净水有限公司 Method for preparing ceramic artware by utilizing dried sludge
CN115707674A (en) * 2022-11-02 2023-02-21 中建能源管理(辽宁)有限公司 Method for treating domestic sludge by fermenting ultrahigh-temperature aerobic microorganisms

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Address before: 215699, No. 10, Tang Qiao Road, Zhangjiagang Economic Development Zone (South District, Suzhou, Jiangsu)

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