CN106995256A - A kind of handling process of starch wastewater - Google Patents

A kind of handling process of starch wastewater Download PDF

Info

Publication number
CN106995256A
CN106995256A CN201610049917.XA CN201610049917A CN106995256A CN 106995256 A CN106995256 A CN 106995256A CN 201610049917 A CN201610049917 A CN 201610049917A CN 106995256 A CN106995256 A CN 106995256A
Authority
CN
China
Prior art keywords
water outlet
waste water
pond
starch wastewater
biochemical denitrification
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610049917.XA
Other languages
Chinese (zh)
Inventor
郭晓娅
年跃刚
闫海红
殷勤
高鹏
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chinese Research Academy of Environmental Sciences
Original Assignee
Chinese Research Academy of Environmental Sciences
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chinese Research Academy of Environmental Sciences filed Critical Chinese Research Academy of Environmental Sciences
Priority to CN201610049917.XA priority Critical patent/CN106995256A/en
Publication of CN106995256A publication Critical patent/CN106995256A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5281Installations for water purification using chemical agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F2001/007Processes including a sedimentation step
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/28Anaerobic digestion processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes
    • C02F3/301Aerobic and anaerobic treatment in the same reactor

Abstract

The present invention provides a kind of handling process of starch wastewater, including two kinds of processing modes.The first is that starch wastewater passes through " preliminary sedimentation tank+coagulative precipitation tank+hydrolysis acidification regulating reservoir+anaerobic reactor+biochemical denitrification pond+second pond ", wherein laying pipeline connection between preliminary sedimentation tank water exit position and biochemical denitrification pond.Second is that waste water passes through " preliminary sedimentation tank+hydrolysis acidification regulating reservoir+coagulative precipitation tank+anaerobic reactor+biochemical denitrification pond+second pond ", wherein laying pipeline connection between hydrolysis acidification regulating reservoir water exit position and biochemical denitrification pond.Two ways using coagulative precipitation tank be placed in pretreatment stage and biochemical denitrification pond introduce starch wastewater treatment during node waste water as biochemical denitrification pond supplementary carbon source.Enterprise can select suitable processing mode according to itself waste water quality and capital construction condition.The starch wastewater treatment technique that the present invention is provided, improves system denitrogenation dephosphorizing efficiency, and operating cost economical rationality realizes the recycling of waste water.

Description

A kind of handling process of starch wastewater
Technical field
The invention belongs to Treatment of Industrial Water and waste water reclaiming technical field.Specifically related to a kind of handling process of starch wastewater With the method for recycling.
Background technology
China is Starch Production and consumption big country, since reform and opening-up, China's starch total output by 1978 280,000 Ton develops into 23,050,000 tons in 2013, and yield is only second to the U.S., occupies second place of the world.With continuous adjustment production pattern, The level of production of the import of advanced technology, China's starch and its process deeply industry is obviously improved.But undeniable to be, starch Waste water is still one of waste water of pollution most serious in food industry.The middle-size and small-size starch number of the enterprise of China is numerous, comprehensively utilizes ability Relatively low, starch recoveries in its production technology are relatively low, loss rate of macaroni is high, ton product water consume and the steam consumption are but higher by greatly 100,000 Tonne starch factory, wastewater discharge is big.Containing organic matters such as much starch, protein, carbohydrate, fat in the waste water of discharge, Belong to high-concentration acidic wastewater organic wastewater (CODcrConcentration is up to 30,000 more than mg/L).Contain more dissolved organic matter in waste water, Increase the intractability of waste water.If the technique without efficient stable is handled it, enterprise periphery and regional environment will be caused Rapid deterioration.
Generally use both at home and abroad at present using anaerobic-aerobic and combine biological treatment as main processing mode processing starch wastewater.This COD can effectively be removed in practical engineering application by planting technique, but system anti impulsion load is poor, it is difficult to ensure that pollutant is stable Efficiently remove.Current domestic all starch enterprises have built up waste water disposal facility, but in Facilities Construction, scale is less to form sediment Powder enterprise, fund input is small, causes treatment facility scarce capacity, and the processing of many wastewater treatment engineerings and clean-up effect are undesirable. Larger starch enterprise, though pollution reducing facility is complete, compliance rate is also higher, exist engineering construction investment it is big, The problems such as running expense is high.With the raising of energy-saving and emission-reduction requirement, starch processing enterprise will face higher discharge standard, reinforcing Denitrogenation dephosphorizing turns into inevitable requirement.Raising system turns into TN and TP removal effect to be needed badly in transformation sewage treatment process The problem of solution.
In the technology for improving system nitric efficiency, the selection of biochemical denitrification pond internal carbon source and add as key link.Mesh Preceding to handle waste water based on anaerobic-aerobic combination biological treatment compared with multiple enterprises, water outlet COD can meet emission request, But the problem of often there is nitrogen and exceeded phosphorus.It is primarily due to that anaerobic reactor water outlet C/N is relatively low, carbon source deficiency result in Follow-up aerobic-anaerobic technique denitrogenation dephosphorizing efficiency is not good enough, it is therefore desirable to adds supplementary carbon source into aerobic-anaerobic workshop section.Conventional carbon Source includes methanol, ethanol etc., and such carbon source can be quickly utilized by the microorganisms, but be limited by cost, transport and security problems, It is difficult to promote the use of in sewage treatment plant.The many researchers of recent domestic find cheap carbon source by number of ways.Such as beer Wine waste water, cotton etc..This kind of carbon source can meet efficient denitrification rate, can also reduce cost of sewage disposal, while can also realize useless The recycling of thing.
In processing starch wastewater dephosphorization technique, bioanalysis phosphor-removing effect is limited, generally in waste water treatment process end, profit Use chemical method reinforced phosphor-removing.But because the suitable use condition of flocculant is more harsh, some flocculants are limited in end process In use or add further processing cost.For example Wu Hao exists《Research of the different flocculants to starch wastewater phosphor-removing effect》 Described in, in the removal effect of total phosphorus during the different flocculants investigated are to starch wastewater biochemical treatment water outlet, iron chloride is removed Phosphorus best results, but due to after processing water outlet pH in acidity, do not reach discharging standards requirement, need and calcium chloride be combined and be made With.
Organic concentration in starch wastewater is high, small toxicity, is the perfect medium for cultivating microorganism.Both at home and abroad using all kinds of Starch wastewater, such as potato starch wastewater, corn starch wastewater, sago starch waste water cultivate a variety of functional microorganisms, such as micro- Biological insecticides Dipel (Bacillus thuringiensis), bio-feritlizer Paenibacillus polymyxa (Paenibacillus ) and microbial flocculant etc. polymyxa.Organic matter in these research explanation starch wastewaters is easy to be utilized by microorganism.
The present invention in view of the high efficiency of coagulation for phosphorus removal, and starch wastewater high biochemical, propose a kind of strengthening treatment process. So far, through domestic and foreign literature and patent retrieval, do not inquire and starch wastewater is handled with handling process proposed by the present invention Report.The proposition of the present invention provides new foundation for the processing of starch wastewater.
The content of the invention
The brief overview on the present invention is given below, to provide the basic comprehension on certain aspects of the invention. It should be appreciated that this general introduction is not the exhaustive general introduction on the present invention.It is not intended to determine that the present invention's is crucial or again Part is wanted, nor is it intended to limit the scope of the present invention.Its purpose only provides some concepts in simplified form, is made with this For the preamble in greater detail discussed later.
The present invention provides a kind of handling process of starch wastewater, it is characterised in that:It includes following two modes:
(1) high-concentration waste water is first passed through the protein that preliminary sedimentation tank removes partial contamination thing and reclaims precipitation by pretreatment stage, its Secondary entrance coagulative precipitation tank carries out coagulating sedimentation and goes dephosphorization and suspension, furthermore enters " hydrolysis acidification regulating reservoir+anaerobic reactor ", Then anaerobic reactor water outlet enters the progress biochemical denitrification processing of biochemical denitrification pond together with the preliminary sedimentation tank water outlet of part, last biochemical de- The water outlet of nitrogen pond enters second pond, water outlet is stably reached discharge standard.
(2) high-concentration waste water is first passed through " preliminary sedimentation tank+hydrolysis acidification regulating reservoir " removal partial contamination thing, returned by pretreatment stage The protein and regulation pH of precipitation are received, carrying out coagulating sedimentation subsequently into coagulative precipitation tank goes dephosphorization and suspension, subsequently enters Anaerobic reactor, then anaerobic reactor water outlet enters biochemical denitrification with part preliminary sedimentation tank water outlet or together with hydrolysis acidification pool water outlet Pond carries out biochemical denitrification processing, and the water outlet of last biochemical denitrification pond enters second pond, water outlet is stably reached discharge standard.
A kind of handling process of above-mentioned starch wastewater, it is characterised in that:Aforesaid way (1) or mode (2) are not exist together Reason mode, enterprise can voluntarily select according to itself condition of water quality, capital construction condition, when there is multiple preliminary sedimentation tanks, can will it is therein just Heavy pond transform coagulative precipitation tank as, is now adapted to selection mode (1), and selection mode (2) is adapted to when biochemical denitrification pool volume is smaller.
Enterprise can select suitable mode according to condition of water quality, capital construction condition.Have in investigation Some Enterprises have two and more than Preliminary sedimentation tank, if land used is nervous as, last preliminary sedimentation tank can be transform to coagulative precipitation tank, now suitable selection mode (1); Node waste water, which is introduced, as carbon source will certainly increase waste water water, and the increase of water will shorten waterpower of the waste water in biochemical denitrification pond Residence time.If biochemical denitrification pool volume is smaller, it is too short to be easily caused the residence time, causes denitrification effect poor.In view of water Solution acidifying regulating reservoir water outlet biodegradability is better than preliminary sedimentation tank water outlet, and waste water introduction volume is small, if therefore enterprise's biochemical denitrification pool volume compared with It is small, then suitably carry out wastewater treatment from mode (2).
A kind of above-mentioned starch wastewater, it is characterised in that high COD, the high P acid waste water produced in starch process.
A kind of handling process of above-mentioned starch wastewater, it is characterised in that:Described in aforesaid way (1) or mode (2) just Heavy pond is used for the protein for removing the partial contamination thing in waste water and reclaiming precipitation.
A kind of handling process of above-mentioned starch wastewater, it is characterised in that:Mixed described in aforesaid way (1) or mode (2) Solidifying sedimentation basin, for going dephosphorization and suspension, the hydrolysis acidification regulating reservoir, its water outlet pH is faintly acid, neutral or weak base Property.
Coagulative precipitation tank is set to be used to go dephosphorization and suspension purpose, primarily to solving the problems, such as three below.One be because Carry out water pollutant especially SS excessive concentrations for starch wastewater and fluctuation range is larger, cause anaerobic reactor to stablize and transport OK, therefore oil removal is removed;Two be the easy fouling of anaerobic reactor pipeline, blocks pipeline.It is primarily due to protein in waste water Content is high, and protein produces the phosphate radical generation ammonium magnesium phosphate in a large amount of inorganic ammonias and waste water after anaerobic reactor hydrolytic deaminzation base Crystal salt, causes line clogging.Therefore dephosphorization is gone.Three be that Phosphorus From Wastewater content is high, and biological treatment dephosphorizing rate is not good enough.Therefore Go dephosphorization.
A kind of handling process of above-mentioned starch wastewater, it is characterised in that:Coagulative precipitation tank described in aforesaid way (1), From appropriate acid waste water and the flocculant of efficient dephosphorization.
Advantage from the flocculant for treating waste water of appropriate acid waste water is that the pH of raw wastewater belongs to acid waste water 3~5, From the flocculant of appropriate acid water quality, without carrying out water quality adjustment to waste water.The removal to most of phosphorus and suspension is completed, The problem of easy fouling of anaerobic reactor fluctuation of service, pipeline and exceeded water outlet phosphorus can be solved in traditional starch handling process.
A kind of handling process of above-mentioned starch wastewater, it is characterised in that:Coagulative precipitation tank described in aforesaid way (2), From suitable neutral waste water and the flocculant of efficient dephosphorization.
Advantage from the flocculant for treating waste water of suitable neutral waste water is that the requirement of anaerobic reactor inlet flow-patterm is neutral or weak Under conditions of acid-base property.Using waste water after hydrolysis acidification regulating reservoir, water outlet need to adjust the characteristics of pH is to neutral or weak acid alkalescence, Coagulating sedimentation facility is set after hydrolysis acidification regulating reservoir.The flocculant of the suitable neutral water quality of addition, without additional adjustment pH or PH fine adjustments only need to be carried out after coagulative precipitation tank.Solve anaerobic reactor fluctuation of service in traditional starch handling process, pipe The problem of easy fouling in road and exceeded water outlet phosphorus.
A kind of handling process of above-mentioned starch wastewater, it is characterised in that:Described in aforesaid way (1) or mode (2) Biochemical denitrification pond, for comprising aerobic and anoxia functions, the reaction tank with denitrification functions.
A kind of handling process of above-mentioned starch wastewater, it is characterised in that:Preliminary sedimentation tank water outlet described in aforesaid way (1), By being laid between preliminary sedimentation tank delivery port and biochemical denitrification pond water inlet, exported in the pipeline for being provided with flow control valve Waste water, the biochemical denitrification described in proportional mode of entrance (1) is distinguished with the anaerobic reactor water outlet described in mode (1) Pond.
A kind of handling process of above-mentioned starch wastewater, it is characterised in that:Hydrolysis acidification regulation described in aforesaid way (2) Pond water outlet, by being laid between hydrolysis acidification regulating reservoir delivery port and biochemical denitrification pond water inlet, is provided with Flow-rate adjustment The waste water exported in the pipeline of valve, proportional mode of entrance (2) is distinguished with the anaerobic reactor water outlet described in mode (2) Described biochemical denitrification pond.
In the present invention process biochemical treatment stage using preliminary sedimentation tank water outlet as biochemical denitrification pond supplementary carbon source.Advantage is (1) Improve waste water C/N.Solve the problem of denitrifying carbon source is not enough in existing starch wastewater treatment technique;(2) supplement part phosphorus member Element.Solve after pretreatment Coagulation Method high efficiency dephosphorization, phosphorus easily occurs after Anaerobic Treatment again in waste water in biochemical denitrification pond not enough The problem of, and the phosphorus content introduced is few, can meet growth but not the influence standard water discharge of microorganism;(3) managed as original place Waste water in system, will not make the microbiologic population in biochemical denitrification pond occur larger change, therefore microorganism can be in the short period Endoadaptation, the domestication time is short, and utilization of carbon source rate is high;(4) load of pretreatment and Anaerobic Treatment is lowered into, promotes follow-up structure Build the stable operation of thing;(5) recycling of waste water is realized.Shortcoming is:While introducing COD and P, it can also draw Enter part nitrogen substance.But it is due to that waste water introducing small amount can meet the carbon requirement in biochemical denitrification pond, introducing nitrogen content is few, And subsequently have biochemical denitrification pond that it is further processed, therefore do not interfere with standard water discharge.
In the present invention process biochemical treatment stage using hydrolysis acidification pool water outlet as biochemical denitrification pond supplementary carbon source.Except with Outside above-mentioned preliminary sedimentation tank water outlet is as biochemical denitrification pond supplementary carbon source advantage, hydrolysis acidification pool goes out the molecular weight of Organic substance in water than just The molecular weight of organic matter is small in sinking pool effluent, is more easy to be utilized by microorganism.Reason is the larger molecular organicses warp in preliminary sedimentation tank water outlet Cross after hydrolysis acidification, macromolecular substances are degraded and generated in the presence of hydrolase and a large amount of hydrolysis, non-hydrolytic microorganism It is capable of the small-molecule substance of penetration cell wall film.Therefore the biodegradability of hydrolysis acidification pool water outlet is better than preliminary sedimentation tank water outlet, Ke Yigeng Efficiently utilized by denitrifying microorganism.
The present invention mainly overcome in existing starch wastewater treatment technology the change of waste water water water quality and quantity greatly, anaerobic reactor transports Unstable, the easy fouling of anaerobic reactor pipeline of row and aerobic-anaerobic section carbon source are not enough, cause effluent quality to be difficult to ensure that row up to standard A kind of the problem of putting, it is proposed that combined treatment process of high-efficient denitrification and dephosphorization, and technique has investment cost small, Operation and Maintenance letter It is single, the advantage that water outlet stably reaching standard and waste water can be made to get utilization.
Brief description of the drawings
Fig. 1 is the process chart of the embodiment of the present invention.
Embodiment
The flow of solid line connection as shown in Figure 1, a kind of processing mode of starch wastewater:Waste water enters preliminary sedimentation tank, removes Partial contamination thing and the recovery for carrying out protein.The removal to most of phosphorus and suspension is completed into coagulative precipitation tank:It need not change Become the condition of water quality such as raw water temperature and pH, add a certain amount of acid flocculant, rotating speed is 200r/min, and the sedimentation time is 40min. It is using hydrolysis acidification regulating reservoir that the macromolecular in coagulative precipitation tank water outlet based on aromatic hydrocarbons, alkane alkene and heterocyclic material is organic Thing, is degraded to low molecular organic acidses and the alcohols such as valeric acid, the furfuryl alcohol of being capable of penetration cell wall film.When hydrolysis acidification regulating reservoir is stopped Between be 8h.PH is adjusted to after neutrality enter anaerobic reactor by water outlet using lime supernatant, in anaerobic reactor further Macromolecular substances are changed into small-molecule substance, is finally changed into methane, carbon dioxide and thoroughly removes, the COD of waste water is reduced, The pollutant such as partially protein, fat is by heterotroph ammonification simultaneously.Anaerobic reactor water outlet enters biochemical denitrification pond, now just heavy Pond water outlet also enters biochemical denitrification pond by a certain percentage, is used as the supplementary carbon source of microorganism, it is to avoid because anaerobic reactor water outlet carbon Nitrogen is than biochemical system imbalance caused by too low.In biochemical denitrification pond, aerobic section heterotroph amonifying bacteria is by residual protein The pollutants such as matter, fat carry out ammonification, and the nitrification of autotrophic bacterium willIt is oxidized toAnoxic section denitrifying bacteria willIt is reduced to N2.Waste water enters second pond after the water outlet of biochemical denitrification pond, completes mud-water separation, concentration and returnedactivatedsludge Effect, make water outlet qualified discharge.
The flow that solid line as shown in Figure 1 is combined with dotted line, the processing mode of another starch wastewater.Waste water enters just heavy Enter hydrolysis acidification regulating reservoir behind pond, complete after the regulation to water quality and quantity, regulation hydrolysis acidification regulating reservoir water outlet pH to neutrality Waste water enters coagulative precipitation tank, adds a certain amount of neutral flocculant.Coagulative precipitation tank water outlet enters anaerobic reactor.Anaerobic reaction Device water outlet enters biochemical denitrification pond, and now preliminary sedimentation tank water outlet or hydrolysis acidification pool water outlet also enter biochemical denitrification pond by a certain percentage, It is used as the supplementary carbon source of microorganism.Except coagulative precipitation tank position be placed in after hydrolysis acidification regulating reservoir and supplementary carbon source may be selected just Beyond two kinds of heavy water outlet or hydrolysis acidification regulating reservoir water outlet, each structures function and embodiment and the above-mentioned reality being connected with solid line Apply identical described by mode.
Application example:Five effects for illustrating the present invention, but scope of the presently claimed invention not office are enumerated below It is limited to this.
Application example 1:One enterprise's corn starch wastewater water, CODcrFor 9787mg/L, TN is 622mg/L, and TP is 93mg/L, SS is 2610mg/L.Precipitate COD after 1hcr, TN, TP, SS clearance be respectively 39.09%, 30.14%, 17.87%, 88.03%.Obtain sediment 2.30kg/m3.Experiment waste water enterprise day processing hc effluent 1700m used3, recyclable dry 3.91t/d.Sediment is based on protein.The mass fraction of crude protein and true albumen is respectively:42.25%, 40.40%, it is good Good animal feed additive.
Application example 2:It is flocculant of 40% ferric chloride solution as acid coagulative precipitation tank by the use of commercial available quality fraction.In raw water temperature 32 DEG C of degree is with conditions of pH=3.6, and dosage is 0.40g/L, rotating speed 250r/min stirring 1min, rotating speed 40r/min stirrings 20min, precipitates 40min.Total phosphorus content is down to 10.6mg/L by 112mg/L in starch wastewater, and clearance is 90.5%, SS Content is down to 11.4mg/L by 220mg/L, and clearance is 94.8%.Understand from chlorination ferric flocculant need not change raw water pH, The condition of water quality such as temperature, go dephosphorization and suspension effect significantly, cost is low;And commercially available ferric chloride in aqueous solution, is saved The problems such as enterprise sets up medicine dissolving tank, reduces capital cost.
Application example 3:The flocculant of neutral coagulative precipitation tank is used as by the use of aluminum sulfate.Under conditions of 32 DEG C of wastewater temperature and pH=7.0, Dosage is 0.40g/L, rotating speed 250r/min stirring 1min, rotating speed 40r/min stirring 20min, precipitates 40min.Starch gives up Total phosphorus content is down to 11.5mg/L by 104mg/L in water, and clearance is that 88.9%, SS contents are down to 2.1mg/L by 232mg/L, Clearance is 99.1%.
Application example 4:Cornstarch enterprise Sewage Disposal vertical sedimentation tank water outlet and EGSB anaerobic reactor water outlets are gathered, is pressed The ratio of water 1,/25 one denitrification reactor of introducing, C/N=4.8,30 DEG C of composite waste temperature, pH=6.9, the residence time is 6h, MLSS=5248mg/L, nitrate nitrogen content is down to 3.9mg/L by 99.8mg/L, and clearance is 96.09%.
Application example 5:Cornstarch enterprise Sewage Disposal hydrolysis acidification regulating reservoir water outlet and EGSB anaerobic reactor water outlets are gathered, A denitrification reactor is introduced in the ratio of water 3/100, C/N=3,30 DEG C of composite waste temperature, pH=6.9, the residence time is 6h, MLSS=4892mg/L, nitrate nitrogen content are down to 3.0mg/L by 100.2mg/L, and clearance is 97.01%.
Finally it should be noted that:Although be described in detail above the present invention and its advantage it should be appreciated that without departing from Various changes can be carried out in the case of the spirit and scope of the present invention being defined by the claims appended hereto, substitutes and converts. Moreover, the scope of the present invention is not limited only to process described by specification, equipment, means, the specific embodiment of method and steps. One of ordinary skilled in the art will readily appreciate that from the disclosure, according to the present invention can use execution with herein The essentially identical function of described corresponding embodiment or acquisition are to be developed result, the existing and future essentially identical with it Process, equipment, means, method or step.Therefore, appended claim is directed in the range of them including such Process, equipment, means, method or step.

Claims (10)

1. a kind of handling process of starch wastewater, it is characterised in that:It includes following two modes:
(1) high-concentration waste water is first passed through the protein that preliminary sedimentation tank removes partial contamination thing and reclaims precipitation by pretreatment stage, and next enters Enter coagulative precipitation tank progress coagulating sedimentation and go dephosphorization and suspension, furthermore enter " hydrolysis acidification regulating reservoir+anaerobic reactor ", so Anaerobic reactor water outlet enters the progress biochemical denitrification processing of biochemical denitrification pond, last biochemical denitrification together with the preliminary sedimentation tank water outlet of part afterwards Pond water outlet enters second pond, water outlet is stably reached discharge standard.
(2) high-concentration waste water is first passed through " preliminary sedimentation tank+hydrolysis acidification regulating reservoir " removal partial contamination thing, reclaims heavy by pretreatment stage The protein and regulation pH in shallow lake, carry out coagulating sedimentation subsequently into coagulative precipitation tank and go dephosphorization and suspension, subsequently enter anaerobism Reactor, then anaerobic reactor water outlet enters the progress biochemical denitrification processing of biochemical denitrification pond together with partial hydrolysis acidification pool water outlet, Last biochemical denitrification pond water outlet enters second pond, water outlet is stably reached discharge standard.
2. a kind of starch wastewater treatment technique according to claim 1, it is characterised in that:Aforesaid way (1) and mode (2) For starch wastewater Different treatments, enterprise can voluntarily select according to condition of water quality, capital construction condition, when there is multiple preliminary sedimentation tanks, Preliminary sedimentation tank therein can be transform as coagulative precipitation tank, now be adapted to selection mode (1), fitted when biochemical denitrification pool volume is smaller Close selection mode (2).
3. starch wastewater according to claim 1, it is characterised in that the high COD that is produced in starch process, high P acidity Waste water.
4. a kind of starch wastewater treatment technique according to claim 1, it is characterised in that:Aforesaid way (1) or mode (2) Described in preliminary sedimentation tank be used to remove the partial contamination thing in waste water and reclaim the protein of precipitation.
5. a kind of starch wastewater treatment technique according to claim 1, it is characterised in that:Aforesaid way (1) or mode (2) Described in coagulative precipitation tank, for going dephosphorization and suspension, the hydrolysis acidification regulating reservoir, its water outlet pH be faintly acid, in Property or alkalescent.
6. a kind of starch wastewater treatment technique according to claim 1, it is characterised in that:It is mixed described in aforesaid way (1) Solidifying sedimentation basin, from appropriate acid waste water and the flocculant of efficient dephosphorization.
7. a kind of starch wastewater treatment technique according to claim 1, it is characterised in that:It is mixed described in aforesaid way (2) Solidifying sedimentation basin, from suitable neutral waste water and the flocculant of efficient dephosphorization.
8. a kind of starch wastewater treatment technique according to claim 1, it is characterised in that:Aforesaid way (1) or mode (2) Described in biochemical denitrification pond, for comprising aerobic and anoxia functions, the reaction tank with denitrification functions.
9. a kind of starch wastewater treatment technique according to claim 1, it is characterised in that:It is first described in aforesaid way (1) Sinking pool effluent, by being laid between preliminary sedimentation tank delivery port and biochemical denitrification pond water inlet, is provided with the pipe of flow control valve The waste water exported in road, distinguishes proportional mode of entrance (1) described with the anaerobic reactor water outlet described in mode (1) Biochemical denitrification pond.
10. a kind of starch wastewater treatment technique according to claim 1, it is characterised in that:Water described in aforesaid way (2) Solution acidifying regulating reservoir water outlet, by being laid between hydrolysis acidification regulating reservoir delivery port and biochemical denitrification pond water inlet, is installed The waste water exported in the pipeline for having flow control valve, with the proportional entrance side of anaerobic reactor water outlet described in mode (2) Biochemical denitrification pond described in formula (2).
CN201610049917.XA 2016-01-26 2016-01-26 A kind of handling process of starch wastewater Pending CN106995256A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610049917.XA CN106995256A (en) 2016-01-26 2016-01-26 A kind of handling process of starch wastewater

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610049917.XA CN106995256A (en) 2016-01-26 2016-01-26 A kind of handling process of starch wastewater

Publications (1)

Publication Number Publication Date
CN106995256A true CN106995256A (en) 2017-08-01

Family

ID=59428845

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610049917.XA Pending CN106995256A (en) 2016-01-26 2016-01-26 A kind of handling process of starch wastewater

Country Status (1)

Country Link
CN (1) CN106995256A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108569824A (en) * 2018-04-28 2018-09-25 陕西昕宇表面工程有限公司 A kind of starch gourmet powder waste water biochemistry intensive treatment system and technique
CN108585194A (en) * 2018-07-05 2018-09-28 江苏安德信超导加速器科技有限公司 A kind of potato starch wastewater system for anaerobic treatment
CN108773984A (en) * 2018-07-05 2018-11-09 江苏安德信超导加速器科技有限公司 A kind of potato starch wastewater treatment process
CN114538695A (en) * 2020-11-24 2022-05-27 山东福洋生物科技股份有限公司 Method for treating modified starch industrial wastewater by using microorganisms
CN115490331A (en) * 2022-10-24 2022-12-20 中国电建集团华东勘测设计研究院有限公司 Urban polluted rainwater SBBR treatment device and treatment method for introducing domestic sewage

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0522966B1 (en) * 1991-07-12 1995-08-23 Norihito Tambo Process and plant for waste water purification comprising dephosphorisation and anaerobic/aerobic treatment
CN101891338A (en) * 2010-06-30 2010-11-24 潍坊盛泰药业有限公司 Waste water treatment method in starch and glucose production
CN103304110A (en) * 2013-07-09 2013-09-18 华北制药康欣有限公司 Wastewater treatment method in starch glucose production
CN105110553A (en) * 2015-08-05 2015-12-02 山东益源环保科技有限公司 Method for treating high-concentration starch wastewater

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0522966B1 (en) * 1991-07-12 1995-08-23 Norihito Tambo Process and plant for waste water purification comprising dephosphorisation and anaerobic/aerobic treatment
CN101891338A (en) * 2010-06-30 2010-11-24 潍坊盛泰药业有限公司 Waste water treatment method in starch and glucose production
CN103304110A (en) * 2013-07-09 2013-09-18 华北制药康欣有限公司 Wastewater treatment method in starch glucose production
CN105110553A (en) * 2015-08-05 2015-12-02 山东益源环保科技有限公司 Method for treating high-concentration starch wastewater

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
刘耕耘等: "淀粉废水的絮凝沉淀及生物处理", 《内蒙古大学学报(自然科学版)》 *
闫海红等: "预处理-水解酸化-厌氧-好氧工艺对玉米淀粉废水有机污染物的降解", 《环境工程学报》 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108569824A (en) * 2018-04-28 2018-09-25 陕西昕宇表面工程有限公司 A kind of starch gourmet powder waste water biochemistry intensive treatment system and technique
CN108585194A (en) * 2018-07-05 2018-09-28 江苏安德信超导加速器科技有限公司 A kind of potato starch wastewater system for anaerobic treatment
CN108773984A (en) * 2018-07-05 2018-11-09 江苏安德信超导加速器科技有限公司 A kind of potato starch wastewater treatment process
CN114538695A (en) * 2020-11-24 2022-05-27 山东福洋生物科技股份有限公司 Method for treating modified starch industrial wastewater by using microorganisms
CN115490331A (en) * 2022-10-24 2022-12-20 中国电建集团华东勘测设计研究院有限公司 Urban polluted rainwater SBBR treatment device and treatment method for introducing domestic sewage

Similar Documents

Publication Publication Date Title
KR101665636B1 (en) Wastewater pretreatment method and sewage treatment method using the pretreatment method
CN100361910C (en) Waste water treatment method of anerobic- anoxia-aerobic-coagulated precipitation
CN104163543B (en) A kind of waste disposal plant and sewage water treatment method thereof
CN106995256A (en) A kind of handling process of starch wastewater
JP2013527023A (en) System and method for reducing sludge produced in wastewater treatment facilities
CN206486407U (en) A kind of livestock breeding wastewater processing system
CN108383320B (en) Integrated treatment method for livestock and poultry breeding wastewater
CN114291964B (en) Sewage treatment system and method for denitrification and phosphorus recovery
CN101659502B (en) Method for treating waste leachate by utilizing high denitrification shared type Orbal oxidation ditch
CN106517516A (en) Industrial wastewater upgrading and reconstruction biological treatment equipment and treatment technology
CN108002535A (en) A kind of gentamicin pharmacy waste water nitration denitrification processing method
CN103395882A (en) Processing method and processing apparatus of high ammonia-nitrogen wastewater
CN108163997A (en) A kind of microorganism of dyeing and printing sewage denitrogenates method
CN112047468A (en) Biochemical treatment method of landfill leachate
CN111003816A (en) Biochemical tail water biological denitrification method for inhibiting non-filamentous bacterium expansion
CN105110573A (en) Treatment system and method for removing total nitrogen in sewage
JP2018075567A (en) System and method for reducing sludge produced in effluent treatment facility
CN210711177U (en) Pig manure fermentation biogas slurry treatment system
CN204981483U (en) Coking wastewater optimization processing device
CN109081452B (en) Sequencing batch sewage treatment device and process with immobilized carrier biological membrane and activated sludge coupled
CN110563285B (en) Integrated biogas slurry wastewater treatment system and treatment process thereof
KR20010045253A (en) Advanced method for treating wastewater and apparatus therefor
CN105152453B (en) A kind of processing system and processing method of the reverse osmosis concentrated salt solution of coking
CN202671346U (en) Wastewater treatment system for waste paper making
CN112811611A (en) Double-group B-BAF filter tank device and sewage denitrification treatment method

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20170801

WD01 Invention patent application deemed withdrawn after publication