CN106994843A - Marking print material and seal - Google Patents

Marking print material and seal Download PDF

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Publication number
CN106994843A
CN106994843A CN201611019838.0A CN201611019838A CN106994843A CN 106994843 A CN106994843 A CN 106994843A CN 201611019838 A CN201611019838 A CN 201611019838A CN 106994843 A CN106994843 A CN 106994843A
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CN
China
Prior art keywords
composition
marking
raw material
print material
print
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Granted
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CN201611019838.0A
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Chinese (zh)
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CN106994843B (en
Inventor
吉田胜也
新宫千春
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Co Ltd Wu Zhu
Kuretake Co Ltd
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Co Ltd Wu Zhu
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Publication of CN106994843A publication Critical patent/CN106994843A/en
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Publication of CN106994843B publication Critical patent/CN106994843B/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41KSTAMPS; STAMPING OR NUMBERING APPARATUS OR DEVICES
    • B41K1/00Portable hand-operated devices without means for supporting or locating the articles to be stamped, i.e. hand stamps; Inking devices or other accessories therefor
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Printing Plates And Materials Therefor (AREA)

Abstract

The invention provides marking print material and seal, the marking print material is the marking print material with the engraving portion for being carried out the marking endorsed, thermoplastic resin elements, filler composition are contained in the engraving portion, and the filler composition contains calcium constituent composition, magnesium elements composition and element silicon composition.

Description

Marking print material and seal
Technical field
The present invention relates to marking print material and seal.
Background technology
A kind of seal is used in the past, and the seal is used in the marking with the lithotome formed by natural stones such as stone from Qingtian county in Zhejiang Province, used to make seals Print the seal for implementing marking on material.
But, the quality of lithotome is unstable, be difficult to obtain, and expensive.
On the other hand, this seal be used for the artist such as calligraphist reflected on the works of oneself print authors' name, lead to Cross endorse meet artist complete works when sense of fulfillment, depth and a luxurious touch hobby.
Therefore, as marking print material, it is considered to using with the substitute with lithotome equal extent weight.
But, if with artificial stone as substitute of the marking with print material, may be with lithotome when implementing marking Compared to be more difficult to engraving.
The content of the invention
Invent the problem to be solved
In view of the foregoing, problem of the invention, which is that offer is a kind of, can turn into the substitute of lithotome and in reality It is easy to the seal that the marking of engraving is marked with print material and in the marking with being implemented with print material when applying marking.
The marking of present invention print material,
It is the print material of the marking with the engraving portion for being carried out the marking endorsed,
Thermoplastic resin elements and filler composition are contained in the engraving portion,
The filler composition contains calcium constituent composition, magnesium elements composition and element silicon composition.
The marking of above-mentioned composition print material, it is preferable that
The thermoplastic resin elements contain ABS resin raw material.
The marking of above-mentioned composition print material, it is preferable that
In the filler composition,
Relative to total first prime number of the calcium constituent composition, magnesium elements composition and element silicon composition,
The calcium constituent composition containing 4~85 yuan of prime number %,
The magnesium elements composition containing 5~50 yuan of prime number %, and
The element silicon composition containing 5~60 yuan of prime number %.
The marking of above-mentioned composition print material, it is preferable that
In the filler composition,
Contain calcium carbonate raw material as the raw material containing the calcium constituent composition, and
Contain talcum raw material as the raw material containing the magnesium elements composition and element silicon composition.
The seal of the present invention,
With marking print material,
It is the seal that the marking endorsed is carried out in the engraving portion.
Brief description of the drawings
Fig. 1 is the photo for printing the section of print material when material is engraved for representing sample.
Embodiment
Hereinafter, the marking to embodiments of the present invention is illustrated with print material and seal.
First, the marking print material of present embodiment is illustrated.
The marking print material of present embodiment has engraving portion, the marking that the engraving portion is endorsed for implementation,
Thermoplastic resin elements and filler composition are contained in the engraving portion,
The filler composition includes:Calcium constituent composition, magnesium elements composition and element silicon composition.
According to the marking of present embodiment print material, thermoplastic resin elements and filler composition are contained in engraving portion, the filler Composition includes calcium constituent composition, magnesium elements composition and element silicon composition, thus, and marking print material can turn into lithotome Substitute, moreover, the marking with print material be easily cut by shearing force.
In addition, when operator cuts the blade of marking in the marking stone material, the blade can be made with desired Angle incision, moreover, can side cut with desired power, while making the blade of incision advance.
Here, if being difficult to cutting by shearing force, it is difficult to the surface for making the blade of marking print material from marking Inside is cut into, therefore, this point, which may turn into, causes the reason for engraving becomes difficulty.In addition, using blade incision marking When printing in material, it may result in the blade to deviate the angle incision of desired angle or make the knife edge of incision to carving When print carries out cutting edge traveling with print material, entered with the Lixing inconsistent with desired power, this, which may turn into, causes engraving to become The reason for obtaining difficult.
But, according to said structure, marking can be easily cut with print material by shearing force, so as to easily make marking Blade is cut, in addition, the blade can be made to be cut with desired angle, moreover, can be cut with desired power side While making the blade of incision advance.Therefore, marking of the invention is that the marking easily carved when implementing and marking prints material with print material.
The marking of present embodiment is with print material, and the thermoplastic resin elements preferably comprise ABS resin raw material.
Because thermoplastic resin elements contain ABS resin raw material, therefore, marking print material can more reliably turn into easily quilt The material of shearing force cutting, and easily cut the blade of marking, in addition, the blade can be made to be cut with desired angle Enter, it can also enough make the blade of incision advance with desired power side cutting edge.Therefore, marking of the invention print material energy It is enough more reliably to turn into the marking print material easily carved when implementing marking.
The marking of present embodiment is used in print material,
In the filler composition,
Relative to total first prime number of the calcium constituent composition, magnesium elements composition and element silicon composition, preferably comprise:
4~85 yuan of prime number % calcium constituent composition,
5~50 yuan of prime number % magnesium elements composition, and
5~60 yuan of prime number % element silicon composition.
Here, first prime number % of calcium constituent composition, magnesium elements composition and element silicon composition refers to, embodiment as be described hereinafter It is shown, to be implemented with marking face (print face) any three at carry out energy dispersion-type X-ray analysis so as to each element composition First prime number be measured, and calculate the conjunction of first prime number of first prime number relative to resulting each element composition of each element composition The percentage of the ratio of meter, value obtained from by calculating the average at three.
Filler composition contains calcium constituent composition, magnesium elements composition and element silicon composition with above-mentioned ratio, thus, marking It can more reliably be turned into print material and easily be sheared the material that power is cut, and easily cut the blade of marking, in addition, can The blade is cut with desired angle, moreover, can side cutting edge carried out with desired power the blade of incision is advanced. Therefore, marking of the invention can more reliably turn into the marking print material easily carved when implementing and marking with print material.
The marking of present embodiment is used in print material,
In the filler composition,
As the raw material containing the calcium constituent composition, calcium carbonate raw material is preferably comprised, and conduct contains the magnesium elements The raw material of composition and element silicon composition, preferably comprises talcum raw material.
In filler composition, contain calcium carbonate raw material as the raw material containing calcium constituent composition, and conduct contains magnesium elements The raw material of composition and element silicon composition and contain talcum raw material, thus, because these raw materials are readily available, with regard to this point for mark use Print material is more easily manufactured.In addition, can become more cheap.
As described above, the marking print material of present embodiment has engraving portion, the marking that the engraving portion is endorsed for implementation,
Thermoplastic resin elements and filler composition are contained in the engraving portion,
The filler composition contains calcium constituent composition, magnesium elements composition and element silicon composition.
Thermoplastic resin elements and filler composition are contained in the marking of present embodiment print material, its engraving portion, the filler into Subpackage calcic elemental composition, magnesium elements composition and element silicon composition, therefore, marking print material can turn into replacing for lithotome Dai Pin, moreover, the material being cut easily by shearing force can be turned into, so that easily cut the blade of marking, in addition, The blade can be made to be cut with desired angle, it can also enough make the knife of incision with desired power side progress cutting edge Sword is advanced.Therefore, the marking of present embodiment turns into the marking print material easily carved when implementing and marking with print material.
In addition, by that as the material so easily carved, can also suppress in marking (seal) for implementing to endorse Marking is bad.Moreover, marking also has the engraving performance that can brightly endorse with print material.
Specifically, the marking of present embodiment is formed with print material by engraving portion, and the engraving portion, which has, has been carried out pushing The face (print face) of marking.
Contain thermoplastic resin elements and filler composition in the engraving portion.
The thermoplastic resin elements can be as making filler composition turn into the knot of formed body in the engraving portion Mixture and play a role.
As thermoplastic resin contained in the thermoplastic resin elements, ABS resin (acrylic nitrile-butadiene two can be enumerated Alkene-styrene copolymerized synthetic resin), polypropylene (PP) resin etc..
Among these, if considering these remarkable factors of hardness, formability, the thermoplastic resin elements preferably comprise ABS Resin raw material.
In addition, the thermoplastic resin elements contain ABS resin raw material, thus, marking print material can more reliably into To be easily sheared the material of power cutting, and easily cut the blade of marking, in addition, the blade can be made with desired angle Degree incision, it can also enough make the blade of incision advance with desired power side cutting edge.
The filler composition adheres to one another to be formed as the main body in engraving portion via thermoplastic resin elements.
The filler composition contains calcium constituent composition, magnesium elements composition and element silicon composition.
The content ratio of the calcium constituent composition, magnesium elements composition and the element silicon composition that contain in the filler composition is without spy Do not limit, can suitably set.
For example, in the filler composition, it is preferable that relative to the calcium constituent composition, magnesium elements composition and element silicon into The total first prime number divided, the calcium constituent composition containing 4~85 yuan of prime number %, the magnesium containing 5~50 yuan of prime number % Elemental composition, and the element silicon composition containing 5~60 yuan of prime number %.
Coordinated by such, the material for being easily sheared power cutting can more reliably be turned into print material by marking, and easily Cut the blade of marking, in addition, the blade can be made to be cut with desired angle, it can also enough with desired Power side cutting edge makes the blade of incision advance.Thus, the marking print material of present embodiment, which can more reliably turn into, is implementing The marking easily carved during marking print material.
For example, in the filler composition, it is preferable that relative to the calcium constituent composition, magnesium elements composition and element silicon into The total first prime number divided, the calcium constituent composition containing 4~60 yuan of prime number %, the magnesium containing 15~45 yuan of prime number % Elemental composition, and the element silicon composition containing 20~55 yuan of prime number %.
According to the cooperation, the material for being easily sheared power cutting can more reliably be turned into print material by marking, and easily make quarter The blade incision of print, in addition, the blade can be made to be cut with desired angle, it can also enough with desired power side Cutting edge makes the blade of incision advance.Thereby, it is possible to more reliably turn into the marking easily carved when implementing marking print material.
For example, in the filler composition, it is highly preferred that relative to the calcium constituent composition, magnesium elements composition and element silicon Total first prime number of composition, the calcium constituent composition containing 30~60 yuan of prime number %, the institute containing 15~40 yuan of prime number % State magnesium elements composition, and the element silicon composition containing 20~40 yuan of prime number %.
According to the cooperation, the material for being easily sheared power cutting can more reliably be turned into print material by marking, and easily make quarter The blade incision of print, in addition, the blade can be made to be cut with desired angle, it can also enough with desired power side Cutting edge makes the blade of incision advance.Used thereby, it is possible to further reliably turn into the marking easily carved when implementing marking Print material.
For example, in the filler composition, it is highly preferred that relative to the calcium constituent composition, magnesium elements composition and element silicon Total first prime number of composition, the calcium constituent composition containing 30~40 yuan of prime number %, the institute containing 25~35 yuan of prime number % State magnesium elements composition, and the element silicon composition containing 30~40 yuan of prime number %.
By the cooperation, marking further can reliably turn into the material for being easily sheared power cutting with print material, and hold Easily cut the blade of marking, in addition, the blade can be made to be cut with desired angle, it can also enough with desired Power side cutting edge the blade of incision is advanced.Easily carved thereby, it is possible to further reliably turn into when implementing marking Marking with print material.
First prime number % of the calcium constituent composition, magnesium elements composition and element silicon composition, shown in embodiment as be described hereinafter, be Implement the face (print face) of marking any three at, carry out energy dispersion-type X-ray analysis, so as to determine each element composition First prime number, calculates the hundred of total ratio of first prime number of first prime number relative to resulting each element composition of each element composition Divide rate, and calculate the thus obtained value of the mean deviation at three.
Shown in embodiment as be described hereinafter, energy dispersion-type X-ray analysis is specifically to utilize to be equipped with detector and parse soft The scanning electron microscope of part is measured.
The calcium constituent composition, being can be in the state of included in the raw material containing the calcium constituent composition by the carving Quarter, portion was contained.
The magnesium elements composition, being can be in the state of included in the raw material containing the magnesium elements composition by the carving Quarter, portion was contained.
The element silicon composition, being can be in the state of included in the raw material containing the element silicon composition by the carving Quarter, portion was contained.
Therefore, first prime number % of calcium constituent composition in the filler composition, magnesium elements composition and element silicon composition can By to the raw material containing the calcium constituent composition, the raw material containing magnesium elements composition and the raw material containing element silicon composition Use level carries out appropriate change to be adjusted.
As the raw material containing the calcium constituent composition, calcium carbonate raw material, calcium hydroxide raw material etc. can be enumerated.
As the raw material containing the magnesium elements composition, magnesium hydroxide raw material, raw materials of magnesium oxide etc. can be enumerated.
As the raw material containing the element silicon composition, silica material etc. can be enumerated.
So, the filler composition can also contain and contain the calcium constituent composition, magnesium elements composition and element silicon respectively The raw material of composition, in addition, for example, it is also possible to which containing following raw material, the raw material contains one or both of three kinds of compositions Elemental composition.
For example, the filler composition as the raw material containing the calcium constituent composition can also containing calcium carbonate raw material and It can also contain talcum raw material as the raw material containing the magnesium elements composition and element silicon composition.
In the filler composition, calcium carbonate raw material is contained as the raw material containing calcium constituent composition and is used as and contains magnesium The raw material of elemental composition and element silicon composition and contain talcum raw material, thus, because these raw materials are readily available, examined from this respect Consider, marking is more easily manufactured with print material.In addition, can also become more cheap.
In this case, the match ratio of calcium carbonate and talcum, preferably 90~10 Quality Mgmt Dept:10~90 Quality Mgmt Dept, more preferably For 80~20 Quality Mgmt Dept:20~80 Quality Mgmt Dept, more preferably 60~40 Quality Mgmt Dept:40~60 Quality Mgmt Dept.
In the marking use print material of present embodiment, the match ratio of thermoplastic resin elements and filler composition, without special Limit, can suitably set.
If for example, in view of mouldability and because containing above-mentioned calcium constituent composition, magnesium elements composition and two in filler composition Silica elemental composition and marking can actually be made to be more easy to the factors such as engraving, then thermoplastic resin elements and filler composition with print material Match ratio be preferably 10~50 Quality Mgmt Dept:50~90 Quality Mgmt Dept, more preferably 20~40 Quality Mgmt Dept:60~80 Quality Mgmt Dept, enter One step is preferably 25~35 Quality Mgmt Dept:65~75 Quality Mgmt Dept.
In the marking use print material of present embodiment, the face marked can be used as using arbitrary face.
In addition, the marking of present embodiment print material, in engraving portion except above-mentioned thermoplastic resin elements and filler into , can also be suitably containing other compositions beyond point.In addition, present embodiment marking print material can also have engraving portion with Outer part.Moreover, the marking of present embodiment print material, mentioned component is contained at least engraving portion.
The marking of present embodiment is not particularly limited with the manufacture method of print material.
It is melted for example, carrying out heating to thermoplastic resin, and by the thermoplastic resin elements of melting and filler composition Melting mixing is simultaneously granulated, and can be had by carrying out ejection formation to obtained particle to be produced on engraving portion for endorsing Marking face marking with print material.
Next, being illustrated to the seal of present embodiment.
The seal of present embodiment, with marking print material,
The seal of present embodiment is carried out the marking endorsed in the engraving portion.
The seal of present embodiment, the engraving portion in the marking print material of above-mentioned present embodiment is carried out Implement the marking (seal) for endorsing on the face of the marking (print face).
The seal of present embodiment, by being carried out the marking endorsed in above-mentioned engraving portion, thus, during as marking Engraving is easy, i.e. the excellent seal of manufacturing.
As the marking, be not particularly limited, for example, can enumerate by seal cutting formed desired pattern word, Figure etc..
The seal of present embodiment can be for example, by the graver of seal cutting manually or by marking forming apparatus Blade is carved desired marking in above-mentioned engraving portion and formed therefrom.
In addition, the seal of present embodiment, at least its print surface side are formed by above-mentioned marking with print material.
The seal of present embodiment, adheres to after ink paste etc. on print face, by the works such as calligraphy work, paint Progress is endorsed etc. and used.
By described above, according to present embodiment, using the teaching of the invention it is possible to provide one kind implements the easy marking print of engraving during marking Material and the seal marked that implementation is endorsed on marking print material.
The marking of present embodiment is with print material and seal as described above, but marking of the invention is not special with print material and seal Above-mentioned embodiment is defined in, change can be suitably designed without departing from the spirit and scope of the invention.
Next, enumerating embodiment and the present invention being described in more detail.
【Embodiment】
Following materials are used.
ABS resin raw material:TechnoABS 55NP (production of Techno Polymer Co., Ltd. (big section's energy resin))
Calcium carbonate raw material:Sunlight SL-100 (production of Zhu Yuan chemical industry Co., Ltd.)
Talcum raw material:P- talcums (production of Zhu Yuan Industrial Co., Ltd)
Stone from Qingtian county in Zhejiang Province, used to make seals (lithotome):New green grass or young crops field (in domestic, Co., Ltd. Wu Zhu productions)
Calcium carbonate raw material to the talcum raw material containing magnesium elements composition and element silicon composition and containing calcium constituent composition enters Row mixing, to modulate filler composition 1~5, and turns into the cooperation of table 1 below.
In order to obtain the cooperation of table 2 below, mixed in the ABS resin raw material as thermoplastic resin elements of heating melting Filler composition 1~5 is closed simultaneously to granulate, by carry out ejection formation to obtained particle, and make being shaped to 24mm × 24mm × The marking of 50mm corner post shape print material (sample 1~5).In addition, by cut off stone from Qingtian county in Zhejiang Province, used to make seals and as 23mm × 23mm × 70mm corner post shape, and the thus marking print material to make sample 6.
【Table 1】
【Table 2】
To the face of obtained 24mm × 24mm of sample 1~5 square shape, at any the three of each face, by following Method carries out elemental composition analysis.Specifically, for a position, first prime number, the magnesium (Mg) of calcium (Ca) elemental composition are calculated First prime number of first prime number and silicon (Si) elemental composition of elemental composition, calculate obtained by first prime number relative to these three elements into Total percentage of the first prime number divided, thus, calculates the content (first prime number %) of each element composition.To any the three of each sample Place carries out the measure.In addition, calculating the average value at three to each sample.It the results are shown in table 3.It also show in table 3 each First prime number % of each element composition theoretical value in sample.Specifically, content of following methods to each element composition is passed through It is measured.
During measure, a calcium carbonate (CaCO3) contain a Ca element, a talcum (Mg in molecule3Si4O10(OH)2) point Containing three Mg elements, four Si elements in son, detection elements are determined as described below.
The assay method > of < element component contents
Use the scanning electron microscope for being equipped with detector (production of Octane Plus, AMETEK companies) (SU3500, high and new technology company of Hitachi production), by each sample with 24mm × 24mm face (face marked) upward Mode is placed on table top, and energy dispersion-type X-ray (EDX) analysis is carried out to any three positions in the face.By obtained knot Fruit is parsed by analysis software (production of Team, AMETEK company), thus, obtains first prime number, the magnesium member of calcium constituent composition First prime number of plain composition and first prime number of element silicon composition.First prime number of each element composition in each position is calculated relative to obtaining Total percentage (content ratio) of first prime number of each element composition.In addition, on each element composition, calculating the content ratio at three Average value.
Operation distance:10mm
Accelerating potential:20kV
Detection elements:C/O/Mg/Si/Ca
Multiplying power:50 times
【Table 3】
As known from Table 3, the measured value of each element composition is close to theoretical value.In addition, not finding caused by measurement site Relatively large deviation.
In addition, the measured value on carbon (C) elemental composition, does not find the relatively large deviation caused by measurement site.
In addition, the result that the element to each measurement site is drawn is understood, it is distributed on the whole in each measurement site There are C compositions (coming from resin), Ca elemental compositions, Mg elemental compositions and Si elemental compositions.
Its result understands that ABS resin, Ca elemental compositions, Mg elemental compositions and Si elemental compositions are distributed in marking face (print Face) it is overall.
In addition, stone from Qingtian county in Zhejiang Province, used to make seals typically has Al2Si4O10(OH)2Composition, it is same with sample 1~5 on sample 6 (stone from Qingtian county in Zhejiang Province, used to make seals) Sample, when carrying out EDX analyses in the face (face marked) to 23mm × 23mm, detected Al elemental compositions and Si elements into Point, but do not detect Ca elemental compositions and Mg elemental compositions.
Using obtained sample 1~6, by following methods, the cutting easy degree based on shearing force is evaluated, That is, the decrement of size is evaluated.The sample being cut easily by shearing force, when implementing marking, more easily makes blade Incision, accordingly and as the sample easily carved.
Cutting easy degree >s of the < based on shearing force
Sand paper is fixed on sample platform, by each sample 1~6 with its 24mm × 24mm face and 23mm × 23mm face and sand The mode of paper contact is fixed on the sand paper, and the sample 1~6 fixed from upper direction applies following loads, in this condition, under It is set to be moved back and forth on sand paper under conditions of stating.Quality to the sample 1~6 before and after reciprocating motion is measured, and is surveyed Determine shuttle era quality and reciprocating motion after quality difference as grinding stone amount (g).In addition, will using the density of each sample The grinding stone amount (g) is converted into grinding stone amount (cm3).Moreover, by obtained grinding stone amount (cm3) divided by each sample 1~6 in and sand paper The sectional area in the face of contact, and thus calculate the cutting output of depth direction (grinding stone reduces size (because of the grinding stone chi of reduction It is very little)).In addition, often determining an once sand paper of replacing.It the results are shown in table 4.
【Table 4】
According to table 4, compared with the sample 6 used generally as lithotome, the grinding stone of sample 1~5 reduces size [mm] It is larger.
On sample 1~5, the grinding stone reduction size [mm] of sample 1 is relatively small, and the grinding stone of sample 3 reduces size [mm] It is relatively large.
Thus, it can be known that sample 1~5 is compared with sample 6, it is easier to be cut by shearing force, especially, sample 3 is by cutting Shear force is easy to be cut.
(sensory evaluation of engraving sense of touch)
In addition to talcum raw material is used only as filler composition, in the same manner as sample 1~5, the marking for making sample 7 is used Print material.
Except pp material (PP) is used only as thermoplastic resin elements, talcum raw material is used only as filler composition In addition, in the same manner as sample 1~5, the marking print material of sample 8 is made.
Except as thermoplastic resin be used only pp material (PP), as filler composition be used only calcium carbonate raw material with Outside, in the same manner as sample 1~5, the marking print material of sample 9 is made.
Then, using sample 1~9, engraving sense of touch is evaluated.
Specifically, operator is carved using the print knife (blade of V-shape) of seal cutting to sample 1~9, to this When hardness and engraving sense of touch carry out aesthetic (by the thoughts and feelings of hand) and evaluate, and judged with following benchmark.
It the results are shown in table 5.
The evaluation > of < hardness
Firmly:5
It is slightly hard:4
Commonly:3
It is slightly soft:2
It is soft:1
< carves the evaluation > of sense of touch
Easily carve:○
Slightly difficult engraving:△
Hardly possible engraving:×
【Table 5】
As shown in table 5, compared with sample 7~9, sample 1~6 is all achieved preferably in hardness and the aspect of engraving sense of touch two As a result.
In addition, sample 1~5 is same with sample 6, good result is all shown in hardness and the aspect of engraving sense of touch two.
In addition, according to the result of sample 1~9, talcum is more, sample becomes softer, but toughness becomes strong, it is necessary to with wishing The power that the power of prestige is different makes blade advance, and there is the tendency for being difficult to make blade advance.Therefore, understand that the sample is present accordingly to be difficult to The tendency of engraving.Especially, the combination of the talcum, PP of sample 8, soft, toughness is too strong, is very difficult to engraving.
(evaluation in section after engraving)
On sample 1~6, using print knife similar to the above, in the section vertical with the direct of travel that it prints blade, Relative to the face (print face) marked, print blade is set obliquely to be cut with the constant angle between 40 °~50 °, for each examination Material 1~6, makes print knife advance with constant power.Relatively strong power (engraving power) is applied and relatively weak to print blade respectively Power (engraving power), and three operations are repeated.
In addition, being shot to the section (engraving section) after the once engraving in three times repeatedly operation.Result is represented In Fig. 1.
Although the V words section of each sample is almost without difference, with sample 6 (stone from Qingtian county in Zhejiang Province, used to make seals) equally, blade is sharp for sample 2,3 Cut sharply, because blade is cut into desired angle, therefore, it is the sample easily carved that sample 2,3 is understood accordingly.
It can be seen from result more than, because calcium constituent composition, magnesium elements composition and silicon composition are contained in engraving portion, therefore, Marking turns into the material being easily cut by shearing force with print material.Moreover, marking print material, is somebody's turn to do by the blade incision of marking During engraving portion, the blade can be made to be cut with desired angle, moreover, incision can be made with desired power side cutting edge Blade is advanced.Thereby, it is possible to as the marking print material easily carved when being implemented and being marked with print material to marking.
In addition, so, it is comprehensive for, the reasons why as easy engraving, although it is not understood that detailed mechanism, but can push away Examine:If easily cutting off filler composition in engraving portion each other by printing blade, its result is that the grinding stone in engraving portion reduces size [mm] is relative to become big, in addition, can suppress the cut-in angle of blade and desired angle is deviated, moreover, can suppress Power on blade is applied in engraving portion and desired power is inconsistent, this is can to improve the easy journey of engraving that marking prints material One reason of degree.

Claims (9)

1. one kind marking print material, with the engraving portion for being carried out the marking endorsed, it is characterised in that
Thermoplastic resin elements and filler composition are contained in the engraving portion,
The filler composition contains calcium constituent composition, magnesium elements composition and element silicon composition.
2. marking according to claim 1 print material, it is characterised in that the thermoplastic resin elements contain ABS resin Raw material.
3. marking according to claim 1 print material, it is characterised in that
In the filler composition,
Relative to total first prime number of the calcium constituent composition, magnesium elements composition and element silicon composition,
The calcium constituent composition containing 4~85 yuan of prime number %,
The magnesium elements composition containing 5~50 yuan of prime number %, and
The element silicon composition containing 5~60 yuan of prime number %.
4. marking according to claim 2 print material, it is characterised in that
In the filler composition,
Relative to total first prime number of the calcium constituent composition, magnesium elements composition and element silicon composition,
The calcium constituent composition containing 4~85 yuan of prime number %,
The magnesium elements composition containing 5~50 yuan of prime number %, and
The element silicon composition containing 5~60 yuan of prime number %.
5. marking according to claim 1 print material, it is characterised in that
In the filler composition,
Contain calcium carbonate raw material as the raw material containing the calcium constituent composition, and
Contain talcum raw material as the raw material containing the magnesium elements composition and element silicon composition.
6. marking according to claim 2 print material, it is characterised in that
In the filler composition,
Contain calcium carbonate raw material as the raw material containing the calcium constituent composition, and
Contain talcum raw material as the raw material containing the magnesium elements composition and element silicon composition.
7. marking according to claim 3 print material, it is characterised in that
In the filler composition,
Contain calcium carbonate raw material as the raw material containing the calcium constituent composition, and
Contain talcum raw material as the raw material containing the magnesium elements composition and element silicon composition.
8. marking according to claim 4 print material, it is characterised in that
In the filler composition,
Contain calcium carbonate raw material as the raw material containing the calcium constituent composition, and
Contain talcum raw material as the raw material containing the magnesium elements composition and element silicon composition.
9. a kind of seal, it is characterised in that the marking print material recorded with any one of claim 1~8, the seal The marking endorsed is carried out in the engraving portion.
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Citations (10)

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JPH10337943A (en) * 1997-04-08 1998-12-22 Yamahachi Chem Kk Penetration type stamper and manufacture thereof
CN101076561A (en) * 2004-12-16 2007-11-21 西巴特殊化学品控股有限公司 Stabilized organic materials containing fillers
US20100099784A1 (en) * 2005-11-30 2010-04-22 Tsrc Corporation Thermoplastic elastomer foaming material
CN101930682A (en) * 2008-12-24 2010-12-29 天津市世纪东方建筑景观雕塑技术开发中心 Building block type Tang poem seal die toy for children to learn to read
CN102248819A (en) * 2011-04-30 2011-11-23 浦洪杰 Anti-counterfeiting stamp and machining method thereof
CN102476516A (en) * 2010-11-29 2012-05-30 天津市世纪东方建筑景观雕塑技术开发中心 Resin template imitating ink-printed celebrity calligraphy of Duoyunxuan and manufacturing method
CN102601907A (en) * 2011-01-19 2012-07-25 松下几三 Method of producing plastic stamp
US20120240802A1 (en) * 2011-03-22 2012-09-27 Landry-Coltrain Christine J Laser-engraveable flexographic printing precursors
CN103539998A (en) * 2012-07-10 2014-01-29 沙奇哈塔株式会社 Porous material for ink stamps, production method therefor, and self-inking stamp
JP2015106674A (en) * 2013-12-02 2015-06-08 住友ベークライト株式会社 Semiconductor package and structure

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10337943A (en) * 1997-04-08 1998-12-22 Yamahachi Chem Kk Penetration type stamper and manufacture thereof
CN101076561A (en) * 2004-12-16 2007-11-21 西巴特殊化学品控股有限公司 Stabilized organic materials containing fillers
US20100099784A1 (en) * 2005-11-30 2010-04-22 Tsrc Corporation Thermoplastic elastomer foaming material
CN101930682A (en) * 2008-12-24 2010-12-29 天津市世纪东方建筑景观雕塑技术开发中心 Building block type Tang poem seal die toy for children to learn to read
CN102476516A (en) * 2010-11-29 2012-05-30 天津市世纪东方建筑景观雕塑技术开发中心 Resin template imitating ink-printed celebrity calligraphy of Duoyunxuan and manufacturing method
CN102601907A (en) * 2011-01-19 2012-07-25 松下几三 Method of producing plastic stamp
US20120240802A1 (en) * 2011-03-22 2012-09-27 Landry-Coltrain Christine J Laser-engraveable flexographic printing precursors
CN102248819A (en) * 2011-04-30 2011-11-23 浦洪杰 Anti-counterfeiting stamp and machining method thereof
CN103539998A (en) * 2012-07-10 2014-01-29 沙奇哈塔株式会社 Porous material for ink stamps, production method therefor, and self-inking stamp
JP2015106674A (en) * 2013-12-02 2015-06-08 住友ベークライト株式会社 Semiconductor package and structure

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