CN106994802A - A kind of preparation method of high performance ballistic composites - Google Patents
A kind of preparation method of high performance ballistic composites Download PDFInfo
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- CN106994802A CN106994802A CN201710219230.0A CN201710219230A CN106994802A CN 106994802 A CN106994802 A CN 106994802A CN 201710219230 A CN201710219230 A CN 201710219230A CN 106994802 A CN106994802 A CN 106994802A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/02—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by a sequence of laminating steps, e.g. by adding new layers at consecutive laminating stations
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/08—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer the fibres or filaments of a layer being of different substances, e.g. conjugate fibres, mixture of different fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/005—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile
- B32B9/007—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile comprising carbon, e.g. graphite, composite carbon
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B9/047—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material made of fibres or filaments
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/20—All layers being fibrous or filamentary
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/106—Carbon fibres, e.g. graphite fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/558—Impact strength, toughness
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2571/00—Protective equipment
- B32B2571/02—Protective equipment defensive, e.g. armour plates, anti-ballistic clothing
Abstract
A kind of preparation method of high performance ballistic composites, using the compound high-performance special fiber of multicomponent as main reinforcement, using high-performance toughened resin matrix as adhesive, bullet resistant material body is formed by high temperature hot pressing global formation.Bullet resistant material body bullet face be stained with high-performance ceramic reach shellproof class 5 level and more than, and then given full play to the shellproof advantage of Material cladding.The ratio for playing surface layer carbon fiber volume content and back of the body bullet surface layer carbon fiber volume content less than 1.Using the material, on the premise of smaller surface density is ensured, preferable anti-penetration performance can be both realized, can reduce that the larger convex amount of the back of the body causes again injures to human body non-through.Overcome traditional metal materials heaviness and the universal relatively low shortcoming of one-component ballistic composite ballistic performance.
Description
Technical field
The present invention relates to a kind of shellproof technology, particularly a kind of preparation method of high performance ballistic composites.
Background technology
Traditional bullet resistant material is the metal with high intensity mostly, ceramics, the material such as fiberglass.If these materials will take
Bulletproof effect that must be good, generally requires enough thickness, so as to cause the bulletproof device weight being made very big, to bulletproof device
Manufacture and design and bring detrimental effect, the design to bulletproof device brings a variety of limitations.
Fiber-reinforced resin matrix compound material is widely used with its excellent performance in field of compound material, advanced composite
Material is the important component of Aero-Space high-tech product, and it can effectively reduce aircraft, carrier rocket, guided missile and satellite
Weight, increase payload and range, reduce cost.With the change of international situation, terrified and incident of violence also happens occasionally,
Protection question enjoys the concern of society always, and flak jackets, the bulletproof halmet that present police, soldier wear etc. is all the weight of personnel protection
Want part.Specifically now be local war explosion injury ratio it is higher, application of some high-tech products in military affairs makes
Obtain explosion injury end of love and obtain more complicated, while the security protection to people proposes challenge.The science of current various countries national defence
Family various optimization designs just are carried out to bullet resistant material.
The content of the invention
The technical problem to be solved in the present invention is in view of the shortcomings of the prior art, it is proposed that a kind of to ensure smaller surface density
On the premise of, preferable anti-penetration performance can be both realized, can reduce that the convex amount of the larger back of the body causes again hinders to human body non-through
The preparation method of harmful high performance ballistic composites.
The technical problem to be solved in the present invention is achieved through the following technical solutions, a kind of high performance ballistic composite wood
The preparation method of material, is characterized in：Using the compound high-performance special fiber of multicomponent as main reinforcement, with high-performance toughness tree
Aliphatic radical body is adhesive, and bullet resistant material body is formed by high temperature hot pressing global formation.
The technical problem to be solved in the present invention can also come further to realize by the following technical programs, bullet resistant material body
Bullet face be stained with high-performance ceramic reach shellproof class 5 level and more than, and then given full play to the shellproof excellent of Material cladding
Gesture.
The technical problem to be solved in the present invention can also come further to realize by the following technical programs, described multicomponent
Compound high-performance fiber is that carbon fiber is composited with high-performance fiber alternative stacked, and high-performance fiber is that high-strength polyethylene is fine
One or more in dimension, aramid fiber, polyparaphenylene's Benzo-dioxazole, glass fibre.Synthetic fibre fiber, polyparaphenylene Ben Bing bis- Evil
Compound, the carbon fiber of one or both of fibers such as azoles, glass fibre and the above
The technical problem to be solved in the present invention can also come further to realize by the following technical programs, and bullet resistant material body is with thickness
The central compartment of degree is that bullet surface layer and the back of the body play surface layer, bullet surface layer carbon fiber volume content and contains with back of the body bullet surface layer carbon fiber volume
The ratio of amount is less than 1.
The technical problem to be solved in the present invention can also come further to realize by the following technical programs, and the high-performance is tough
Property resin matrix be high-toughness epoxy resin, thermoplasticity or heat-curable urethane, TPO plastics, thermoplastic poly esters
Any one in plastics or two or more combinations.
The technical problem to be solved in the present invention can also come further to realize by the following technical programs, the high-performance pottery
Porcelain comprising oxide, carbide ceramics and nitride special cermacis and with one or both of the composite ceramics of carbon fiber and with
On compound.
The technical problem to be solved in the present invention can also come further to realize by the following technical programs, and the multicomponent is answered
Mould assembly high-performance fiber with high-performance toughened resin matrix is formed by hot pressing global formation, and temperature range is 80 ~ 400 DEG C,
Pressure limit is 0.1 ~ 3.0MPa, and hot pressing time is 20 ~ 300min.
The technical problem to be solved in the present invention can also come further to realize by the following technical programs, the high-performance pottery
Porcelain with bullet resistant material body is formed by high-performance toughness adhesive quick-binding, and the adhesion process is individually shaping pottery
Bonded again after porcelain and bullet resistant material body.
The technical problem to be solved in the present invention can also come further to realize by the following technical programs, bullet resistant material body
Back of the body bullet face conformed to the convex carbon fibre laminates of the anti-back of the body.
The present invention compared with prior art, material sheet is played by main enhancing of the compound high-performance special fiber of multicomponent
Body, using the material, on the premise of smaller surface density is ensured, can both realize preferable anti-penetration performance, can reduce again
What the larger convex amount of the back of the body was caused injures to human body non-through.Overcome traditional metal materials heaviness and one-component ballistic composite
The universal relatively low shortcoming of ballistic performance.
Embodiment
Concrete technical scheme of the invention described further below, in order to which those skilled in the art is further understood that
The present invention, without constituting the limitation to its right.
A kind of preparation method of high performance ballistic composites, using the compound high-performance special fiber of multicomponent as main increasing
Qiang Ti, using high-performance toughened resin matrix as adhesive, bullet resistant material body is formed by high temperature hot pressing global formation.
The compound high-performance fiber of described multicomponent is that carbon fiber is composited with high-performance fiber alternative stacked.
Wherein high-performance fiber is in high-tenacity polyethylene fibre, aramid fiber, polyparaphenylene's Benzo-dioxazole, glass fibre
Any one.Can also be it is above-mentioned it is any two or more.
Its example 1 is that carbon fiber is combined with high-tenacity polyethylene fibre alternative stacked；
Its example 2 is that carbon fiber is combined with aramid fiber alternative stacked；
Its example 3 is that carbon fiber is combined with polyparaphenylene's Benzo-dioxazole alternative stacked；
Its example 4 is that carbon fiber is combined with glass fibre alternative stacked；
Its example 5 is compound for one layer of one floor height strong polyethylene fibres of carbon fiber, one layer of such alternative stacked of aramid fiber；
Its example 6 is that one layer of such alternative stacked of carbon fiber one layer of one floor height strong polyethylene fibres, one layer of carbon fiber aramid fiber is answered
Close；
Its example 7 is one layer of carbon fiber one layer of one floor height strong polyethylene fibres, one layer of carbon fiber, one layer of aramid fiber strata of carbon fiber one
It is compound to the such alternative stacked of penylene Benzo-dioxazole；Etc..
It is 1 ~ 30% that carbon fiber, which accounts for cumulative volume ratio,.
Bullet resistant material body is by bullet surface layer of the central compartment of thickness and the back of the body plays surface layer, bullet surface layer carbon fiber volume and contains
The ratio that amount plays surface layer carbon fiber volume content with the back of the body is less than 1.
The high-performance toughened resin matrix is high-toughness epoxy resin, thermoplasticity or heat-curable urethane, thermoplastic poly
Any one in olefin plastics, thermoplastic poly esters plastics or two or more combinations.
The anti-convex carbon fibre laminates of the back of the body can have individually been conformed in the back of the body bullet face of bullet resistant material body in addition.Reduce to greatest extent
Convex amount is carried on the back, personal safety is protected.
The compound high-performance fiber of multicomponent and high-performance toughened resin matrix are formed by hot pressing global formation,
Temperature range is 80 ~ 400 DEG C, and pressure limit is 0.1 ~ 3.0MPa, and hot pressing time is 20 ~ 300min.
Bullet resistant material body bullet face be stained with high-performance ceramic reach shellproof class 5 level and more than, and then fully send out
The shellproof advantage of Material cladding is waved.
The high-performance ceramic includes oxide, carbide ceramics and nitride special cermacis and the composite ceramic with carbon fiber
The compound of one or both of porcelain and the above.
The high-performance ceramic with bullet resistant material body is formed by high-performance toughness adhesive quick-binding, the bonding
Process is individually bonded after forming ceramic and bullet resistant material body again.
Claims (9)
1. a kind of preparation method of high performance ballistic composites, it is characterised in that：It is fine with the compound high-performance special of multicomponent
Tie up as main reinforcement, using high-performance toughened resin matrix as adhesive, bullet resistant material is formed by high temperature hot pressing global formation
Body.
2. the preparation method of high performance ballistic composites according to claim 1, it is characterised in that：Bullet resistant material body
Bullet face be stained with high-performance ceramic reach shellproof class 5 level and more than.
3. the preparation method of high performance ballistic composites according to claim 1, it is characterised in that：Described multicomponent
Compound high-performance fiber is that carbon fiber is composited with high-performance fiber alternative stacked, and high-performance fiber is that high-strength polyethylene is fine
One or more in dimension, aramid fiber, polyparaphenylene's Benzo-dioxazole, glass fibre.
4. the preparation method of the high performance ballistic composites according to claim 1 or 3, it is characterised in that：Bullet resistant material
Body is by bullet surface layer of the central compartment of thickness and carries on the back bullet surface layer, bullet surface layer carbon fiber volume content and plays surface layer carbon fibre with the back of the body
The ratio for tieing up volume content is less than 1.
5. the preparation method of high performance ballistic composites according to claim 1, it is characterised in that：The high-performance is tough
Property resin matrix be high-toughness epoxy resin, thermoplasticity or heat-curable urethane, TPO plastics, thermoplastic poly esters
Any one in plastics or two or more combinations.
6. the preparation method of high performance ballistic composites according to claim 2, it is characterised in that：The high-performance pottery
Porcelain comprising oxide, carbide ceramics and nitride special cermacis and with one or both of the composite ceramics of carbon fiber and with
On compound.
7. the preparation method of high performance ballistic composites according to claim 1, it is characterised in that：The multicomponent is answered
Mould assembly high-performance fiber with high-performance toughened resin matrix is formed by hot pressing global formation, and temperature range is 80 ~ 400 DEG C,
Pressure limit is 0.1 ~ 3.0MPa, and hot pressing time is 20 ~ 300min.
8. the preparation method of high performance ballistic composites according to claim 2, it is characterised in that：The high-performance pottery
Porcelain with bullet resistant material body is formed by high-performance toughness adhesive quick-binding, and the adhesion process is individually shaping pottery
Bonded again after porcelain and bullet resistant material body.
9. the preparation method of high performance ballistic composites according to claim 1, it is characterised in that：Bullet resistant material body
Back of the body bullet face conformed to the convex carbon fibre laminates of the anti-back of the body.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710219230.0A CN106994802B (en) | 2017-04-06 | 2017-04-06 | A kind of preparation method of high performance ballistic composites |
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| CN201710219230.0A CN106994802B (en) | 2017-04-06 | 2017-04-06 | A kind of preparation method of high performance ballistic composites |
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| CN106994802B CN106994802B (en) | 2019-08-16 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112592561A (en) * | 2020-12-10 | 2021-04-02 | 四川辉腾科技股份有限公司 | Resin for bulletproof ceramic/aramid III composite armor and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112592561A (en) * | 2020-12-10 | 2021-04-02 | 四川辉腾科技股份有限公司 | Resin for bulletproof ceramic/aramid III composite armor and preparation method thereof |
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| CN106994802B (en) | 2019-08-16 |
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