CN106994725A - It is a kind of to be used to impregnate rosin furans preservative of poplar and its preparation method and application - Google Patents
It is a kind of to be used to impregnate rosin furans preservative of poplar and its preparation method and application Download PDFInfo
- Publication number
- CN106994725A CN106994725A CN201710388498.7A CN201710388498A CN106994725A CN 106994725 A CN106994725 A CN 106994725A CN 201710388498 A CN201710388498 A CN 201710388498A CN 106994725 A CN106994725 A CN 106994725A
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- China
- Prior art keywords
- rosin
- furans
- poplar
- preservative
- parts
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
- B27K3/50—Mixtures of different organic impregnating agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/02—Processes; Apparatus
- B27K3/08—Impregnating by pressure, e.g. vacuum impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K5/00—Treating of wood not provided for in groups B27K1/00, B27K3/00
- B27K5/001—Heating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K2240/00—Purpose of the treatment
- B27K2240/20—Removing fungi, molds or insects
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Forests & Forestry (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of rosin furans preservative for being used to impregnate poplar and its preparation method and application.The preservative is main as made by the raw material of following parts by weight：100 parts of rosin alcoholic solution, 20 30 parts of furans monomer；The rosin alcoholic solution is that 20 30 parts of rosin and 100 200 parts of organic solvents are stirred and are made by parts by weight.The rosin furans preservative for being used to impregnate poplar of the present invention is prepared simply, and cost is low, nonhazardous effect；The heavy metal chemical preservation of conventional high pollution can effectively be replaced, pollution, and favorable anti-corrosion effect is reduced, the durability of poplar can be effectively improved；The physics and chemical property of poplar material can be changed by the rosin furan polymer impregnation, so that poplar material corrosion resistant performance is good, resistance leachability is good, and without heavy metal, Anti-moth-eating, antimycotic, rotproof performance are strengthened.
Description
Technical field
The invention belongs to wood processing field, it is related to raising wood preservation from decay moth, prevents rotten and physical property processing side
Method, and in particular to a kind of to be used to impregnate rosin furans preservative of poplar and its preparation method and application.
Technical background
In today of timber resources growing tension, how fast-growing forest timber is effectively utilized, make it have more wide answer
It is to alleviate the nervous effective ways of timber resources with scope.Poplar material is poor, easily damages by worms rotten, and existing poplar wood preservation is main
Be by impregnate anti-corrosion agent and destroy mushroom life condition, suppress domestomycetes breeding and existence and realize.In recent years
Come, poplar wood working industry is handled fast-growing forest timber by a variety of methods, to obtain ideal material, Yi Jifang
Damage by worms, prevent rotten performance.Processing method is a lot, but the maceration extract used that exists that these methods have is polluted to environment, state
Inside and outside conventional timber preservative mainly has CCA, copper chromium boron (CCB), fluorine chromium phenol arsenic (FCAP), ammonical copper arsenite (ACA), acidity
Copper chromate (ACC) etc., some handling process route length, cost are high.Rich in phenols, organic acid, furans, alcohols etc. in rosin
Compound, with certain bactericidal effect, also has application potential, but still lack corresponding technical side at present in corrosion-resistant field
Method.
The content of the invention
Goal of the invention：The problem of existing for prior art, the present invention provides a kind of rosin furans for being used to impregnate poplar
Preservative.The rosin furans preservative, raw material sources are wide, can effectively replace the heavy metal chemical preservation of conventional high pollution,
Pollution, and favorable anti-corrosion effect are reduced, the durability of poplar can be effectively improved.
The present invention also provides the preparation method and application that this is used to impregnate the rosin furans preservative of poplar.
Technical scheme：To achieve these goals, a kind of rosin furans for being used to impregnate poplar is prevented as described in the present invention
Rotten agent, mainly as made by the raw material of following parts by weight：100 parts of rosin alcoholic solution, 20-30 parts of furans monomer；The rosin spirit
Solution is that 20-30 parts of rosin and 100-200 parts of organic solvents are stirred and are made by parts by weight.
Preferably, the furans monomer is high pure tetrahydrofuran.
The high pure tetrahydrofuran is hydrolyzed generation butylene glycol by Isosorbide-5-Nitrae-dichloro-butenes in sodium hydroxide solution, is centrifuged dense
Contracting, removes high-boiling components, and butylene glycol is hydrogenated to after butanediol, distillation to generate thick tetrahydrofuran, continues distillation dehydration and de-
High-boiling components are obtained.
Wherein, the organic solvent is absolute ethyl alcohol.
The rosin is acquired from resin tapping seeds masson pine, pinus yunnanensis, pinus khasys or pinus finlaysoniana seeds.
The rosin alcoholic solution is stirred by rosin and organic solvent in the case where temperature is 40 DEG C of water bath conditions, until
To uniform rosin solution, as rosin alcoholic solution.
The preparation method of the present invention for being used to impregnate the rosin furans preservative of poplar, comprises the following steps：In pine
Furans monomer is added in lipidol solution, microwave treatment is carried out after being well mixed, microwave treatment power is 100-200W, processing time
For 5-10min or so, treatment temperature is 20-30 DEG C, and reaction end obtains rosin furans preservative.
Application of the rosin furans preservative of the present invention for being used to impregnate poplar in poplar durability is improved.
The method for improving poplar durability, comprises the following steps：Cottonwood plank stuff is dried to moisture content less than 10%,
Then in the process tank for being placed on filling rosin furans preservative, 90-100 DEG C is warming up to, pressure inside the tank is 0.8-
1.2MPa, reacts 2.5-3.5 hours in this case, is cooled down more than 4 hours after pressure release.
Beneficial effect：Compared with prior art, the rosin furans preservative for being used to impregnate poplar of the invention is prepared simply,
Raw material sources are wide, and cost is low, nonhazardous effect；The heavy metal chemical preservation of conventional high pollution can effectively be replaced, weight is reduced
Metallic pollution, and favorable anti-corrosion effect, can effectively improve the durability of poplar；Soaked by the rosin furan polymer preservative
Stain can change the physics and chemical property of poplar material, so that poplar material corrosion resistant performance is good, resistance leachability is good, and be free of
Heavy metal, Anti-moth-eating, antimycotic, rotproof performance are strengthened.
Embodiment
The invention will be further described with reference to embodiments.
Embodiment 1
(1) 20 parts of rosin, 100 parts of absolute ethyl alcohol are gathered from masson pine, is stirred in the case where temperature is 40 DEG C of water bath conditions
Mix, until obtaining uniform rosin solution, as rosin alcoholic solution.
(2) Isosorbide-5-Nitrae-dichloro-butenes is hydrolyzed in sodium hydroxide solution, butylene glycol is generated at 110 DEG C, centrifugation is gone
Fall sodium chloride, filtrate concentrates in crystallizing evaporator, isolates alkali metal carboxylate, then removes high-boiling components in a distillation column.Will
Butylene glycol feeding reactor after refined, using nickel as catalyst, under 80~120 DEG C and certain pressure, butylene glycol hydrogenation
Butanediol is generated, laggard people's ring-closure reaction device is distilled, generates thick tetrahydrochysene furan in acid medium at normal pressure and 120~140 DEG C
Mutter, distillation dehydration and de- high-boiling components finally distill to obtain high pure tetrahydrofuran.
(3) high 20 parts of pure tetrahydrofuran is added in 100 parts of rosin alcoholic solutions, microwave treatment, microwave is carried out after being well mixed
Processing power is 100W, and processing time is 5min or so, and treatment temperature is 20 DEG C, and reaction end obtains rosin furans preservative.
Embodiment 2
(1) 30 parts of rosin, 200 parts of absolute ethyl alcohol are gathered from pinus yunnanensis, is stirred in the case where temperature is 40 DEG C of water bath conditions
Mix, until obtaining uniform rosin solution, as rosin alcoholic solution.
(2) Isosorbide-5-Nitrae-dichloro-butenes is hydrolyzed in sodium hydroxide solution, butylene glycol is generated at 110 DEG C, centrifugation is gone
Fall sodium chloride, filtrate concentrates in crystallizing evaporator, isolates alkali metal carboxylate, then removes high-boiling components in a distillation column.Will
Butylene glycol feeding reactor after refined, using nickel as catalyst, under 80~120 DEG C and certain pressure, butylene glycol hydrogenation
Butanediol is generated, laggard people's ring-closure reaction device is distilled, generates thick tetrahydrochysene furan in acid medium at normal pressure and 120~140 DEG C
Mutter, distillation dehydration and de- high-boiling components finally distill to obtain high pure tetrahydrofuran.
(3) high 30 parts of pure tetrahydrofuran is added in 100 parts of rosin alcoholic solutions, microwave treatment, microwave is carried out after being well mixed
Processing power is 200W, and processing time is 10min or so, and treatment temperature is 30 DEG C, and reaction end obtains rosin furans preservative.
Embodiment 3
(1) 25 parts of rosin, 150 parts of absolute ethyl alcohol are gathered from pinus finlaysoniana, is stirred in the case where temperature is 40 DEG C of water bath conditions
Mix, until obtaining uniform rosin solution, as rosin alcoholic solution.
(2) Isosorbide-5-Nitrae-dichloro-butenes is hydrolyzed in sodium hydroxide solution, butylene glycol is generated at 110 DEG C, centrifugation is gone
Fall sodium chloride, filtrate concentrates in crystallizing evaporator, isolates alkali metal carboxylate, then removes high-boiling components in a distillation column.Will
Butylene glycol feeding reactor after refined, using nickel as catalyst, under 80~120 DEG C and certain pressure, butylene glycol hydrogenation
Butanediol is generated, laggard people's ring-closure reaction device is distilled, generates thick tetrahydrochysene furan in acid medium at normal pressure and 120~140 DEG C
Mutter, distillation dehydration and de- high-boiling components finally distill to obtain high pure tetrahydrofuran.
(3) high 25 parts of pure tetrahydrofuran is added in 100 parts of rosin alcoholic solutions, microwave treatment, microwave is carried out after being well mixed
Processing power is 150W, and processing time is 8min or so, and treatment temperature is 25 DEG C, and reaction end obtains rosin furans preservative.
Embodiment 4
Cottonwood plank stuff is dried to moisture content less than 10%, is then placed on filling any one side of embodiment 1-3
In the process tank of rosin furans preservative prepared by method, 90 DEG C are warming up to, pressure inside the tank is 0.8MPa, is reacted in this case
2.5 hours, cooled down 5 hours after pressure release.
Embodiment 5
Cottonwood plank stuff is dried to moisture content less than 10%, is then placed on filling the processing of rosin furans preservative
In tank, 100 DEG C are warming up to, pressure inside the tank is 1.2MPa, reacted 3.5 hours in this case, cooled down 6 hours after pressure release.
Test example 1
Detected using the method for the embodiment of the present invention 5, at the rosin furans impregnation poplar with embodiment 1-3 preparations
After reason, (quality of rotproofness is the weight loss percentage by calculating every piece of sample after rotten to the rotproofness of detection poplar
Height evaluate), whether containing indexs such as heavy metal, Anti-moth-eating effect, cost, leachabilities.Commonly used simultaneously using in the market
Timber preservative CCA, handled as a comparison using the method for embodiment 5, investigate same batch timber, use different anti-corrosions
Each index situation after agent processing certain time；It the results are shown in Table 1.
Table 1
From table 1, the rosin furans preservative and existing timber preservative for impregnating poplar prepared by the present invention
Compare, corrosion resistant performance is good, resistance leachability can effectively improve well the durability of poplar, and without heavy metal, do not result in weight
Metallic pollution, and cost is low, and Anti-moth-eating, antimycotic, anti-rotten performance are strong.The rosin furans of used dipping poplar of the invention
Preservative, can not only improve the durability of poplar, be equally applicable for other timber.
Claims (8)
1. a kind of rosin furans preservative for being used to impregnate poplar, it is characterised in that main made by the raw material of following parts by weight
Into：100 parts of rosin alcoholic solution, 20-30 parts of furans monomer；The rosin alcoholic solution is 20-30 parts of rosin and 100- by parts by weight
200 parts of organic solvent stirrings are made.
2. the rosin furans preservative according to claim 1 for being used to impregnate poplar, it is characterised in that the furans monomer
For high pure tetrahydrofuran.
3. the rosin furans preservative according to claim 2 for being used to impregnate poplar, it is characterised in that high-purity tetrahydrochysene
Furans is hydrolyzed generation butylene glycol by Isosorbide-5-Nitrae-dichloro-butenes in sodium hydroxide solution, and centrifugal concentrating removes high-boiling components, by butylene
Glycol is hydrogenated to after butanediol, distillation generate thick tetrahydrofuran, continues distillation dehydration and de- high-boiling components are obtained.
4. the rosin furans preservative according to claim 1 for being used to impregnate poplar, it is characterised in that the organic solvent
For absolute ethyl alcohol.
5. according to claim 1 be used to impregnate the rosin furans preservative of poplar, it is characterised in that the rosin is from adopting
It is acquired on fat seeds masson pine, pinus yunnanensis, pinus khasys or pinus finlaysoniana seeds.
6. being used for described in a kind of claim 1 impregnates the preparation method of the rosin furans preservative of poplar, it is characterised in that bag
Include following steps：Furans monomer is added in rosin alcoholic solution, microwave treatment is carried out after being well mixed, microwave treatment power is
100-200W, processing time is 5-10min or so, and treatment temperature is 20-30 DEG C, and reaction end obtains rosin furans preservative.
7. being used for described in a kind of claim 1 impregnates the rosin furans preservative of poplar answering in poplar durability is improved
With.
8. application according to claim 7, it is characterised in that the method for improving poplar durability, including following step
Suddenly：Cottonwood plank stuff is dried to moisture content less than 10%, in the process tank for being then placed on filling rosin furans preservative,
90-100 DEG C is warming up to, pressure inside the tank is 0.8-1.2MPa, reacted 2.5-3.5 hours in this case, cooled down 4 hours after pressure release
More than.
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| CN201710388498.7A CN106994725B (en) | 2017-05-27 | 2017-05-27 | It is a kind of to be used to impregnate rosin furans preservative of poplar and its preparation method and application |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109352776A (en) * | 2018-11-13 | 2019-02-19 | 中国林业科学研究院林产化学工业研究所 | A kind of method that abietyl unsaturated-resin improves fast growing wood performance |
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| CN109352776A (en) * | 2018-11-13 | 2019-02-19 | 中国林业科学研究院林产化学工业研究所 | A kind of method that abietyl unsaturated-resin improves fast growing wood performance |
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| CN106994725B (en) | 2018-08-21 |
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