CN106987225A - A kind of road and bridge quickly repairs glue - Google Patents
A kind of road and bridge quickly repairs glue Download PDFInfo
- Publication number
- CN106987225A CN106987225A CN201710328587.2A CN201710328587A CN106987225A CN 106987225 A CN106987225 A CN 106987225A CN 201710328587 A CN201710328587 A CN 201710328587A CN 106987225 A CN106987225 A CN 106987225A
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- CN
- China
- Prior art keywords
- parts
- road
- bridge
- glue
- heat filling
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J171/00—Adhesives based on polyethers obtained by reactions forming an ether link in the main chain; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
Glue is quickly repaired the invention discloses a kind of road and bridge, is prepared from by the raw material of following parts by weight：MG anchors 31 39 parts of resin, 39 parts of AS resins, 35 45 parts of trihydroxy polyethers, 5 25 parts of heat filling, 7 13 parts of talcum powder, 11 27 parts of benzoyl peroxide, 9 11 parts of 2 Australia, 3 nitrotoleune, 6 12 parts of 3 cyano group, 5 flurophenyl boronic acid, 0.1 0.2 parts of nano silicon, 0.5 5 parts of chemicals-resistant modifying agent, 10 15 parts of propylene Korean pine (2 p-nitrophenyl) thiadiazoles, 0.75 3.25 parts of infrared external reflection titanium dioxide, 4.5 6.5 parts of PPG, 0.3 0.7 parts of light stabilizer.Reparation glue obtained by the present invention has the advantages that hardening time is fast, gain in strength is fast, intensity is high, rotproofness is good, good weatherability, can be firmly cohesive miscible in one with original reinforcing bar, concrete, wood etc..
Description
Technical field
Glue is repaired the present invention relates to one kind, and in particular to a kind of road and bridge quickly repairs glue.
Background technology
As the links of the developing rapidly of economic society, road traffic, transportation economics society and people are all played
Road caused by all unavoidable such or such uncertain natural calamity in vital field, China or even the whole world
Road and bridge beam it is impaired, existing road rehabilitation glue generally existing corrosion-resistant, poor weatherability, hardening time length, intensity are low
Defect, therefore, urgent need develop a kind of quick reparation glue for road and bridge.
The content of the invention
To solve the above problems, quickly repairing glue the invention provides a kind of road and bridge.
To achieve the above object, the technical scheme taken of the present invention is：
A kind of road and bridge quickly repairs glue, is prepared from by the raw material of following parts by weight：
31-39 parts of resin of MG anchorings, 3-9 parts of AS resins, 35-45 parts of trihydroxy polyethers, 5-25 parts of heat filling, talcum powder
7-13 parts, 11-27 parts of benzoyl peroxide, 9-11 parts of 2- bromo- 3- nitrotoleunes, 6-12 parts of 3- cyano group -5- fluoro-phenyl boric acid,
0.1-0.2 parts of nano silicon, 0.5-5 parts of chemicals-resistant modifying agent, propylene Korean pine (2- p-nitrophenyls) thiadiazoles 10-15
Part, 0.75-3.25 parts of infrared external reflection titanium dioxide, 4.5-6.5 parts of PPG, 0.3-0.7 parts of light stabilizer.
Wherein, the molecular weight of the AS is 10000~80000, includes 10~30% acrylonitrile, 70~90% benzene second
Alkene.
Wherein, the chemicals-resistant modifying agent is the acrylic acid series additive of perfluoroalkyl, and molecular weight is 1000-10000,
Can exist for liquid or solid form.
Wherein, described heat filling is magnesia, aluminum oxide, zinc oxide, magnesium hydroxide, aluminium hydroxide, boron nitride, nitrogen
Change one or both of aluminium, the particle diameter of the heat filling is in 0.5um-2um, and purity is more than 98%.
Wherein, described light stabilizer be salicylate, benzophenone, triazines, benzotriazole UV absorbents with
And one or more mixtures in hindered amines free radical scavenger.
Preferably, it is prepared from by the raw material of following parts by weight：
31 parts of resin of MG anchorings, 3 parts of AS resins, 35 parts of trihydroxy polyethers, 5 parts of heat filling, 7 parts of talcum powder, peroxidating
9 parts of the bromo- 3- nitrotoleunes of 11 parts of benzoyl, 2-, 6 parts of 3- cyano group -5- fluoro-phenyls boric acid, 0.1 part of nano silicon, resistance toization
0.5 part of product modifying agent, 10 parts of propylene Korean pine (2- p-nitrophenyls) thiadiazoles, 0.75 part of infrared external reflection titanium dioxide, polyethers
4.5 parts of polyalcohol, 0.3 part of light stabilizer.
Preferably, it is prepared from by the raw material of following parts by weight：
39 parts of resin of MG anchorings, 9 parts of AS resins, 45 parts of trihydroxy polyethers, 25 parts of heat filling, 13 parts of talcum powder, peroxide
Change 27 parts of benzoyl, 11 parts of the bromo- 3- nitrotoleunes of 2-, 12 parts of 3- cyano group -5- fluoro-phenyls boric acid, 0.2 part of nano silicon,
It is 5 parts of chemicals-resistant modifying agent, 15 parts of propylene Korean pine (2- p-nitrophenyls) thiadiazoles, 3.25 parts of infrared external reflection titanium dioxide, poly-
6.5 parts of ethoxylated polyhydric alcohol, 0.7 part of light stabilizer.
Preferably, it is prepared from by the raw material of following parts by weight：
35 parts of resin of MG anchorings, 6 parts of AS resins, 40 parts of trihydroxy polyethers, 15 parts of heat filling, 10 parts of talcum powder, peroxide
Change 19 parts of benzoyl, 10 parts of the bromo- 3- nitrotoleunes of 2-, 9 parts of 3- cyano group -5- fluoro-phenyls boric acid, 0.15 part of nano silicon,
2.75 parts of chemicals-resistant modifying agent, 12.5 parts of propylene Korean pine (2- p-nitrophenyls) thiadiazoles, 2 parts of infrared external reflection titanium dioxide,
5.5 parts of PPG, 0.5 part of light stabilizer.
The invention has the advantages that：
The reparation glue of gained has the advantages that hardening time is fast, gain in strength is fast, intensity is high, rotproofness is good, good weatherability,
And can firmly be bonded with original reinforcing bar, concrete, wood, stone structure it is miscible in one, also with integrated cost is low, solidification
Advantage nontoxic afterwards, easy to operation, is the emergent preferred material of road and bridge.By adding the bromo- 3- nitros first of 2-
The materials such as benzene, 3- cyano group -5- fluoro-phenyl boric acid, add the intensity for repairing glue, make the toughness of reparation glue more preferable；Introduce perfluor
The acrylic acid series additive of alkyl is as chemicals-resistant modifying agent, and the transport efficiency of the additive is high, is in the curing process
Surface can be completely migrating to and form a kind of diaphragm, this layer of diaphragm and water is incompatible and performance with stronger acid and alkali-resistance,
So as to improve repair glue anticorrosive property, using infrared external reflection titanium dioxide, can significantly the visible ray of reflected sunlight and
The collaboration contribution of infrared part energy, in addition the heat release of heat filling, can make greatly to reduce the surface for repairing glue
Temperature, improves the weatherability for repairing glue.
Embodiment
In order that objects and advantages of the present invention are more clearly understood, the present invention is carried out with reference to embodiments further
Describe in detail.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to limit this hair
It is bright.
In following examples, used AS molecular weight is 10000~80000, includes 10~30% acrylonitrile, 70
~90% styrene, the chemicals-resistant modifying agent is the acrylic acid series additive of perfluoroalkyl, and molecular weight is 1000-
10000, can exist for liquid or solid form, described heat filling is magnesia, aluminum oxide, zinc oxide, magnesium hydroxide,
One or both of aluminium hydroxide, boron nitride, aluminium nitride, the particle diameter of the heat filling is in 0.5um-2um, and purity is more than
98%, described light stabilizer is salicylate, benzophenone, triazines, the UV absorbents and hindered amine of benzotriazole
One or more mixtures in type free base agent for capturing.
Embodiment 1
A kind of road and bridge quickly repairs glue, is prepared from by the raw material of following parts by weight：
31 parts of resin of MG anchorings, 3 parts of AS resins, 35 parts of trihydroxy polyethers, 5 parts of heat filling, 7 parts of talcum powder, peroxidating
9 parts of the bromo- 3- nitrotoleunes of 11 parts of benzoyl, 2-, 6 parts of 3- cyano group -5- fluoro-phenyls boric acid, 0.1 part of nano silicon, resistance toization
0.5 part of product modifying agent, 10 parts of propylene Korean pine (2- p-nitrophenyls) thiadiazoles, 0.75 part of infrared external reflection titanium dioxide, polyethers
4.5 parts of polyalcohol, 0.3 part of light stabilizer.
Embodiment 2
A kind of road and bridge quickly repairs glue, is prepared from by the raw material of following parts by weight：
39 parts of resin of MG anchorings, 9 parts of AS resins, 45 parts of trihydroxy polyethers, 25 parts of heat filling, 13 parts of talcum powder, peroxide
Change 27 parts of benzoyl, 11 parts of the bromo- 3- nitrotoleunes of 2-, 12 parts of 3- cyano group -5- fluoro-phenyls boric acid, 0.2 part of nano silicon,
It is 5 parts of chemicals-resistant modifying agent, 15 parts of propylene Korean pine (2- p-nitrophenyls) thiadiazoles, 3.25 parts of infrared external reflection titanium dioxide, poly-
6.5 parts of ethoxylated polyhydric alcohol, 0.7 part of light stabilizer.
Embodiment 3
A kind of road and bridge quickly repairs glue, is prepared from by the raw material of following parts by weight：
35 parts of resin of MG anchorings, 6 parts of AS resins, 40 parts of trihydroxy polyethers, 15 parts of heat filling, 10 parts of talcum powder, peroxide
Change 19 parts of benzoyl, 10 parts of the bromo- 3- nitrotoleunes of 2-, 9 parts of 3- cyano group -5- fluoro-phenyls boric acid, 0.15 part of nano silicon,
2.75 parts of chemicals-resistant modifying agent, 12.5 parts of propylene Korean pine (2- p-nitrophenyls) thiadiazoles, 2 parts of infrared external reflection titanium dioxide,
5.5 parts of PPG, 0.5 part of light stabilizer.
Described above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, under the premise without departing from the principles of the invention, some improvements and modifications can also be made, these improvements and modifications also should
It is considered as protection scope of the present invention.
Claims (8)
1. a kind of road and bridge quickly repairs glue, it is characterised in that be prepared from by the raw material of following parts by weight：
31-39 parts of resin of MG anchorings, 3-9 parts of AS resins, 35-45 parts of trihydroxy polyethers, 5-25 parts of heat filling, talcum powder 7-13
Part, 11-27 parts of benzoyl peroxide, 9-11 parts of 2- bromo- 3- nitrotoleunes, 6-12 parts of 3- cyano group -5- fluoro-phenyl boric acid, nanometer
0.1-0.2 parts of silica, 0.5-5 parts of chemicals-resistant modifying agent, 10-15 parts of propylene Korean pine (2- p-nitrophenyls) thiadiazoles,
0.75-3.25 parts of infrared external reflection titanium dioxide, 4.5-6.5 parts of PPG, 0.3-0.7 parts of light stabilizer.
2. a kind of road and bridge as claimed in claim 1 quickly repairs glue, it is characterised in that the molecular weight of the AS is
10000~80000, including 10~30% acrylonitrile, 70~90% styrene.
3. a kind of road and bridge as claimed in claim 1 quickly repairs glue, it is characterised in that the chemicals-resistant modifying agent is
The acrylic acid series additive of perfluoroalkyl, molecular weight is 1000-10000, can be existed for liquid or solid form.
4. a kind of road and bridge as claimed in claim 1 quickly repairs glue, it is characterised in that described heat filling is oxidation
One or both of magnesium, aluminum oxide, zinc oxide, magnesium hydroxide, aluminium hydroxide, boron nitride, aluminium nitride, the heat filling
Particle diameter is more than 98% in 0.5um-2um, purity.
5. a kind of road and bridge as claimed in claim 1 quickly repairs glue, it is characterised in that described light stabilizer is bigcatkin willow
Acid esters, benzophenone, triazines, the UV absorbents of benzotriazole and one kind or many in hindered amines free radical scavenger
Plant mixture.
6. a kind of road and bridge as claimed in claim 1 quickly repairs glue, it is characterised in that by the raw material system of following parts by weight
It is standby to form：
31 parts of resin of MG anchorings, 3 parts of AS resins, 35 parts of trihydroxy polyethers, 5 parts of heat filling, 7 parts of talcum powder, benzoyl peroxide first
9 parts of the bromo- 3- nitrotoleunes of 11 parts of acyl, 2-, 6 parts of 3- cyano group -5- fluoro-phenyls boric acid, 0.1 part of nano silicon, chemicals-resistant
0.5 part of modifying agent, 10 parts of propylene Korean pine (2- p-nitrophenyls) thiadiazoles, 0.75 part of infrared external reflection titanium dioxide, polyether polyols
4.5 parts of alcohol, 0.3 part of light stabilizer.
7. a kind of road and bridge as claimed in claim 1 quickly repairs glue, it is characterised in that by the raw material system of following parts by weight
It is standby to form：
39 parts of resin of MG anchorings, 9 parts of AS resins, 45 parts of trihydroxy polyethers, 25 parts of heat filling, 13 parts of talcum powder, benzoyl peroxide
11 parts of the bromo- 3- nitrotoleunes of 27 parts of formyl, 2-, 12 parts of 3- cyano group -5- fluoro-phenyls boric acid, 0.2 part of nano silicon, resistance toization
5 parts of product modifying agent, 15 parts of propylene Korean pine (2- p-nitrophenyls) thiadiazoles, 3.25 parts of infrared external reflection titanium dioxide, polyethers are more
First 6.5 parts of alcohol, 0.7 part of light stabilizer.
8. a kind of road and bridge as claimed in claim 1 quickly repairs glue, it is characterised in that by the raw material system of following parts by weight
It is standby to form：
35 parts of resin of MG anchorings, 6 parts of AS resins, 40 parts of trihydroxy polyethers, 15 parts of heat filling, 10 parts of talcum powder, benzoyl peroxide
10 parts of the bromo- 3- nitrotoleunes of 9 parts of formyl chloride-1,2-, 9 parts of 3- cyano group -5- fluoro-phenyls boric acid, 0.15 part of nano silicon, resistance toization
2.75 parts of product modifying agent, 12.5 parts of propylene Korean pine (2- p-nitrophenyls) thiadiazoles, 2 parts of infrared external reflection titanium dioxide, polyethers
5.5 parts of polyalcohol, 0.5 part of light stabilizer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710328587.2A CN106987225A (en) | 2017-05-06 | 2017-05-06 | A kind of road and bridge quickly repairs glue |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710328587.2A CN106987225A (en) | 2017-05-06 | 2017-05-06 | A kind of road and bridge quickly repairs glue |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106987225A true CN106987225A (en) | 2017-07-28 |
Family
ID=59418266
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710328587.2A Pending CN106987225A (en) | 2017-05-06 | 2017-05-06 | A kind of road and bridge quickly repairs glue |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106987225A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108300409A (en) * | 2018-02-06 | 2018-07-20 | 山东交通学院 | A kind of high viscoplasticity gap-grouting material and preparation method thereof for acid aggregate bituminous paving |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105906231A (en) * | 2016-04-19 | 2016-08-31 | 鄂尔多斯市益山煤炭应用化学研究所 | A road and bridge rapid repairing adhesive |
-
2017
- 2017-05-06 CN CN201710328587.2A patent/CN106987225A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105906231A (en) * | 2016-04-19 | 2016-08-31 | 鄂尔多斯市益山煤炭应用化学研究所 | A road and bridge rapid repairing adhesive |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108300409A (en) * | 2018-02-06 | 2018-07-20 | 山东交通学院 | A kind of high viscoplasticity gap-grouting material and preparation method thereof for acid aggregate bituminous paving |
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| PB01 | Publication | ||
| PB01 | Publication | ||
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170728 |
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| RJ01 | Rejection of invention patent application after publication |