CN106979963A - A kind of device for measuring water quality pH value - Google Patents

A kind of device for measuring water quality pH value Download PDF

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Publication number
CN106979963A
CN106979963A CN201710418105.2A CN201710418105A CN106979963A CN 106979963 A CN106979963 A CN 106979963A CN 201710418105 A CN201710418105 A CN 201710418105A CN 106979963 A CN106979963 A CN 106979963A
Authority
CN
China
Prior art keywords
electrode
measuring
impedance transducer
value
water quality
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710418105.2A
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Chinese (zh)
Inventor
金为民
马丹
邱立斌
王亮
王春林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DALIAN HUACHENG ELECTRONICS Co Ltd
Original Assignee
DALIAN HUACHENG ELECTRONICS Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DALIAN HUACHENG ELECTRONICS Co Ltd filed Critical DALIAN HUACHENG ELECTRONICS Co Ltd
Priority to CN201710418105.2A priority Critical patent/CN106979963A/en
Publication of CN106979963A publication Critical patent/CN106979963A/en
Pending legal-status Critical Current

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Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/28Electrolytic cell components
    • G01N27/30Electrodes, e.g. test electrodes; Half-cells
    • G01N27/302Electrodes, e.g. test electrodes; Half-cells pH sensitive, e.g. quinhydron, antimony or hydrogen electrodes
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/28Electrolytic cell components
    • G01N27/30Electrodes, e.g. test electrodes; Half-cells
    • G01N27/36Glass electrodes

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Molecular Biology (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)

Abstract

A kind of device for measuring water quality pH value, has measuring instrumentss and sensor, sensor includes resistance converter, measuring electrode, glass ball bulb, reference liquid, reference electrode, temperature electrode, the measuring instrumentss are connected by common cable with impedance transducer one end, and measuring electrode is connected with the impedance transducer other end, and impedance transducer is externally provided with electrode cap, sealing is provided with electrode cap, the impedance transducer other end is also associated with reference electrode, glass ball bulb, temperature electrode.Shorten the transmission range of high resistant signal, it is ensured that signal does not lose and improves interference free performance.

Description

A kind of device for measuring water quality pH value
Technical field
The present invention relates to water quality measurement field, specifically a kind of water quality pH value measurement apparatus.
Background technology
Often occur that measured value is inaccurate in the pH value measurement of existing water quality, multilist measures same water sample simultaneously, several The inconsistent phenomenon of value, also, measuring instrument the problem of also have potential drifting in use for some time, is brought to user Inconvenience, can seriously cause the failure of controlled industrial equipment, and sewage discharge is unqualified, the problem of pollution environment.
It has been investigated that the appearance of above mentioned problem, electric potential signal, insulation mainly due to the glass sensitive membrane of pH electrodes Caused by the parameter such as characteristic and the noise signal of electrode signal transmission cable.Electrode is easily by extraneous temperature, humidity, tested water The influence of electromagnetism harmonic wave interference in sample conductivity value, dielectric insulation degree, signal-transmitting cable self-noise and air, and cause pH The unordered fluctuation of electrode signal, so cause measured value change, it is inaccurate.
The content of the invention
To solve the above problems, the present invention provides a kind of measured value accurate, stable measurement water quality pH value device.
Scheme of the present invention is:Measuring instrumentss in device are connected by common cable and impedance transducer one end Connect, the impedance transducer other end is directly connected with measuring electrode, shorten the transmission range of high resistant signal, it is ensured that signal is not damaged Lose and improve interference free performance.Impedance transducer is externally provided with electrode cap, and electrode cap has the effect of protection impedance transducer.Electricity Sealing is provided with polar cap, the sealing is high insulation and shielding material.The impedance transducer other end is also associated with reference electrode, glass Glass ball bubble, temperature electrode.
Using the measurement apparatus of this structure, when measuring water quality pH value, signal antijamming capability is improved, is measured Water quality PH numerical value it is accurate, and stably.The numerical value that this invention is measured not only is stablized, accurately, and the transmission of signal Distance is still stablized after extending hundreds of meters, expands the use scope at scene.
Brief description of the drawings
Fig. 1 is original measurement apparatus structure chart;
Fig. 2 is the structure chart of this invention;
In figure, 1- glass ball bulbs, 2- measuring electrodes, 3- reference electrodes, 4- low noise cables, 5- impedance transducers, 6- measuring instrumentss, 7- electrode caps, 8- sealings, 9- temperature electrodes, 10- common cables.
Specific embodiment
A kind of device of measurement water quality pH value as shown in Figure 2, measuring instrumentss 6 pass through common cable 10 and impedance transducer 5 one end are connected, and impedance transducer 5 is externally provided with electrode cap 7, and electrode cap plays protection impedance transducer, and shielding uses copper aluminium Alloy Foil.Sealing 8 is provided with electrode cap 7, height insulation sealing uses epoxy resin and polytetrafluoroethylene (PTFE).Impedance transducer 5 is another End is directly connected with measuring electrode 2, and the other end of impedance transducer 5 is also associated with temperature electrode 9, reference electrode 3 and glass marble Bubble 1.
Measurement apparatus is put into water sample to be measured, switched on power, water sample to be measured is measured, the data after measurement pass through Instrument display is shown.
Present invention reduces the transmission range of high resistant signal, signal antijamming capability is improved, the water quality PH measured It is value stabilization, accurate.

Claims (2)

1. a kind of device for measuring water quality pH value, there is measuring instrumentss and sensor, sensor includes resistance converter, measurement electricity Pole, glass ball bulb, reference liquid, reference electrode, temperature electrode, it is characterised in that:Measuring instrumentss are turned by common cable and impedance Parallel operation one end is connected, and measuring electrode is connected with the impedance transducer other end, and impedance transducer is externally provided with electrode cap, electrode cap and set There is sealing, the impedance transducer other end is also associated with reference electrode, glass ball bulb, temperature electrode.
2. a kind of device for measuring water quality pH value as claimed in claim 1, it is characterised in that:The sealing is high insulation and shielded Cover material.
CN201710418105.2A 2017-06-06 2017-06-06 A kind of device for measuring water quality pH value Pending CN106979963A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710418105.2A CN106979963A (en) 2017-06-06 2017-06-06 A kind of device for measuring water quality pH value

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710418105.2A CN106979963A (en) 2017-06-06 2017-06-06 A kind of device for measuring water quality pH value

Publications (1)

Publication Number Publication Date
CN106979963A true CN106979963A (en) 2017-07-25

Family

ID=59344190

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710418105.2A Pending CN106979963A (en) 2017-06-06 2017-06-06 A kind of device for measuring water quality pH value

Country Status (1)

Country Link
CN (1) CN106979963A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109959693A (en) * 2017-12-12 2019-07-02 恩德莱斯和豪瑟尔分析仪表两合公司 Determine the method that connection is established between the potentiometric sensor and its central siphon and glass-film of pH
CN110584668A (en) * 2019-10-24 2019-12-20 重庆金山科技(集团)有限公司 impedance-pH electrode catheter

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3338497A1 (en) * 1983-10-22 1985-05-15 Schott-Geräte GmbH, 6238 Hofheim Combination pH measuring cell with integrated temperature sensor
CN2033512U (en) * 1988-02-01 1989-03-01 江苏省劳动保护科研所 Low out-put impedance ion selecting electrod
CN1034998A (en) * 1988-02-13 1989-08-23 江苏省劳动保护科研所 Ion-selecting electrode with low output impedance
CN2824028Y (en) * 2005-10-12 2006-10-04 国家海洋技术中心 PH sensor for ocean scene
CN201207042Y (en) * 2008-04-21 2009-03-11 上海骏维实业有限公司 Novel composite pH electrode
EP2423678A1 (en) * 2010-08-31 2012-02-29 Hamilton Bonaduz AG Measuring device and method for potentiometric determination of electric indicators in liquids
CN106383144A (en) * 2015-07-26 2017-02-08 江苏中农物联网科技有限公司 Intelligent ph sensor
CN207007764U (en) * 2017-06-06 2018-02-13 大连华城电子有限公司 A kind of device for measuring water pH value

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3338497A1 (en) * 1983-10-22 1985-05-15 Schott-Geräte GmbH, 6238 Hofheim Combination pH measuring cell with integrated temperature sensor
CN2033512U (en) * 1988-02-01 1989-03-01 江苏省劳动保护科研所 Low out-put impedance ion selecting electrod
CN1034998A (en) * 1988-02-13 1989-08-23 江苏省劳动保护科研所 Ion-selecting electrode with low output impedance
CN2824028Y (en) * 2005-10-12 2006-10-04 国家海洋技术中心 PH sensor for ocean scene
CN201207042Y (en) * 2008-04-21 2009-03-11 上海骏维实业有限公司 Novel composite pH electrode
EP2423678A1 (en) * 2010-08-31 2012-02-29 Hamilton Bonaduz AG Measuring device and method for potentiometric determination of electric indicators in liquids
CN106383144A (en) * 2015-07-26 2017-02-08 江苏中农物联网科技有限公司 Intelligent ph sensor
CN207007764U (en) * 2017-06-06 2018-02-13 大连华城电子有限公司 A kind of device for measuring water pH value

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109959693A (en) * 2017-12-12 2019-07-02 恩德莱斯和豪瑟尔分析仪表两合公司 Determine the method that connection is established between the potentiometric sensor and its central siphon and glass-film of pH
CN109959693B (en) * 2017-12-12 2021-09-10 恩德莱斯和豪瑟尔分析仪表两合公司 Potentiometric sensor for determining pH value and method for establishing connection between shaft tube and glass film
CN110584668A (en) * 2019-10-24 2019-12-20 重庆金山科技(集团)有限公司 impedance-pH electrode catheter

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Application publication date: 20170725