CN106978565A - A kind of high intensity non-hardened and tempered steel - Google Patents

A kind of high intensity non-hardened and tempered steel Download PDF

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Publication number
CN106978565A
CN106978565A CN201710216692.7A CN201710216692A CN106978565A CN 106978565 A CN106978565 A CN 106978565A CN 201710216692 A CN201710216692 A CN 201710216692A CN 106978565 A CN106978565 A CN 106978565A
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CN
China
Prior art keywords
steel
hardened
tempered steel
tensile strength
yield strength
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Pending
Application number
CN201710216692.7A
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Chinese (zh)
Inventor
刘年富
纪仁峰
钟凡
钟芳华
周成宏
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Baosteel Special Steel Shaoguan Co Ltd
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Baosteel Special Steel Shaoguan Co Ltd
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Priority to CN201710216692.7A priority Critical patent/CN106978565A/en
Publication of CN106978565A publication Critical patent/CN106978565A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/002Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/22Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/24Ferrous alloys, e.g. steel alloys containing chromium with vanadium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/46Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium

Abstract

The present invention relates to a kind of non-hardened and tempered steel of high intensity, it is characterised in that its component is by weight percentage:C:0.34% 0.39%, Si:0.61% 0.75%, Mn:1.35 1.45%, S≤0.010%, P≤0.020%, Cr:0.10% 0.20%, Mo≤0.10%, Al:0.01 0.03%, V:0.16 0.25%, Ni≤0.10%, N:0.012 0.020%, O≤15 × 10‑6, remainder is Fe and inevitable impurity;A type impurity≤1.0 grade of obtained non-hardened and tempered steel.The present invention adds enough N by increasing substantially V content, it is ensured that V/N is 8 15, forms enough VN, V (CN);Simultaneously by adding a small amount of Cr and carrying high Si content, the solution strengthening ability of steel is added, crystal grain thinning makes the tensile strength of steel reach more than 922Mpa, yield strength reaches more than 700Mpa;By the scope for controlling various composition, it is ensured that the Ceq in steel obtains unexpected extremely stable yield strength and tensile strength in the range of 0.67 0.74, and tensile strength reaches 922 1020MPa, and yield strength reaches 700 780MPa;Simultaneously by reducing the S contents in steel, sulphide grade is reduced, the service life of steel is improved.

Description

A kind of high intensity non-hardened and tempered steel
Technical field
The invention belongs to technical field of metallurgical manufacturing, be related to a kind of design production of non-hardened and tempered steel, specifically automobile, A kind of design production of high intensity non-hardened and tempered steel of the parts such as the engine crankshafts such as truck, connecting rod.
Background technology
With the progress of automobile making, requirement of the part such as automobile crane, connecting rod to non-hardened and tempered steel material is also improved constantly, It is required that material has good process industrial art performance, high-intensity high-tenacity etc..Non-hardened and tempered steel relies primarily on the micro member such as Nb, Ti, V The addition of element combines the cold technique of follow-up forging control by the strength control of part in a suitable scope.
04 phase in 1994《Automobile Technology and Material》Entitled " 35MnVS easily cuts non-hardened and tempered steel " document, steel it is main Composition Control is:0.33%~0.40%C, 0.30%~0.60%Si, 1.00%~1.40%Mn ,≤0.039%P, 0.035 ~0.075%S, 0.06%~0.12%V.The actual control of yield strength is in 464-729.8MPa, and tensile strength is controlled in 732- 922MPa.It can be seen that, it is difficult to which stability contorting is in yield strength >=700MPa, tensile strength is in >=900MPa.
In the Micro Alloying engineering steel standards of GB/T 15712,38MnV main component control is:0.34%~0.41% C ,≤0.60%Si, 1.20%~1.60%Mn ,≤0.035%P, 0.035~0.075%S ,≤0.30%Cr, 0.08%~ 0.15%V.The product is also mainly Mn and micro V by adding certain content, takes the side such as solution strengthening, dispersion-strengtherning Formula improves the intensity of steel.Yield strength requirement >=620MPa of the product, tensile strength >=800MPa.The tension of standard requirement is strong Degree is relatively low.
In summary, using conventional composition design, the tensile strength of current non-hardened and tempered steel is difficult that stability contorting exists More than 922MPa, and due to the addition of substantial amounts of element sulphur, the higher sulfide-based field trash of rank can be formed, although can be Improve processing characteristics to a certain extent, but can also easily become formation of crack, reduce the service life of part.In present steel row In the case that industry homogeneity competition is more serious, how more preferably to improve product quality and meet the requirement of client by significant increase enterprise Competitiveness.
The content of the invention
The problem of to overcome above-mentioned, the present invention provides a kind of tensile strength more than 922Mpa and yield strength is more than 700 The manufacture method of MPa non-hardened and tempered steel, the characteristics of non-hardened and tempered steel is also equipped with good processing characteristics, long lifespan.
To reach above-mentioned purpose, the technical solution adopted in the present invention is:A kind of tensile strength is more than 922Mpa and surrender Intensity is more than 700 MPa non-hardened and tempered steel, and its component and its percentage by weight are:C:0.34%-0.39%, Si:0.61%- 0.75%, Mn:1.35-1.45%, S≤0.010%, P≤0.020%, Cr:0.10%-0.20%, Mo≤0.10%, Al:0.01- 0.03%, V:0.16-0.25%, Ni≤0.10%, N:0.012-0.020%; O≤15×10-6, remainder is for Fe and inevitably Impurity.
In order to ensure the intensity of steel, the content of the V and N are met:8≤V/N≤15.
In order to ensure the strength stability of steel, the primary alloy constituent content and proportioning in steel are strictly controlled, so that it is guaranteed that Carbon equivalent Ceq in steel(=C+Mn/6+Si/24+Cr/5+V/5)Control is in 0.67-0.74 scopes.
The present invention takes the composition design of the above, passes through converter smelting, LF refining, RH refinings and bloom continuous casting, heating And continuous rolling is become a useful person, the Micro Alloying round steel intensity stabilization of sampling detection is controlled in a higher scope.
The beneficial effects of the invention are as follows:V content is increased substantially, and adds enough N, it is ensured that V/N:8-15, can be formed Enough VN, V (CN);A small amount of Cr is added simultaneously, the solution strengthening ability of steel is improved, and crystal grain thinning improves intensity;By improving Si contents, more than conventional Si content ranges, strengthen solution strengthening, improve the yield strength of steel;By controlling various composition Scope, it is ensured that the Ceq in steel is in the range of 0.67-0.74.By the combination of several enhancements, obtain it is unexpected extremely Stable yield strength and tensile strength;Simultaneously by reducing the S contents in steel, sulphide grade is reduced, so as to improve steel Service life.
Embodiment
With reference to embodiment, the present invention is further described.
A kind of novel high-strength non-hardened and tempered steel, its component and percentage by weight (Wt%) are:C:0.34%-0.39%, Si: 0.61%-0.75%, Mn:1.35-1.45%, S≤0.010%, P≤0.020%, Cr:0.10%-0.20%, Mo≤0.10%, Al: 0.01-0.03%, V:0.16-0.25%, Ni≤0.10%, N:0.012-0.020%;Residual elements O≤15 × 10-6, it is remaining to be Fe and some other micro residue elements.Simultaneously in order to ensure strength stability, controlled by chemical composition arrowbandization, it is ensured that steel In Ceq controls in 0.67-0.74, V/N is controlled in 8-15.
According to the composition design of scheme, converter smelting, LF refining and RH refinings and bloom continuous casting are taken, by the several of smelting Stove steel billet is rolled into the round steel of 40mm, 50mm and 60mm specification after heating respectively, round steel, which is taken, to be rolled rear the natural type of cooling and be cooled to Room temperature.Chemical composition, performance and the hoc scenario of sampling detection round steel, composition detection result are as shown in table 1, performance and tissue feelings As shown in table 2, through hardening implementations are as shown in table 3 for condition.
The testing result of round steel prepared by 3 embodiments is respectively as shown in table 1-2.The change of comparative example 1,2 in Tables 1 and 2 Study point document " 35MnVS easily cuts non-hardened and tempered steel " corresponding with performance and " the standard 35MnV " of GB/T 15712 chemical composition and property Can situation.
The Micro Alloying round steel finished product main chemical compositions of table 1 control situation(Wt, %)
The round steel tissue of table 2, behavior pattern
The chemical Composition Control of the Micro Alloying round steel of preparation is stable, and intensity is relatively high and stable, and Control of gas content is relatively low, A classes folder Debris rank is low.

Claims (3)

1. a kind of non-hardened and tempered steel of high intensity, it is characterised in that its component is by weight percentage:
C:0.34%-0.39%, Si:0.61%-0.75%, Mn:1.35-1.45%, S≤0.010%, P≤0.020%, Cr:0.10%- 0.20%, Mo≤0.10%, Al:0.01-0.03%, V:0.16-0.25%, Ni≤0.10%, N:0.012-0.020%, O≤15× 10-6, remainder is Fe and inevitable impurity;A type impurity≤1.0 grade of wherein obtained non-hardened and tempered steel.
2. a kind of high intensity non-hardened and tempered steel as claimed in claim 1, it is characterised in that:8≤V/N≤15.
3. a kind of high intensity non-hardened and tempered steel as described in claim 1 or claim 2, it is characterised in that:0.67≤Ceq=C+ Mn/6+Si/24+ Cr/5+V/5≤0.74。
CN201710216692.7A 2017-04-05 2017-04-05 A kind of high intensity non-hardened and tempered steel Pending CN106978565A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111549287A (en) * 2020-06-28 2020-08-18 宝钢特钢韶关有限公司 Medium carbon steel and production process thereof
CN112143965A (en) * 2019-06-28 2020-12-29 宝山钢铁股份有限公司 Non-quenched and tempered oil casing pipe and manufacturing method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003055715A (en) * 2001-08-09 2003-02-26 Kobe Steel Ltd Method for producing hot forged non-heat treated connecting rod
CN102899575A (en) * 2012-11-12 2013-01-30 莱芜钢铁集团有限公司 Non-quenched and tempered steel used for welding and electroplating hydraulic rod and production method thereof
CN103695793A (en) * 2013-12-17 2014-04-02 西宁特殊钢股份有限公司 Large-sized non-quenched and tempered steel and smelting method thereof
CN103958714A (en) * 2011-11-21 2014-07-30 新日铁住金株式会社 Rolled steel bar for hot forging

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003055715A (en) * 2001-08-09 2003-02-26 Kobe Steel Ltd Method for producing hot forged non-heat treated connecting rod
CN103958714A (en) * 2011-11-21 2014-07-30 新日铁住金株式会社 Rolled steel bar for hot forging
CN102899575A (en) * 2012-11-12 2013-01-30 莱芜钢铁集团有限公司 Non-quenched and tempered steel used for welding and electroplating hydraulic rod and production method thereof
CN103695793A (en) * 2013-12-17 2014-04-02 西宁特殊钢股份有限公司 Large-sized non-quenched and tempered steel and smelting method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
齐宝森等: "《新型材料及其应用》", 30 September 2007, 哈尔滨工业大学出版社 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112143965A (en) * 2019-06-28 2020-12-29 宝山钢铁股份有限公司 Non-quenched and tempered oil casing pipe and manufacturing method thereof
CN112143965B (en) * 2019-06-28 2022-06-28 宝山钢铁股份有限公司 Non-quenched and tempered oil casing pipe and manufacturing method thereof
CN111549287A (en) * 2020-06-28 2020-08-18 宝钢特钢韶关有限公司 Medium carbon steel and production process thereof

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Application publication date: 20170725

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