CN106977845A - A kind of KPU sole materials of wear-resisting antiskid - Google Patents

A kind of KPU sole materials of wear-resisting antiskid Download PDF

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Publication number
CN106977845A
CN106977845A CN201710248737.9A CN201710248737A CN106977845A CN 106977845 A CN106977845 A CN 106977845A CN 201710248737 A CN201710248737 A CN 201710248737A CN 106977845 A CN106977845 A CN 106977845A
Authority
CN
China
Prior art keywords
wear
kpu
sole
resisting
resisting antiskid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710248737.9A
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Chinese (zh)
Inventor
陈宏平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FUZHOU LUYA SHOES Co Ltd
Original Assignee
FUZHOU LUYA SHOES Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by FUZHOU LUYA SHOES Co Ltd filed Critical FUZHOU LUYA SHOES Co Ltd
Priority to CN201710248737.9A priority Critical patent/CN106977845A/en
Publication of CN106977845A publication Critical patent/CN106977845A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • A—HUMAN NECESSITIES
    • A43—FOOTWEAR
    • A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B13/00—Soles; Sole-and-heel integral units
    • A43B13/02—Soles; Sole-and-heel integral units characterised by the material
    • A43B13/026—Composites, e.g. carbon fibre or aramid fibre; the sole, one or more sole layers or sole part being made of a composite
    • A—HUMAN NECESSITIES
    • A43—FOOTWEAR
    • A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B13/00—Soles; Sole-and-heel integral units
    • A43B13/02—Soles; Sole-and-heel integral units characterised by the material
    • A43B13/04—Plastics, rubber or vulcanised fibre
    • A—HUMAN NECESSITIES
    • A43—FOOTWEAR
    • A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B13/00—Soles; Sole-and-heel integral units
    • A43B13/14—Soles; Sole-and-heel integral units characterised by the constructive form
    • A43B13/22—Soles made slip-preventing or wear-resisting, e.g. by impregnation or spreading a wear-resisting layer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/02—Copolymers with acrylonitrile
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)

Abstract

It is by mass percentage, composed of the following components the invention discloses a kind of KPU sole materials of wear-resisting antiskid：Dibutyl ester 35 ~ 45%, polyvinyl chloride 15 ~ 25%, nitrile rubber 10 ~ 20%, butadiene 8 ~ 12%, acrylonitrile 8 ~ 12%, UV resistant agent 1 ~ 5%, antioxidant 1 ~ 5% and essence 0.5 ~ 1.5%.The KPU soles of the wear-resisting antiskid of the present invention have very excellent anti-skidding, wear-resisting performance with material, it is not only soft, light by its obtained sole, and do not tell frost, do not play thick, wear-resisting on-slip, it is resistant to bending, service life is long, for a long time not aging and undifferentiated generation slight crack.In addition, the KPU soles material of the present invention can direct gluing, without any processing cost.

Description

A kind of KPU sole materials of wear-resisting antiskid
Technical field
Material field is used the invention belongs to sole, and in particular to a kind of KPU sole materials of wear-resisting antiskid.
Background technology
Shoes are the articles that we will wear daily, and sole is to make the essential part of shoes.Conventionally manufactured footwear Bottom uses TPR materials（Thermoplastic rubber material）, using the good elasticity of TRP, the sole for being produced from it out have compared with Good elasticity, has good comfortableness in dress.However, the sole being made up of TPR materials is elongated with use time, Easily break up and produce slight crack, substantially reduce its life-span, and easily occur telling frost, turn white, beat thick phenomenon, largely On have impact on its using effect.
KPU（Fast solidification polyurethane elastomer）, it is one kind of polyurethane, it is formulated and is simply changed or changed Property, the physical properties such as different densities, elasticity, wearability, antiskid property just can be obtained, it is very heavy with play on material preparing sole The role wanted.
The content of the invention
It is an object of the invention in view of the shortcomings of the prior art, a kind of KPU sole materials of wear-resisting antiskid are provided, by it Obtained sole is not only soft, light, and do not tell frost, do not play thick, wear-resisting on-slip, it is resistant to bending, service life is long, for a long time not Aging and undifferentiated generation slight crack.In addition, the KPU soles material of the present invention can direct gluing, without any processing cost.
To achieve the above object, the present invention is adopted the following technical scheme that：
A kind of KPU sole materials of wear-resisting antiskid, it is by mass percentage, composed of the following components：
Dibutyl ester：35~45%；
Polyvinyl chloride：15~25%；
Nitrile rubber：10~20%；
Butadiene：8~12%；
Acrylonitrile：8~12%；
UV resistant agent：1~5%；
Antioxidant：1~5%；
Essence：0.5~1.5%；
Wherein the mass percent sum of each component is 100%.
Preferably, the KPU sole materials of a kind of wear-resisting antiskid, it is characterised in that：By mass percentage, by with the following group It is grouped into：
Dibutyl ester：40%；
Polyvinyl chloride：20%；
Nitrile rubber：15%；
Butadiene：10%；
Acrylonitrile：10%；
UV resistant agent：2%；
Antioxidant：2%；
Essence：1%.
The beneficial effects of the present invention are：The KPU soles of the wear-resisting antiskid of present invention material has very excellent anti- Sliding, wear-resisting performance, it is not only soft, light by its obtained sole, and do not tell frost, do not play thick, wear-resisting on-slip, it is resistant to bending, Service life is long, not aging for a long time and undifferentiated generation slight crack.In addition, the KPU soles of the present invention can be applied directly with material Glue, without any processing cost.
Embodiment
Below in conjunction with specific embodiment, the present invention will be further described, but the present invention is not limited only to these embodiments.
Embodiment 1
A kind of KPU sole materials of wear-resisting antiskid, it is by mass percentage, composed of the following components：
Dibutyl ester：45%；
Polyvinyl chloride：15%；
Nitrile rubber：10%；
Butadiene：12%；
Acrylonitrile：12%；
UV resistant agent：3.5%；
Antioxidant：1%；
Essence：1.5%.
Embodiment 2
A kind of KPU sole materials of wear-resisting antiskid, it is by mass percentage, composed of the following components：
Dibutyl ester：35%；
Polyvinyl chloride：25%；
Nitrile rubber：15%；
Butadiene：9%；
Acrylonitrile：11%；
UV resistant agent：3%；
Antioxidant：1.5%；
Essence：0.5%.
Embodiment 3
A kind of KPU sole materials of wear-resisting antiskid, it is by mass percentage, composed of the following components：
Dibutyl ester：42%；
Polyvinyl chloride：18%；
Nitrile rubber：20%；
Butadiene：8%；
Acrylonitrile：8%；
UV resistant agent：1.5%；
Antioxidant：1%；
Essence：1.5%.
Embodiment 4
A kind of KPU sole materials of wear-resisting antiskid, it is by mass percentage, composed of the following components：
Dibutyl ester：40%；
Polyvinyl chloride：20%；
Nitrile rubber：15%；
Butadiene：10%；
Acrylonitrile：10%；
UV resistant agent：2%；
Antioxidant：2%；
Essence：1%.
Sole is made of material for the KPU soles of the wear-resisting antiskid of above-described embodiment 1 ~ 4, and carries out performance test, as a result It is as shown in the table：
Presently preferred embodiments of the present invention is the foregoing is only, all equivalent changes done according to scope of the present invention patent are with repairing Decorations, should all belong to the covering scope of the present invention.

Claims (3)

1. a kind of KPU sole materials of wear-resisting antiskid, it is characterised in that：By mass percentage, it is composed of the following components：
Dibutyl ester：35~45%；
Polyvinyl chloride：15~25%；
Nitrile rubber：10~20%；
Butadiene：8~12%；
Acrylonitrile：8~12%；
UV resistant agent：1~5%；
Antioxidant：1~5%；
Essence：0.5~1.5%；
Wherein the mass percent sum of each component is 100%.
2. a kind of KPU sole materials of wear-resisting antiskid according to claim 1, it is characterised in that：By mass percent Meter, it is composed of the following components：
Dibutyl ester：40%；
Polyvinyl chloride：20%；
Nitrile rubber：15%；
Butadiene：10%；
Acrylonitrile：10%；
UV resistant agent：2%；
Antioxidant：2%；
Essence：1%.
3. sole made from a kind of KPU sole materials of the wear-resisting antiskid described in utilization claim 1 or 2.
CN201710248737.9A 2017-04-17 2017-04-17 A kind of KPU sole materials of wear-resisting antiskid Pending CN106977845A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710248737.9A CN106977845A (en) 2017-04-17 2017-04-17 A kind of KPU sole materials of wear-resisting antiskid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710248737.9A CN106977845A (en) 2017-04-17 2017-04-17 A kind of KPU sole materials of wear-resisting antiskid

Publications (1)

Publication Number Publication Date
CN106977845A true CN106977845A (en) 2017-07-25

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710248737.9A Pending CN106977845A (en) 2017-04-17 2017-04-17 A kind of KPU sole materials of wear-resisting antiskid

Country Status (1)

Country Link
CN (1) CN106977845A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101948595A (en) * 2010-10-26 2011-01-19 曾广胜 Waste rubber powder/PVC thermoplastic elastomer material and preparation process thereof
CN202233304U (en) * 2011-10-18 2012-05-30 远宏（福建）实业有限公司 Sports shoe with polyvinyl chloride (PVC) modified sole
CN102924770A (en) * 2012-11-22 2013-02-13 广州市邦尔福鞋材有限公司 Mirror varnishing rubber sole and manufacturing method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101948595A (en) * 2010-10-26 2011-01-19 曾广胜 Waste rubber powder/PVC thermoplastic elastomer material and preparation process thereof
CN202233304U (en) * 2011-10-18 2012-05-30 远宏（福建）实业有限公司 Sports shoe with polyvinyl chloride (PVC) modified sole
CN102924770A (en) * 2012-11-22 2013-02-13 广州市邦尔福鞋材有限公司 Mirror varnishing rubber sole and manufacturing method thereof

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
化工部科学技术研究总院: "《精细化工品种手册》", 31 October 1986, 化工部科学技术研究总院 *
吴石山 等: "NBR改性HPVC鞋底材料的研制", 《制鞋科技》 *
潘才元: "《高分子化学》", 31 July 2012, 中国科学技术大学出版社 *
赖逸云 等: "丁腈橡胶改性聚氯乙烯鞋用材料的研究", 《塑料科技》 *

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Address after: 350000 3rd floor, building 2, Yusheng Plaza, 98 Huaxi North Road, Jianxin Town, Cangshan District, Fuzhou City, Fujian Province

Applicant after: Fujian Luya Technology Co.,Ltd.

Address before: 350000 building 26, Cangshan Park, juyuanzhou, Jinshan Industrial Zone, Cangshan District, Fuzhou City, Fujian Province

Applicant before: FUZHOU LUYA SHOES Co.,Ltd.

RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20170725