CN106974293A - Chelate mineral composition and preparation method thereof - Google Patents
Chelate mineral composition and preparation method thereof Download PDFInfo
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- CN106974293A CN106974293A CN201611271778.1A CN201611271778A CN106974293A CN 106974293 A CN106974293 A CN 106974293A CN 201611271778 A CN201611271778 A CN 201611271778A CN 106974293 A CN106974293 A CN 106974293A
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- metal
- organic ligand
- mineral composition
- chelate
- acid
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- 229910052500 inorganic mineral Inorganic materials 0.000 title claims abstract description 84
- 239000011707 mineral Substances 0.000 title claims abstract description 84
- 239000000203 mixture Substances 0.000 title claims abstract description 77
- 239000013522 chelant Substances 0.000 title claims abstract description 59
- 238000002360 preparation method Methods 0.000 title claims description 16
- 229910052751 metal Inorganic materials 0.000 claims abstract description 191
- 239000002184 metal Substances 0.000 claims abstract description 191
- 239000013110 organic ligand Substances 0.000 claims abstract description 88
- 150000003839 salts Chemical class 0.000 claims abstract description 55
- 150000001875 compounds Chemical class 0.000 claims abstract description 10
- 239000003575 carbonaceous material Substances 0.000 claims description 49
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 33
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 claims description 31
- 239000004021 humic acid Substances 0.000 claims description 31
- PUKLDDOGISCFCP-JSQCKWNTSA-N 21-Deoxycortisone Chemical compound C1CC2=CC(=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@@](C(=O)C)(O)[C@@]1(C)CC2=O PUKLDDOGISCFCP-JSQCKWNTSA-N 0.000 claims description 30
- FCYKAQOGGFGCMD-UHFFFAOYSA-N Fulvic acid Natural products O1C2=CC(O)=C(O)C(C(O)=O)=C2C(=O)C2=C1CC(C)(O)OC2 FCYKAQOGGFGCMD-UHFFFAOYSA-N 0.000 claims description 30
- 239000002509 fulvic acid Substances 0.000 claims description 30
- 229940095100 fulvic acid Drugs 0.000 claims description 30
- 229910021645 metal ion Inorganic materials 0.000 claims description 27
- 238000006243 chemical reaction Methods 0.000 claims description 21
- 241001465754 Metazoa Species 0.000 claims description 18
- 239000002253 acid Substances 0.000 claims description 18
- 239000002904 solvent Substances 0.000 claims description 17
- 239000001569 carbon dioxide Substances 0.000 claims description 16
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 16
- 239000000463 material Substances 0.000 claims description 16
- 238000000605 extraction Methods 0.000 claims description 12
- 239000003337 fertilizer Substances 0.000 claims description 12
- 239000010440 gypsum Substances 0.000 claims description 11
- 229910052602 gypsum Inorganic materials 0.000 claims description 11
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 10
- 235000015170 shellfish Nutrition 0.000 claims description 8
- 150000007522 mineralic acids Chemical class 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 7
- 238000005341 cation exchange Methods 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 235000013305 food Nutrition 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 150000002736 metal compounds Chemical class 0.000 claims description 5
- 238000001556 precipitation Methods 0.000 claims description 5
- 229910000000 metal hydroxide Inorganic materials 0.000 claims description 4
- 150000004692 metal hydroxides Chemical class 0.000 claims description 4
- 229910052976 metal sulfide Inorganic materials 0.000 claims description 4
- 239000000460 chlorine Substances 0.000 claims description 3
- 229910044991 metal oxide Inorganic materials 0.000 claims description 3
- 150000004706 metal oxides Chemical class 0.000 claims description 3
- 159000000007 calcium salts Chemical class 0.000 claims description 2
- 229910052801 chlorine Inorganic materials 0.000 claims description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- 239000004615 ingredient Substances 0.000 abstract description 32
- 238000000034 method Methods 0.000 abstract description 17
- 239000002994 raw material Substances 0.000 abstract description 15
- 235000010755 mineral Nutrition 0.000 description 64
- 239000003415 peat Substances 0.000 description 28
- 241000196324 Embryophyta Species 0.000 description 23
- 239000000126 substance Substances 0.000 description 23
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 21
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 20
- 229960004424 carbon dioxide Drugs 0.000 description 16
- 239000003077 lignite Substances 0.000 description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 12
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 229910052799 carbon Inorganic materials 0.000 description 12
- 239000010949 copper Substances 0.000 description 12
- 239000002245 particle Substances 0.000 description 12
- -1 now Substances 0.000 description 11
- 239000005416 organic matter Substances 0.000 description 11
- 229910000019 calcium carbonate Inorganic materials 0.000 description 10
- 229910052742 iron Inorganic materials 0.000 description 10
- 239000002689 soil Substances 0.000 description 10
- 239000000376 reactant Substances 0.000 description 9
- 235000010216 calcium carbonate Nutrition 0.000 description 8
- 230000008859 change Effects 0.000 description 8
- 239000007924 injection Substances 0.000 description 8
- 238000002347 injection Methods 0.000 description 8
- 239000011777 magnesium Substances 0.000 description 8
- 239000011572 manganese Substances 0.000 description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 7
- 239000010426 asphalt Substances 0.000 description 7
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 7
- 229910052802 copper Inorganic materials 0.000 description 7
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 239000002585 base Substances 0.000 description 6
- 239000011575 calcium Substances 0.000 description 6
- 239000003245 coal Substances 0.000 description 6
- 229910000514 dolomite Inorganic materials 0.000 description 6
- 239000010459 dolomite Substances 0.000 description 6
- 125000000524 functional group Chemical group 0.000 description 6
- 239000003864 humus Substances 0.000 description 6
- 150000002500 ions Chemical class 0.000 description 6
- 229910052749 magnesium Inorganic materials 0.000 description 6
- 229910052748 manganese Inorganic materials 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 5
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 5
- 125000003118 aryl group Chemical group 0.000 description 5
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 5
- 239000010931 gold Substances 0.000 description 5
- 229910052737 gold Inorganic materials 0.000 description 5
- 239000007791 liquid phase Substances 0.000 description 5
- 229920002521 macromolecule Polymers 0.000 description 5
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 5
- 239000001095 magnesium carbonate Substances 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 230000008635 plant growth Effects 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 229910052586 apatite Inorganic materials 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
- 239000003610 charcoal Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 230000012010 growth Effects 0.000 description 4
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 4
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 4
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Inorganic materials O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 4
- 244000005700 microbiome Species 0.000 description 4
- 229910052750 molybdenum Inorganic materials 0.000 description 4
- 239000011733 molybdenum Substances 0.000 description 4
- 235000015097 nutrients Nutrition 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 description 4
- 235000011118 potassium hydroxide Nutrition 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 229910052683 pyrite Inorganic materials 0.000 description 4
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 4
- 229910021646 siderite Inorganic materials 0.000 description 4
- 235000011121 sodium hydroxide Nutrition 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 229910021532 Calcite Inorganic materials 0.000 description 3
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 241000907663 Siproeta stelenes Species 0.000 description 3
- 239000004480 active ingredient Substances 0.000 description 3
- 229910052934 alunite Inorganic materials 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 238000003763 carbonization Methods 0.000 description 3
- 229910052951 chalcopyrite Inorganic materials 0.000 description 3
- DVRDHUBQLOKMHZ-UHFFFAOYSA-N chalcopyrite Chemical compound [S-2].[S-2].[Fe+2].[Cu+2] DVRDHUBQLOKMHZ-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 201000010099 disease Diseases 0.000 description 3
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000284 extract Substances 0.000 description 3
- 230000035784 germination Effects 0.000 description 3
- 238000003306 harvesting Methods 0.000 description 3
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 3
- 229920005610 lignin Polymers 0.000 description 3
- 235000014380 magnesium carbonate Nutrition 0.000 description 3
- 229910001510 metal chloride Inorganic materials 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 229910052961 molybdenite Inorganic materials 0.000 description 3
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000011028 pyrite Substances 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000004016 soil organic matter Substances 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 2
- 244000025254 Cannabis sativa Species 0.000 description 2
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 2
- 208000005156 Dehydration Diseases 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 2
- WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical compound [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 239000010424 alunite Substances 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000009530 blood pressure measurement Methods 0.000 description 2
- 238000009529 body temperature measurement Methods 0.000 description 2
- 229910001424 calcium ion Inorganic materials 0.000 description 2
- 239000000292 calcium oxide Substances 0.000 description 2
- 235000012255 calcium oxide Nutrition 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 229910001431 copper ion Inorganic materials 0.000 description 2
- KYRUBSWVBPYWEF-UHFFFAOYSA-N copper;iron;sulfane;tin Chemical compound S.S.S.S.[Fe].[Cu].[Cu].[Sn] KYRUBSWVBPYWEF-UHFFFAOYSA-N 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 230000035558 fertility Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 210000000936 intestine Anatomy 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 229910001425 magnesium ion Inorganic materials 0.000 description 2
- 229910001437 manganese ion Inorganic materials 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
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- 102000004169 proteins and genes Human genes 0.000 description 2
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- JBQYATWDVHIOAR-UHFFFAOYSA-N tellanylidenegermanium Chemical compound [Te]=[Ge] JBQYATWDVHIOAR-UHFFFAOYSA-N 0.000 description 2
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- 239000011573 trace mineral Substances 0.000 description 2
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- KPZTWMNLAFDTGF-UHFFFAOYSA-D trialuminum;potassium;hexahydroxide;disulfate Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Al+3].[Al+3].[Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O KPZTWMNLAFDTGF-UHFFFAOYSA-D 0.000 description 2
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- 229910052844 willemite Inorganic materials 0.000 description 2
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- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- 108091005950 Azurite Proteins 0.000 description 1
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- 240000007817 Olea europaea Species 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 235000003283 Pachira macrocarpa Nutrition 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
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- MMDJDBSEMBIJBB-UHFFFAOYSA-N [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] Chemical compound [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] MMDJDBSEMBIJBB-UHFFFAOYSA-N 0.000 description 1
- 235000011054 acetic acid Nutrition 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
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- 150000007824 aliphatic compounds Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
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- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
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- 125000000129 anionic group Chemical group 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
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- 238000006701 autoxidation reaction Methods 0.000 description 1
- 244000285940 beete Species 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- KIZFHUJKFSNWKO-UHFFFAOYSA-M calcium monohydroxide Chemical compound [Ca]O KIZFHUJKFSNWKO-UHFFFAOYSA-M 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 229910001748 carbonate mineral Inorganic materials 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- ONIOAEVPMYCHKX-UHFFFAOYSA-N carbonic acid;zinc Chemical compound [Zn].OC(O)=O ONIOAEVPMYCHKX-UHFFFAOYSA-N 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 229910052947 chalcocite Inorganic materials 0.000 description 1
- 235000011222 chang cao shi Nutrition 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 229930002875 chlorophyll Natural products 0.000 description 1
- 235000019804 chlorophyll Nutrition 0.000 description 1
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 150000004696 coordination complex Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 230000000994 depressogenic effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 210000001339 epidermal cell Anatomy 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 235000011087 fumaric acid Nutrition 0.000 description 1
- 235000013376 functional food Nutrition 0.000 description 1
- 230000002518 glial effect Effects 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 150000002337 glycosamines Chemical class 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229910052595 hematite Inorganic materials 0.000 description 1
- 239000011019 hematite Substances 0.000 description 1
- 239000002663 humin Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052909 inorganic silicate Inorganic materials 0.000 description 1
- 150000002506 iron compounds Chemical class 0.000 description 1
- 229910000015 iron(II) carbonate Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 239000011656 manganese carbonate Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 229910000016 manganese(II) carbonate Inorganic materials 0.000 description 1
- XMWCXZJXESXBBY-UHFFFAOYSA-L manganese(ii) carbonate Chemical compound [Mn+2].[O-]C([O-])=O XMWCXZJXESXBBY-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052960 marcasite Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 235000015816 nutrient absorption Nutrition 0.000 description 1
- 235000021232 nutrient availability Nutrition 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 239000010450 olivine Substances 0.000 description 1
- 229910052609 olivine Inorganic materials 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000002927 oxygen compounds Chemical class 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 230000010496 root system development Effects 0.000 description 1
- 235000009165 saligot Nutrition 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 230000032258 transport Effects 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- GWBUNZLLLLDXMD-UHFFFAOYSA-H tricopper;dicarbonate;dihydroxide Chemical compound [OH-].[OH-].[Cu+2].[Cu+2].[Cu+2].[O-]C([O-])=O.[O-]C([O-])=O GWBUNZLLLLDXMD-UHFFFAOYSA-H 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000011667 zinc carbonate Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F11/00—Other organic fertilisers
- C05F11/02—Other organic fertilisers from peat, brown coal, and similar vegetable deposits
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
Abstract
The present invention relates to including being combined with the chelating mineral composition of the metallo-chelate of organic ligand and raw metal containing metal ingredient, and the method for preparing the chelating mineral composition or complex compound.The chelating mineral composition obtained according to the present invention includes raw metal, thus even in removing after the metal ingredient of metallo-chelate form, can also make the raw metal and organic ligand in conjunction with the new metallo-chelate of generation.By using the raw material of low price, suppress the generation of unnecessary inorganic salts, so as to ensure the economy and efficiency of the technique for preparing chelating mineral composition.
Description
Technical field
The present invention relates to chelating mineral composition, more specifically, it is related to one kind and can be used for fertilizer, animal feed
Or the chelating mineral composition and the method for preparing the chelating mineral composition of food etc..
Background technology
Mineral composition is to aid in the development of plant or animal and promotes growth necessary.For example, as in order to promote
Mineral composition needed for biological growth, is denitrogenated, outside the fertilizer factor such as phosphorus, potassium, sulphur, boron, micro metal ion (copper,
Zinc, iron, manganese, magnesium etc.) also undertake essential effect in biological metabolic process.This trace metal ion with it is biological into
Long required nutrient is the same, helps the Fast Growth of plant or animal, harvest yield, increasing particularly in increase vegetables or fruit
Big plant is played a great role to the ability aspect of disease and insect resistance.As the mankind are because particular kind of nutrient lacks and induces
Disease is the same, if plant can not balancedly absorb trace metal ion in set soil limit, causes lacking for fertility
It is weary.
Plant or animal are in order to absorb mineral matter, and one of optimal morphology is mineral sequestration thing.Metal and organic ligand knot
Close and generate metallo-chelate, now, organic ligand selected and set extremely important with the reaction condition of metal etc..
But, for conventional chelate, it is not only unnecessary mineral composition and is generated as inorganic salts form, Er Qieti
The problem of can not obtaining highly effective chelating thing is gone out.For example, disclosed in U.S. Patent No. 4,588,145, HO- can will be made
EDTANa3 and nitric acid and iron and the HO-EDTAFe prepared+2Na metallo-chelate is used as fertilizer.Disclosing in addition must
Iron can be substituted when wanting with copper, zinc, magnesium etc. and prepares chelate.But, conventional metal chelate compound companion in preparation technology
Impurity is included with heating, drying process etc., thus in chelate compound, it is difficult to obtain effective chelate.Moreover, by
In the raw material using relative high price, it is impossible to seek the economy of preparation technology, exist and consumed in trace meter composition by organism
Afterwards, it is impossible to the problem of recycling organic ligand.
【Prior art literature】
【Patent document】
(patent document 0001) U.S. Patent No. 4,588,145
The content of the invention
The technical problem to be solved in the present invention
The present invention precisely in order to the problem of solving foregoing conventional art and research and develop, the purpose of the present invention aims to provide one kind
Metal ingredient remains able to chelating mineral composition recycled and preparation method thereof after being absorbed by life entity.
Another object of the present invention, which aims to provide a kind of raw material that can use low price, to be ensured the economy of technique, can press down
The generation of making undesirable inorganic salts, the chelating mineral composition that can efficiently prepare and preparation method thereof.
Technical scheme
According to one aspect of the present invention with object defined above, the present invention provides a kind of chelating mineral composition, bag
Include：It is combined with the metallo-chelate of organic ligand；And inorganic metal compound, it is selected from by raw metal, inorganic metal salt, gold
Belong to the group that ion and combinations thereof are constituted.
In selective embodiment, the chelating mineral composition may further include carbonaceous material.
For example, the raw metal can be selected in the group being made up of shell, shellfish fossil, mineral and combinations thereof.
The inorganic metal salt can by metal inorganic acid, metal oxide, metal hydroxides, metal sulfide,
Selected in the group that metal chloride, metal hydrate and combinations thereof are constituted.
In an exemplary embodiment, the organic ligand can be by humic acid (Humicacid), fulvic acid
Selected in the group that (Fulvic acid), ulmic acid (Ulmic acid) and combinations thereof are constituted.
For example, the organic ligand can be derived from by fertile soil, peat moss (peat moss), peat (peat), wind
Change the selection middle in groups of lignite (leonardite), lignite (lignite), asphalt carbon (bitumen) and combinations thereof structure
Carbonaceous material.
In addition, the present invention provides mineral food, animal feed and/or the fertilizer for including foregoing chelating mineral composition
Material.
According to another aspect of the present invention, the present invention provides a kind of preparation method for chelating mineral composition, including：a)
Carbonaceous (carbonaceous) material containing organic ligand, is made an addition to the reactor containing solvent by step, extracts the carbon
The organic ligand contained in metallic substance；B) step, raw metal is put into the reactor containing the organic ligand；And
C) step, the organic ligand for making the extraction and the metal salt or metal ion that are obtained from the raw metal react, generation
Metallo-chelate.
, can be together with the carbonaceous material, containing in a) step in an exemplary embodiment
Alkaline agent is added in the reactor for stating solvent.
For example, c) the step can include：Carbon dioxide is injected in the reactor that the raw metal is put into, is obtained
The step of metal salt or metal ion for containing in the raw metal.
In an embodiment of selectivity, it can include in a) step：Stone is added in the reactor
Cream, the organic ligand of the extraction reacts with the gypsum, the step of forming calcium chelate.
Now, it can include in the c) step：Generate the metal by constituting the calcium chelate and the metal salt
Metallo-chelate, calcium salt (such as CaSO combined with the organic ligand4) the step of.
For example, the raw metal can press 1 relative to the carbonaceous material:1~10:1, preferably by 1:1~5:1
Weight is than addition.
In an exemplary embodiment, it may further include after the c) step：Generating the metal
Inject and air and stir in the reactor of chelate, the step of being separated, extracted to the upper liquid and precipitation solid of acquisition.
Beneficial effect
The chelating mineral composition of the present invention contains the metallo-chelate and raw metal combined with organic ligand.Have
Advantage be, after with the metal ingredient of chelate combination of shape and state by biological uptake, the raw metal and organic ligand of residual
Recombine, new metallo-chelate can be formed.
In addition, organic ligand is extracted from coal constituent, metal ingredient is obtained from shell or mineralogical composition, uses the original of low price
Material, in preparation process, realizes the generation of the unwanted unnecessary inorganic salts of life entity and minimizes, so as to height
Effect, economic method prepare mineral sequestration thing.
Therefore, comprising according to the present invention and synthesize metallo-chelate chelating mineral composition be separated into liquid phase or
Solid phase, is expected to may be used as to promote the fertilizer of plant growth, or the feed as animal or the mineral food of human intake
Active ingredient.
Brief description of the drawings
Fig. 1 is roughly to illustrate to chelate the anti-of mineral composition for preparing according to the exemplary embodiment of the present invention
Answer the figure of the composition of device.
Fig. 2 is roughly to illustrate to prepare the technique for chelating mineral composition for the exemplary embodiment according to the present invention
Precedence diagram.
Reference
1：Reactor 10：Raw material throw-in part
20：Air injection unit 30：Reactant discharge unit
40：Stirring tool 50：Carbon dioxide injection portion
60：Pressure-control valve 70：Temperature/pressure measurement portion
Embodiment
Below, in the case of necessary, the present invention is described in more detail with reference to.
[chelating mineral composition]
The chelating mineral composition of the present invention can include：It is combined with the metallo-chelate of organic ligand；Inorganic metal
Compound, it is selected from the group being made up of raw metal, inorganic metal salt, metal ion and combinations thereof.
Constitute the organic ligand of the metallo-chelate, for example can with the metal ingredient from raw metal by with
Position combines and connected.In an exemplary embodiment, the organic ligand can derive from carbonaceous (carbonaceous)
Humus (humic) material contained in material.
The carbonaceous material in the organic ligand source, for example, be selected from by fertile soil, peat moss (peat
Moss), peat (peat), leonardite (leonardite), lignite (lignite), asphalt carbon (bitumen) and their group
Close the carbonaceous material of the group constituted.For example, coal can be divided into peat moss, peat, wind according to carry out degree of carbonization etc.
Change lignite, lignite, asphalt carbon etc., in these carbonaceous materials, include Humus composition.
Peat moss (peat moss) is such as water plant, moss, the plant of wetland grass of wet depression or marshland etc.
Material buildup and the carbonaceous material that through biochemistry is carbonized of the remains in adjacent ground surface incomplete decomposing.Peat moss contain 90% with
On organic matter, be the Porous carbonaceous material of voidage substantially 60~85%.According to material, can be divided into sedimentary peat tongue,
Fibrous peat tongue, wood peat tongue etc., in the wet depression of excessive water supply, the activity of microorganism etc. is suppressed, remains
It can not decompose completely, with yellowish-brown or dark brown.The moisture absorption of peat moss, absorb water, inhale that smelly property etc. is outstanding, inorganic constituents content is few
And it is light, it is easily disposed.
Peat (peat) is grass or wooden remains are thickly accumulated in basin, by means of biochemical
Carbonization and rotten carbonaceous material.Made different from being embedded in the wooden of underground during the very long years by means of ground pressure and underground heat
With and generate coal, as lignin (lignin) or cellulose of phyteral principal component etc. under earth's surface by means of decompose make
With and formed.
Leonardite (leonardite) is peat horizon after marshland formation, and soil is piled up in top, by means of soil pressure
And dry out, moisture is removed due to underground heat, plant containing natural macromolecule is condensed, cellulose completes to lose, vegetalitas
Macromolecule contains organic carbon and oxygen, is partially oxidized and is formed in outside.
Lignite (lignite) is as the minimum carbonaceous material of degree of carbonisation in coal, with dark brown, with other coal phases
Than, be moisture and volatile ingredient it is many, easily into powder carbonaceous material.The shape of plant log as organic matter root, annual ring or
The tissue naked eyes of trunk etc. are visible, account for coal buries total amount about 45%.Asphalt carbon is also known as black wood charcoal, and charring degree is higher than lignite, is
Carbon amount is 89~90% carbonaceous material.
In these carbonaceous materials, the humic substance for being decomposed by microorganism etc. containing soil organic matter and being polymerize, being modified
(Humus) organic matter, in other words, containing referred to as humus (Humus substance).In general, soil organic matter
It is divided into, the tissue of animals and plants is decomposed and the not rotten organic matter in digest process by microorganism etc., in not rotten organic matter quilt
The non-humic substance such as polysaccharide, protein, lipid, amino acid during humification (humification) (Non-Humus),
And non-humic substance is further change in and turns into the Humus as organic matter of organic colloid (colloid) of brown-black
Matter.
That is, so-called humic substance, condensed ring is formed as soil organic matter while long-term decomposition, condensation, polymerization, oxidation
High-molecular compound, it is meant that the substantially organic matter of organic glial state of 1-100nm sizes.Humic substance is according to its chemistry
Characteristic, can be divided into humic charcoal (Humin), humic acid (Humic acid), fulvic acid (Fulvic acid), ulmic acid
(Ulmic acid)。
Constitute the present invention chelating mineral composition organic ligand can in the humic substance that carbonaceous material contains,
Selected from the group being made up of humic acid, fulvic acid, ulmic acid and combinations thereof.Therefore, it is preferable to carry out at one in form,
The of a relatively high carbonaceous material of the content of these humic substances can be preferably used, it is, for example, possible to use fertile soil, peat moss,
At least one of peat, leonardite and lignite carbonaceous material as organic ligand raw material.
The metal ingredient for constituting metallo-chelate is not particularly limited, for example, can be golden for the alkali of such as sodium (Na), potassium (K)
Belong to, such as magnesium (Mg), the alkaline-earth metal of calcium (Ca), the transition of iron (Fe), copper (Cu), zinc (Zn), manganese (Mn), molybdenum (Mo) etc.
Metal
The raw metal of central metal composition that metallo-chelate is constituted for providing is not particularly limited, for example can by
Selected in the group that shell, shellfish fossil, mineral (such as the mineral containing foregoing metal ingredient) and combinations thereof are constituted.
For shell, mineral salt accounts for more than 95%, and the major part of mineral salt is metal salt component.Contain in shell
Metal salt component can be calcium carbonate, calcium phosphate and magnesium carbonate.On the other hand, shellfish fossil is shellfish etc. from covering soft body
The metal (such as calcium) of the state combined with protein is secreted into shell side by the epidermal cell of outer embrane, the metal of the secretion into
Divide in marine dissolving, the material for being combined and being existed with crystalline solid such as calcium carbonate with carbon dioxide.
The mineral that may be used as raw metal are not particularly limited, and can be following inorganic acid mineral, such as pyrite
(pyrite,FeS2), vitreous copper (chalcocite, Cu2S), stannite (stannite, Cu2FeSnS4), molybdenite
(molybdenite,MoS2), chalcopyrite (chalcopyrite, CuFeS2) and combinations thereof sulfide mineral, such as magnet
Ore deposit (magnetite, Fe3O4), bloodstone (hematite, Fe2O3) and bloodstone is hydrated or the quilt such as siderite, pyrite
Limonite (limonite, Fe formed by oxidation2O3·nH2O the iron ore, such as ferriferous oxide or molten iron compound)
Zincite (zincite, (Zn, Mn) O), pyrolusite (pyrolusite, MnO2) and combinations thereof oxidation/hydroxide ore deposit
Thing, such as dolomite (dolomite), siderite (siderite, FeCO3), chessy copper (azurite, Cu3(CO3)2(OH)2)、
Malachite (malachite, Cu2(CO3)(OH)2), aragonite (aragonite, CaCO3), calcite (calcite, CaCO3), water chestnut
Manganese ore (rhodochrosite, MnCO3), smithsonite (smithonite, ZnCO3), magnesite (magnesite, MgCO3) or stone
Cream (CaSO4·2(H2O)), alunite (alunite, KAl3(SO4)2(OH)6), can be divided according to the change of F/Cl/OH compositions
For apatite (apatite, the Ca of fluoridated apatite/chlorination apatite/phosphonium hydroxide lime stone5(PO4)3(F, Cl, OH)), olive
Stone (olivine, (Mg, Fe)2SiO4), willemite (willemite, ZnSiO4) and combinations thereof.It is used as inorganic acid ore deposit
Thing, the inorganic acid mineral particularly preferably containing carbonate composition or phosphate composition.In mineralogical composition, it can particularly preferably use all
Such as dolomite or the cheap mineral of the iron ore as magnetic iron ore, bloodstone, limonite and siderite.
For example, dolomite is also known as dolomite, generated by means of the dolomitized of calcite, basic chemical composition is
CaMg (the CO for the carbon restoration hydrochlorate being made up of calcium carbonate and magnesium carbonate3)2, but a part for magnesium replaced by iron or manganese.These metal raws
Material is such as extracting metal ingredient by means of the processing carbon dioxide, and metal ingredient can have with foregoing humic substance
Machine part forms complex bound while and forming metallo-chelate.
In an exemplary embodiment, the inorganic metal salt obtained from raw metal can include metal carbonate,
Calcium carbonate can preferably be included.Raw metal containing this inorganic metal salt can for shell, shellfish fossil, dolomite,
Manganese spar, chessy copper, malachite etc..
In an exemplary embodiment, raw metal, can be by 1 relative to the carbonaceous material of generation organic ligand:1
To 10:1 weight is than addition, preferably by 1:1 to 5:1 weight is than addition.In other words, it is preferable that raw metal is organic with containing
The carbonaceous material of part, which is compared, to be excessively added.In an exemplary embodiment, carbonaceous material can be carried out with raw metal
Coordinate, so that the mol ratio of organic ligand and metallic atom approximately reaches 1:5 to 1:20, preferably reach 1:5 to 1:10.
Therefore, it is not anti-with organic ligand after raw metal and organic ligand reaction form metallo-chelate
Should and exist with free state metal salt, be not converted to the metal raw of metal ion and/or metal salt or metal ion form
Material, can residue in the chelating mineral composition of the present invention.
In an exemplary embodiment, the metallo-chelate of chelating mineral composition of the present invention is constituted in entirety
In composition, about 10~50 parts by weight can be included, 20~30 parts by weight are preferably comprised, raw metal, be used as inorganic metal salt
And/or the inorganic metal compound of metal ion can include 50~90 parts by weight, preferably comprise 70~80 parts by weight, but this hair
It is bright and non-exclusively this.As long as not referring to differently in this manual, parts by weight mean the relative weight of the composition coordinated
Ratio.
In other words, chelating mineral composition of the invention removes the metallo-chelate that organic ligand is combined with metal ingredient
Outside, in addition to intentionally not with organic ligand react inorganic metal salt, be not converted to metal cation component and/or inorganic gold
Belong to salt or the raw metal of metal ion form.Therefore, when the metal ingredient of metallo-chelate form is absorbed by plant etc. and has
When machine ligand component is remained, with inorganic metal salt, metal cation component and/or the metal raw contained in chelating mineral composition
Material reaction, re-forms metallo-chelate, has the advantages that the material for needed for bio-absorbable can be recycled.
Inorganic metal salt is obtained from foregoing raw metal, is not combined and existed with free state with organic ligand.It is inorganic
The species of metal salt can be by the metal inorganic acid of the metal ingredient including foregoing raw metal (for example, metal carbonate, phosphoric acid
Metal or sulfuric acid metal), metal oxide, metal hydroxides, metal hydrate, metal sulfide, metal chloride and it
Combination constitute, but the present invention is not limited to this.For example, the metal salt is metal carbonate.
On the other hand, metal salt can derive from foregoing raw metal.For example, the metal ion can by sodium from
What son, potassium ion, magnesium ion, calcium ion, iron ion, copper ion, zinc ion, manganese ion, molybdenum ion and combinations thereof were constituted
Selected in group, but the present invention is not limited to this.
According to an exemplary embodiment, it can be derived from such as with the complex bound organic ligand of metallo-chelate
The humic substance person of humic acid, fulvic acid etc..These humic substances carry negative electrical charge, promote root system of plant to attract the micro- of positive charge
Secondary element, promotes plant fertility, promotes energetic supersession, promote the activity of enzyme, and due to being amphipathic molecule, thus promote thin
The permeability of after birth performs carrier function.
For example, can be the humic acid of one of the organic ligand extracted from carbonaceous material, plant can be promoted to give birth to, promoted
Enter root system development, activate rhizosphere microorganism, increase nutrient availability and absorption, raising is used as the main nitrogen form being absorbed by plants
One of nitrate nitrogen (NO3-N) utilization rate.Therefore, not only increase the chlorophyll amount of plant and improve light compositing ability, increase
Plus the harvest yield of crop, and contribute to increase pol and vitamin content, improve the quality of plant harvest thing.
Mitigate water stress, increase WUEL moreover, humic acid is performed, mitigate drought, increase to plant disease
Repellence, increase to functions such as the repellences of insect, played a great role in terms of stable arable farming basis is built.And
And, humic acid produces influence to crop seed, increases germination percentage and speed of germination in germination, promotes growth of seedling, carries
High division rate etc..That is, as the humic acid of one of the organic ligand that can be included in metallo-chelate, nutrient needed for promoting, i.e.
Promote trace element and organic matter etc. to be put aside in the organism that plant etc. lives, help the growth of organism.
On the other hand, as the fulvic acid of one of the organic ligand for constituting metallo-chelate, with more stronger than humic acid
Acidity, hydrophily is high, can dissolve the mineral grain that humic acid can not dissolve.In addition, fulvic acid can play mineral matter
Dissolving, nutritional ingredient media feature, therefore, compared with humic acid, can be beneficial to the growth of plant.But, fulvic acid is due to height
Hydrophily, it is soluble in water, stopped not in soil, before being absorbed by plants, soil can be penetrated into by rainwater or underground water etc.
Deep layer and be removed.Therefore, the fulvic acid of too high amount and uneconomical is directly used.Therefore, according to the present invention, when being used as metal
The organic ligand composition of chelate and when using fulvic acid, may be used as spraying the fertilizer of axis and leaf.
Therefore, chelating mineral composition of the invention can be by the use of being used as the organic ligand for being incorporated into metallo-chelate
The humic substance of humic acid or fulvic acid etc., is easy to absorb the chelate of the nutrient source of such as mineral matter with animal and plant
Form is extracted, the active ingredient as the fertilizer needed for plant growth.
Moreover, the organic ligand of complex bound complex compound form is formed with metal ingredient, as important in animal
Inorganic electrolyte composition is acted on.Organic ligand from humic substance can also stablize the micropopulation in animal intestine
Fall, promote the efficiency to food, not only prevent animal intestines and stomach excessive dehydration, and with antibacterial, antiviral effect.Therefore, originally
The chelating mineral composition of invention may be used as the effective of animal feed or the mankind mineral matter functional food to be absorbed
Composition.
[preparation method of chelating mineral composition]
The technique and method that prepare foregoing chelating mineral composition are illustrated below.Fig. 1 is roughly to illustrate
For the figure for the composition that the reactor for chelating mineral composition is prepared according to the exemplary embodiment of the present invention, Fig. 2 is general
Slightly illustrate the precedence diagram for preparing the technique for chelating mineral composition according to the exemplary embodiment of the present invention.Simultaneously
Reference picture 1 and Fig. 2, the method to the preparation chelating mineral composition of exemplary embodiment of the invention are illustrated.
As shown in figure 1, the reactor 1 of the chelating mineral composition for synthesizing the present invention can include：Raw material is put into
Portion 10, air injection unit 20, reactant discharge unit 30, the stirring tool 40 of such as puddler, the alternative titanium dioxide being equipped with
Carbon injection unit 50, temperature/pressure measurement portion 60, pressure-control valve (70).In fig. 1 it is illustrated that the composition of raw material throw-in part etc.
It is provided to the situation of single-reactor, but it is also possible to use more than two reactors.For example, in first reactor, performing
The reaction of organic ligand is extracted from carbonaceous material, in second reactor, the organic ligand and gold by means of extraction can be performed
Belong to the reaction of raw material and generate the reaction of metallo-chelate.
On the other hand, as shown in Fig. 2 the method for preparing mineral matter mineral composition of the present invention can include：Prepare
The step of carbonaceous material containing organic ligand (S210 steps)；(S220 is walked the step of extracting organic ligand from carbonaceous material
Suddenly)；The step of being selectively generating calcium chelate compound (S230 steps)；Input contains what can be reacted with the organic ligand
The step of raw metal of metal ingredient (S240 steps)；Optionally to the reactor for being mixed with organic ligand and raw metal
The step of injecting carbon dioxide (S250 steps)；Make the metal reaction that contains in organic ligand and raw metal and generate metal chelating
The step of compound (S260 steps)；And separated from the chelating mineral composition containing metallo-chelate, extract liquid phase and precipitation
The step of thing (S270 steps).
First, the carbonaceous material of the raw material as organic ligand, made an addition to by raw material throw-in part 10 containing such as water
Solvent reactor 1, prepare carbonaceous material (S210 steps).As it was previously stated, the carbonaceous material as organic ligand raw material can
To be made up of the fertile soil containing humic substance, peat moss, peat, leonardite, lignite, asphalt carbon and combinations thereof
Selected in group, wherein, the humic substance is the organic matter of such as humic acid, fulvic acid, ulmic acid and combinations thereof.It is preferred that
Ground, as carbonaceous material, can select at least one in peat moss, peat, leonardite and lignite.
Preferably, before carbonaceous material devotes reactor 1, the pretreatment work for being ground into suitable size etc. can be performed
Skill.For example, the carbonaceous material such as peat moss, peat, leonardite, lignite can be fed to crushing, part flow arrangement, it is suitable to be ground into
Size is simultaneously shunted, dried.Now, carbonaceous particle is ground into reducing mechanism, wind or hot blast are supplied in reducing mechanism bottom, can
Carbonaceous fraction (fraction) with carbonaceous particle only to dust form and with suitable size is shunted, and is supplied to reaction
Device 1.It therefore, it can be processed into the mass transport process institute of the Extraction solvent in it may require that the separation type of accurate fraction or spoon type extractor
It is required that carbonaceous material.
In an exemplary embodiment, devoting the carbonaceous of reactor 1 can use with average of 0.5 below ㎜
Grain size carbonaceous particle, for example, with mean particle size be 0.01 to 0.5 ㎜ carbonaceous particle, preferably use 0.05 to
0.5 ㎜ carbonaceous particle.If foregoing scope that the size of carbonaceous particle is not enough, although the extraction of organic ligand composition is held
Easily, but there is the increased worry of processing charges of carbonaceous particle, if it exceeds foregoing scope, then needed for extracting organic ligand
Reaction time can extend.
Then, organic ligand is extracted from the carbonaceous material, for example, the corruption such as extracted humic acid, fulvic acid and/or ulmic acid
Grow material (S220 steps).In order to extract fulvic acid from carbonaceous material, special processing can not be required, but in order to extract humic
Acid is, it is necessary to make the pH of reactant be changing into alkalescence.Therefore, can in reactor 1 be added suitably by raw material throw-in part 10
Basifier.
The basifier that can be used is not particularly limited, but basifier can by quick lime (CaO), calcium hydroxide (CaOH),
Selected in the group that caustic soda (NaOH), caustic potash (KOH) and combinations thereof are constituted.By means of the processing of this basifier,
The pH of reactor 1 containing carbonaceous material and solvent is transformed into alkaline state.In an exemplary embodiment, by means of adding
Plus the alkaline agent, the pH of reactant can be adjusted to 8 to 12, preferably be adjusted to 8 to 10 or so.Therefore, the basifier can
Reactor 1 is devoted with the concentration for pressing about 5~30% (w/v) in a solvent.
Basifier has optionally been put into, using stirring tool 40 to being dissolved with the carbonaceous of suitable particulate size in solvent
The reactor 1 of material is stirred, and makes reactant more than 50 DEG C, for example, more than 80~100 DEG C of temperature and atmospheric pressure, example
Such as under 1~2 air, react more than 12 hours, preferably react 24 hours to 72 hours.Therefore, contain in carbonaceous material
Humic substance is dissolved in solvent with the form of organic ligand and is extracted by swelling.Now, the temperature and pressure of reactor can lead to
Cross measurement portion (70) to measure, the air under atmospheric pressure can be for example injected inside reactor 1 by air injection unit 20.
By means of this processing, humic substance soluble in water is not only, even being used as the humic substance for being insoluble in water
Macromolecule, also some hydrolyzable is into forms such as the humic acid, fulvic acid, ulmic acid of small molecule.Extract molecular weight it is small or
The organic ligand of form soluble in water, this organic ligand can be extracted by reactant outlet 30.For example, conduct
The humic acid of one of organic ligand contains a variety of anion, in the state of pH risings are alkalescence, with each of anionic property
Molecule is mutually extruded, and carries out swelling while condensation is disintegrated in this way, becomes collagen phase, it is thus possible to which extracting these has
Machine part.
On the other hand, fulvic acid is although soluble in water, but under the pH of acid condition, can be more soluble in water.In order to extract
Fulvic acid, for example, can add acidulant in a solvent, and the acidulant can be the inorganic strong acid of such as nitric acid or hydrochloric acid,
Or such as organic acid of lactic acid, acetic acid, fumaric acid, formic acid, propionic acid, malic acid, citric acid.For example, by means of adding these acid
The pH of reactant, can be adjusted to 3~5 or so by agent.
According to an exemplary embodiment, in the humic substance contained in foregoing carbonaceous material, humic charcoal and acid
Degree it is independently water insoluble, therefore, in other humic substances in addition, for example humic acid, fulvic acid, ulmic acid and they
Combination in, at least one organic matter preferably selected in humic acid and fulvic acid is decomposed into organic ligand.
From the humic substance of carbonaceous material, according to color, the degree of polymerization, molecular weight, such as COOH bases/OH bases function
Quantity, the quantity of carbon and oxygen, degree of exchange, water solubility of group (functional group) etc., can be divided into humic charcoal, humic
Acid, fulvic acid, ulmic acid etc..These humic substances can make a distinction according to paradigmatic structure, ring/chain form etc., with substantially 5
~50nm size, stereochemical structure and size are determined in humification process.
For example, humic acid is as being practically insoluble in water but by means of the alkaline agent of caustic potash (KOH), caustic soda (NaOH) etc.
The high-molecular compound for handling and dissolving, with brown-dark brown, the functional group of intramolecular is more, thus various trace element appearances
Easily combine, the part Nature District negative electrical charge of oxidation.Humic acid is intricately combined with ammonia as between aromatic ring and ring
The complex aromatic race high-molecular compound (aromatic of base acid, amino sugar, peptide, aliphatic compound etc.
Macromolecules), nitrogen, oxygen, hydroxyl, carboxyl etc. are diversely combined with aromatic rings.In humic acid organic structure, permitted
Many part autoxidations and it is negatively charged.
Fulvic acid (Fulvic acid) is the high-molecular compound independently soluble in water with acidity, with yellow or Zhu
Yellow.Fulvic acid has aromatic series, aliphatic structure, and two kinds of structures are widely replaced into containing aerobic functional group.Fulvic acid
As the quantity of oxygen more than humic acid but carbon the quantity humic composition fewer than humic acid, largely contain functional group, it is particularly big
Amount contains COOH bases, OH base C=O bases.
In a selective embodiment, the step of organic ligand is extracted in (S220 steps), can with it is foregoing
Basifier together or independently of basifier adds gypsum (CaSO in reactor 14·nH2O).Gypsum is when generating phosphoric acid
The trade waste of appearance, can be used as the presoma composition for constituting the metallo-chelate for chelating mineral composition of the invention
And recycle.
If the organic ligand and gypsum of extraction are made an addition in solvent, due to gypsum the solubility of water is better than it is aftermentioned
Raw metal, thus combined with the humic acid or fulvic acid as organic ligand etc., form calcium chelate.In the process,
Free sulfuric acid and the metal salt or metal ion that are obtained from raw metal composition react, for example, and calcium carbonate reaction, become again
Change calcium sulfate into, prevent that the pH of composition is low.The calcium sulfate of conversion can again with remove metallo-chelate form metal
Remaining organic ligand reaction afterwards.
For example, the organic matter such as the humic acid contained in carbonaceous material, fulvic acid is huge macromolecular structure, central whole
With by functional group is few, the low aromatic compound for being used as aliphatic acid and lignin of liposoluble constituent etc. to have phenyl ring of polarity
Fat-soluble functional group formed by the influence of thing by representative of phenolic hydroxy group, and by the high water-soluble natural macromolecule of polarity
Amino acid or sugar compounds influence formed by with the water-soluble function of alcoholic hydroxyl (ROH) and carboxyl (RCOOH) for representative
Group.Therefore, these organic ligands due to cation exchange properties it is very high, thus the cationic various with periphery can be passed through
The cation exchange reaction of material and generate chelate.
But, if gypsum, i.e. if calcium sulfate is excessive, be used as when the chelating mineral composition of the present invention
During fertilizer etc., soil meeting acidification, the intake of animals and plants can become difficult.Therefore, gypsum is relative to carbonaceous material, substantially can be with
Add, can preferably be added by 5~10 parts by weight ratios by 5~20 parts by weight ratios.
After suitable organic ligand is extracted from carbonaceous material, raw metal is devoted containing the organic ligand extracted
Reactor (S240 steps).Raw metal is not particularly limited, and can contain such as sodium (Na), the alkali metal of potassium (K), such as magnesium
(Mg), the alkaline-earth metal of calcium (Ca), the transiting metal component of iron (Fe), copper (Cu), zinc (Zn), manganese (Mn), molybdenum (Mo) etc..
For example, raw metal can be selected in the group being made up of shell, shellfish fossil, mineral and combinations thereof.These raw metals
With powder morphology or the block of suitable size can be truncated into put into.The raw metal of powder morphology can be preferably used, this
When, raw metal can substantially have 0.1 to 2 ㎜ mean particle size.In the case where raw metal is with block use, its
Size is not particularly limited, if for example using the calx of 0.5~20 ㎝ sizes, if preferably using 0.5~5 ㎝ sizes
Raw metal, then having the advantages that being capable of high efficiency extraction metal ingredient.But, in the present invention, the size of raw metal is not
What problem.
According to the present invention, compared with as the carbonaceous material of organic ligand raw material, offer and organic ligand knot is excessively added
The raw metal of the metal ingredient of conjunction.Therefore, by means of organic ligand with from raw metal generate metal salt and/or metal from
Son reaction and form metallo-chelate, meanwhile, include not with organic ligand react inorganic metal salt, such as metal ion
And/or the inorganic metal compound of raw metal.Metal ingredient as metallo-chelate form is absorbed by organism, remaining
Organic ligand can react with inorganic metal salt, metal ion and/or raw metal free in composition or remain again, weight
Newly-generated new metallo-chelate.
In an exemplary embodiment, raw metal can be used for the carbonaceous material of organic ligand raw material excessively
Addition.For example, raw metal is relative to carbonaceous material, can be by 1:1 to 10:1 weight, preferably can be by 1 than addition:1 to
5:1 weight is than addition.Therefore, the metal salt and/or a part for metal ion and organic ligand obtained from raw metal is anti-
Answer and form metallo-chelate, but remainder can form the metal salt and/or metal ion of free state.Moreover, must
In the case of wanting, a part for the metal ingredient that raw metal contains is transformed into free metal salt and/or metal salt, but a part
Metal ingredient can be residued in raw metal.
Mineral as raw metal can be with the sulfide mineral containing foregoing metal ingredient, oxidation and/or hydrogen-oxygen
Change inorganic acid mineral and combinations thereof that the forms such as mineral, carbonate, sulfate, silicate, phosphate contain metal ingredient.
Can obtain suitable inorganic metal salt and/or metal ion from these raw metals, these inorganic metal salts and/or metal from
Son can with the organic ligand of extraction directly in conjunction with.
As it was previously stated, the cation exchange capacity (CEC) of organic ligand is very outstanding.Therefore, in the embodiment of selectivity,
In the state of generating calcium chelate using gypsum, by means of the inorganic metal salt and/or gold obtained from these raw metals
Belong to the cation exchange reaction of ion and calcium chelate, the metal that can be obtained from inorganic metal salt is combined with organic ligand
Metallo-chelate.
The inorganic metal salt obtained from raw metal is not particularly limited, as the species of inorganic metal salt, can by including
The metal inorganic of the metal ingredient of foregoing raw metal sour (such as metal carbonate, phosphate metal or sulfuric acid metal), metal oxygen
Compound, metal hydroxides, metal hydrate, metal sulfide, metal chloride and combinations thereof are constituted.In addition, metal
Ion can be come from origin the sodium ion of raw metal, potassium ion, magnesium ion, calcium ion, iron ion, copper ion, zinc ion,
Selected in the group that manganese ion, molybdenum ion and combinations thereof are constituted.
For example, the organic ligand and the inorganic metal salt that is obtained from raw metal and/or metal that are extracted from carbonaceous material from
Reaction between son, for example, being depressed into air under 2 atmospheric pressure, can be performed more than 24 hours more than atmospheric pressure, for example,
Perform 24 hours to 48 hours.Therefore, between the metal salt and/or metal ion that are obtained by organic ligand and from raw metal
Reaction, metallo-chelate can be generated.
If as metallo-chelate presoma, gypsum is not used, then, in order to extract foregoing metal raw in a solvent
The metal ingredient contained in material, can be by carbon dioxide injection portion 50, in the organic ligand containing extraction and raw metal
Carbon dioxide (S250 steps) is injected in reactor.Therefore, it can using make the inorganic metal salt that contains in raw metal and/or
The method that metal ion is dissolved in solvent is extracted.
As an exemplary embodiment, when using shell, shellfish fossil and carbonate mineral as raw metal, make
The calcium carbonate of metal ingredient to contain in shell etc. is not readily dissolved in the water as solvent.Now, if injecting two to reactor 1
Carbonoxide so that be dissolved in the water as solvent, then, carbon dioxide is transformed into carbonic acid, and the pH of solvent declines, dissolution of calcium carbonate
Yu Shui.The calcium carbonate dissolved in water can be combined easily with organic ligand, it is thus possible to which generating metallo-chelate, (S260 is walked
Suddenly).
According to the amount of the carbon dioxide of injection, metal ingredient in raw metal both can be to be fully dissolved in the nothing in water
Machine metal salt and/or metal ion form are dissociated or a part of metal ingredient only in raw metal is with inorganic gold
Belong to salt and/or metal ion form is free.In order that the metal ingredient in raw metal is all with inorganic metal salt and/or metal
Ionic formses dissociate, and can inject excessive carbon dioxide.Carbon dioxide can both use gaseous state person, can also use liquid
Body state person.In the case of necessary, it can also use in the high-temperature heat treatment mistake for extracting organic ligand from carbonaceous material
The carbon dioxide occurred in journey.
In order to generate metallo-chelate and in the case of using carbon dioxide, organic ligand and inorganic metal salt and/
Or after the chelatropic reaction between metal ion, pressure-regulating valve 60 is adjusted, pressure is adjusted, unnecessary carbon dioxide is discharged and reacted
Outside device.Now, after metallo-chelate is formed, the temperature of reactor can be made to increase, removing carbon dioxide is removed, be transformed into neutrality
State.For example, after the completion of metallo-chelate formation, if the temperature of reactor 1 is warming up to more than 50 DEG C, being such as warming up to
80~100 DEG C of temperature, is injected air by air injection unit 20, is sufficiently stirred for using stirring tool 40, then, organic ligand
Reaction between metal salt can be carried out effectively.Then, confirm the pH of reactant, if neutrality, then can stop stirring,
Terminate reaction.The pH changes of reactant can use pH test paper or pH meter to be confirmed.
By between the metal salt and/or metal ion obtained from the organic ligand of carbonaceous material and from raw metal
Chelatropic reaction, generation comprising metallo-chelate chelating mineral composition after, make precipitate, separation and Extraction upper liquid
(S270 steps).In beige liquid phase ingredient, as Determination of Organic Acids, containing it is relative be low molecular fulvic acid composition,
These liquid phase ingredients can be packaged into product, be used as the liquid fertilizer needed for plant growth and/or the supply of the mineral matter of animal
Feed.
On the other hand, particle (granule) form can be made in the precipitation solid of dark brown or black, as solid fertilizer
Material, or the mineral matter supply feed as animal.Particle shape can utilize the method for being mixed, being dried to precipitation solid
Manufacture, if it is desired, can carry out extrusion processing to be mixed with the form of adhesive with aperture, prepare homogeneous size
Particle.
By means of separation, the liquid phase extracted and obtained or solid, comprising animal being made and plant easily absorbs mineral matter
The metal complex of chelate form, thus may be used as the fertilizer of plant, the feed of animal or the mineral matter applied to human body
The raw material or active ingredient of product.
Exemplary embodiment and embodiment above based on the present invention, the present invention is described, but the present invention is not
It is defined in the embodiment and the technological thought described in embodiment.As long as on the contrary, the skill of the technical field of the invention
Art personnel, just can easily carry out various deformation and change based on foregoing embodiment and embodiment.But, it is this
Deformation and change belong to the interest field of the present invention, by appended claims, the fact that will be apparent from.
Claims (13)
1. one kind chelating mineral composition, including：
It is combined with the metallo-chelate of organic ligand；And
Inorganic metal compound, it is selected from the group being made up of raw metal, inorganic metal salt, metal ion and combinations thereof.
2. chelating mineral composition according to claim 1, wherein,
The raw metal is selected from the group being made up of shell, shellfish fossil, mineral and combinations thereof.
3. chelating mineral composition according to claim 1, wherein,
The inorganic metal salt is selected from by metal inorganic acid, metal oxide, metal hydroxides, metal sulfide, metal chlorine
The group that compound, metal hydrate and combinations thereof are constituted.
4. chelating mineral composition according to claim 1, wherein,
The organic ligand is selected from by humic acid (Humic acid), fulvic acid (Fulvic acid), ulmic acid (Ulmic
Acid) and combinations thereof constitute group.
5. a kind of mineral food, the chelating mineral composition recorded comprising any one of Claims 1-4.
6. a kind of animal feed, the chelating mineral composition recorded comprising any one of Claims 1-4.
7. a kind of fertilizer, the chelating mineral composition recorded comprising any one of Claims 1-4.
8. a kind of preparation method for chelating mineral composition, including：
Carbonaceous (carbonaceous) material containing organic ligand, is made an addition to the reactor containing solvent by a) step, is extracted
The organic ligand contained in the carbonaceous material；
B) step, raw metal is put into the reactor of the organic ligand contained；And
C) step, makes the organic ligand of extraction and the inorganic metal salt or metal ion that are obtained from the raw metal anti-
Should, generate metallo-chelate.
9. the preparation method of chelating mineral composition according to claim 8, wherein,
Include in a) step：Together with the carbonaceous material, alkaline agent is made an addition to the reactor containing solvent
Step.
10. the preparation method of chelating mineral composition according to claim 8, wherein,
C) the step includes：Carbon dioxide is injected in the reactor that the raw metal is put into, the raw metal is obtained
In contain inorganic metal salt or metal ion the step of.
11. the preparation method of chelating mineral composition according to claim 8, wherein,
Include in a) step：Gypsum is added in the reactor, the organic ligand and the gypsum of extraction are anti-
The step of answering and form calcium chelate；
C) the step includes：The calcium chelate and the inorganic metal salt or metal ion carry out cation exchange reaction,
Generate the metallo-chelate for constituting the metal of the inorganic metal salt or metal ion and being combined with the organic ligand, the step of calcium salt
Suddenly.
12. the preparation method of chelating mineral composition according to claim 8, wherein,
The raw metal presses 1 relative to the carbonaceous material:1~10:1 weight is than addition.
13. the preparation method of chelating mineral composition according to claim 8, wherein,
After the c) step, further comprise：Air is injected in the reactor for generating the metallo-chelate and is stirred,
The step of being separated, extracted to the upper liquid and precipitation solid of acquisition.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
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| KR1020160005518A KR20170085859A (en) | 2016-01-15 | 2016-01-15 | Mineral chelate composition and process of fabricating the composition |
| KR10-2016-0005518 | 2016-01-15 |
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| CN106974293A true CN106974293A (en) | 2017-07-25 |
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| CN109566867A (en) * | 2017-09-29 | 2019-04-05 | 金范圭 | Organic mineral substance composition and application |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0954514A1 (en) * | 1996-11-13 | 1999-11-10 | Stoller Enterprises, Inc. | Fertilizer compositions including chelated metal ions |
| KR100453560B1 (en) * | 2001-08-01 | 2004-10-20 | 서희동 | Artificial manufacturing method of activated humic substances |
| CN101684132A (en) * | 2008-09-25 | 2010-03-31 | 唐毅 | Production method and application of humic acid and fulvic acid extracted from humus and organic salts of mineral compounds thereof |
| CA2786236A1 (en) * | 2010-01-04 | 2011-07-07 | Timac Agro International | Phosphate compounds and use thereof as fertiliser |
| JP5833490B2 (en) * | 2012-04-10 | 2015-12-16 | 株式会社日本自動車部品総合研究所 | Metal ion remover |
-
2016
- 2016-01-15 KR KR1020160005518A patent/KR20170085859A/en not_active Application Discontinuation
- 2016-12-29 CN CN201611271778.1A patent/CN106974293A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0954514A1 (en) * | 1996-11-13 | 1999-11-10 | Stoller Enterprises, Inc. | Fertilizer compositions including chelated metal ions |
| KR100453560B1 (en) * | 2001-08-01 | 2004-10-20 | 서희동 | Artificial manufacturing method of activated humic substances |
| CN101684132A (en) * | 2008-09-25 | 2010-03-31 | 唐毅 | Production method and application of humic acid and fulvic acid extracted from humus and organic salts of mineral compounds thereof |
| CA2786236A1 (en) * | 2010-01-04 | 2011-07-07 | Timac Agro International | Phosphate compounds and use thereof as fertiliser |
| JP5833490B2 (en) * | 2012-04-10 | 2015-12-16 | 株式会社日本自動車部品総合研究所 | Metal ion remover |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109566867A (en) * | 2017-09-29 | 2019-04-05 | 金范圭 | Organic mineral substance composition and application |
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