CN106968655A - A kind of oil production method - Google Patents

A kind of oil production method Download PDF

Info

Publication number
CN106968655A
CN106968655A CN201710325487.4A CN201710325487A CN106968655A CN 106968655 A CN106968655 A CN 106968655A CN 201710325487 A CN201710325487 A CN 201710325487A CN 106968655 A CN106968655 A CN 106968655A
Authority
CN
China
Prior art keywords
oil
displacement agent
salinity
viscosity
oil displacement
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201710325487.4A
Other languages
Chinese (zh)
Other versions
CN106968655B (en
Inventor
周明辉
孙文杰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
China Petroleum and Natural Gas Co Ltd
Original Assignee
China Petroleum and Natural Gas Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by China Petroleum and Natural Gas Co Ltd filed Critical China Petroleum and Natural Gas Co Ltd
Priority to CN201710325487.4A priority Critical patent/CN106968655B/en
Publication of CN106968655A publication Critical patent/CN106968655A/en
Application granted granted Critical
Publication of CN106968655B publication Critical patent/CN106968655B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • EFIXED CONSTRUCTIONS
    • E21EARTH DRILLING; MINING
    • E21BEARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/16Enhanced recovery methods for obtaining hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/58Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids
    • C09K8/584Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids characterised by the use of specific surfactants
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/58Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids
    • C09K8/588Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids characterised by the use of specific polymers

Abstract

The invention provides a kind of oil production method.This method comprises the following steps:To meet following three points requirement simultaneously oil displacement agent is selected for standard:1) viscosity of oil displacement agent has single peak type feature with salinity altercation curve;2) viscosity of oil displacement agent is more than or equal to the salinity range of stratum water in oil reservoir with the unimodal corresponding salinity range in salinity altercation curve;3) viscosity of the corresponding oil displacement agent of lowest salinity value of stratum water is not less than 100mPas in oil reservoir;Selected oil displacement agent is injected to oil reservoir by injection well, and crude oil is produced from producing well, to exploit the crude oil in oil field.The oil production method of the present invention is mainly used in exploiting the crude oil in the oil field for having undergone the waterflooding behavior stage, the viscosity of the selected oil displacement agent of method different zones in oil reservoir of the present invention produces difference, this method is compared with the oil production method of existing water drive, chemical flooding and gas drive, oil displacement agent can be expanded and involve scope in oil reservoir, Development Response of Oilfield is improved.

Description

A kind of oil production method
Technical field
The present invention relates to a kind of oil production method in DP technology field, and in particular to a kind of oil reservoir portion in different permeabilities Oil displacement agent has different viscosities feature in position, to improve the oil production method of oil recovery effect.
Background technology
In field of petroleum exploitation, the viscosity of oil displacement agent is to influence the key factor of exploitation effect and oil recovery.Typically For, oil displacement agent viscosity is higher, then the oil reservoir scope that can be fed through to is wider, and exploitation effect and recovery ratio are better.But work as Viscosity is increased to after certain threshold value, because the oil displacement agent of injection is excessively sticky, will reduce exploitation effect and recovery ratio.This glues Degree threshold value and the permeability of oil reservoir are strong positively related, and general permeability is higher, and the upper viscosity limit for suitably injecting oil displacement agent is got over It is high.For the oil reservoir of homogeneous everywhere in theory, the permeability of internal each position is equal, can directly be selected according to permeability The suitable viscosity of injection oil displacement agent is selected, but in reality, due to deposition, the influence into the geologic(al) factor such as Tibetan and construction, actual oil The permeability for each position hidden simultaneously is differed, or even widely different in many cases, it is virtually impossible to is found and be can adapt to institute There is the oil displacement agent viscosity criterion of position, this is the one of the main reasons for restricting Modern oil field development effectiveness.
For above mentioned problem, what current industrial quarters was generally taken is lower limit strategy, that is, selects a unified relatively low drive Finish viscosity.The strategy can avoid the relatively low position of permeability in oil reservoir from blocking as far as possible, but be the problem of bring, for The higher position of permeability, because the oil displacement agent viscosity of selection is far below the viscosity threshold that can be blocked, makes these positions Oil displacement efficiency is unsatisfactory.If the oil displacement agent viscosity selected is higher than lower limit strategy viscosity, then local oil reservoir will be had and occurred Block, overall oil displacement efficiency is less than lower limit strategy.
After all, the technical reason of above-mentioned predicament is because existing all oil displacement agents are all difficult to show in oil reservoir Different viscosity, to adapt to different Reservoir Permeabilities.It is therefore desirable to develop a kind of oil production method, driven in oil displacement process Finish viscosity can change at the oil reservoir position of different permeabilities, to adapt to this permeability contrast.
The content of the invention
In order to solve the above technical problems, it is an object of the invention to provide a kind of oil production method.This method is one kind not There is different viscosities feature with oil displacement agent in the oil reservoir position of permeability, to improve the oil production method of oil recovery effect.
In order to achieve the above object, the invention provides a kind of oil production method, this method comprises the following steps:
(1) oil displacement agent is selected to meet following three points requirement simultaneously for standard:
1) viscosity of oil displacement agent has single peak type feature with salinity altercation curve;
2) viscosity of oil displacement agent with the unimodal corresponding salinity range in salinity altercation curve be more than or equal to oil reservoir in The salinity range of layer water;
3) the lowest salinity value of stratum water corresponding oil displacement agent in the viscosity of oil displacement agent is with salinity altercation curve in oil reservoir Viscosity be more than 100mPas;
(2) selected oil displacement agent is injected to oil reservoir by injection well, and crude oil is produced from producing well, to exploit in oil field Crude oil.
According to the embodiment of the present invention, it is preferable that the above method further comprises step (3):Recover the oil in producing The monitoring of production fluid salinity is kept, such as finds that salinity has greatly changed, so that 3 points no longer met in step (1) will Ask, then determine the distribution of formation water salinity again, and filtered out and meet with salinity altercation curve according to the viscosity of oil displacement agent The oil displacement agent of 3 points of requirements in step (1) is repeated up to oil field to replace current oil displacement agent, so and scrapped.
In the above-mentioned methods, it is preferable that selected oil displacement agent also meets claimed below:The viscosity of oil displacement agent becomes with salinity Change minimum of the corresponding salinity of peak value less than the distribution of formation water salinity in oil reservoir of curve.
In the above-mentioned methods, it is preferable that selected oil displacement agent is the mixture of a solvent and solute, the solvent is general For water, the solute can be single solute or multi-component solute, and the solute is in the oil displacement agent Weight content is 0.1% to 50%.
In the above-mentioned methods, it is preferable that the viscosity of selected oil displacement agent is with the excursion of salinity altercation in 1mPas To 1 × 107mPa·s。
In the above-mentioned methods, it is preferable that selected oil displacement agent is NaCl matter in an atmospheric pressure, 25 DEG C of temperature, salinity Range of viscosities under conditions of amount concentration 200ppm is 1mPas to 500mPas.In the present invention, 1ppm=1mg/L.
In the above-mentioned methods, it is preferable that the viscosity of selected oil displacement agent is with unimodal corresponding in salinity altercation curve Salinity range is 1 × 103Mg/L to 1 × 106mg/L。
In the above-mentioned methods, it is preferable that the viscosity of selected oil displacement agent has single peak type feature with salinity altercation curve Show as:In the case where other conditions are constant, in salinity from 1 × 103Mg/L increases to 1 × 106During mg/L, drive The viscosity of finish successively experienced to be uprised and by two variation tendencies of high step-down, the two changes are continuous, scopes by low 1 × 103Mg/L to 1 × 106mg/L。
In the above-mentioned methods, it is preferable that parts by weight meter, the raw material composition of selected oil displacement agent includes:Host 0.1-10 82-99.8 parts of part, 0.1-5 parts of agent of association, 0-2 parts of synergist, 0-1 parts of polymer and water.
In above-mentioned oil displacement agent, it is preferable that the host is that formula is CnH2n+1O(CH2CH2O)yXM anionic surface is lived Property agent, in formula, n is 1-38 integer, and y is 1-6 integer, and X is an electronegative acid group, and M is the metal ion of a positively charged Or ammonium root.Wherein, it is highly preferred that the electronegative acid group can include sulfate radical, sulfonate radical, inferior sulfate radical, phosphate radical or Benzene sulfonic acid root etc., but not limited to this;The metal ion of the positively charged includes potassium, sodium or lithium etc., but not limited to this.
In above-mentioned oil displacement agent, it is preferable that the association agent is nonionic surfactant, can specifically include polyoxy second Ene-type nonionic surfactant and/or polyol-based non-ionic surfactant etc..
In above-mentioned oil displacement agent, it is preferable that the synergist is the anion surfactant insensitive to alkali and hard water, 12 to sodium stearyl sulfate (C can specifically be includednH2n+1SO4Na, wherein n be 12-18 integer), 12 to octadecane Base sodium sulfonate (CnH2n+1SO3Na, wherein n are 12-18 integer) and 12 to octadecyl benzenesulfonic acid sodium (CnH2n+ 1C6H4SO3Na, wherein n are 12-18 integer) etc. in one or more of combinations, but not limited to this.
In above-mentioned oil displacement agent, it is preferable that the polymer is water-soluble polymer, it can increase the viscous of the aqueous solution Degree, can specifically include partially hydrolyzed polyacrylamide (PHPA) class (HPAM) polymer (such as partially hydrolyzed polyacrylamide (PHPA)) or xanthan Glue is birdsed of the same feather flock together compound (such as xanthans), but not limited to this.
According to the embodiment of the present invention, it is preferable that above-mentioned oil displacement agent is through the following steps that prepare:With weight Part meter is measured, stirring 4-8 hours after 0-1 parts of polymer are added in 82-99.8 part water, aqueous solutions of polymers is obtained, then to described Sequentially added in aqueous solutions of polymers 0.1-10 parts of host, association 0.1-5 part of agent and 0-2 parts of synergist after stirring 1-3 hours, so 18-30 hours are stood afterwards, the oil displacement agent composition of described variable viscosity is obtained.
In the above-mentioned methods, it is preferable that the salinity range of stratum water is 1 × 10 in the oil reservoir3Mg/L to 1 × 106mg/ L。
In the above-mentioned methods, the injection well and the producing well can be straight well or horizontal well, or a straight well One horizontal well, and the well pattern form being made up of multiple injection wells and producing well is not restricted.
In the above-mentioned methods, it is preferable that the oil field is the oil field for having undergone the waterflooding behavior stage.It is highly preferred that described The average oil saturation in oil field is 20% to 80%, and Produced Liquid moisture content is 0 to 95%.
In the oil production method of the present invention, the viscosity of oil displacement agent is related to the seepage flow machine of reservoir porous with salinity altercation Reason, is explained as follows.Stratum water in original oil field for not undergoing waterflooding behavior, oil reservoir under different parts, different permeabilities Salinity is relatively, and to undergo after waterflooding behavior, due to filtrational resistance difference, makes the water at different permeability positions in oil reservoir Wash that degree is different, the water that high permeability position is flowed through is more, and washing degree is higher, and the water that low-permeability position is flowed through is on the low side, Washing degree is relatively low.In view of the salinity of injection water is far below prime stratum salinity water, therefore washing degree is universal higher hypertonic Saturating rate position salinity is relatively low, and the universal relatively low low-permeability position salinity of washing degree is higher.
The principles of science of the oil production method of the present invention is Reservoir Permeability-washing degree-stratum water after the above-mentioned water drive of analysis The incidence relation of salinity, implementation method is the distribution according to formation water salinity, determines the viscosity of oil displacement agent with salinity altercation The characteristic value of curve, filters out the oil displacement agent for meeting this feature value, to realize matching for oil displacement agent viscosity and formation water salinity, reaches To matching and linkage of the oil displacement agent viscosity from different permeabilities, oil displacement efficiency is improved.
After method using the present invention, oil displacement efficiency will improve, then through after a period of time, can be it is observed that producing well The salinity of the stratum water of output has greatly changed, in oil reservoir the lowest salinity value of stratum water in the viscosity of oil displacement agent with salinity The viscosity of corresponding oil displacement agent is less than 100mPas in change curve, and now oil displacement efficiency will be deteriorated, and stratum water should be determined again The distribution of salinity, selects the oil displacement agent of the 3 points of requirements met in step (1) to replace current oil displacement agent, so repeats Until oil field is scrapped.
The oil production method provided by the present invention, it is possible to achieve oil displacement agent viscosity is in different permeabilities in oil displacement process Oil reservoir position changes, and has novelty in seepage flow mechanism than existing methods;It can also realize that oil displacement agent is high in oil reservoir The position viscosity of permeability is higher, and relatively low in the position viscosity of low-permeability, and such oil production method can be from porous media The efficiency of existing oil exploitation is improved in the mechanism of seepage flow, there is novelty in application effect than existing methods.The present invention is carried It is single that the oil production method of confession solves existing oil displacement agent viscosity characteristics, it is difficult to adapts to different parts permeability in Complex Reservoir Difference, the problem of oil displacement efficiency is poor.The oil production method is applied to sandstone, the gravel of the common hypotonic and middle and high infiltration of water drive intermediary and later stages Shale oil is hidden, to improve recovery ratio, especially suitable for oil reservoir stronger with plane heterogeneity in above-mentioned oil reservoir middle level.Also, The oil production method of the present invention is compared with the oil production method of existing water drive, chemical flooding and gas drive, with the viscosity changeable in oil reservoir The advantage of change, expands oil displacement agent and involves scope in oil reservoir, improve Development Response of Oilfield.
Brief description of the drawings
Fig. 1 is the principle and steps flow chart schematic diagram of the oil production method of the specific embodiment of the invention.
Fig. 2 be the present invention oil production method in oil displacement agent viscosity with salinity altercation curve and the schematic diagram of characteristic value.
Embodiment
In order to which technical characteristic, purpose and beneficial effect to the present invention are more clearly understood from, now to the skill of the present invention Art scheme carry out it is described further below, but it is not intended that to the present invention can practical range restriction.
According to the embodiment of the present invention, it is preferable that as shown in figure 1, according to analysis Reservoir Permeability-washing journey The principle of the incidence relation of degree-formation water salinity, the oil production method that the present invention is provided may comprise steps of:
(1) distribution (can sample and determine with Produced Liquid according to well logging) of formation water salinity in oil reservoir is determined;
(2) require to select oil displacement agent for standard to meet simultaneously at following 4 points:The viscosity of oil displacement agent is with salinity altercation curve With single peak type feature;The viscosity of oil displacement agent is more than or equal to oil reservoir with the unimodal corresponding salinity range in salinity altercation curve The salinity range of interior stratum water;The lowest salinity value of stratum water correspondence in the viscosity of oil displacement agent is with salinity altercation curve in oil reservoir Oil displacement agent viscosity be more than 100mPas;Oil displacement agent viscosity is with the corresponding salinity of peak value of salinity altercation curve less than oil The minimum of the distribution of formation water salinity in hiding;
The viscosity of oil displacement agent is with salinity altercation curve and characteristic value schematic diagram as shown in Fig. 2 in figure:μ0For salinity M0= Oil displacement agent viscosity during 50ppm, μ1For oil displacement agent peak viscosity, M1Corresponding salinity, μ during for oil displacement agent peak viscosity2For salinity M2=1 × 106Oil displacement agent viscosity during ppm;
For " viscosity of oil displacement agent is more than or equal in oil reservoir with the unimodal corresponding salinity range in salinity altercation curve The salinity range of stratum water;Oil displacement agent viscosity is with the corresponding salinity of peak value of salinity altercation curve less than formation water salinity in oil reservoir Distribution minimum " explanation be:For example, as shown in Fig. 2 oil displacement agent viscosity with salinity altercation curve unimodal correspondence Salinity range be M0To M2, the corresponding salinity of peak value is M1;The salinity range of stratum water is M in oil reservoir3To M4;Then need to meet M0 < M3And M2≥M4(i.e. the viscosity of oil displacement agent is more than or equal to oil reservoir with the unimodal corresponding salinity range in salinity altercation curve The salinity range of interior stratum water), and also need to meet M1<M3(i.e. oil displacement agent viscosity with salinity altercation curve the corresponding salt of peak value Minimum of the degree less than the distribution of formation water salinity in oil reservoir);
(3) selected oil displacement agent is injected to oil reservoir by injection well, and crude oil is produced from producing well, to exploit in oil field Crude oil;
(4) recover the oil and the monitoring of production fluid salinity is kept in producing, such as find that salinity has greatly changed, then determine again The distribution of formation water salinity, and four met in step (2) are filtered out with salinity altercation curve according to the viscosity of oil displacement agent The oil displacement agent that point is required is repeated up to oil field to replace current oil displacement agent, so and scrapped.
Using the oil production method of the present invention, it is possible to achieve oil reservoir of the oil displacement agent viscosity in different permeabilities in oil displacement process Position changes, and makes oil displacement agent higher in the position viscosity of oil reservoir medium to high permeable rate, and low-permeability position viscosity compared with Low, the oil production method can improve the efficiency of existing oil exploitation from the mechanism of Porous Media.
The present invention is explained in more detail referring to specific embodiment, it is the mesh for explanation to provide these examples , and it is not intended to limit the present invention.
Embodiment 1
With Numerical Method Study, oil reservoir block is using the effect of the oil production method of the present invention, and wherein oil deposit parameter is such as Under:Core intersection 10m, area 10km2, porosity 28%, permeability 20-1000mD, initial oil saturation 72%, crude oil Lower viscosity 15mPas, prime stratum water salinity (salinity) 20000ppm, injection salinity water 300ppm.
After the water drive of 0.5 times of pore volume, average oil saturation is 54%, and difference occurs for formation water salinity Change, scope is 2500ppm-18000ppm.Now waterflooding effect is deteriorated, and production fluid moisture content 86%, rate of oil production is 0.4%.
Certain oil displacement agent is chosen, in parts by weight, its raw material composition is:10 parts of fatty alcohol-ether sodium sulfate, polyethylene glycol are stearic 0.1 part of acid esters, 0.1 part of lauryl sodium sulfate, 0.05 part of the partially hydrolyzed polyacrylamide (PHPA) and water of 15,000,000 molecular weight 89.75 parts;The oil displacement agent through the following steps that prepare:According to above-mentioned weight ratio, 1500 are added in water very much Stirred 6 hours after the partially hydrolyzed polyacrylamide (PHPA) of amount, then sequentially add fatty alcohol-ether sodium sulfate, polyethylene glycol stearate Stirred 2 hours with after lauryl sodium sulfate, then stand 24 hours, obtain a clear transparent solutions, be described oil displacement agent. The viscosity of the oil displacement agent is with the characteristic value of salinity altercation curve:μ0=8mPas, μ1=310mPas, μ2=18mPas, M0=50ppm, M1=2400ppm, M2=1 × 106Ppm, while the lowest salinity value 2500ppm of stratum water is in the drive in oil reservoir The viscosity of finish is 280mPas with the viscosity of corresponding oil displacement agent in salinity altercation curve.Inject 0.2 times of hole of the oil displacement agent After volume, initial stage, production fluid moisture content was down to 33%, and rate of oil production rises to 1.5%, but latter stage effect is deteriorated, production fluid moisture content 65% is risen to, rate of oil production is down to 0.7%, and formation water salinity distribution is changed into 4000ppm-12000ppm, now ground in oil reservoir Layer water lowest salinity value 4000ppm in the viscosity of the oil displacement agent is with salinity altercation curve the viscosity of corresponding oil displacement agent be only 65mPas, desired 100mPas is chosen less than oil displacement agent, therefore should change oil displacement agent.
Again certain oil displacement agent is chosen, in parts by weight, its raw material composition is:0.1 part of fatty alcohol ether sodium sulfonate, nonyl phenol gather 5 parts of oxygen vinethene, 2 parts of dodecyl sodium sulfate, 0.1 part of the partially hydrolyzed polyacrylamide (PHPA) and water 92.8 of 18,000,000 molecular weight Part;The oil displacement agent through the following steps that prepare:According to above-mentioned weight ratio, the portion of 18,000,000 molecular weight is added in water Divide after hydrolyzed polyacrylamide and stir 8 hours, then sequentially add fatty alcohol ether sodium sulfonate, NPE and 12 Stirred 3 hours after sodium alkyl sulfonate, then stand 30 hours, obtain a clear transparent solutions, be described oil displacement agent.The displacement of reservoir oil The viscosity of agent is with the characteristic value of salinity altercation curve, μ0=10mPas, μ1=380mPas, μ2=19mPas, M0= 50ppm, M1=3800ppm, M2=1 × 106Ppm, while the lowest salinity value 4000ppm of stratum water is in the oil displacement agent in oil reservoir Viscosity with corresponding oil displacement agent in salinity altercation curve viscosity be 330mPas.Inject 0.2 times of pore volume of the oil displacement agent Afterwards, production fluid at initial stage moisture content is down to 39%, and rate of oil production rises to 1.3%, but latter stage effect is deteriorated, and production fluid moisture content rises to 71%, rate of oil production is down to 0.6%, and formation water salinity distribution is changed into 6000ppm-10000ppm, now stratum water in oil reservoir Lowest salinity value 6000ppm in the viscosity of the oil displacement agent is with salinity altercation curve the viscosity of corresponding oil displacement agent be only 77mPas, desired 100mPas is chosen less than oil displacement agent, therefore should change oil displacement agent.
Again certain oil displacement agent is chosen, in parts by weight, its raw material composition is:0.3 part of fatty alcohol ether benzene sulfonic acid potassium, dehydration mountain 97.8 parts of 0.4 part of pears alcohol laurate, 0.5 part of neopelex, 1 part of xanthans and water;The oil displacement agent is to pass through Prepared by following steps:According to above-mentioned weight ratio, add after xanthans and stir 4 hours in water, then sequentially add fat Stirred 1 hour after fat alcohol ether benzene sulfonic acid potassium, anhydrous sorbitol laurate and neopelex, then stand 18 hours, A clear transparent solutions are obtained, are described oil displacement agent.The viscosity of the oil displacement agent is with the characteristic value of salinity altercation curve, μ0 =12mPas, μ1=330mPas, μ2=22mPas, M0=50ppm, M1=5800ppm, M2=1 × 106Ppm, simultaneously The lowest salinity value 6000ppm of stratum water corresponding oil displacement agents in the viscosity of the oil displacement agent is with salinity altercation curve in oil reservoir Viscosity is 240mPas.Inject after 0.2 times of pore volume of the oil displacement agent, initial stage, production fluid moisture content was down to 46%, rate of oil production 1.1% is risen to, but latter stage effect is deteriorated, and production fluid moisture content rises to 77%, and rate of oil production is down to 0.6%, formation water salinity Distribution is changed into 8000ppm-9000ppm.
According to this oil production method, by above three-wheel regulating measures, accumulation injection 0.6 times of pore volume of oil displacement agent, it is contemplated that Improve waterflood recovery efficiency factor 21%.
In order to which to more solito oil production method, the present invention has carried out three groups of comparative simulation experiments, is passed through with this method identical After the water drive for crossing 0.5 times of pore volume, three kinds of displacement of reservoir oils that viscosity is 50mPas, 100mPas, 150mPas are injected separately into Agent, these three oil displacement agents are respectively concentration 200ppm, 250ppm and 300ppm 18,000,000 molecular weight partial hydrolysis polyacrylamides The aqueous solution of amine.Injection rate is respectively 0.6 times of pore volume.Simulated experiment result shows, the oil displacement agent of above-mentioned three kinds of viscosity, By the injection of 0.6 times of pore volume, waterflood recovery efficiency factor 11%, 8.3% and 7.9% is respectively increased.
As can be seen that the oil production method of the present invention can carry out match control to the oil displacement agent viscosity of oil reservoir different parts, Oil recovery is greatly improved compared to existing conventional oil production method.

Claims (10)

1. a kind of oil production method, this method comprises the following steps:
(1) oil displacement agent is selected to meet following three points requirement simultaneously for standard:
1) viscosity of oil displacement agent has single peak type feature with salinity altercation curve;
2) viscosity of oil displacement agent is more than or equal to stratum water in oil reservoir with the unimodal corresponding salinity range in salinity altercation curve Salinity range;
3) in oil reservoir the lowest salinity value of stratum water in the viscosity of oil displacement agent is with salinity altercation curve corresponding oil displacement agent it is viscous Spend for more than 100mPas;
(2) selected oil displacement agent is injected to oil reservoir by injection well, and crude oil is produced from producing well, to exploit the original in oil field Oil;
Preferably, the above method further comprises step (3):Recover the oil and the monitoring of production fluid salinity is kept in producing, such as find salt Degree has greatly changed, so that no longer meeting 3 points of requirements in step (1), then determines the distribution of formation water salinity again Scope, and filtered out with salinity altercation curve according to the viscosity of oil displacement agent the oil displacement agent of the 3 points of requirements met in step (1) with Current oil displacement agent is replaced, oil field is so repeated up to and scraps.
2. oil production method according to claim 1, wherein, selected oil displacement agent also meets claimed below:Oil displacement agent Viscosity is less than the minimum of the distribution of formation water salinity in oil reservoir with the corresponding salinity of peak value of salinity altercation curve.
3. oil production method according to claim 1, wherein, selected oil displacement agent is the mixture of a solvent and solute, The solvent is water, and the solute is single solute or multi-component Solute, and weight of the solute in the oil displacement agent Content is 0.1% to 50%.
4. oil production method according to claim 1, wherein, the viscosity of selected oil displacement agent with salinity altercation change model 1mPas is trapped among to 1 × 107mPa·s;Preferably, selected oil displacement agent is in an atmospheric pressure, 25 DEG C of temperature, salinity Range of viscosities under conditions of NaCl mass concentrations 200ppm is 1mPas to 500mPas.
5. oil production method according to claim 1, wherein, the viscosity of selected oil displacement agent is with salinity altercation curve Unimodal corresponding salinity range is 1 × 103Mg/L to 1 × 106mg/L。
6. oil production method according to claim 1 or 5, wherein, the viscosity of selected oil displacement agent is with salinity altercation curve With showing as single peak type feature:In the case where other conditions are constant, in salinity from 1 × 103Mg/L increases to 1 × 106During mg/L, the viscosity of oil displacement agent successively experienced to be uprised and by two variation tendencies of high step-down by low, the two Change is continuous, and scope is 1 × 103Mg/L to 1 × 106mg/L。
7. the oil production method according to any one of claim 1-6, wherein, in parts by weight, selected oil displacement agent Raw material composition includes:0.1-10 parts of host, 0.1-5 parts of agent of association, 0-2 parts of synergist, 0-1 parts of polymer and water 82-99.8 Part.
8. oil production method according to claim 7, wherein, the host is that formula is CnH2n+1O(CH2CH2O)yXM the moon In ionic surface active agent, formula, n is 1-38 integer, and y is 1-6 integer, and X is an electronegative acid group, and M is a positively charged Metal ion or ammonium root;Preferably, the electronegative acid group includes sulfate radical, sulfonate radical, inferior sulfate radical, phosphate radical or benzene Sulfonate radical, the metal ion of the positively charged includes potassium, sodium or lithium;
The association agent is nonionic surfactant;Preferably, the association agent is lived including polyoxyethylene-type non-ionic surface Property agent and/or polyol-based non-ionic surfactant;
The synergist is the anion surfactant insensitive to alkali and hard water;Preferably, the synergist includes 12 To sodium stearyl sulfate, 12 to sodium stearyl sulfonate and 12 one or more into octadecyl benzenesulfonic acid sodium Combination;
The polymer is water-soluble polymer;Preferably, the polymer is birdsed of the same feather flock together compound including partially hydrolyzed polyacrylamide (PHPA) Or xanthans is birdsed of the same feather flock together compound.
9. oil production method according to claim 1, wherein, the salinity range of stratum water is 1 × 10 in the oil reservoir3mg/L To 1 × 106mg/L。
10. oil production method according to claim 1, wherein, the oil field is the oil field for having undergone the waterflooding behavior stage;It is excellent Selection of land, the average oil saturation in the oil field is 20% to 80%, and Produced Liquid moisture content is 0 to 95%.
CN201710325487.4A 2017-05-10 2017-05-10 A kind of oil production method Active CN106968655B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710325487.4A CN106968655B (en) 2017-05-10 2017-05-10 A kind of oil production method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710325487.4A CN106968655B (en) 2017-05-10 2017-05-10 A kind of oil production method

Publications (2)

Publication Number Publication Date
CN106968655A true CN106968655A (en) 2017-07-21
CN106968655B CN106968655B (en) 2019-05-07

Family

ID=59332128

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710325487.4A Active CN106968655B (en) 2017-05-10 2017-05-10 A kind of oil production method

Country Status (1)

Country Link
CN (1) CN106968655B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107936938A (en) * 2017-12-05 2018-04-20 张晓静 A kind of negative pressure on ground DP technology and its device

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3841401A (en) * 1972-11-06 1974-10-15 Ici America Inc Process for recovering hydrocarbon using polymer obtained by radiation polymerization
CN1346012A (en) * 2000-09-30 2002-04-24 大庆石油学院 Visco-elastic low tension chemical oil displacement method for raising crude oil productivity
US20030015321A1 (en) * 2001-05-31 2003-01-23 Lim Git B. Cyclic solvent process for in-situ bitumen and heavy oil production
CN101885804A (en) * 2010-05-28 2010-11-17 中国海洋石油总公司 Method for preparing cationic polymer for increasing and/or stabilizing viscosity of hydrophobic association type polymer oil-displacing agent
CN102127411A (en) * 2010-12-17 2011-07-20 北京海恩润德化工科学技术有限公司 Viscosity adjustable crosslinked polymer displacement agent and preparation method thereof
CN103582688A (en) * 2011-03-16 2014-02-12 沙特阿拉伯石油公司 Oil recovery process for carbonate reservoirs
CN103842469A (en) * 2011-10-04 2014-06-04 沙特阿拉伯石油公司 Polymer-enhanced surfactant flooding for permeable carbonates
CN104099077A (en) * 2013-10-28 2014-10-15 中国石油化工股份有限公司 High mineralization oil reservoir composite oil displacement agent
CN104861950A (en) * 2015-05-19 2015-08-26 重庆科技学院 Supramolecular linear polyacrylamide oil displacement agent and preparation method thereof

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3841401A (en) * 1972-11-06 1974-10-15 Ici America Inc Process for recovering hydrocarbon using polymer obtained by radiation polymerization
CN1346012A (en) * 2000-09-30 2002-04-24 大庆石油学院 Visco-elastic low tension chemical oil displacement method for raising crude oil productivity
US20030015321A1 (en) * 2001-05-31 2003-01-23 Lim Git B. Cyclic solvent process for in-situ bitumen and heavy oil production
CN101885804A (en) * 2010-05-28 2010-11-17 中国海洋石油总公司 Method for preparing cationic polymer for increasing and/or stabilizing viscosity of hydrophobic association type polymer oil-displacing agent
CN102127411A (en) * 2010-12-17 2011-07-20 北京海恩润德化工科学技术有限公司 Viscosity adjustable crosslinked polymer displacement agent and preparation method thereof
CN103582688A (en) * 2011-03-16 2014-02-12 沙特阿拉伯石油公司 Oil recovery process for carbonate reservoirs
CN103842469A (en) * 2011-10-04 2014-06-04 沙特阿拉伯石油公司 Polymer-enhanced surfactant flooding for permeable carbonates
CN104099077A (en) * 2013-10-28 2014-10-15 中国石油化工股份有限公司 High mineralization oil reservoir composite oil displacement agent
CN104861950A (en) * 2015-05-19 2015-08-26 重庆科技学院 Supramolecular linear polyacrylamide oil displacement agent and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
金羽: ""驱油剂的研究进展"", <辽宁化工> *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107936938A (en) * 2017-12-05 2018-04-20 张晓静 A kind of negative pressure on ground DP technology and its device

Also Published As

Publication number Publication date
CN106968655B (en) 2019-05-07

Similar Documents

Publication Publication Date Title
Seright et al. Injectivity characteristics of EOR polymers
CA2863352C (en) Enhanced oil recovery process using low salinity water
Shi et al. Necessity and feasibility of improving the residual resistance factor of polymer flooding in heavy oil reservoirs
CN110905460B (en) Viscosity-reducing foaming exploitation method for common heavy oil reservoir
CN102816558A (en) Plugging agent for deep profile control and water plugging and preparation method thereof
GB2053325A (en) Microemulsions which compatibly incorporate viscosifiers and their use in enhanced oil recovery
Leonhardt et al. From flask to field–The long road to development of a new polymer
CN106968655B (en) A kind of oil production method
CN103773348A (en) Polymer-surfactant binary composite oil-displacing agent and oil-displacing method
RU2487234C1 (en) Method of development for wet oil strata with inhomogeneous permeability
RU2610961C1 (en) Justification method of input profile in injection well
RU2536070C1 (en) Development and oil recovery improvement method for inhomogeneous oil pools
CN107189773B (en) A kind of oil production method
US11492882B2 (en) Oil reservoir conformance improvement system and method
RU2451168C1 (en) Method for control of flooding area of oil formations
CN112980419B (en) Thick oil foaming agent and preparation method and application thereof
RU2748198C1 (en) Method for development of oil reservoir heterogeneous in permeability
RU2302519C2 (en) Method for watered non-uniform oil reservoir permeability treatment
RU2811129C1 (en) Composition for displacement of oil from formations and selective limitation of water inflow
RU2347896C1 (en) Oil field development method
RU2729667C1 (en) Control method of injectivity acceptance profile of injection well
RU2811097C1 (en) Method for increasing efficiency of enhanced oil recovery (eor) methods
RU2105871C1 (en) Method for development of oil deposit
US20230265749A1 (en) Methodology to improve the efficiency of gravity drainage co2 gas injection processes
SU1316568A3 (en) Method of regeneration of crude oil from underground oil formation

Legal Events

Date Code Title Description
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant