CN106957730B - A kind of Washine-machine chute detergent - Google Patents
A kind of Washine-machine chute detergent Download PDFInfo
- Publication number
- CN106957730B CN106957730B CN201710307884.9A CN201710307884A CN106957730B CN 106957730 B CN106957730 B CN 106957730B CN 201710307884 A CN201710307884 A CN 201710307884A CN 106957730 B CN106957730 B CN 106957730B
- Authority
- CN
- China
- Prior art keywords
- sodium
- washine
- corrosion
- chute detergent
- machine chute
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0073—Anticorrosion compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/14—Fillers; Abrasives ; Abrasive compositions; Suspending or absorbing agents not provided for in one single group of C11D3/12; Specific features concerning abrasives, e.g. granulometry or mixtures
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/32—Amides; Substituted amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38609—Protease or amylase in solid compositions only
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3937—Stabilising agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
Abstract
The invention discloses a kind of Washine-machine chute detergent; it, which includes sodium carbonate 50~60%, SODIUM PERCARBONATE 20~30%, tetraacetyl ethylene diamine 1~4%, binary complex enzyme 1~2%, α sodium olefin sulfonates 2~5%, calcium carbonate 4~8% and 6~9% Washine-machine chute detergent of the present invention of metal protecting agent, can effectively remove dirt in washing machine tank, while corrosion-free to washing machine；Effectively kill and suppress harmful levels of pathogens, avoid clothing secondary pollution.
Description
Technical field
The invention belongs to detergent technical field, and in particular to a kind of Washine-machine chute detergent.
Background technology
With the increasingly raising of people's living standard, washing machine is quite popularized in Modern Family.But in reality
In life, people often ignore the cleaning problems of washing machine itself, and washing machine can adhere to greatly after cleaning clothing for a long time in inside groove
The dirt of amount, these dirts are mainly by the depositions such as incrustation scale, clothes fiber, liquid detergent (powder) softener, the organic substance, thin of human body
Bacterium, mould microorganism etc. form.If these dirts cannot be cleared up timely, then these dirts when cleaning clothing, it is special
It is not that the microbes such as bacterium, mould pollute the clothing after cleaning, and attached clothing surface after cleaning with current again, makes
Into clothing secondary pollution；Simultaneously as the water of washing machine inside groove is not easy to empty, in the long-term moist accumulation dirt again of washing machine internal
In the environment of, bacterial micro-organism is easily grown, if wherein containing pathogenic bacteria, can be detrimental to health.
Washing machine tank cleaning way is common two kinds, is cleaned first, asking specialized maintenance worker to dismantle washing machine tank, this
Kind mode cost is higher also cumbersome；Another kind is cleaned using the Washine-machine chute detergent of the high degerming rate of specialty,
The degerming step of decontamination is completed, easy to operate effective.
At present, the Washine-machine chute detergent of commercial type has many kinds, all has the function of stain removal bactericidal, and these products
Substantially oxidative bleaching agent such as SODIUM PERCARBONATE, sodium perborate etc. are all contained, oxidative bleaching agent is sterilized using active oxygen, still, living
Property oxygen is strong oxidizer, has damage effect to many kinds of substance, corrodible metal makes metal rust staining occur, so as to damage laundry
Groove drum and metal parts of machine etc., influence the service life of washing machine.Also, the user of this kind of Washine-machine chute detergent
Formula be soaked after being dissolved in water at least 1 it is small when, it is first to use or when dirt is serious, also need to extend soaking time, therefore in this length
Under the immersion of time, corrosion of metal can be aggravated, so this kind of Washine-machine chute detergent is not appropriate for being used for multiple times for a long time.
And in order to protect washing machine internal metal not to be corroded, technical staff can add in right amount in Washine-machine chute detergent
Metal protecting agent, common metal protecting agent has anhydrous sodium metasilicate, metasilicate pentahydrate sodium, non-hydrate sodium metasilicate and sodium metasilicate
Deng, but the effect of this kind of inorganic inhibitor in practical applications is little, and metal in cleaning agent for washing machine tank is protected at present
The research for protecting agent is also less.Therefore, it is necessary to research and develop a kind of Washine-machine chute detergent, it can give full play to the work of oxidative bleaching agent
With, while have good protective effect to metal, it is adapted to be used for multiple times for a long time.
The content of the invention
It is an object of the invention to provide a kind of Washine-machine chute detergent, it can effectively kill bacteria antibacterial, can strongly remove and wash
Dirt on clothing trough, while to washing machine non-corrosiveness.
The present invention is a kind of Washine-machine chute detergent by the following technical programs to realize above-mentioned purpose, including following heavy
Measure the component of percentages：Sodium carbonate 50~60%, SODIUM PERCARBONATE 20~30%, tetraacetyl ethylene diamine 1~4%, binary are compound
Enzyme 1~2%, α-sodium olefin sulfonate 2~5%, calcium carbonate 4~8% and metal protecting agent 6~9%.
As currently preferred implementation, the Washine-machine chute detergent by following percentage by weight meter component group
Into：Sodium carbonate 55%, SODIUM PERCARBONATE 24%, tetraacetyl ethylene diamine 3%, binary complex enzyme 1%, α-sodium olefin sulfonate 3%, carbonic acid
Calcium 6% and metal protecting agent 8%.
Further, the metal protecting agent is chitosan oligosaccharide and the composition of calcium gluconate.
Further, the weight ratio of the chitosan oligosaccharide and calcium gluconate is (2~4):1.
Further, the binary complex enzyme is the compound of lipase and protease, the lipase and protease
Weight ratio is 1:2.
The preparation method of Washine-machine chute detergent of the present invention comprises the following steps：By sodium carbonate, SODIUM PERCARBONATE, four acetyl second
Diamines, binary complex enzyme, α-sodium olefin sulfonate, calcium carbonate and metal protecting agent mixing, stir evenly.
SODIUM PERCARBONATE of the present invention is coated SODIUM PERCARBONATE, and coated SODIUM PERCARBONATE can discharge after being dissolved in water
Hydrogen oxide, sodium carbonate, which can be used as decentralized medium as auxiliary agent and provide an alkaline environment, enables SODIUM PERCARBONATE faster
Hydrogen peroxide is discharged, the presence of bleach-activating tetraacetyl ethylene diamine can cause the peroxide bond in hydrogen peroxide molecule to occur to turn
Move, improve the ozone burst size of system.After Active oxygen release comes out so that dirt can be cutd open rapidly from washing machine interlayer
From getting off, calcium carbonate does not hinder surface as rubbing agent.The metal protecting agent can effectively prevent washing machine groove drum and metal portion
Part is corroded, and good protective action is played in metal surface.Binary complex enzyme single-minded can efficiently disintegrate fat and albumen
Dirt, α-sodium olefin sulfonate can preferably be sprawled on dirt and metal surface, soak, permeate, so as to strengthen going for product
Dirty and metal coating effect.Each component collaboration of the present invention, enhanced products sterilization, the effect of dispel dirt and metal coating.
Metal protecting agent of the present invention is chitosan oligosaccharide and the composition of calcium gluconate, and calcium gluconate is a kind of seawater
Corrosion inhibiter, it has carbon steel in Seawater preferable corrosion mitigating effect, paper《Chitosan analog derivative is situated between in 3.5%NaCl
Inhibition evaluation and mechanism study in matter》Corrosion mitigating effect after chitosan oligosaccharide and calcium gluconate compounding is studied, is found
Both does not act synergistically well, but the composition of chitosan oligosaccharide and calcium gluconate is applied to the present invention by inventor
In cleaning agent for washing machine tank, but it is surprised to find that it can play the role of good metal protection, inventor speculates after experiment, this
It is probably because surfactant α-sodium olefin sulfonate in cleaning agent for washing machine tank is compounded with chitosan oligosaccharide, gluconic acid radical ion
After cooperate with, effectively protect the metal from the corrosion of active oxygen.Specifically, chitosan oligosaccharide and calcium gluconate all easily with metal from
Son forms chelate, but absorption of the cover layer that is formed of chitosan oligosaccharide in metal surface is insecure, is hardly formed complete guarantor
Cuticula, easily produces local corrosion, and the film forming speed of calcium gluconate is slow, and needs higher concentration；α-sodium olefin sulfonate sheet
Body has no corrosion inhibition, but is potentially based on its molecular structure and property, can promote chitosan oligosaccharide, calcium gluconate well in metal
The absorption on surface, three mutually cooperate with, are complementary, the absorbent-type protective film of densification are formed, so as to effectively inhibit corrosion of metal.
Therefore, compared with prior art, advantage of the invention is that：
(1) Washine-machine chute detergent of the present invention has good antibacterial effect, to escherichia coli, staphylococcus aureus
Be up to 99%, and strong detergency with harmful bacteria killing rates such as Candida albicans, make dirt promptly cutd open from washing machine interlayer from,
Come off, play cleaning, bactericidal effect, effectively avoid the secondary pollution of clothing；
(2) Washine-machine chute detergent of the present invention can effectively prevent active oxygen and alkali to corrosions of metal such as stainless steels, to washing
The metal such as stainless steel has good protective action inside clothing machine, is adapted to be used for multiple times for a long time, and the longevity is used without influence washing machine
Life；In addition, Washine-machine chute detergent stable system of the present invention, ozone loss amount is few, can store for a long time, without " rise bag " risk.
Embodiment
The present invention is further described below by way of embodiment, but the present invention is not limited only to following embodiments.
In the scope of the present invention or do not departing from present disclosure, in spirit and scope, it is clear to washing machine tank of the present invention
Clean dose is suitably modified, replaces the identical component of effect, it will become apparent to those skilled in the art that they are all
It is deemed to be included within the scope of the present invention.
Embodiment 1, Washine-machine chute detergent of the present invention
Formula：Sodium carbonate 500g, SODIUM PERCARBONATE 300g, tetraacetyl ethylene diamine 40g, binary complex enzyme 20g (lipase and egg
The weight ratio of white enzyme is 1:2), α-sodium olefin sulfonate 30g, calcium carbonate 50g and metal protecting agent 60g (chitosan oligosaccharide and gluconic acid
The weight ratio of calcium is 2:1).
Prepare：By sodium carbonate, SODIUM PERCARBONATE, tetraacetyl ethylene diamine, binary complex enzyme, α-sodium olefin sulfonate, calcium carbonate and
Metal protecting agent mixes, and stirs evenly.
Embodiment 2, Washine-machine chute detergent of the present invention
Formula：Sodium carbonate 580g, SODIUM PERCARBONATE 200g, tetraacetyl ethylene diamine 20g, binary complex enzyme 10g (lipase and egg
The weight ratio of white enzyme is 1:2), α-sodium olefin sulfonate 40g, calcium carbonate 60g and metal protecting agent 90g (chitosan oligosaccharide and gluconic acid
The weight ratio of calcium is 4:1).
Prepare：By sodium carbonate, SODIUM PERCARBONATE, tetraacetyl ethylene diamine, binary complex enzyme, α-sodium olefin sulfonate, calcium carbonate and
Metal protecting agent mixes, and stirs evenly.
Embodiment 3, Washine-machine chute detergent of the present invention
Formula：Sodium carbonate 550g, SODIUM PERCARBONATE 240g, tetraacetyl ethylene diamine 30g, binary complex enzyme 10g (lipase and egg
The weight ratio of white enzyme is 1:2), α-sodium olefin sulfonate 30g, calcium carbonate 60g and metal protecting agent 80g (chitosan oligosaccharide and gluconic acid
The weight ratio of calcium is 3:1).
Prepare：By sodium carbonate, SODIUM PERCARBONATE, tetraacetyl ethylene diamine, binary complex enzyme, α-sodium olefin sulfonate, calcium carbonate and
Metal protecting agent mixes, and stirs evenly.
Embodiment 4, Washine-machine chute detergent of the present invention
Formula：Sodium carbonate 550g, SODIUM PERCARBONATE 240g, tetraacetyl ethylene diamine 30g, binary complex enzyme 10g (lipase and egg
The weight ratio of white enzyme is 1:2), α-sodium olefin sulfonate 50g, calcium carbonate 40g and metal protecting agent 80g (chitosan oligosaccharide and gluconic acid
The weight ratio of calcium is 3:1).
Prepare：By sodium carbonate, SODIUM PERCARBONATE, tetraacetyl ethylene diamine, binary complex enzyme, α-sodium olefin sulfonate, calcium carbonate and
Metal protecting agent mixes, and stirs evenly.
The corrosion inhibition test of test example one, Washine-machine chute detergent of the present invention
Weight-loss method tests corrosion inhibition rate：1) it is sodium carbonate 5.5g, SODIUM PERCARBONATE 2.4g, tetraacetyl ethylene diamine 0.3g, binary is multiple
(weight ratio of lipase and protease is 1 to synthase 0.1g:2) it is dissolved in calcium carbonate 0.6g in 400g water, is configured to corrosion mixing
Liquid.
2) stainless steel substrates of 5.0cm × 5.0cm × 0.2cm are polishing to mirror with 500,800,1200 mesh water-proof abrasive papers successively
Face is bright, acetone grease removal, after being precisely weighed, test piece suspension is immersed and is not added with being made with adding the above-mentioned of corrosion inhibiter A~J respectively
Corrosion mixed liquor in, constant temperature processing 72h, test piece weighs again, according to the front and rear weight difference of immersion, calculates corrosion inhibition rate v：In formula, M is the weight difference that test piece immersion is front and rear when being not added with corrosion inhibiter, and m is test piece when adding corrosion inhibiter
The front and rear weight difference of immersion.
The composition of each corrosion inhibiter is as follows：
Corrosion inhibiter A：(weight ratio of chitosan oligosaccharide and calcium gluconate is α-sodium olefin sulfonate 0.3g+ metal protecting agents 0.6g
2:1)
Corrosion inhibiter B：(weight ratio of chitosan oligosaccharide and calcium gluconate is α-sodium olefin sulfonate 0.4g+ metal protecting agents 0.9g
4:1)
Corrosion inhibiter C：(weight ratio of chitosan oligosaccharide and calcium gluconate is α-sodium olefin sulfonate 0.3g+ metal protecting agents 0.8g
3:1)
Corrosion inhibiter D：(weight ratio of chitosan oligosaccharide and calcium gluconate is α-sodium olefin sulfonate 0.5g+ metal protecting agents 0.8g
3:1)
Corrosion inhibiter E：α-sodium olefin sulfonate 0.3g+ chitosan oligosaccharides 0.8g
Corrosion inhibiter F：α-sodium olefin sulfonate 0.3g+ calcium gluconates 0.8g
Corrosion inhibiter G：(weight ratio of chitosan oligosaccharide and calcium gluconate is α-sodium olefin sulfonate 0.3g+ metal protecting agents 0.8g
1:1)
Corrosion inhibiter H：The neopelex 0.3g+ metal protecting agents 0.8g (weight of chitosan oligosaccharide and calcium gluconate
Than for 3:1)
Corrosion inhibiter I：α-sodium olefin sulfonate 1.1g
Corrosion inhibiter J：(weight ratio of chitosan oligosaccharide and calcium gluconate is 3 to metal protecting agent:1)1.1g
The corrosion inhibition result of the test such as table 1 below of each corrosion inhibiter：
The corrosion mitigating effect of 1 each corrosion inhibiter of table
| Corrosion inhibiter species | Corrosion inhibition rate |
| Corrosion inhibiter A | 92.4% |
| Corrosion inhibiter B | 91.6% |
| Corrosion inhibiter C | 98.3% |
| Corrosion inhibiter D | 92.7% |
| Corrosion inhibiter E | 22.5% |
| Corrosion inhibiter F | 30.8% |
| Corrosion inhibiter G | 76.4% |
| Corrosion inhibiter H | 34.3% |
| Corrosion inhibiter I | 1.6% |
| Corrosion inhibiter J | 31.4% |
From upper table 1：
1) corrosion inhibiter (corrosion inhibiter A~D) being made of α-sodium olefin sulfonate, chitosan oligosaccharide and calcium gluconate is to stainless steel substrates
Corrosion inhibition rate it is high, be all higher than 91%, illustrate that the combination can effectively prevent the corruption of active oxygen and alkali to stainless steel in alkaline system
Erosion, has stainless steel good protective action.
2) compared with corrosion inhibiter C, it is 1 that corrosion inhibiter G, which changes chitosan oligosaccharide and the weight ratio of calcium gluconate,:1, as a result it is slow
Erosion rate drops to 76.4%, illustrates the proportioning of chitosan oligosaccharide and calcium gluconate and can influence the corrosion mitigating effect of said composition.
3) compared with corrosion inhibiter C, corrosion inhibiter H replaces α-sodium olefin sulfonate, as a result its inhibition with neopelex
Rate drops to 34.3%, close with the corrosion mitigating effect of corrosion inhibiter J (chitosan oligosaccharide+calcium gluconate), illustrates dodecyl benzene sulfonic acid
Sodium can not with chitosan oligosaccharide, calcium gluconate rise synergistic effect, this also reflects at the same time α-sodium olefin sulfonate can with chitosan oligosaccharide and
Calcium gluconate plays synergistic effect, may be related with its molecular structure and property.
4) corrosion inhibiter I is α-sodium olefin sulfonate, its corrosion inhibition rate is only 1.6%, illustrates α-sodium olefin sulfonate to stainless steel simultaneously
There is no corrosion inhibition.
5) corrosion inhibition rate of corrosion inhibiter E (α-sodium olefin sulfonate+chitosan oligosaccharide) is 22.5%, corrosion inhibiter F (α-sodium olefin sulfonate+
Calcium gluconate) corrosion inhibition rate be 30.8%, and the corrosion inhibition rate of corrosion inhibiter J (chitosan oligosaccharide+calcium gluconate) be 31.4%, explanation
In alkaline system, synergistic corrosion inhibition is not played to corrosion of metal, the combination of chitosan oligosaccharide+calcium gluconate for active oxygen.
In addition, taking copper sheet and aluminium flake to carry out above-mentioned experiment, using corrosion inhibiter A~D, as a result corrosion inhibiter A~D is to copper sheet and aluminium
The corrosion inhibition rate of piece is all higher than 90%, shows to be compounded by a certain percentage by α-sodium olefin sulfonate, chitosan oligosaccharide and calcium gluconate and forms
Inhibitors On Copper and aluminium also have good corrosion inhibition.
The anti-microbial property test of test example two, Washine-machine chute detergent of the present invention
According to《Disinfection technology standard》The antibacterial effect of Washine-machine chute detergent prepared by the embodiment of the present invention 1~4 is measured,
Its result such as table 2 below.
The antibacterial effect of 2 Washine-machine chute detergent of the present invention of table
From upper table 2, Washine-machine chute detergent of the present invention reads escherichia coli, staphylococcus aureus and white
The killing rate of the harmful bacterias such as pearl bacterium reaches 99%, has very strong bactericidal effect.
The detergency detection of test example three, Washine-machine chute detergent of the present invention
According to GB/T 13174-2008《Dress material washes the measure of agent detergency and anti-stain redeposition ability by liquid》It is right
The detergency of the Washine-machine chute detergent of embodiment 1~4 is detected, testing result such as table 3 below.
The testing result of the Washine-machine chute detergent detergency of the present invention of table 3
From upper table 3, the strong detergency of the embodiment of the present invention 1~4, can strongly remove the dirt on washing machine tank.
The stability test of test example four, Washine-machine chute detergent of the present invention
According to GB/T 13176.3-1991《The measure (titration) of active o content in washing powder》To embodiment 1~4 into
Row test, as a result such as table 4 below.
The stability test of 4 Washine-machine chute detergent of the present invention of table
| Project | Ozone loss late (%) after 4 weeks at 45 DEG C |
| Embodiment 1 | 8 |
| Embodiment 2 | 10 |
| Embodiment 3 | 6 |
| Embodiment 4 | 9 |
From upper table 4, at 45 DEG C after 4 weeks, 1~4 ozone loss late of the embodiment of the present invention illustrates this within 10%
Invention Washine-machine chute detergent stable system, ozone loss amount is few, can store for a long time, without " rise bag " risk.
It the above is only the preferred embodiment of the present invention, it is noted that above-mentioned preferred embodiment is not construed as pair
The limitation of the present invention, protection scope of the present invention should be subject to claim limited range.For the art
For those of ordinary skill, without departing from the spirit and scope of the present invention, some improvements and modifications can also be made, these change
Protection scope of the present invention is also should be regarded as into retouching.
Claims (3)
1. a kind of Washine-machine chute detergent, it is characterised in that be made of the component of following percentage by weight meter：Sodium carbonate 50 ~
60%th, SODIUM PERCARBONATE 20 ~ 30%, tetraacetyl ethylene diamine 1 ~ 4%, binary complex enzyme 1 ~ 2%, α-sodium olefin sulfonate 2 ~ 5%, calcium carbonate 4 ~
8% and metal protecting agent 6 ~ 9%；
The metal protecting agent is the composition of chitosan oligosaccharide and calcium gluconate, the weight ratio of the chitosan oligosaccharide and calcium gluconate
For（2~4）:1；The binary complex enzyme is lipase and the compound of protease, and the weight ratio of the lipase and protease is
1:2。
2. Washine-machine chute detergent as claimed in claim 1, it is characterised in that the Washine-machine chute detergent is by following weight
The component composition of percentages：Sodium carbonate 55%, SODIUM PERCARBONATE 24%, tetraacetyl ethylene diamine 3%, binary complex enzyme 1%, α-alkenyl sulphur
Sour sodium 3%, calcium carbonate 6% and metal protecting agent 8%.
A kind of 3. method for preparing Washine-machine chute detergent as claimed in claim 1 or 2, it is characterised in that including following step
Suddenly：By sodium carbonate, SODIUM PERCARBONATE, tetraacetyl ethylene diamine, binary complex enzyme, α-sodium olefin sulfonate, calcium carbonate and metal protecting agent
Mixing, stirs evenly.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710307884.9A CN106957730B (en) | 2017-05-04 | 2017-05-04 | A kind of Washine-machine chute detergent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710307884.9A CN106957730B (en) | 2017-05-04 | 2017-05-04 | A kind of Washine-machine chute detergent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106957730A CN106957730A (en) | 2017-07-18 |
| CN106957730B true CN106957730B (en) | 2018-05-11 |
Family
ID=59481807
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710307884.9A Active CN106957730B (en) | 2017-05-04 | 2017-05-04 | A kind of Washine-machine chute detergent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106957730B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108048251B (en) * | 2018-01-04 | 2019-08-23 | 虞城能臣家居用品有限公司 | A kind of low damage, by force sterilizing, high-clean cleaning agent for washing machine tank |
| CN110684601A (en) * | 2018-07-05 | 2020-01-14 | 漳州甘净日用品有限公司 | Corrosion-free type washing machine tank decontamination sterilization effervescent tablet and preparation method thereof |
| CN109468178A (en) * | 2018-10-09 | 2019-03-15 | 王思淇 | A kind of Washine-machine chute detergent and preparation method thereof |
| CN115145236B (en) * | 2022-08-31 | 2022-11-25 | 南京狮尚生物科技有限公司 | Intelligent production control system and method for decontamination aerobic soaking powder composition |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104479908A (en) * | 2014-12-23 | 2015-04-01 | 青岛海芬海洋生物科技有限公司 | Teacup detergent |
| CN106148021A (en) * | 2016-06-30 | 2016-11-23 | 北京华景联化工制品有限责任公司 | A kind of high-effective cleansing, the environmental protection aerobic laundry powder composition of sterilization |
-
2017
- 2017-05-04 CN CN201710307884.9A patent/CN106957730B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104479908A (en) * | 2014-12-23 | 2015-04-01 | 青岛海芬海洋生物科技有限公司 | Teacup detergent |
| CN106148021A (en) * | 2016-06-30 | 2016-11-23 | 北京华景联化工制品有限责任公司 | A kind of high-effective cleansing, the environmental protection aerobic laundry powder composition of sterilization |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106957730A (en) | 2017-07-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106957730B (en) | A kind of Washine-machine chute detergent | |
| EP3399014B1 (en) | Development of an aluminum hydroxycarboxylate builder | |
| AU2012245234B2 (en) | Calcium sequestering composition | |
| CN103131542A (en) | Active oxygen washing machine tank cleaning agent and preparation method thereof | |
| ZA200706561B (en) | Anti-corrosion detergent compositions and use of same in cleaning dental and medical instruments | |
| CN104877765A (en) | Cleaning agent for washing machine slot | |
| ES2672303T3 (en) | Formulations, their use as a dishwashing agent and their production | |
| CN105062715B (en) | A kind of household automatic dishwasher purificant for having high degerming effect and excellent rinsing effect concurrently | |
| CN106590949A (en) | Clothes washing tank biological enzyme sterilization cleaning agent and preparing method thereof | |
| MX2013012288A (en) | Calcium sequestering composition. | |
| JP2016183242A (en) | Hard surface cleaner composition and hard surface cleaning method | |
| CN106675827A (en) | Washing machine tank cleaning agent and preparation method thereof | |
| EP0845525B1 (en) | Cleaning, disinfecting and bleaching composition | |
| JP6375129B2 (en) | How to wash dishes | |
| CN110684601A (en) | Corrosion-free type washing machine tank decontamination sterilization effervescent tablet and preparation method thereof | |
| US3968047A (en) | Detergent compositions | |
| JP2024026451A (en) | cleaning composition | |
| JP6700453B1 (en) | Hard surface cleaner composition and hard surface cleaning method | |
| JP2020012056A (en) | Hard surface detergent composition, sterilization method of microorganism or bacterial flora, method for preventing bacterial flora coagulation from generating in a washing machine, cleaning method of article having hard surface by washing machine and bactericidal agent | |
| JP2020012057A (en) | Hard surface detergent composition, sterilization method of microorganism or bacterial flora, method for preventing bacterial flora coagulation from generating in a washing machine, cleaning method of article having hard surface by washing machine and bactericidal agent | |
| CN114058450A (en) | Stable granular detergent composition and preparation method thereof | |
| CN107267296B (en) | Liquid washing machine tank cleaning agent | |
| RU2165961C2 (en) | Washing and disinfecting agent for treatment of milk equipment | |
| CN111269760B (en) | Detergent composition for endowing washed fabrics with long-acting antibacterial and odor inhibition effects and odor evaluation method | |
| CN107523428A (en) | Detergent composition and its application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |