CN106957686A - 催化直接鼓动气冷热法生产改性氯化石蜡‑70方法 - Google Patents

催化直接鼓动气冷热法生产改性氯化石蜡‑70方法 Download PDF

Info

Publication number
CN106957686A
CN106957686A CN201710242124.4A CN201710242124A CN106957686A CN 106957686 A CN106957686 A CN 106957686A CN 201710242124 A CN201710242124 A CN 201710242124A CN 106957686 A CN106957686 A CN 106957686A
Authority
CN
China
Prior art keywords
paraffin
chlorine
chlorinated paraffin
agitation device
heat
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201710242124.4A
Other languages
English (en)
Inventor
林群祥
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201710242124.4A priority Critical patent/CN106957686A/zh
Publication of CN106957686A publication Critical patent/CN106957686A/zh
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G73/00—Recovery or refining of mineral waxes, e.g. montan wax
    • C10G73/38—Chemical modification of petroleum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006—Controlling or regulating processes
    • B01J19/0013—Controlling the temperature of the process
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

本发明名称是催化直接鼓动气冷热法生产改性氯化石蜡‑70方法，属氯化石蜡技术领域，为了提高氯化石蜡‑70生产速度，基于对原87106851.6专利改进其采取的技术方案是石蜡中增加催化剂酮类过氧化物，氯源氯气经换热器直接放入鼓动器，循环部分与鼓动器之间串联换热器，把原料石蜡加热到一定温度(110℃左右)，然后按一定比例(5％左右)加入聚乙烯进行加热熔化，然后投入釜内氯化，并以热确保聚乙烯为熔化状，提供一种更快速的生产方法。

Description

催化直接鼓动气冷热法生产改性氯化石蜡-70方法
(一)技术领域：本发明涉及一种生产改性氯化石蜡-70的方法。
(二)背景技术：“强制循环鼓动法生产氯化石蜡装置”(原专利号：87106851.6)其技术方案是：将氯气送入反应釜空间，氯气和反应生成的氯化氢气体抽出，经喷射泵和贮液槽，被水吸收，余下氯气鼓压进鼓动器，如此连续快速反应。但用于生产氯化石蜡速度还不够理想，尤其是生产高氯化石蜡产品，到反应后期，速度趋缓。
(三)发明内容：本发明的任务是基于对原87106851.6发明专利的一种改进，提供一种更快的生产改性氯化石蜡-70的方法，采取的技术方案是加催化剂。由氯源供应的氯气经换热器直接通入鼓动器，对反应釜内物料进行鼓动。这样在强制循环鼓动下提高反应速度。在装置鼓动器与循环部分出口之间串联换热器，对进入鼓动器的反应气体先进行加热或者冷却后通入鼓动器，确保最佳反应温度，把原料石蜡加热到一定温度(110℃左右)，然后按一定比例(5％左右)加入聚乙烯进行加热熔化，然后投入釜内氯化，并以热确保聚乙烯为熔化状。
(四)具体实施方式：一套“强制循环鼓动法生产氯化石蜡装置”，使用500升反应釜，预先在石蜡中加入酮类过氧化物，浓度为0.01～6.00％。其氯源供应的氯气经换热器直接通入釜内鼓动器，用换热面2.5米2的换热器串联在鼓动器与循环部分出口之间，把原料石蜡加热到一定温度(110℃左右)，然后按一定比例(5％左右)加入聚乙烯进行加热熔化，然后投入釜内氯化，并以热确保聚乙烯为熔化状。
本发明操作与“强制循环鼓动法生产氯化石蜡装置”同，料温低，换热器加热，反之冷却。

Claims (1)

1.一种催化直接鼓动气冷热法生产改性氯化石蜡-70方法，包括把氯气和氯化氢气体抽出，氯化氢气体在喷射泵和贮液槽被水吸收，余下氯气鼓压进鼓动器，如此连续，其特征是：石蜡中加入浓度为0.01～6.00％酮类过氧化物催化。氯源供应的氯气经换热器直接通入鼓动器。鼓动器与循环部分出口之间串联换热器，对反应气体加热或冷却，把原料石蜡加热到一定温度(110℃左右)，然后按一定比例(5％左右)加入聚乙烯进行加热熔化，然后投入釜内氯化，并以热确保聚乙烯为熔化状。
CN201710242124.4A 2017-04-04 2017-04-04 催化直接鼓动气冷热法生产改性氯化石蜡‑70方法 Withdrawn CN106957686A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710242124.4A CN106957686A (zh) 2017-04-04 2017-04-04 催化直接鼓动气冷热法生产改性氯化石蜡‑70方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710242124.4A CN106957686A (zh) 2017-04-04 2017-04-04 催化直接鼓动气冷热法生产改性氯化石蜡‑70方法

Publications (1)

Publication Number Publication Date
CN106957686A true CN106957686A (zh) 2017-07-18

Family

ID=59483441

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710242124.4A Withdrawn CN106957686A (zh) 2017-04-04 2017-04-04 催化直接鼓动气冷热法生产改性氯化石蜡‑70方法

Country Status (1)

Country Link
CN (1) CN106957686A (zh)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1105372A (zh) * 1994-01-12 1995-07-19 林群祥 氯化聚乙烯石蜡
CN105885942A (zh) * 2016-05-08 2016-08-24 林群祥 催化直接鼓动气冷热法生产氯化石蜡-70方法

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1105372A (zh) * 1994-01-12 1995-07-19 林群祥 氯化聚乙烯石蜡
CN105885942A (zh) * 2016-05-08 2016-08-24 林群祥 催化直接鼓动气冷热法生产氯化石蜡-70方法

Similar Documents

Publication Publication Date Title
CN105838440A (zh) 催化加压光氯化直接鼓动气冷热法生产氯化石蜡-70方法
CN105925311A (zh) 催化加压直接鼓动气冷热法生产氯化石蜡-70方法
CN105885942A (zh) 催化直接鼓动气冷热法生产氯化石蜡-70方法
CN105838438A (zh) 催化加压鼓泡鼓动气冷热法生产氯化石蜡-70方法
CN105838434A (zh) 催化加压光氯化鼓泡鼓动气冷热法生产氯化石蜡-70方法
CN105838436A (zh) 催化鼓泡鼓动气冷热法生产氯化石蜡-70方法
CN105950216A (zh) 鼓泡鼓动气冷热法生产氯化石蜡-70方法
CN105838433A (zh) 加压直接鼓动气冷热法生产氯化石蜡-70方法
CN106010647A (zh) 催化鼓动气冷热法生产氯化石蜡-70方法
CN106995721A (zh) 催化加压直接鼓动气冷热法生产改性氯化石蜡‑70方法
CN105838439A (zh) 催化加压光氯化鼓动气冷热法生产氯化石蜡-70方法
CN105950215A (zh) 催化加压鼓动气冷热法生产氯化石蜡-70方法
CN106010645A (zh) 光氯化直接鼓动气冷热法生产氯化石蜡-70方法
CN106957686A (zh) 催化直接鼓动气冷热法生产改性氯化石蜡‑70方法
CN106010644A (zh) 直接鼓动气冷热法生产氯化石蜡-70方法
CN106010646A (zh) 光氯化鼓动气冷热法生产氯化石蜡-70方法
CN106987272A (zh) 加压光氯化鼓泡鼓动气冷热法生产改性氯化石蜡‑70方法
CN106978210A (zh) 催化鼓动气冷热法生产改性氯化石蜡‑70方法
CN107099332A (zh) 催化鼓泡鼓动气冷热法生产改性氯化石蜡‑70方法
CN106929102A (zh) 直接鼓动法生产改性氯化石蜡方法
CN107033957A (zh) 催化加压鼓动气冷热法生产改性氯化石蜡‑70方法
CN106947537A (zh) 催化加压鼓泡鼓动气冷热法生产改性氯化石蜡‑70方法
CN106947538A (zh) 催化加压光氯化鼓动气冷热法生产改性氯化石蜡‑70方法
CN106978211A (zh) 催化光氯化直接鼓动气冷热法生产改性氯化石蜡‑70方法
CN107057765A (zh) 直接鼓动气冷热法生产改性氯化石蜡‑70方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication

Application publication date: 20170718

WW01 Invention patent application withdrawn after publication