CN106955598A - The open runner network pipe type high pressure reverse osmosis membrane assembly of super-pressure - Google Patents
The open runner network pipe type high pressure reverse osmosis membrane assembly of super-pressure Download PDFInfo
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Abstract
Description
技术领域technical field
本发明涉及反渗透膜组件,用于水体中有机物和无机盐等杂质去除。可用于净水处理技术,高盐废水、高有机废水以及其余工业废水的高度浓缩工艺。尤其涉及一种开放式网管流道反渗透膜组件。The invention relates to a reverse osmosis membrane module, which is used for removing impurities such as organic matters and inorganic salts in water bodies. It can be used in water purification treatment technology, highly concentrated process of high-salt wastewater, high-organic wastewater and other industrial wastewater. In particular, it relates to an open network pipe channel reverse osmosis membrane module.
背景技术Background technique
近年来,膜技术发展迅速,在电力、冶金、石油石化、医药、食品、市政工程、污水回用及海水淡化等领域得到较为广泛的应用,各类工程对膜技术及其装备的需求量更是急速增加。目前在渗滤液和浓盐水零排放应用领域,网管式反渗透膜组件已得到广泛的应用。但是普通的网管式膜组件存在以下几个缺陷,本发明在现有网管式膜组件的基础之上做了相应的改进:In recent years, membrane technology has developed rapidly and has been widely used in fields such as electric power, metallurgy, petroleum and petrochemical, medicine, food, municipal engineering, sewage reuse, and seawater desalination. The demand for membrane technology and equipment in various projects is even higher. is a rapid increase. At present, in the field of zero discharge of leachate and concentrated brine, network-tube reverse osmosis membrane modules have been widely used. However, the common network-managed membrane module has the following defects, and the present invention makes corresponding improvements on the basis of the existing network-managed membrane module:
(1)传统的160公斤超高压网管式膜组件采用昂贵的316Ti不锈钢压力容器使得超高压网管式膜组件的推广受到限制。 此外传统的316Ti不锈钢压力容器在于污水接触时会出现生锈现象,进而缩短了超高压网管式膜组件的寿命。(1) The traditional 160 kg ultra-high pressure net-tube membrane module uses expensive 316Ti stainless steel pressure vessel, which limits the promotion of ultra-high pressure net-tube membrane module. In addition, the traditional 316Ti stainless steel pressure vessel will rust when exposed to sewage, which shortens the life of the ultra-high pressure network tube membrane module.
(2)传统的网管式膜组件采用梯状开放式流道,该开放式进水隔网分粗隔网和细隔网(图1),水流在工作时与细隔网成90°夹角进入流道中。通道中形成较大阻力的水流,因此进水中的悬浮颗粒物和有机物易附着在进水隔网中导致膜的污堵。此外,无机盐的浓缩在膜的表面由于浓差极化易形成结垢。进水隔网中较大的阻力会导致较大的压力损失,当压力损失高于1公斤时,由于抗应力盘与中心渗透液收集管较弱的粘结可导致抗应力盘沿着中心渗透液收集管滑动。抗应力盘的移动会导致膜元件环氧树脂胶外壳的破裂,最终会引发进水隔网和膜袋的损坏。此外,膜污堵和浓差极化会导致膜通量的下降,最终导致膜寿命的缩短。(2) The traditional network-tube membrane module adopts a ladder-shaped open flow channel. The open water inlet divider is divided into a coarse divider and a fine divider (Fig. 1). The water flow forms an angle of 90° with the fine divider during work. into the flow channel. The water flow with greater resistance is formed in the channel, so the suspended particles and organic matter in the feed water are easy to adhere to the feed water separator and cause the fouling of the membrane. In addition, the concentration of inorganic salts easily forms fouling on the surface of the membrane due to concentration polarization. Larger resistance in the inlet separator will lead to larger pressure loss. When the pressure loss is higher than 1 kg, the anti-stress disc will permeate along the center due to the weak bond between the anti-stress disc and the central permeate collection pipe. Liquid collection tube slide. The movement of the anti-stress disc will cause the rupture of the epoxy resin shell of the membrane element, which will eventually lead to the damage of the inlet screen and the membrane bag. In addition, membrane fouling and concentration polarization will lead to a decrease in membrane flux, which will eventually lead to a shortened membrane life.
(3)传统网管式膜组件的抗应力盘其中心环与外环间连接支撑片均采用直片式连接,支撑片与片之间形成扇形通道,进水时水流无法均匀混合,且不能随圆周膜面积的渐变而适量分配,故进水无法均匀分配至不同圆周向的进水通道内,易导致部分膜通道堵塞。此外传统网管式膜组件的抗应力盘其中心环的内壁没有安全锁定机制,因此容易导致抗应力盘沿着中心渗透液收集管滑动,最终会导进水隔网和膜袋的损坏。(3) The support plate connecting the center ring and the outer ring of the traditional network-tube membrane module’s anti-stress plate adopts a straight piece connection, and a fan-shaped channel is formed between the support plate and the plate. Due to the gradual change of the circumferential membrane area and appropriate distribution, the feed water cannot be evenly distributed to the feed water channels in different circumferential directions, which may easily lead to blockage of some membrane channels. In addition, the inner wall of the center ring of the anti-stress plate of the traditional network-tube membrane module has no safety locking mechanism, so it is easy to cause the anti-stress plate to slide along the central permeate collection pipe, and eventually lead to the damage of the water separator and the membrane bag.
(4)传统导流盘进水口由于缺乏弧度,水流从直孔进入,导致进水不能均匀分布于膜元件的进水通道,因此,易导致部分膜通道堵塞。中心导流管上的密封圈通过抱紧密封中心导流管的方式进行密封。这种密封方式易导致漏水现象,进而恶化产水水质。长期的漏水会导致不锈钢中心拉杆腐蚀。(4) Due to the lack of radian at the water inlet of the traditional deflector, the water flow enters from the straight hole, so the water cannot be evenly distributed in the water inlet channel of the membrane element, so it is easy to cause some membrane channels to be blocked. The sealing ring on the center draft tube is sealed by hugging and sealing the center draft tube. This sealing method can easily lead to water leakage, which in turn deteriorates the quality of the produced water. Long-term water leakage can cause corrosion of the stainless steel center tie rod.
发明内容Contents of the invention
本发明所要解决的技术问题是,针对现有螺旋式、卷式反渗透膜元件的进水流道不畅、耐污堵能力差、易造成浓差极化,以及碟管式反渗透膜组件的膜面积小、检修繁琐、投资成本高、进水分布不均、以及耐高压能力差等缺点。提供一种超高压开放式流道网管式反渗透膜组件。The technical problem to be solved by the present invention is to solve the problems of the existing spiral and coiled reverse osmosis membrane elements with poor water inlet channels, poor resistance to fouling and clogging, easy to cause concentration polarization, and disc tube type reverse osmosis membrane components. The disadvantages are small membrane area, cumbersome maintenance, high investment cost, uneven water distribution, and poor high pressure resistance. Provided is an ultra-high pressure open channel network pipe reverse osmosis membrane module.
具体技术方案为:一种超高压开放式流道网管式高压反渗透膜组件,包括膜壳(2)、设置在膜壳内的中心产水管(17)、中心拉杆(18)、单只膜元件(1),所述膜壳为玻璃纤维压力容器,膜壳(2)进水的一端设置有原水接头(7),出水的一端设置有浓水接头(8),膜壳(2)进水口一端设置有进水法兰端盖(3),进水法兰端盖(3)内侧再设置有进水旋流式导流盘(5)和抗应力盘(10),所述进水法兰端盖(3)、进水旋流式导流盘(5)、抗应力盘(10)三者分别与膜壳(2)之间设置密封圈;所述原水接头(7)穿过所述进水法兰端盖(3)与进水旋流式导流盘(5)的输水孔对接,该输水孔靠近导流盘的盘边缘呈切向进水,并且所述输水孔为弧形孔以产生旋流式布水,所述原水接头(7)与进水旋流式导流盘(5)之间设置有密封圈。The specific technical solution is: an ultra-high pressure open flow channel network-managed high-pressure reverse osmosis membrane module, including a membrane shell (2), a central water production pipe (17) arranged in the membrane shell, a central tie rod (18), a single membrane The element (1), the membrane shell is a glass fiber pressure vessel, the water inlet end of the membrane shell (2) is provided with a raw water joint (7), the water outlet end is provided with a concentrated water joint (8), and the membrane shell (2) enters One end of the water inlet is provided with a water inlet flange end cover (3), and the inner side of the water inlet flange end cover (3) is further provided with a water inlet swirling flow guide plate (5) and an anti-stress plate (10). Sealing rings are set between the flange end cover (3), the water inlet swirling diversion plate (5), and the stress-resisting plate (10) respectively, and the membrane shell (2); the raw water joint (7) passes through The water inlet flange end cover (3) is docked with the water delivery hole of the water inlet swirling flow guide plate (5), and the water delivery hole is close to the edge of the guide plate to form a tangential water inlet, and the delivery The water hole is an arc-shaped hole to generate swirling water distribution, and a sealing ring is arranged between the raw water joint (7) and the water inlet swirling diversion plate (5).
所述膜壳出水的一端设置有出水法兰端盖(4),出水法兰端盖(4)内侧再设置有出水旋流式导流盘(6)、抗应力盘(10),所述出水法兰端盖(4)、出水旋流式导流盘(6)、抗应力盘(10)三者分别与膜壳(2)之间设置密封圈,所述浓水接头(8)穿过所述出水法兰端盖(4)与出水旋流式导流盘(6)的输水孔对接,所述浓水接头(8)与出水旋流式导流盘(6)之间设置有密封圈;抗应力盘(10)与进、出水旋流式导流盘间构成均匀旋流式布水方式。One end of the water outlet of the membrane shell is provided with a water outlet flange end cover (4), and the inner side of the water outlet flange end cover (4) is provided with a water outlet swirling flow guide plate (6) and an anti-stress plate (10). Sealing rings are provided between the water outlet flange end cover (4), the water outlet swirling diversion plate (6), and the anti-stress plate (10) respectively, and the membrane shell (2), and the concentrated water joint (8) wears The water outlet flange end cover (4) is docked with the water delivery hole of the outlet swirl flow guide plate (6), and the concentrated water joint (8) is arranged between the outlet water swirl flow guide plate (6). There is a sealing ring; the anti-stress disc (10) forms a uniform swirl water distribution mode with the inlet and outlet water swirl flow guide discs.
所述中心产水管(17)的两端分别与进、出水旋流式导流盘(6)内侧面上开设的台阶顶紧,中心拉杆(18)穿设在中心产水管(17)内腔,且中心拉杆两端均露出于膜壳之外,中心拉杆(18)与中心产水管(17)之间保留流通间隙,且中心拉杆(18)的一端与中心产水管(17)之间密封,另一端设置与流通间隙导通的透过液接头(9),透过液接头(9)与中心拉杆(18)之间设置产水密封圈(15)。The two ends of the central water production pipe (17) are respectively pressed against the steps set on the inner side of the water inlet and outlet swirling flow guide plate (6), and the central tie rod (18) is installed in the inner cavity of the central water production pipe (17). , and both ends of the center tie rod are exposed outside the membrane shell, there is a flow gap between the center tie rod (18) and the center water production pipe (17), and one end of the center tie rod (18) is sealed with the center water production pipe (17) , the other end is provided with a permeate joint (9) connected to the flow gap, and a permeate seal ring (15) is provided between the permeate joint (9) and the center tie rod (18).
膜壳(2)的两端设置端头固定盘(11),所述端头固定盘(11)与进、出水法兰端盖顶紧(3、4),所述端头固定盘(11)的内侧面上开设有固定槽,膜壳(2)的两端被固定在所述固定槽内;端头固定盘(11)的盘边缘超出膜壳之外,两端头固定盘(11)之间设置有外围拉杆。The two ends of the membrane shell (2) are provided with terminal fixing plates (11), and the terminal fixing plates (11) are tightly connected to the inlet and outlet flange end covers (3, 4), and the terminal fixing plates (11) ) is provided with a fixing groove on the inner surface, and the two ends of the membrane shell (2) are fixed in the fixing groove; ) are provided with peripheral tie rods.
单只膜元件设置在前后两抗应力盘之间,中心产水管(17)上开设有数列小孔,经膜元件过滤后的渗透液从数列小孔汇入中心产水管。A single membrane element is arranged between the front and rear stress-resisting plates, and the central water production pipe (17) is provided with a series of small holes, and the permeate filtered by the membrane element flows into the central water production pipe through the series of small holes.
进一步地,抗应力盘采用水力学设计,中心与圆周连接的支撑片为弧形,呈辐射状支撑,此类设计可有效使进水均匀分布到盘面。盘面上采用从中心向四周环形开孔,孔径由内向外逐渐变大。因为膜元件呈卷式结构,中心向外每一周的膜面积在慢慢扩大(即中心圆周膜面积最小,最外圈圆周膜面积最大),故此设计可使不同部位膜面上承受的进水量趋近一致,使膜元件处于最佳使用性能,并能将进水应力的传递与分散。)Furthermore, the anti-stress plate adopts a hydraulic design, and the support piece connecting the center and the circumference is arc-shaped and radially supported. This type of design can effectively distribute the water inflow to the plate surface evenly. The surface of the disk adopts ring-shaped openings from the center to the surroundings, and the diameter of the holes gradually increases from the inside to the outside. Because the membrane element is a roll structure, the membrane area is gradually expanding every week from the center (that is, the membrane area of the center circle is the smallest, and the membrane area of the outermost circle is the largest), so the design can make the water intake of different parts of the membrane surface Approximate to the same, so that the membrane element is in the best performance, and can transmit and disperse the stress of the inlet water. )
进一步地,进、出水旋流式导流盘的所述台阶内设置中心产水管密封圈。Further, a sealing ring of the central water production pipe is arranged in the step of the water inlet and outlet swirl flow guide plate.
进一步地,端头固定盘采用端头固定盘螺丝固定,外围拉杆通过固定螺母固定在端头固定盘上。Further, the terminal fixing plate is fixed with terminal fixing plate screws, and the peripheral pull rods are fixed on the terminal fixing plate through fixing nuts.
优选地,所述膜元件具有开放式网管流道。具体膜元件包括包覆在中心产水管外周的分离层,所述分离层是由若干膜袋和开放式隔网以同一方向卷制而成的膜袋层,所述开放式隔网设置在相邻膜袋层表面间的进水流道中,且开放式隔网与膜袋表面为凸点式的接触方式,连接凸点的为菱形细隔网,在与膜袋接触表面的两列凸点状隔网间沿进出水方向形成一条条菱形宽敞的开放式流道;所述膜袋和开放式隔网的内侧边与中心产水管相连接固定,呈中心向周围发射状排列,然后膜袋及开放式隔网一起朝同一方向旋紧以构成所述的膜袋层,在卷好的膜袋层外周用玻璃纤维及环氧树脂胶进行缠绕包裹密封,两端再安装所述抗应力盘。Preferably, the membrane element has an open mesh channel. The specific membrane element includes a separation layer coated on the outer periphery of the central water production pipe. The separation layer is a membrane bag layer rolled in the same direction by several membrane bags and open spacers. In the water inlet flow channel between the surface of the adjacent film bag layer, and the contact mode between the open partition and the surface of the film bag is a bump type, and the connection of the bump is a diamond-shaped fine partition, and the two rows of bumps on the contact surface with the film bag A diamond-shaped spacious open flow channel is formed between the screens along the direction of water inlet and outlet; the inner sides of the membrane bags and the open screens are connected and fixed with the central water production pipe, arranged radially from the center to the surroundings, and then the membrane bags and the open spacer are screwed together in the same direction to form the film bag layer, and the outer periphery of the rolled film bag layer is wrapped and sealed with glass fiber and epoxy resin glue, and the stress-resisting discs are installed at both ends .
优选地,所述膜袋由两片膜片正面相背粘接而成,在两片膜片间的产水流道中设置有纯水导流网,过滤得到的渗透液经纯水导流网流出。Preferably, the membrane bag is formed by bonding two membranes with their front faces facing each other, and a pure water diversion net is set in the water production channel between the two membranes, and the filtered permeate flows out through the pure water diversion net .
本发明的抗应力盘与进、出水旋流式导流盘两种结构的配合形成均匀旋流式布水方式。The anti-stress plate of the present invention cooperates with the two structures of the inflow and outflow swirl flow diversion plate to form a uniform swirl water distribution mode.
与现有技术相比,本发明的优点在于:Compared with the prior art, the present invention has the advantages of:
(1)采用菱形开放式隔网,在膜袋表面间的进水流道中设置开放式隔网,开放式隔网根据流体特性与膜片承压要求,与膜袋表面接触的仅为凸起状颗粒隔网,在起支撑作用的同时减少了与膜表面的接触。连接凸起状颗粒的为菱形细隔网,在与膜袋接触表面的两列凸起颗粒状隔网间沿进出水方向形成一条条菱形宽敞的开放式流道,水流在工作时与菱形细隔网成45°角进入流道中。通道中形成极小阻力的水流,膜表面流速较快,从进水中带入的悬浮物杂质,及被截留下的无机盐、有机物不易被阻挡,随着浓水的水流排出膜元件,从而有效避免了被截留的污染物附着于进水通道和膜的表面导致膜的污堵和浓差极化而结垢,进一步避免膜通量的下降,延长膜寿。此外单支膜压力损降低可以避免抗应力盘沿着中心渗透液收集管滑动,进而避免了膜元件环氧树脂胶的破裂和进水隔网和膜袋的损坏。(1) A diamond-shaped open partition is used, and an open partition is set in the water inlet channel between the surfaces of the membrane bag. According to the fluid characteristics and the pressure requirements of the diaphragm, the open partition is only in contact with the surface of the membrane bag. Particle separator, which reduces the contact with the surface of the membrane while playing a supporting role. The rhombus-shaped fine partitions are connected to the raised particles. Between the two rows of raised granular partitions on the contact surface with the film bag, there are rhombus-shaped spacious open flow channels along the direction of water in and out. The mesh enters the flow channel at an angle of 45°. A water flow with minimal resistance is formed in the channel, and the flow velocity on the membrane surface is fast. The suspended impurities brought in from the feed water, as well as the intercepted inorganic salts and organic matter are not easy to be blocked, and are discharged from the membrane element with the flow of concentrated water, thus It effectively prevents the trapped pollutants from adhering to the water inlet channel and the surface of the membrane, resulting in fouling of the membrane and scaling due to concentration polarization, further avoiding the decrease of membrane flux and prolonging the life of the membrane. In addition, the reduced pressure loss of a single membrane can prevent the anti-stress disk from sliding along the central permeate collection pipe, thereby avoiding the rupture of the epoxy resin glue of the membrane element and the damage of the water inlet screen and the membrane bag.
(2)将单只开放式网管流道反渗透膜元件置于一个压力膜壳中,可以减少膜组件的压力损失。采用不锈钢中心拉杆,有助于操作压力的提高。(2) Placing a single reverse osmosis membrane element with an open network pipe flow channel in a pressure membrane shell can reduce the pressure loss of the membrane module. The use of stainless steel center tie rod helps to improve the operating pressure.
(3)抗应力盘采用水力学设计,中心与圆周连接的支撑片采用弧形设计,此类设计可有效使进水均匀分布至盘面。盘面上采用从中心向四周环形开孔,孔径由小到大。新开发的抗应力盘采用安全锁定机制消除了抗应力盘沿着中心产水管滑动的问题,因为膜元件成卷式结构,从中心向外每一周的膜面积在慢慢扩大(即中心圆周膜面积最小,最外圈圆周膜面积最大),故此设计可使不同部位膜面上承受的进水量趋近一致,使膜元件处于最佳使用性能,可满足90bar作业。(3) The anti-stress plate adopts a hydraulic design, and the support piece connecting the center and the circumference adopts an arc design, which can effectively distribute the water evenly to the plate surface. The surface of the disk adopts ring-shaped openings from the center to the surroundings, and the diameter of the holes increases from small to large. The newly developed anti-stress disc adopts a safety locking mechanism to eliminate the problem of the anti-stress disc sliding along the central water production pipe, because the membrane element is in a roll structure, and the membrane area is slowly expanding from the center to the outside every week (that is, the central circumferential membrane The area is the smallest, and the membrane area of the outermost circle is the largest), so the design can make the water inflow on different parts of the membrane surface close to the same, so that the membrane element is in the best performance and can meet the 90bar operation.
(4)原水由膜元件一个端面进,在进水端设置一个旋流式进水导流盘,水流在导流盘上通过带有弧度的口子,呈切向运动均匀进入到膜的一个端面,在膜表面形成错流过滤,且导流盘中心孔与中心产水管密封改变常规的抱箍式密封,通过缩小中心孔及缩短台阶,直接将密封圈置于台阶上,将中心产水管端面直接与密封圈压紧密封。过滤后的浓水由另一个端面排出,过滤后的净水由渗透水接头导出。此举可有效解决普通圆孔型直接进水布水不均的缺陷,以及以往抱箍式密封方式的密封不可靠的缺点。进一步的,在进水端设置原水接头,出水端设置浓水接头,纯水接头位于膜组件的底部。(4) Raw water enters from one end face of the membrane element, and a swirling water inlet diversion plate is set at the water inlet end, and the water flows on the diversion plate through the opening with a radian, and enters one end face of the membrane evenly in a tangential movement , forming cross-flow filtration on the surface of the membrane, and the seal between the center hole of the diversion plate and the central water production pipe is changed from the conventional hoop seal. Directly press and seal with the sealing ring. The filtered concentrated water is discharged from the other end, and the filtered clean water is led out from the permeate water joint. This can effectively solve the defects of uneven water distribution of ordinary round hole direct water inlet and the unreliable sealing of the previous hoop-type sealing method. Further, a raw water connector is provided at the water inlet, a concentrated water connector is provided at the water outlet, and a pure water connector is located at the bottom of the membrane module.
(5)通过设置端头固定盘,通过端头固定盘在膜组件外围安装四根外围拉杆将膜元件安全有效地固定在玻璃纤维压力容器(玻璃纤维材料的膜壳)里。端头固定盘的内侧设置有固定槽,压力容器的两端被固定于两个端头固定盘的固定槽里,显著提高了膜组件的承压能力。由于使用玻璃纤维压力容器,膜组件的费用大大降低。此外玻璃纤维压力容器在与污水接触时不会出现生锈现象,进而延长了超高压网管式膜组件的寿命。本发明有利于160公斤级超高压网管式膜组件在高含盐废水领域的推广。(5) By setting the end fixing plate, four peripheral pull rods are installed on the periphery of the membrane module through the end fixing plate to securely and effectively fix the membrane element in the glass fiber pressure vessel (membrane shell made of glass fiber material). The inner side of the end fixing plate is provided with fixing grooves, and the two ends of the pressure vessel are fixed in the fixing grooves of the two end fixing plates, which significantly improves the pressure bearing capacity of the membrane module. Due to the use of glass fiber pressure vessels, the cost of membrane modules is greatly reduced. In addition, the glass fiber pressure vessel will not rust when in contact with sewage, thereby prolonging the life of the ultra-high pressure network tube membrane module. The invention is beneficial to the popularization of the 160-kilogram ultra-high pressure network-managed membrane module in the field of high-salt waste water.
本发明的反渗透膜元组件可同时兼顾耐污耐堵,(SDI≦20)、压力损失小、水流分布均匀、膜的有效面积更大、回收率和膜通量获得显著的提高、能够满足160公斤级超高压操作等优点。此外本申请的结构简单,便于维护保养、使用寿命更长。The reverse osmosis membrane element assembly of the present invention can simultaneously take into account pollution resistance and blockage resistance (SDI≦20), small pressure loss, uniform water flow distribution, larger effective area of the membrane, significantly improved recovery rate and membrane flux, and can meet 160kg ultra-high pressure operation and other advantages. In addition, the utility model has a simple structure, is convenient for maintenance and has a longer service life.
附图说明Description of drawings
图1为传统梯状开放式流道进水隔网;Figure 1 is a traditional ladder-shaped open channel water inlet screen;
图2为传统膜元件抗应力盘的结构示意图;Figure 2 is a structural schematic diagram of a traditional membrane element anti-stress disk;
图3为传统导流盘示意图;Fig. 3 is a schematic diagram of a traditional deflector;
图4为传统导流盘示意图;Fig. 4 is a schematic diagram of a traditional deflector;
图5为本发明实施例中菱形开放式流道进水隔网示意图;Fig. 5 is a schematic diagram of a rhombus-shaped open channel water inlet partition in an embodiment of the present invention;
图6为本发明实施例中开放式网管流道反渗透膜组件的剖视图;Fig. 6 is a cross-sectional view of the reverse osmosis membrane module of the open network pipe channel in the embodiment of the present invention;
图7为本发明实施例中旋流式导流盘的结构示意图;Fig. 7 is a schematic structural diagram of a swirling flow deflector in an embodiment of the present invention;
图8为本发明实施例中旋流式导流盘的正面示意图;Fig. 8 is a schematic front view of a swirling flow deflector in an embodiment of the present invention;
图9为本发明实施例中抗应力盘的结构示意图。Fig. 9 is a schematic diagram of the structure of the anti-stress disk in the embodiment of the present invention.
具体实施方式detailed description
以下结合附图实施例对本发明作进一步详细描述。The present invention will be further described in detail below in conjunction with the accompanying drawings and embodiments.
如图5至9所示,本实施例中的超高压开放式流道网管式高压反渗透膜组件,包括膜壳2(玻璃纤维压力容器)、设置在膜壳内的中心产水管17、中心拉杆18、单只膜元件1,膜壳2进水的一端设置有原水接头7,出水的一端设置有浓水接头8,膜壳进水口一端设置有进水法兰端盖3,进水法兰端盖3内侧再设置有进水旋流式导流盘5和抗应力盘10,进水法兰端盖3、进水旋流式导流盘5、抗应力盘10三者分别与膜壳2之间对应设置端盖密封圈12、导流盘密封圈13。原水接头7穿过进水法兰端盖3与进水旋流式导流盘5的输水孔对接,该输水孔靠近导流盘的盘边缘呈切向进水,并且所述输水孔为弧形孔以产生旋流式布水。原水接头7与进水旋流式导流盘5之间设置有产水密封圈15。As shown in Figures 5 to 9, the ultra-high pressure open flow channel network-managed high-pressure reverse osmosis membrane module in this embodiment includes a membrane shell 2 (glass fiber pressure vessel), a central water production pipe 17 arranged in the membrane shell, a central Tie rod 18, a single membrane element 1, a raw water connector 7 at the inlet end of the membrane shell 2, a concentrated water connector 8 at the outlet end, and a water inlet flange end cover 3 at the water inlet end of the membrane shell. The inner side of the flange end cover 3 is further provided with a water inlet swirl flow guide plate 5 and an anti-stress plate 10, and the water inlet flange end cover 3, the water inlet swirl flow guide plate 5, and the anti-stress plate 10 are respectively connected with the membrane The end cover sealing ring 12 and the deflector disk sealing ring 13 are arranged correspondingly between the shells 2 . The raw water joint 7 passes through the water inlet flange end cover 3 and docks with the water delivery hole of the water inlet swirling flow diversion plate 5, and the water delivery hole is close to the edge of the diversion plate in a tangential water inlet, and the water delivery The holes are curved holes to produce swirl water distribution. A water production sealing ring 15 is arranged between the raw water connector 7 and the water inlet swirling flow deflector plate 5 .
膜壳出水的一端设置有出水法兰端盖4,出水法兰端盖4内侧再设置有出水旋流式导流盘6、抗应力盘10,出水法兰端盖4、出水旋流式导流盘6、抗应力盘10三者分别与膜壳2之间设置密封圈,浓水接头8穿过出水法兰端盖4与出水旋流式导流盘6的输水孔对接,所述浓水接头8与出水旋流式导流盘6之间设置有密封圈。One end of the water outlet of the membrane shell is provided with a water outlet flange end cover 4, and the inner side of the water outlet flange end cover 4 is provided with a water outlet swirl flow guide plate 6, an anti-stress plate 10, a water outlet flange end cover 4, and a water outlet swirl flow guide plate. A sealing ring is provided between the flow plate 6 and the anti-stress plate 10 and the membrane shell 2 respectively, and the concentrated water joint 8 passes through the water outlet flange end cover 4 and is docked with the water delivery hole of the water outlet swirling flow guide plate 6. A sealing ring is provided between the concentrated water joint 8 and the water outlet swirl flow deflector plate 6 .
膜壳2的两端设置端头固定盘11,端头固定盘11与进、出水法兰端盖3、4顶紧,端头固定盘11的内侧面上开设有16毫米的固定槽,膜壳2的两端被固定在固定槽内。端头固定盘11采用端头固定盘螺丝20固定。端头固定盘11的盘边缘超出膜壳之外,两端头固定盘11之间设置有四根外围拉杆21,外围拉杆21通过固定螺母22固定在端头固定盘11上。The two ends of the membrane shell 2 are provided with a terminal fixing plate 11, which is tightly connected to the inlet and outlet flange end covers 3 and 4, and a 16mm fixing groove is provided on the inner side of the terminal fixing plate 11, and the membrane Both ends of the shell 2 are fixed in the fixing groove. The terminal fixing disc 11 is fixed by the terminal fixing disc screw 20 . The edge of the terminal fixed disk 11 is beyond the membrane shell, and four peripheral pull rods 21 are arranged between the two fixed disks 11 , and the peripheral pull rods 21 are fixed on the terminal fixed disk 11 by fixing nuts 22 .
中心产水管17的两端分别与进、出水旋流式导流盘5、6内侧面上开设的台阶顶紧,进、出水旋流式导流盘5、6的台阶内设置中心产水管密封圈16。中心拉杆18穿设在中心产水管17内腔,且中心拉杆18两端均露出于膜壳2之外,中心拉杆18的两端设置中心拉杆固定螺母19。中心拉杆18与中心产水管17之间保留流通间隙,且中心拉杆18的一端与中心产水管17之间通过密封圈密封,另一端设置与流通间隙导通的透过液接头9,中心产水管中汇集的渗透水经由透过液接头9导出。The two ends of the central water production pipe 17 are tightly pressed against the steps provided on the inner sides of the water inlet and outlet swirl flow diversion plates 5 and 6 respectively, and the central water production pipes are sealed in the steps of the inlet and outlet water swirl flow diversion disks 5 and 6. Circle 16. The central tie rod 18 is installed in the inner cavity of the central water production pipe 17, and both ends of the central tie rod 18 are exposed outside the membrane shell 2, and the two ends of the central tie rod 18 are provided with central tie rod fixing nuts 19. A circulation gap is reserved between the central tie rod 18 and the central water production pipe 17, and one end of the central tie rod 18 and the central water production pipe 17 are sealed by a sealing ring, and the other end is provided with a permeate joint 9 connected to the circulation gap, and the central water production pipe The permeate water collected in is exported through the permeate connection 9.
单只膜元件1设置在前后两抗应力盘之间,中心产水管17上开设有数列小孔,经膜元件过滤后的渗透液从数列小孔汇入中心产水管17,膜元件与膜壳2之间设置有膜元件密封圈14。A single membrane element 1 is set between the front and rear two anti-stress disks, and the central water production pipe 17 is provided with a series of small holes. The permeate filtered by the membrane element flows into the central water production pipe 17 through the series of small holes. 2 is provided with a membrane element sealing ring 14.
如图9所示,抗应力盘采用水力学设计,中心与圆周连接的支撑片为弧形,呈辐射状支撑,此类设计可有效使进水均匀分布到盘面。盘面上采用从中心向四周环形开孔,孔径由内向外逐渐变大。抗应力盘10与进、出水旋流式导流盘构成均匀旋流式布水方式。As shown in Figure 9, the anti-stress plate adopts a hydraulic design, and the supporting piece connecting the center and the circumference is arc-shaped and radially supported. This design can effectively distribute the water to the plate surface evenly. The surface of the disk adopts ring-shaped openings from the center to the surroundings, and the diameter of the holes gradually increases from the inside to the outside. The anti-stress plate 10 and the water inlet and outlet swirl flow diversion plates constitute a uniform swirl water distribution method.
本实施例中,膜元件具有开放式网管流道。具体膜元件包括包覆在中心产水管17外周的分离层,所述分离层是由若干膜袋和开放式隔网以同一方向卷制而成的膜袋层,所述开放式隔网设置在相邻膜袋层表面间的进水流道中,且开放式隔网与膜袋表面为凸点式的接触方式,连接凸点的为菱形细隔网,在与膜袋接触表面的两列凸点状隔网间沿进出水方向形成一条条菱形宽敞的开放式流道,如图5所示。膜袋和开放式隔网的内侧边与中心产水管相连接固定,呈中心向周围发射状排列,然后膜袋及开放式隔网一起朝同一方向旋紧以构成所述的膜袋层,在卷好的膜袋层外周用玻璃纤维及环氧树脂胶进行缠绕包裹密封,两端再安装所述抗应力盘。In this embodiment, the membrane element has an open network pipe flow channel. The specific membrane element includes a separation layer coated on the periphery of the central water production pipe 17. The separation layer is a membrane bag layer rolled in the same direction by a number of membrane bags and an open spacer. The open spacer is arranged on In the water inlet channel between the surfaces of adjacent film bags, the contact between the open spacer and the surface of the film bag is in the form of bumps. A diamond-shaped spacious open flow channel is formed along the direction of water in and out between the nets, as shown in Figure 5. The inner side of the membrane bag and the open partition net are connected and fixed with the central water production pipe, arranged radially from the center to the surrounding, and then the membrane bag and the open partition net are screwed together in the same direction to form the membrane bag layer, Use glass fiber and epoxy resin glue to wrap and seal the outer periphery of the rolled film bag layer, and install the stress-resisting discs at both ends.
上述膜袋由两片膜片正面相背粘接而成,在两片膜片间的产水流道中设置有纯水导流网,过滤得到的渗透液经纯水导流网流出。The above-mentioned membrane bag is formed by bonding two pieces of membranes facing each other. A pure water diversion net is set in the water production channel between the two diaphragms, and the filtered permeate flows out through the pure water diversion net.
1.高效开放式网管流道反渗透膜组件不采用不锈钢中心拉杆(参见专利号),而开放式流道网管式高压反渗透膜组件(STRO)采用不锈钢中心拉杆,超高压开放式流道网管式反渗透膜组件(STRO)不但采用不锈钢中心拉杆而且使用了4根外围拉杆,这样使得新膜组件的操作压力由原来的75公斤分别升至90公斤和160公斤。1. The high-efficiency open network tube channel reverse osmosis membrane module does not use stainless steel center rod (see patent number), while the open channel network tube high pressure reverse osmosis membrane module (STRO) adopts stainless steel center rod, ultra-high pressure open channel network tube The reverse osmosis membrane module (STRO) not only uses a stainless steel central tie rod but also uses 4 peripheral tie rods, which makes the operating pressure of the new membrane module rise from the original 75 kg to 90 kg and 160 kg respectively.
2.当原水的含盐量在25000-30000mg/l时,传统的75公斤级别高效开放式网管流道反渗透膜组件,由于较低的操作压力,系统的回收率通常会被限制在50%左右。而采用90公斤级别开放式流道网管式高压反渗透膜组件及160公斤级别的超高压开放式流道网管式反渗透膜组件,系统的回收率可分别升至60%和80%左右,从而将系统的浓缩倍数由2升至5.较高的回收率降低了系统浓水的产量,因此减小了后续蒸发器的处理量,因而可大大降低系统的投资费用和运行费用。较低的操作压力造成膜的产水量较低,因而在系统的产水量一定的情况下所需膜组件的数量较高,因而系统的投资成本较高。而超高压反渗透膜组件可以克服较高的渗透压力,因为进水压力升高使得驱动反渗透的净压力升高,使得产水量加大,进而减少了膜组件的数量,从而降低了系统的投资及运行费用。2. When the salt content of the raw water is 25000-30000mg/l, the recovery rate of the traditional 75kg level high-efficiency open-type network pipe channel reverse osmosis membrane module is usually limited to 50% due to the low operating pressure about. However, if the 90kg-level open-channel network-managed high-pressure reverse osmosis membrane module and the 160-kg ultra-high pressure open-channel network-managed reverse osmosis membrane module are used, the recovery rate of the system can be increased to about 60% and 80% respectively, so that Increase the concentration ratio of the system from 2 to 5. The higher recovery rate reduces the production of concentrated water in the system, thus reducing the processing capacity of the subsequent evaporator, which can greatly reduce the investment and operating costs of the system. The lower operating pressure results in lower water production of the membrane, so when the water production of the system is constant, the number of membrane modules required is higher, so the investment cost of the system is higher. The ultra-high pressure reverse osmosis membrane module can overcome the higher osmotic pressure, because the increase of the inlet water pressure increases the net pressure driving the reverse osmosis, which increases the water production, thereby reducing the number of membrane modules, thereby reducing the system's operating cost. investment and operating costs.
3.当反渗透膜的操作压力升高时,膜对盐分的截留率也随之升高。因为渗透通量随操作压力的升高而增大,当压力增大时,渗透膜的溶剂量增加而盐通量不变,故脱盐率增大。3. When the operating pressure of the reverse osmosis membrane increases, the rejection rate of the membrane to salt also increases. Because the permeation flux increases with the increase of the operating pressure, when the pressure increases, the amount of solvent in the permeable membrane increases while the salt flux remains unchanged, so the desalination rate increases.
4.当原水的含盐量在25000-30000 mg/l时, 75公斤级开放式流道网管式高压反渗透膜组件(STRO)(无中心拉杆)、90公斤级开放式流道网管式高压反渗透膜组件(STRO)及超高压开放式流道网管式反渗透膜组件(STRO)实验测试数据如下表:4. When the salt content of the raw water is 25,000-30,000 mg/l, the 75kg-level open channel network-managed high-pressure reverse osmosis membrane module (STRO) (without central rod), the 90kg-level open channel network-managed high-pressure The experimental test data of the reverse osmosis membrane module (STRO) and the ultra-high pressure open channel network tube reverse osmosis membrane module (STRO) are as follows:
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