CN106947488A - A kind of mineral matter Vegetable Soil modifying agent and preparation method thereof - Google Patents

A kind of mineral matter Vegetable Soil modifying agent and preparation method thereof Download PDF

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Publication number
CN106947488A
CN106947488A CN201710288881.5A CN201710288881A CN106947488A CN 106947488 A CN106947488 A CN 106947488A CN 201710288881 A CN201710288881 A CN 201710288881A CN 106947488 A CN106947488 A CN 106947488A
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China
Prior art keywords
diatomite
modifying agent
mineral matter
insecticide
herbicide
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Pending
Application number
CN201710288881.5A
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Chinese (zh)
Inventor
张其安
方凌
严德生
王成
王家嘉
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Anhui Anhui Agricultural Science And Technology Co Ltd
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Anhui Anhui Agricultural Science And Technology Co Ltd
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Priority to CN201710288881.5A priority Critical patent/CN106947488A/en
Publication of CN106947488A publication Critical patent/CN106947488A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K17/00Soil-conditioning materials or soil-stabilising materials
    • C09K17/02Soil-conditioning materials or soil-stabilising materials containing inorganic compounds only
    • C09K17/08Aluminium compounds, e.g. aluminium hydroxide
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/18Vapour or smoke emitting compositions with delayed or sustained release
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N39/00Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
    • A01N39/02Aryloxy-carboxylic acids; Derivatives thereof
    • A01N39/04Aryloxy-acetic acids; Derivatives thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N61/00Biocides, pest repellants or attractants, or plant growth regulators containing substances of unknown or undetermined composition, e.g. substances characterised only by the mode of action
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K17/00Soil-conditioning materials or soil-stabilising materials
    • C09K17/40Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2101/00Agricultural use
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2109/00MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE pH regulation

Abstract

The present invention relates to technical field of land improvement, and in particular to a kind of mineral matter Vegetable Soil modifying agent, composed of the following components:Diatomite, potassium dihydrogen phosphate, lime stone, zeolite, potassium sulfate, plant ash, peat, sepiolite, weathered coal, herbicide and insecticide;Its preparation method includes diatomaceous modification, crushing and mixed;The present invention to diatomite by being modified, diatomaceous hole wall can be cleared up, so that its aperture increases, herbicide and insecticide are mixed together stir after, insecticide and herbicide is set to be coated in diatomaceous outer surface and internal hole, the insecticide and herbicide being present in the hole of inside can play slow releasing function, extend drug effect;The purpose of weeding and pest-killing can either be reached, the waste of insecticide and herbicide can be reduced again, the hardening soil and the effect of Adsorption of Heavy Metals ion is reduced while also having, reduces the content of Heavy Metals In Vegetables ion, makes that vegetables are more healthy, health.

Description

A kind of mineral matter Vegetable Soil modifying agent and preparation method thereof
Technical field
The present invention relates to technical field of land improvement, and in particular to a kind of mineral matter Vegetable Soil modifying agent and its preparation side Method.
Background technology
All physics for being mainly used in improved soil, chemistry and biological property, make it be more suitable for plant growth, rather than main The material of plant nutrient, referred to as soil conditioner are provided.Such as liming is used for adjusting the pH value of acid soil, applies gypsum For suppressing the Na in soil+, HCO3-And CO3 2-Plasma, biological activity of soil etc. is improved using beneficial microbe.But by Had a large capacity and a wide range in the material of improved soil structure, so traditionally people have been equal to soil conditioner with soil conditioner Come.Existing soil improvement method largely simply changes the acid-base property of soil, but does not prevent and treat effect of pest and disease damage.
Regarding to the issue above, soil pH can be adjusted by how providing one kind, and the soil that pest and disease damage effect can be prevented and treated again changes Good dose, as a urgent problem to be solved.
The content of the invention
For above-mentioned problem, a kind of mineral matter Vegetable Soil modifying agent prepared by the present invention has adjustment soil pH With preventing and treating pest and disease damage function, while can also for vegetables growth offer needed for mineral matter.
To achieve the above object, the present invention uses following technical scheme:
A kind of mineral matter Vegetable Soil modifying agent, it is characterised in that:Its composition by weight percentage, diatomite 50~ 70%th, potassium dihydrogen phosphate 15~20%, lime stone 20~30%, zeolite 8~20%, potassium sulfate 3~7%, plant ash 4~ 11%th, peat 7~12%, sepiolite 4~8%, weathered coal 3~9%, herbicide 15~25% and insecticide 12~20%.
It is preferred that, a kind of preparation method of mineral matter Vegetable Soil modifying agent comprises the following steps:
A, modification infusorial earth:Diatomite is subjected to break process, the diatomite after crushing is then placed in quality for diatom In the cushioning liquid of native three times, in thermostat, 20~35min of heating water bath stands cooling, filtered with fast grade filter paper, will be solid Body natural air drying, obtains modification infusorial earth;
B, crushing:Respectively by lime stone, potassium dihydrogen phosphate, zeolite, potassium sulfate, plant ash, peat, sepiolite and weathered coal Crush, each component is mixed after crushing, stirred, component A is obtained;
C, mixing:Modification infusorial earth, component A, herbicide and insecticide are mixed uniformly, Vegetable Soil improvement is produced Agent.
It is preferred that, the collocation method of cushioning liquid is in the step a:It is accurate to measure the phosphoric acid that concentration is 0.05mol/L Disodium hydrogen solution 50mL is simultaneously mixed, and stir with 26.9mL concentration for 0.1mol/L sodium hydroxide solution;Cushioning liquid Addition the pH of solution can be made stable 12, it is this under the conditions of prepare modification infusorial earth it is best in quality, inside diatomite Hole wall can clear up more thoroughly, pore volume and surface area are optimal.
It is preferred that, diatomite is selected from Zhejiang Shengxian County diatomite ore in the step a.
It is preferred that, bath temperature is maintained at 90 DEG C in the step a.
It is preferred that, the insecticide selects photostability pyrethroid.
It is preferred that, the herbicide selects 2,4-D butyl esters.
Using above-mentioned technical scheme, the beneficial effect that the present invention reaches is:
1st, the cushioning liquid added in the present invention, can make pH be maintained at 12, the modification diatom prepared under these conditions Native is best in quality, and it is more thorough that the hole wall inside diatomite can be cleared up, and increases aperture, and bulk density reduces;And weeding Agent and insecticide are mixed together stir after, insecticide and herbicide is coated in diatomaceous outer surface and internal hole In, the insecticide and herbicide being present in the hole of inside can play slow releasing function, extend drug effect;It can either reach that desinsection is removed The purpose of grass, can reduce the waste of insecticide and herbicide, save cost again.
2nd, the lime stone in component A is dissolved in insecticide and herbicide and flowed into the form of emulsion inside diatomite Kong Zhong, can neutralize the acid in acid soil, and the pH in soil is adjusted, and the moisture of limestone surfaces can slowly evaporate, so Dry lime stone is obtained afterwards, and lime stone reabsorbs the moisture in soil, and the herbicide and insecticide of surrounding are soaked, and makes it Soil is flowed into the form of liquid, during the water suction repeatedly and dehydration of lime stone, enhance the effect of its desinsection and weeding Really, while reducing the generation of hardening soil phenomenon.
3rd, the adsorption capacity of modified Diatomite is stronger, reduces containing for Heavy Metals In Vegetables ion Amount, makes that vegetables are more healthy, health;And the addition of peat, sepiolite, weathered coal and potassium dihydrogen phosphate and potassium sulfate, it is soil Ground makes vegetable growth more vigorous there is provided required mineral matter and potassium element.
Embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention, Technical scheme in the embodiment of the present invention is clearly and completely described.Based on embodiments of the invention, the common skill in this area The every other embodiment that art personnel are obtained under the premise of creative work is not made, belongs to the model that the present invention is protected Enclose.
Embodiment 1:
A kind of mineral matter Vegetable Soil modifying agent, it is characterised in that:Its composition by weight percentage, diatomite 56%, Potassium dihydrogen phosphate 16%, lime stone 22%, zeolite 12%, potassium sulfate 3%, plant ash 6%, peat 7%, sepiolite 5%, weathering Coal 4%, herbicide 17% and insecticide 12%.
It is preferred that, a kind of preparation method of mineral matter Vegetable Soil modifying agent comprises the following steps:
A, modification infusorial earth:Diatomite is subjected to break process, the diatomite after crushing is then placed in quality for diatom In the cushioning liquid of native three times, in thermostat, heating water bath 20min stands cooling, filtered with fast grade filter paper, by solid certainly So air-dry, obtain modification infusorial earth;
B, crushing:Respectively by lime stone, potassium dihydrogen phosphate, zeolite, potassium sulfate, plant ash, peat, sepiolite and weathered coal Crush, each component is mixed after crushing, stirred, component A is obtained;
C, mixing:Modification infusorial earth, component A, herbicide and insecticide are mixed uniformly, Vegetable Soil improvement is produced Agent.
Embodiment 2:
A kind of mineral matter Vegetable Soil modifying agent, it is characterised in that:Its composition by weight percentage, diatomite 50%, Potassium dihydrogen phosphate 15%, lime stone 20%, zeolite 8%, potassium sulfate 5%, plant ash 4%, peat 9%, sepiolite 4%, weathering Coal 3%, herbicide 15% and insecticide 15%.
It is preferred that, a kind of preparation method of mineral matter Vegetable Soil modifying agent comprises the following steps:
A, modification infusorial earth:Diatomite is subjected to break process, the diatomite after crushing is then placed in quality for diatom In the cushioning liquid of native three times, in thermostat, heating water bath 25min stands cooling, filtered with fast grade filter paper, by solid certainly So air-dry, obtain modification infusorial earth;
B, crushing:Respectively by lime stone, potassium dihydrogen phosphate, zeolite, potassium sulfate, plant ash, peat, sepiolite and weathered coal Crush, each component is mixed after crushing, stirred, component A is obtained;
C, mixing:Modification infusorial earth, component A, herbicide and insecticide are mixed uniformly, Vegetable Soil improvement is produced Agent.
Embodiment 3:
A kind of mineral matter Vegetable Soil modifying agent, it is characterised in that:Its composition by weight percentage, diatomite 70%, Potassium dihydrogen phosphate 18%, lime stone 30%, zeolite 16%, potassium sulfate 6%, plant ash 11%, peat 12%, sepiolite 6%, wind Change coal 9%, herbicide 22% and insecticide 18%.
It is preferred that, a kind of preparation method of mineral matter Vegetable Soil modifying agent comprises the following steps:
A, modification infusorial earth:Diatomite is subjected to break process, the diatomite after crushing is then placed in quality for diatom In the cushioning liquid of native three times, in thermostat, heating water bath 35min stands cooling, filtered with fast grade filter paper, by solid certainly So air-dry, obtain modification infusorial earth;
B, crushing:Respectively by lime stone, potassium dihydrogen phosphate, zeolite, potassium sulfate, plant ash, peat, sepiolite and weathered coal Crush, each component is mixed after crushing, stirred, component A is obtained;
C, mixing:Modification infusorial earth, component A, herbicide and insecticide are mixed uniformly, Vegetable Soil improvement is produced Agent.
Embodiment 4:
A kind of mineral matter Vegetable Soil modifying agent, it is characterised in that:Its composition by weight percentage, diatomite 65%, Potassium dihydrogen phosphate 20%, lime stone 26%, zeolite 20%, potassium sulfate 7%, plant ash 9%, peat 10%, sepiolite 8%, wind Change coal 7%, herbicide 25% and insecticide 20%.
It is preferred that, a kind of preparation method of mineral matter Vegetable Soil modifying agent comprises the following steps:
A, modification infusorial earth:Diatomite is subjected to break process, the diatomite after crushing is then placed in quality for diatom In the cushioning liquid of native three times, in thermostat, heating water bath 30min stands cooling, filtered with fast grade filter paper, by solid certainly So air-dry, obtain modification infusorial earth;
B, crushing:Respectively by lime stone, potassium dihydrogen phosphate, zeolite, potassium sulfate, plant ash, peat, sepiolite and weathered coal Crush, each component is mixed after crushing, stirred, component A is obtained;
C, mixing:Modification infusorial earth, component A, herbicide and insecticide are mixed uniformly, Vegetable Soil improvement is produced Agent.
Diatomite before modified and modified diatomaceous specific surface area and aperture are measured by pertinent instruments;And from acid Property soil moderate take two parts of soil samples, measure its pH, then add into soil sample a certain amount of heavy metal ion (predominantly lead from Son and chromium ion) it is well mixed, the Vegetable Soil modifying agent for then preparing the present invention is separately added into commercially available soil conditioner In two parts of soil samples, the pH of each soil and the absorptivity of heavy metal ion are measured after same time.Contrast under the same conditions, Obtain indices data such as following table:
From data in table, it is modified by this invention after diatomaceous aperture be more than diatomite before modified;Diatomite Specific surface area is less than diatomite before modified.Commercially available soil is superior in terms of the adsorption rate of soil pH and heavy metal ion is improved Modifying agent.Show that preparation technology of the present invention is more perfect, product overall performance than control group more preferably, is worthy to be popularized.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations;Although with reference to the foregoing embodiments The present invention is described in detail, it will be understood by those within the art that:It still can be to foregoing each implementation Technical scheme described in example is modified, or carries out equivalent to which part technical characteristic;And these modification or Replace, the essence of appropriate technical solution is departed from the spirit and scope of various embodiments of the present invention technical scheme.

Claims (7)

1. a kind of mineral matter Vegetable Soil modifying agent, it is characterised in that:Its composition by weight percentage, diatomite 50~ 70%th, potassium dihydrogen phosphate 15~20%, lime stone 20~30%, zeolite 8~20%, potassium sulfate 3~7%, plant ash 4~ 11%th, peat 7~12%, sepiolite 4~8%, weathered coal 3~9%, herbicide 15~25% and insecticide 12~20%.
2. a kind of preparation method of mineral matter Vegetable Soil modifying agent, comprises the following steps:
A, diatomaceous modification:Diatomite is subjected to break process, the diatomite after crushing is then placed in quality for diatomite In the cushioning liquid of three times, in thermostat, 20~35min of heating water bath stands cooling, filtered with fast grade filter paper, by solid Natural air drying, obtains modification infusorial earth;
B, crushing:Respectively by lime stone, potassium dihydrogen phosphate, zeolite, potassium sulfate, plant ash, peat, sepiolite and weathering coal dust It is broken, each component is mixed after crushing, stirred, component A is obtained;
C, mixing:Modification infusorial earth, component A, herbicide and insecticide are mixed uniformly, Vegetable Soil modifying agent is produced.
3. a kind of preparation method of mineral matter Vegetable Soil modifying agent according to claim 2, it is characterised in that:The step The collocation method of cushioning liquid is in rapid a:It is accurate measure disodium phosphate soln 50mL that concentration is 0.05mol/L and with 26.9mL concentration mixes for 0.1mol/L sodium hydroxide solution, and stirs.
4. a kind of preparation method of mineral matter Vegetable Soil modifying agent according to claim 2, it is characterised in that:The step Diatomite is selected from Zhejiang Shengxian County diatomite ore in rapid a.
5. a kind of preparation method of mineral matter Vegetable Soil modifying agent according to claim 2, it is characterised in that:The step Bath temperature is maintained at 90 DEG C in rapid a.
6. a kind of preparation method of mineral matter Vegetable Soil modifying agent according to claim 1, it is characterised in that:It is described to kill Photostability pyrethroid is selected in worm agent.
7. a kind of preparation method of mineral matter Vegetable Soil modifying agent according to claim 1, it is characterised in that:It is described to remove 2,4-D butyl esters are selected in careless agent.
CN201710288881.5A 2017-04-27 2017-04-27 A kind of mineral matter Vegetable Soil modifying agent and preparation method thereof Pending CN106947488A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109082277A (en) * 2018-08-16 2018-12-25 湖南泰谷生态工程有限公司 A kind of cadmium arsenic combined pollution renovation agent and the preparation method and application thereof
WO2019114273A1 (en) * 2017-12-11 2019-06-20 陈秋玲 Method for preparing soil treating agent
WO2019114272A1 (en) * 2017-12-11 2019-06-20 陈秋玲 Method for preparing soil treating agent for reducing acidity
CN109913233A (en) * 2019-04-28 2019-06-21 湖南省地球物理地球化学勘查院 A kind of water paddy soil heavy metal passivation modifying agent

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102766465A (en) * 2012-07-31 2012-11-07 湖南永清环境修复有限公司 Ion mineralization stabilizer for treating soil with heavy metal pollution and application method thereof
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CN106187573A (en) * 2016-06-30 2016-12-07 哈尔滨尼亚农业有限公司 The soil conditioner of a kind of ore and preparation method

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019114273A1 (en) * 2017-12-11 2019-06-20 陈秋玲 Method for preparing soil treating agent
WO2019114272A1 (en) * 2017-12-11 2019-06-20 陈秋玲 Method for preparing soil treating agent for reducing acidity
CN109082277A (en) * 2018-08-16 2018-12-25 湖南泰谷生态工程有限公司 A kind of cadmium arsenic combined pollution renovation agent and the preparation method and application thereof
CN109913233A (en) * 2019-04-28 2019-06-21 湖南省地球物理地球化学勘查院 A kind of water paddy soil heavy metal passivation modifying agent
CN109913233B (en) * 2019-04-28 2024-02-02 湖南省地球物理地球化学调查所 Rice field soil heavy metal passivation modifier

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Application publication date: 20170714