CN106947197A - A kind of LSOH anti-flaming eraser sheath material of resistance to 40 DEG C of low temperature, resistance to ASTM3# oil - Google Patents
A kind of LSOH anti-flaming eraser sheath material of resistance to 40 DEG C of low temperature, resistance to ASTM3# oil Download PDFInfo
- Publication number
- CN106947197A CN106947197A CN201710248035.0A CN201710248035A CN106947197A CN 106947197 A CN106947197 A CN 106947197A CN 201710248035 A CN201710248035 A CN 201710248035A CN 106947197 A CN106947197 A CN 106947197A
- Authority
- CN
- China
- Prior art keywords
- resistance
- sheath material
- low temperature
- astm3
- flaming
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/11—Esters; Ether-esters of acyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/22—Halogen free composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of resistance to 40 DEG C of low temperature, the LSOH anti-flaming eraser sheath material of resistance to ASTM3# oil, the eraser sheath material by weight, is made up of following component：1 part of 60~80 parts of ACM, 1 part of lubricant, 2.5 parts of vulcanizing agent, 1 part of assistant crosslinking agent, 200~220 parts of fire retardant, 1 part of age resistor, 5 parts of plasticizer, 0.5 part of processing aid and coupling agent；Wherein, the fire retardant is made up of the magnesium hydroxide of flame-retardant master batch, Firebrake ZB and silane treatment；The eraser sheath material resistance to low temperature can reach 40 DEG C, and be resistant to ASTM3# oil, while the excellent fireproof performance of the eraser sheath material, oxygen index (OI) can reach more than 34, it is adaptable to high performance production requirement.
Description
Technical field
The present invention disclose the technical field for being related to flame retardant cable, more particularly to a kind of resistance to -40 DEG C of low temperature, resistance to ASTM3# oily
LSOH anti-flaming eraser sheath material.
Background technology
In recent years, as country is to environmental protection and the attention of safety, some heavy constructions or public place, such as megastore,
The places such as public place of entertainment, subway, station, ship, nuclear power station, require and use low-smoke halogen-free inflaming-retarding cable.
Fireproofing cable material without halide is also required in performance and kind while quick growth is achieved on product yield
Followed up in class.It is different according to the use environment of cable, it is also different to the performance requirement of cable, for example：Locomotive cable and
Cable for ship etc., due to its special use environment, is not required nothing more than as low-smoke halogen-free inflaming-retarding cable, but also requires that cable has
There are oil resistant, the performance of resistance to -40 DEG C of low temperature.At present, the problem of conventional fireproofing cable material without halide of in the market is due to dispensing,
There is contradiction in the performance indications of oil resistant and resistance to -40 DEG C of low temperature, otherwise oil resistant by and resistance to -40 DEG C of low temperature can't pass,
Resistance to -40 DEG C of low temperature by and oil resistant can't pass, be extremely difficult to balance therebetween.
Therefore, how to research and develop a kind of new LSOH anti-flaming eraser sheath material with and meanwhile meet resistance to -40 DEG C of low temperature and
The requirement of oil resistant, as people's urgent problem to be solved.
The content of the invention
In consideration of it, the invention provides a kind of resistance to -40 DEG C of low temperature, the LSOH anti-flaming eraser sheath of resistance to ASTM3# oil
Material, can not be while meet the requirement of resistance to -40 DEG C of low temperature and oil resistant at least to solve conventional eraser sheath material, it is impossible to preferably suitable
For locomotive cable and cable for ship etc..
The technical scheme that the present invention is provided, specifically, the LSOH anti-flaming of a kind of resistance to -40 DEG C of low temperature, resistance to ASTM3# oil
Eraser sheath material, by weight, is made up of following component：
60~80 parts of ACM, 1 part of lubricant, 2.5 parts of vulcanizing agent, 1 part of assistant crosslinking agent, fire retardant 200~
1 part of 220 parts, 1 part of age resistor, 5 parts of plasticizer, 0.5 part of processing aid and coupling agent；
Wherein, the fire retardant is made up of the magnesium hydroxide of flame-retardant master batch, Firebrake ZB and silane treatment.
It is preferred that, in the fire retardant weight ratio of the magnesium hydroxide of flame-retardant master batch, Firebrake ZB and silane treatment for (5~
10)： 1：(11~14).
Further preferably, in the fire retardant magnesium hydroxide of flame-retardant master batch, Firebrake ZB and silane treatment weight ratio
For 7.5：1：12.5.
Further preferably, resistance to -40 DEG C of low temperature, the LSOH anti-flaming eraser sheath material of resistance to ASTM3# oil, by weight
Meter, is made up of following component：
It is 70 parts of ACM, 1 part of lubricant, 2.5 parts of vulcanizing agent, 1 part of assistant crosslinking agent, 210 parts of fire retardant, anti-old
1 part of 1 part of agent, 5 parts of plasticizer, 0.5 part of processing aid and coupling agent.
Further preferably, the lubricant is stearic acid.
Further preferably, the vulcanizing agent is cumyl peroxide.
Further preferably, the age resistor is 4.4 '-bis- (2.2- dimethyl benzyls) diphenylamines.
Further preferably, the plasticizer is di-n-octyl sebacate.
Further preferably, the processing aid dissipates for Rhein.
Further preferably, the coupling agent is silane.
The LSOH anti-flaming eraser sheath material of resistance to -40 DEG C of low temperature that the present invention is provided, resistance to ASTM3# oil, by acrylate
Rubber, lubricant, vulcanizing agent, assistant crosslinking agent, fire retardant, age resistor, plasticizer, processing aid and coupling agent are made, especially
Its, the eraser sheath material flame-retardant select by flame-retardant master batch, Firebrake ZB and silane treatment magnesium hydroxide constitute it is fire-retardant
Agent, wherein, the magnesium hydroxide of silane treatment is filled into ACM, using between inorganic metal and organic molecule
Chemical bond is formed, the mechanical performance and fire resistance of sizing material can be effectively improved, wherein, the oxygen index (OI) of the eraser sheath material is reachable
To more than 34.Further, since the ACM in eraser sheath material has preferable oil resistivity so that the eraser sheath
Material has preferable oil resistivity, and typically, if added in ACM after the low temperature resistant composition in part, meeting
Influence is produced on the oil resistance of ACM, and eraser sheath material is mainly improved by flame-retardant master batch in the present invention
Resistance to low temperature, it is realized and existed by the Performance Match and appropriate weight proportion of flame-retardant master batch and ACM
Added in ACM after flame-retardant master batch, not only increase overall resistance to low temperature, and without influence acrylic acid
The oil resistivity of ester rubber, while meeting the lower temperature resistance of the eraser sheath material and the double requirements of oil resistivity, it is adaptable to high-performance
Production requirement.
Embodiment
Here exemplary embodiment will be illustrated in detail.Embodiment described in following exemplary embodiment
Do not represent all embodiments consistent with the present invention.On the contrary, they be only with as being described in detail in appended claims
, some consistent examples of aspect of the present invention.
Can not be while meeting two of resistance to -40 DEG C of low temperature and oil resistant in order to solve conventional LSOH anti-flaming eraser sheath material
It is required that, -40 DEG C of low temperature be both resistant to present embodiment provides one kind, the LSOH anti-flaming rubber shield of ASTM3# oil is resistant to again
Jacking, the eraser sheath material, by weight, is made up of following component：
60~80 parts of ACM, 1 part of lubricant, 2.5 parts of vulcanizing agent, 1 part of assistant crosslinking agent, fire retardant 200~220
Part, 1 part of age resistor, 5 parts of plasticizer, 0.5 part of processing aid and 1 part of coupling agent；Wherein, fire retardant is by flame-retardant master batch, boric acid
Zinc and the magnesium hydroxide of silane treatment composition.
It is preferred that, the weight ratio of the magnesium hydroxide of flame-retardant master batch, Firebrake ZB and silane treatment is (5~10) in fire retardant：
1：(11~14), more preferably, the weight ratio of the magnesium hydroxide of flame-retardant master batch, Firebrake ZB and silane treatment is 7.5：1：
12.5。
The proportioning of above-mentioned eraser sheath material preferably is, by weight, 70 parts of ACM, 1 part of lubricant, vulcanization
2.5 parts of agent, 1 part of assistant crosslinking agent, 210 parts of fire retardant, 1 part of age resistor, 5 parts of plasticizer, 0.5 part of processing aid and coupling agent 1
Part.
Wherein, ACM, the combination property of its heat-resisting oil resistant is very excellent, similar to nitrile rubber, uses temperature
Up to 180 DEG C of degree, is widely used in the product for requiring high temperature resistant, heat resistant oils.Wherein, ACM is with acrylic acid
Ester be main monomer through elastomer obtained by copolymerization, its main chain is saturated carbon chains, and side base is polar ester groups, full due to its structure
Its main application feature is determined with property and with polar ester groups side chain, i.e. heatproof air aging performance and oil resistance is excellent
It is different, and resist cold, water-fast, solvent resistance it is poor so that application of the ACM in cable industry is limited.This is also
Conventional low-smoke non-halogen flame-retardant eraser sheath material is existed in the performance indications of oil resistant and resistance to -40 DEG C of low temperature in the market
The major reason of contradiction, otherwise existing eraser sheath material oil resistivity by and resistance to -40 DEG C of low temperature can't pass, or resistance to -40 DEG C
Low temperature by and oil resistant can't pass, be extremely difficult to balance therebetween.
Resistance to -40 DEG C of low temperature of the present embodiment offer, the LSOH anti-flaming eraser sheath material of resistance to ASTM3# oil, with propylene
Acid esters rubber be base-material on the basis of, except with lubricant, vulcanizing agent, assistant crosslinking agent, age resistor, plasticizer, processing aid with
And outside coupling agent coordinates, it is often more important that the cooperation with fire retardant, wherein, fire retardant is by flame-retardant master batch, Firebrake ZB and silicon
The magnesium hydroxide composition of alkane processing, by the addition of above-mentioned fire retardant, can ACM organic molecule and fire retardant
Inorganic metal between form chemical bond, and then improve the mechanical performance and fire resistance of acrylate rubber sizing material, wherein,
The oxygen index (OI) of the eraser sheath material can reach more than 34.Further, since the ACM in eraser sheath material has preferably
Oil resistivity so that the eraser sheath material has preferable oil resistivity, and typically, if in ACM plus
Enter after the low temperature resistant composition in part, influence can be produced on the oil resistance of ACM, and main pass through hinders in the present invention
Combustion masterbatch improves the resistance to low temperature of eraser sheath material, its by the Performance Match of flame-retardant master batch and ACM with
And appropriate weight proportion, realize and added in ACM after flame-retardant master batch, not only increased overall low temperature resistant
Performance, and without the oil resistivity of influence ACM, while meeting the lower temperature resistance and oil resistivity of the eraser sheath material
Double requirements, it is adaptable to high performance production requirement, and then the application office by conventional ACM in cable industry
Limit is broken, and has expanded it and has used scope, can broader applications on locomotive cable and cable for ship.
Wherein, lubricant can select stearic acid；Vulcanizing agent can select cumyl peroxide (DCP)；Age resistor can select
4.4 '-bis- (2.2- dimethyl benzyls) diphenylamines (N445)；Plasticizer can select di-n-octyl sebacate (DOS)；Processing aid can
Dissipated from Rhein；Coupling agent can select silane；The magnesium hydroxide of silane treatment is to inorganic combustion inhibitor hydrogen by coupling agent silane
Magnesia carries out repeatedly the model of effectively modified acquisition, the preferably strange fire proofing factory production in Shenyang City
RXMH1150 fire retardant.
Explanation the present invention is further expalined with specific embodiment below, but be not intended to limit the invention
Protection domain.
Embodiment
Composition is made in the specific of eraser sheath material in 1~embodiment of embodiment 3, by weight, is shown in Table 1.
Wherein, detect that the specific preparation process of sample is as follows in 1~embodiment of embodiment 3：
1) it will be added after ACM stripping and slicing in banbury, then sequentially add lubricant, processing aid, coupling
Agent, age resistor, fire retardant, plasticizer and assistant crosslinking agent, are kneaded, and obtain glue stuff compounding；
2) by step 1) in the uniform bottom sheet of glue stuff compounding after, obtain film, park stand-by；
3) by step 2) in film add banbury in, vulcanizing agent is added, after being vulcanized, by sizing material after vulcanization
Uniform bottom sheet, and by the film natural cooling obtained after bottom sheet again, is made detection sample.
Table 1：
| Composition | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| ACM | 70 | 80 | 60 |
| Flame-retardant master batch (RXMH6050) | 75 | 50 | 100 |
| Stearic acid (HST) | 1 | 1 | 1 |
| Cumyl peroxide (DCP) | 2.5 | 2.5 | 2.5 |
| Assistant crosslinking agent (TMPTMA) | 1 | 1 | 1 |
| The magnesium hydroxide (RXMH1150) of silane treatment | 125 | 140 | 110 |
| Firebrake ZB | 10 | 10 | 10 |
| Age resistor (N445) | 1 | 1 | 1 |
| Di-n-octyl sebacate (DOS) | 5 | 5 | 5 |
| Rhein dissipates 18 | 0.5 | 0.5 | 0.5 |
| Silane coupler | 1 | 1 | 1 |
Embodiment 4
By according to the composition proportion in 1~embodiment of embodiment 3, obtained sample is detected, specific testing result,
It is shown in Table 2.
Table 2：
Those skilled in the art will readily occur to its of the present invention after considering specification and putting into practice invention disclosed herein
Its embodiment.The application is intended to any modification, purposes or the adaptations of the present invention, these modifications, purposes
Or adaptations follow the general principle of the present invention and including undocumented in the art known normal of the present invention
Know or conventional techniques.Description and embodiments are considered only as exemplary, and true scope and spirit of the invention are by following
Claim point out.
It should be appreciated that the invention is not limited in the content being described above, and its model can not departed from
Enclose the various modifications and changes of progress.The scope of the present invention is only limited by appended claim.
Claims (10)
1. the LSOH anti-flaming eraser sheath material of a kind of resistance to -40 DEG C of low temperature, resistance to ASTM3# oil, it is characterised in that by weight,
It is made up of following component：
60~80 parts of ACM, 1 part of lubricant, 2.5 parts of vulcanizing agent, 1 part of assistant crosslinking agent, 200~220 parts of fire retardant,
1 part of 1 part of age resistor, 5 parts of plasticizer, 0.5 part of processing aid and coupling agent；
Wherein, the fire retardant is made up of the magnesium hydroxide of flame-retardant master batch, Firebrake ZB and silane treatment.
2. according to claim 1 resistance to -40 DEG C of low temperature, resistance to ASTM3# oil LSOH anti-flaming eraser sheath material, its feature
It is：The weight ratio of the magnesium hydroxide of flame-retardant master batch, Firebrake ZB and silane treatment is (5~10) in the fire retardant：1：(11
~14).
3. according to claim 1 resistance to -40 DEG C of low temperature, resistance to ASTM3# oil LSOH anti-flaming eraser sheath material, its feature
It is：The weight ratio of the magnesium hydroxide of flame-retardant master batch, Firebrake ZB and silane treatment is 7.5 in the fire retardant：1：12.5.
4. according to claim 1 resistance to -40 DEG C of low temperature, resistance to ASTM3# oil LSOH anti-flaming eraser sheath material, its feature
It is by weight, to be made up of following component：
70 parts of ACM, 1 part of lubricant, 2.5 parts of vulcanizing agent, 1 part of assistant crosslinking agent, 210 parts of fire retardant, 1 part of age resistor,
1 part of 5 parts of plasticizer, 0.5 part of processing aid and coupling agent.
5. resistance to -40 DEG C of low temperature, the LSOH anti-flaming eraser sheath material of resistance to ASTM3# oil according to claim 1 or 4, it is special
Levy and be：The lubricant is stearic acid.
6. resistance to -40 DEG C of low temperature, the LSOH anti-flaming eraser sheath material of resistance to ASTM3# oil according to claim 1 or 4, it is special
Levy and be：The vulcanizing agent is cumyl peroxide.
7. resistance to -40 DEG C of low temperature, the LSOH anti-flaming eraser sheath material of resistance to ASTM3# oil according to claim 1 or 4, it is special
Levy and be：The age resistor is 4.4 '-bis- (2.2- dimethyl benzyls) diphenylamines.
8. resistance to -40 DEG C of low temperature, the LSOH anti-flaming eraser sheath material of resistance to ASTM3# oil according to claim 1 or 4, it is special
Levy and be：The plasticizer is di-n-octyl sebacate.
9. resistance to -40 DEG C of low temperature, the LSOH anti-flaming eraser sheath material of resistance to ASTM3# oil according to claim 1 or 4, it is special
Levy and be：The processing aid dissipates for Rhein.
10. resistance to -40 DEG C of low temperature, the LSOH anti-flaming eraser sheath material of resistance to ASTM3# oil according to claim 1 or 4, its
It is characterised by：The coupling agent is silane.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710248035.0A CN106947197A (en) | 2017-04-17 | 2017-04-17 | A kind of LSOH anti-flaming eraser sheath material of resistance to 40 DEG C of low temperature, resistance to ASTM3# oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710248035.0A CN106947197A (en) | 2017-04-17 | 2017-04-17 | A kind of LSOH anti-flaming eraser sheath material of resistance to 40 DEG C of low temperature, resistance to ASTM3# oil |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106947197A true CN106947197A (en) | 2017-07-14 |
Family
ID=59476239
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710248035.0A Pending CN106947197A (en) | 2017-04-17 | 2017-04-17 | A kind of LSOH anti-flaming eraser sheath material of resistance to 40 DEG C of low temperature, resistance to ASTM3# oil |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106947197A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113801421A (en) * | 2021-09-23 | 2021-12-17 | 江西立德汽车零部件有限公司 | Preparation process of rubber sheath |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1343737A (en) * | 2000-09-21 | 2002-04-10 | 山东鲁能泰山电缆股份有限公司 | Low-smoke non-halogen low-poisin fire-retarding polyolefin material for protective sleeve |
| CN102382358A (en) * | 2011-11-15 | 2012-03-21 | 中天科技装备电缆有限公司 | Halogen-free flame-retardant cable sheath material for railway locomotive and manufacturing method for halogen-free flame-retardant cable sheath material |
| CN104530549A (en) * | 2014-12-30 | 2015-04-22 | 上海至正道化高分子材料股份有限公司 | High cold-resistance and oil-resistance low-smoke halogen-free flame retardant cable material for irradiation crosslinking rolling stock and preparation method thereof |
| CN104804348A (en) * | 2015-04-27 | 2015-07-29 | 苏州统明机械有限公司 | Wear-resistant sealing material and preparation method thereof |
-
2017
- 2017-04-17 CN CN201710248035.0A patent/CN106947197A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1343737A (en) * | 2000-09-21 | 2002-04-10 | 山东鲁能泰山电缆股份有限公司 | Low-smoke non-halogen low-poisin fire-retarding polyolefin material for protective sleeve |
| CN102382358A (en) * | 2011-11-15 | 2012-03-21 | 中天科技装备电缆有限公司 | Halogen-free flame-retardant cable sheath material for railway locomotive and manufacturing method for halogen-free flame-retardant cable sheath material |
| CN104530549A (en) * | 2014-12-30 | 2015-04-22 | 上海至正道化高分子材料股份有限公司 | High cold-resistance and oil-resistance low-smoke halogen-free flame retardant cable material for irradiation crosslinking rolling stock and preparation method thereof |
| CN104804348A (en) * | 2015-04-27 | 2015-07-29 | 苏州统明机械有限公司 | Wear-resistant sealing material and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 张玉龙等主编: "《功能塑料制品配方设计与加工实例》", 31 January 2006 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113801421A (en) * | 2021-09-23 | 2021-12-17 | 江西立德汽车零部件有限公司 | Preparation process of rubber sheath |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102617938B (en) | Cold-resistant ethyl-propylene insulating material for cables | |
| KR101457612B1 (en) | Halogen-free polymer resin composition and polymer resin material made by using said composition | |
| CN106046464A (en) | Oil-resistant and high-temperature-resistant mining cable sheath material and method for preparing same | |
| CN104231420B (en) | 105 DEG C of temperature resistant grade irradiated crosslinking low-smoke halogen-free flame-retardant isolating material and preparation method thereof | |
| CN108410161A (en) | A kind of fire-retardant TPU cable jacket materials and preparation method thereof with electro-magnetic screen function | |
| CN101812208A (en) | Irradiation cross-linking flame-retardant flexible polyvinyl chloride plastic for wire and cable | |
| CN108410160A (en) | A kind of fire-retardant TPU cable jacket materials and preparation method thereof with electro-magnetic screen function | |
| CN108485244B (en) | Flame-retardant polyurethane elastomer and preparation method and application thereof | |
| Yen et al. | Synergistic effect of aluminum hydroxide and nanoclay on flame retardancy and mechanical properties of EPDM composites | |
| CN100999598A (en) | Preparation process for cable material of radiation resisting low flue unhalogen flame-retarded ethylpropyl rubber | |
| CN109651691A (en) | Low-temperature-resistant oil-resistant torsion-resistant low-smoke halogen-free flame-retardant wind energy cable sheath material and preparation method and application thereof | |
| CN106947197A (en) | A kind of LSOH anti-flaming eraser sheath material of resistance to 40 DEG C of low temperature, resistance to ASTM3# oil | |
| CN105860287A (en) | LSZH (low smoke zero halogen) flame-retardant locomotive used brake hose and preparation method thereof | |
| CN108003444A (en) | A kind of low smoke halogen-free fire retardant polyolefin cable material and preparation method thereof | |
| KR20100005502A (en) | Halogen-free flame-retardant resin composition with nanoclay and zinc borate secondary flame-retardants | |
| CA2891253C (en) | Jacket composition for riser and plenum cables | |
| CN106967240A (en) | A kind of LSOH anti-flaming eraser sheath material of resistance to 50 DEG C of low temperature, resistance to ASTM3# oil | |
| CN106928560A (en) | A kind of insulation rubber of fire-retardant second third | |
| CN103483827B (en) | Fire-retardant fluorine silica gel | |
| Chen et al. | Mechanical properties, flame retardancy, hot‐air ageing, and hot‐oil ageing resistance of ethylene‐vinyl acetate rubber/hydrogenated nitrile‐butadiene rubber/magnesium hydroxide composites | |
| Naskar et al. | Development of thin‐walled halogen‐free cable insulation and halogen‐free fire‐resistant low‐smoke cable‐sheathing compounds based on polyolefin elastomer and ethylene vinyl acetate blends | |
| Lu et al. | Selectively located aluminum hydroxide in rubber phase in a TPV: Towards to a halogen‐free flame retardant thermoplastic elastomer with ultrahigh flexibility | |
| CN114213742A (en) | High-flame-retardance low-smoke halogen-free cable material and preparation method and application thereof | |
| US2205654A (en) | Dielectric composition | |
| Kong et al. | Performances of a polymeric intumescent flame retardant in styrene butadiene rubber |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170714 |