CN106947144A - A kind of wear-resisting PE plastic pipes of antibacterial - Google Patents

A kind of wear-resisting PE plastic pipes of antibacterial Download PDF

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Publication number
CN106947144A
CN106947144A CN201710252770.9A CN201710252770A CN106947144A CN 106947144 A CN106947144 A CN 106947144A CN 201710252770 A CN201710252770 A CN 201710252770A CN 106947144 A CN106947144 A CN 106947144A
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CN
China
Prior art keywords
parts
wear
resisting
antibacterial
plastic pipes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710252770.9A
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Chinese (zh)
Inventor
陈绍光
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Suzhou Shanghai Electronic Technology Co Ltd
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Suzhou Shanghai Electronic Technology Co Ltd
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Filing date
Publication date
Application filed by Suzhou Shanghai Electronic Technology Co Ltd filed Critical Suzhou Shanghai Electronic Technology Co Ltd
Priority to CN201710252770.9A priority Critical patent/CN106947144A/en
Publication of CN106947144A publication Critical patent/CN106947144A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/18Applications used for pipes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/062HDPE

Abstract

The invention discloses a kind of wear-resisting PE plastic pipes of antibacterial, it is made up of the raw material of following parts by weight:100 110 parts of high density polyethylene (HDPE), 18 24 parts of ethylene ethyl acrylate copolymer, 15 19 parts of coumarone indene resin, 68 parts of antioxidant 1076,24 parts of dibatyl phithalate, 12 18 parts of butyl ether Lauxite, 59 parts of silica, 26 parts of zinc oxide, 6 10 parts of cumyl peroxide, 15 24 parts of acrylic resin.The wear-resisting PE plastic pipes of antibacterial that the present invention is provided have good antibacterial and mouldproof performance;And the mechanical strength of plastics is not influenceed, and anti-wear performance is good, long service life.

Description

A kind of wear-resisting PE plastic pipes of antibacterial
Technical field
The invention belongs to polymeric material field, and in particular to a kind of wear-resisting PE plastic pipes of antibacterial.
Background technology
Polyethylene(Polyethylene, abbreviation PE)It is a kind of aggregated obtained thermoplastic resin of ethene.Polyethylene according to Polymerization, molecular weight height, the difference of chain structure, point high density polyethylene (HDPE), low density polyethylene (LDPE) and linear low density polyethylene Alkene.Its medium high density polyethylene (HIGH DENSITY POLYETHYLENE, HDPE) is commonly called as low-pressure polyethylene, with LDPE and LLDPE is compared, and has higher heatproof, oil resistivity, resistance to vapour permeability and environmental stress crack resistance, in addition electrical insulating property and anti- Impact and cold tolerance very well, are mainly used in the fields such as blowing, injection.The HDPE tubing being made up of high density polyethylene (HDPE) is Traditional steel tubing, the regeneration product of polychloroethylene pipes, it mainly undertakes appointing for the drainings such as rainwater, sewage, farmland discharging-irrigating Business, is widely used in highway, railway bed, subway engineering, Landfills, tunnel, greenbelt, sports ground and water content higher The draining such as caused side slope protection field, and agricultural, the sub-irrigation of gardening, drainage system.And HDPE in the market Tubing has that case hardness is low, and the shortcoming of easy scratch strongly limit the use of HDPE pipes, therefore, our matching somebody with somebody from product Side sets about, and there is provided a kind of wear-resisting PE plastic pipes of antibacterial for the new high performance HDPE tubing of exploitation.
The content of the invention
It is an object of the invention to provide a kind of wear-resisting PE plastic pipes of antibacterial.
To achieve these goals, the invention provides a kind of wear-resisting PE plastic pipes of antibacterial, by the original of following parts by weight Material is made:100-110 parts of high density polyethylene (HDPE), 18-24 parts of ethylene-ethyl acrylate copolymer, 15-19 parts of coumarone indene resin, 6-8 parts of antioxidant 1076,2-4 parts of dibatyl phithalate, 12-18 parts of butyl ether Lauxite, 5-9 parts of silica, oxidation 2-6 parts of zinc, 6-10 parts of cumyl peroxide, 15-24 parts of acrylic resin.
It also includes 5-9 parts of triphenyl phosphite.
It also includes 3-5 parts of disulfide group 2-ethyl hexyl ethanoate stannous methide.
It also includes 6-8 parts of dibasic lead phosphite.
Beneficial effect:The wear-resisting PE plastic pipes of antibacterial that the present invention is provided have good antibacterial and mouldproof performance;And no The mechanical strength of plastics is influenceed, anti-wear performance is good, long service life.
Embodiment
Embodiment 1
The wear-resisting PE plastic pipes of a kind of antibacterial that the present embodiment is provided, are made by the raw material of following parts by weight:High density polyethylene (HDPE) 100 parts, 18 parts of ethylene-ethyl acrylate copolymer, 15 parts of coumarone indene resin, 6 parts of antioxidant 1076, dibatyl phithalate 2 Part, 12 parts of butyl ether Lauxite, 5 parts of silica, 2 parts of zinc oxide, 6 parts of cumyl peroxide, 15 parts of acrylic resin.
Embodiment 2
The wear-resisting PE plastic pipes of a kind of antibacterial that the present embodiment is provided, are made by the raw material of following parts by weight:High density polyethylene (HDPE) 110 parts, 24 parts of ethylene-ethyl acrylate copolymer, 19 parts of coumarone indene resin, 8 parts of antioxidant 1076, dibatyl phithalate 4 Part, 18 parts of butyl ether Lauxite, 9 parts of silica, 6 parts of zinc oxide, 10 parts of cumyl peroxide, acrylic resin 24 Part, 9 parts of triphenyl phosphite.
Embodiment 3
The wear-resisting PE plastic pipes of a kind of antibacterial that the present embodiment is provided, are made by the raw material of following parts by weight:High density polyethylene (HDPE) 100 parts, 18 parts of ethylene-ethyl acrylate copolymer, 15 parts of coumarone indene resin, 6 parts of antioxidant 1076, dibatyl phithalate 2 Part, 12 parts of butyl ether Lauxite, 5 parts of silica, 2 parts of zinc oxide, 6 parts of cumyl peroxide, 15 parts of acrylic resin, 5 parts of triphenyl phosphite, 3 parts of disulfide group 2-ethyl hexyl ethanoate stannous methide.
Embodiment 4
The wear-resisting PE plastic pipes of a kind of antibacterial that the present embodiment is provided, are made by the raw material of following parts by weight:High density polyethylene (HDPE) 110 parts, 24 parts of ethylene-ethyl acrylate copolymer, 19 parts of coumarone indene resin, 8 parts of antioxidant 1076, dibatyl phithalate 4 Part, 18 parts of butyl ether Lauxite, 9 parts of silica, 6 parts of zinc oxide, 10 parts of cumyl peroxide, acrylic resin 24 Part, 9 parts of triphenyl phosphite, 5 parts of disulfide group 2-ethyl hexyl ethanoate stannous methide and 8 parts of dibasic lead phosphite.
The production technology that above-described embodiment 1-4 is used is conventional production process, and its step is:
Above-mentioned raw materials are added to progress moderate-speed mixer mixing in high mixer together, premix is produced;Premix is put into twin-screw Heating melting extrusion plasticizing in extruder, then carries out tie rod, cooling, drying, granulation;Pellet is finally put into tube extrusion Former, is sufficiently mixed and is extruded by high-temperature heating and screw rod rotation, extruded stock is molded by die orifice, and be cooled, The tubing for meeting use requirement is made in traction, last fixed length cutting.

Claims (4)

1. a kind of wear-resisting PE plastic pipes of antibacterial, it is characterised in that be made up of the raw material of following parts by weight:High density polyethylene (HDPE) 100-110 parts, 18-24 parts of ethylene-ethyl acrylate copolymer, 15-19 parts of coumarone indene resin, 6-8 parts of antioxidant 1076, benzene 2-4 parts of dibutyl carboxylic acid, 12-18 parts of butyl ether Lauxite, 5-9 parts of silica, 2-6 parts of zinc oxide, peroxidating two are different 6-10 parts of propyl benzene, 15-24 parts of acrylic resin.
2. the wear-resisting PE plastic pipes of a kind of antibacterial according to claim 1, it is characterised in that:It also includes phosphorous triphenyl phosphate 5-9 parts of ester.
3. the wear-resisting PE plastic pipes of a kind of antibacterial according to claim 2, it is characterised in that:It also includes disulfide group acetic acid Different 3-5 parts of monooctyl ester stannous methide.
4. the wear-resisting PE plastic pipes of a kind of antibacterial according to claim 3, it is characterised in that:It also includes dibasic phosphorous 6-8 parts of lead plumbate.
CN201710252770.9A 2017-04-18 2017-04-18 A kind of wear-resisting PE plastic pipes of antibacterial Pending CN106947144A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710252770.9A CN106947144A (en) 2017-04-18 2017-04-18 A kind of wear-resisting PE plastic pipes of antibacterial

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710252770.9A CN106947144A (en) 2017-04-18 2017-04-18 A kind of wear-resisting PE plastic pipes of antibacterial

Publications (1)

Publication Number Publication Date
CN106947144A true CN106947144A (en) 2017-07-14

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Family Applications (1)

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CN201710252770.9A Pending CN106947144A (en) 2017-04-18 2017-04-18 A kind of wear-resisting PE plastic pipes of antibacterial

Country Status (1)

Country Link
CN (1) CN106947144A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107828118A (en) * 2017-12-13 2018-03-23 邓权塑业科技(湖南)有限公司 A kind of antibacterial wear-resistant plastic tubing and preparation method thereof
CN109762234A (en) * 2019-01-30 2019-05-17 李丽凤 Wear resistant polyethylene plastics and preparation method

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102417650A (en) * 2011-11-28 2012-04-18 浙江伟星新型建材股份有限公司 Wear-resistant crosslinked PE (Polyethylene) composite pipe and manufacturing method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102417650A (en) * 2011-11-28 2012-04-18 浙江伟星新型建材股份有限公司 Wear-resistant crosslinked PE (Polyethylene) composite pipe and manufacturing method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107828118A (en) * 2017-12-13 2018-03-23 邓权塑业科技(湖南)有限公司 A kind of antibacterial wear-resistant plastic tubing and preparation method thereof
CN109762234A (en) * 2019-01-30 2019-05-17 李丽凤 Wear resistant polyethylene plastics and preparation method

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Application publication date: 20170714