CN106945376B - A kind of shock resistance type vehicle glass and preparation method thereof - Google Patents

A kind of shock resistance type vehicle glass and preparation method thereof Download PDF

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Publication number
CN106945376B
CN106945376B CN201710196910.5A CN201710196910A CN106945376B CN 106945376 B CN106945376 B CN 106945376B CN 201710196910 A CN201710196910 A CN 201710196910A CN 106945376 B CN106945376 B CN 106945376B
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layer
glass
shock resistance
type vehicle
vehicle glass
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CN106945376A (en
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陈鹏
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Longkou Xingmin Safety Glass Co ltd
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Longkou Xingmin Safety Glass Co Ltd
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10064—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising at least two glass sheets, only one of which being an outer layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10779—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing polyester
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/08—Interconnection of layers by mechanical means
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60J—WINDOWS, WINDSCREENS, NON-FIXED ROOFS, DOORS, OR SIMILAR DEVICES FOR VEHICLES; REMOVABLE EXTERNAL PROTECTIVE COVERINGS SPECIALLY ADAPTED FOR VEHICLES
    • B60J1/00—Windows; Windscreens; Accessories therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0276—Polyester fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/106—Carbon fibres, e.g. graphite fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
    • B32B2264/10—Inorganic particles
    • B32B2264/102—Oxide or hydroxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/558—Impact strength, toughness
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00—Vehicles
    • B32B2605/006—Transparent parts other than made from inorganic glass, e.g. polycarbonate glazings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00—Vehicles
    • B32B2605/08—Cars

Abstract

The invention discloses a kind of shock resistance type vehicle glass and preparation method thereof, shock resistance type vehicle glass is made of anti-impacting layer, toughened glass layer, glued layer and glass-base from the outside to the core；Wherein anti-impacting layer is formed by wearing layer and tough layer；Toughened glass layer is formed by float glass tempering；Glued layer is formed by heat curing type transparent resin；Glass-base is formed by silicate-type float glass.Shock resistance type vehicle glass produced by the present invention has excellent impact resistance energy, can satisfy the performance requirement of vehicle glass, and improve the service life of vehicle glass.

Description

A kind of shock resistance type vehicle glass and preparation method thereof
Technical field
The present invention relates to glass arts, and in particular to a kind of shock resistance type vehicle glass and preparation method thereof.
Background technique
Vehicle glass be it is essential in automobile body accessories, primarily serve protective action.Vehicle glass mainly have with Lower three classes: laminated glass, tempered glass and local toughened glass can bear stronger impact force.Vehicle glass presses the position at place It sets and is divided into: front windshield, side window glass, rear seat windscreen and four kinds of skylight glass；Front windshield state compulsion regulation must It must be laminated glass, rear seat windscreen is usually the tempered glass of electrified heating silk.Vehicle glass requires have good anti-impact Hitting property and wearability, to provide good automobile experience and service life.But it is broken by the broken interlayer tempered glass of shock Glass grain after broken can rely on inertia in galloping, head-on disperse to driver, hinder the sight of driver, Influence traffic safety, especially expressway when driving, danger coefficient greatly increases.
Chinese patent CN201611073438.8 discloses a kind of vehicle glass, including interlayer strengthened glass and UV resistance Layer, the parts by weight of each component of UV resistance layer are as follows: 20-24 parts of phenyl salicylic vinegar, to tert-butyl salicylic acid vinegar porous silica 10-20 parts of silicon, nanometer titanium dioxide are admired 8-10 parts, 6-8 parts of antioxidant.But the patent provides only a kind of matching for UV resistance layer Side, does not improve the impact strength of vehicle glass.
Therefore, it is necessary to a kind of vehicle glass with excellent impact resistance energy, to meet the performance requirement of vehicle glass, with And improve the service life of vehicle glass.
Summary of the invention
The present invention is in view of the above-mentioned problems, provide a kind of shock resistance type vehicle glass and preparation method thereof.
Technical solution used by the present invention solves the above problems is: a kind of shock resistance type vehicle glass, shock resistance type vapour Vehicle glass is made of anti-impacting layer, toughened glass layer, glued layer and glass-base from the outside to the core；Wherein, anti-impacting layer is by wear-resisting Layer and tough layer are formed；Toughened glass layer is formed by float glass tempering；Glued layer is formed by heat curing type transparent resin；Glass base Layer is formed by silicate-type float glass.
Further, wearing layer adds titanium dioxide and magnesia is polymerized using polyurethane as substrate.
Further, tough layer adds filament carbon fibre and aluminium polyester is fine using polyethylene terephthalate as substrate Dimension is polymerized.
Further, the average thickness of toughened glass layer is 12mm~18mm, and surface tension is 110MPa~230MPa.
Further, glued layer is mixed to form by phenolic resin, epoxy resin and silane resin.
Another goal of the invention of the invention is to provide a kind of preparation method of above-mentioned shock resistance type vehicle glass, including Following steps:
Step S1, anti-impacting layer preparation: urethane monomer is melted, and titanium dioxide is added and magnesia is uniformly mixed, shape At paste-like, pours into film-making machine and produce wear-resisting layer film；Long filament carbon is added into the polyethylene terephthalate of fusing Fiber and aluminium polyester fiber stir evenly to form molten material, and tough layer is made in blow molding；Wearing layer and the pressurization of tough layer is multiple It closes to get anti-impacting layer；
The obtained anti-impacting layer of step S1 is bonded in toughened glass layer, obtains shock resistance composite layer by step S2；
Step S2 is obtained shock resistance composite layer and glued layer and glass-base progress is hot-forming, after molding by step S3 Glass carry out 30min~60min heat preservation heat treatment, natural cooling is to get shock resistance type vehicle glass.
Further, in step S1, the thickness of wearing layer are as follows: 0.05mm~0.2mm.
Further, in step S1, the thickness of tough layer are as follows: 0.1mm~0.5mm.
Further, in step S3, hot-forming process conditions are as follows: temperature is 115 DEG C~125 DEG C, and pressure is 3.5MPa~6MPa.
Further, the treatment temperature in step S3, when heat preservation is heat-treated are as follows: 65 DEG C~85 DEG C.
The invention has the advantages that
1. vehicle glass produced by the present invention is prepared using multilayered structure, there is good shock resistance and resist and wear Permeability energy can effectively improve the tolerance and service life of vehicle glass；
2. the preparation method that the present invention prepares vehicle glass is easy, easily operated, there is universality.
Specific embodiment
The embodiment of the present invention is described in detail below, but what the present invention can be defined by the claims and cover Multitude of different ways is implemented.
Embodiment 1
A kind of shock resistance type vehicle glass, shock resistance type vehicle glass is from the outside to the core by anti-impacting layer, toughened glass layer, glue Tie layer and glass-base composition；Wherein, anti-impacting layer is formed by wearing layer and tough layer；Toughened glass layer is by float glass tempering It is formed；Glued layer is formed by heat curing type transparent resin；Glass-base is formed by silicate-type float glass.Wherein, wearing layer with Polyurethane is substrate, adds titanium dioxide and magnesia is polymerized；Tough layer using polyethylene terephthalate as substrate, Addition filament carbon fibre and aluminium polyester fiber are polymerized；The average thickness of toughened glass layer is 12mm, and surface tension is 110MPa；Glued layer is mixed to form by phenolic resin, epoxy resin and silane resin.
Embodiment 2
A kind of shock resistance type vehicle glass, shock resistance type vehicle glass is from the outside to the core by anti-impacting layer, toughened glass layer, glue Tie layer and glass-base composition；Wherein, anti-impacting layer is formed by wearing layer and tough layer；Toughened glass layer is by float glass tempering It is formed；Glued layer is formed by heat curing type transparent resin；Glass-base is formed by silicate-type float glass.Wherein, wearing layer with Polyurethane is substrate, adds titanium dioxide and magnesia is polymerized；Tough layer using polyethylene terephthalate as substrate, Addition filament carbon fibre and aluminium polyester fiber are polymerized；The average thickness of toughened glass layer is 18mm, and surface tension is 230MPa；Glued layer is mixed to form by phenolic resin, epoxy resin and silane resin.
Embodiment 3
A kind of shock resistance type vehicle glass, shock resistance type vehicle glass is from the outside to the core by anti-impacting layer, toughened glass layer, glue Tie layer and glass-base composition；Wherein, anti-impacting layer is formed by wearing layer and tough layer；Toughened glass layer is by float glass tempering It is formed；Glued layer is formed by heat curing type transparent resin；Glass-base is formed by silicate-type float glass.Wherein, wearing layer with Polyurethane is substrate, adds titanium dioxide and magnesia is polymerized；Tough layer using polyethylene terephthalate as substrate, Addition filament carbon fibre and aluminium polyester fiber are polymerized；The average thickness of toughened glass layer is 15mm, and surface tension is 170MPa；Glued layer is mixed to form by phenolic resin, epoxy resin and silane resin.
Embodiment 4
A kind of preparation method of shock resistance type vehicle glass, comprising the following steps:
Step S1, anti-impacting layer preparation: urethane monomer is melted, and titanium dioxide is added and magnesia is uniformly mixed, shape At paste-like, the wear-resisting layer film produced with a thickness of 0.12mm is poured into film-making machine；To the polyethylene terephthalate of fusing Filament carbon fibre and aluminium polyester fiber are added in ester, stirs evenly to form molten material, blow molding is made with a thickness of 0.13mm's Tough layer；Wearing layer and the pressurization of tough layer is compound to get anti-impacting layer；
The obtained anti-impacting layer of step S1 is bonded in toughened glass layer, obtains shock resistance composite layer by step S2；
Step S2 is obtained shock resistance composite layer and glued layer and glass-base temperature is 120 DEG C, pressure is by step S3 Carry out hot-forming under conditions of 4.8MPa, glass after molding is carried out under the conditions of 75 DEG C of temperature at the heat preservation hot of 45min Reason, natural cooling is to get shock resistance type vehicle glass.
Embodiment 5
A kind of preparation method of shock resistance type vehicle glass, comprising the following steps:
Step S1, anti-impacting layer preparation: urethane monomer is melted, and titanium dioxide is added and magnesia is uniformly mixed, shape At paste-like, the wear-resisting layer film produced with a thickness of 0.05mm is poured into film-making machine；To the polyethylene terephthalate of fusing Filament carbon fibre and aluminium polyester fiber are added in ester, stirs evenly to form molten material, blow molding is made with a thickness of 0.05mm's Tough layer；Wearing layer and the pressurization of tough layer is compound to get anti-impacting layer；
The obtained anti-impacting layer of step S1 is bonded in toughened glass layer, obtains shock resistance composite layer by step S2；
Step S2 is obtained shock resistance composite layer and glued layer and glass-base temperature is 115 DEG C, pressure is by step S3 Carry out hot-forming under conditions of 3.5MPa, glass after molding is carried out under the conditions of 65 DEG C of temperature at the heat preservation hot of 30min Reason, natural cooling is to get shock resistance type vehicle glass.
Embodiment 6
A kind of preparation method of shock resistance type vehicle glass, comprising the following steps:
Step S1, anti-impacting layer preparation: urethane monomer is melted, and titanium dioxide is added and magnesia is uniformly mixed, shape At paste-like, the wear-resisting layer film produced with a thickness of 0.2mm is poured into film-making machine；To the polyethylene terephthalate of fusing Middle addition filament carbon fibre and aluminium polyester fiber stir evenly to form molten material, and blow molding is made with a thickness of the tough of 0.2mm Layer；Wearing layer and the pressurization of tough layer is compound to get anti-impacting layer；
The obtained anti-impacting layer of step S1 is bonded in toughened glass layer, obtains shock resistance composite layer by step S2；
Step S2 is obtained shock resistance composite layer and glued layer and glass-base temperature is 125 DEG C, pressure is by step S3 Carried out under conditions of 6MPa it is hot-forming, glass after molding carried out under the conditions of 85 DEG C of temperature 60min heat preservation heat treatment, Natural cooling is to get shock resistance type vehicle glass.
Experimental example 1
According to GB9656-2003 " automotive safety glass " and GB5137.1-2002 " automotive safety glass test method the 1st Part: mechanical property test ", 1~sample of sample 6 is labeled as to shock resistance type vehicle glass made from Examples 1 to 6, to sample The mechanical property of 1~sample of product 6 is tested, and test result is as shown in table 1.
The mechanical experimental results for the shock resistance type vehicle glass that table 1 is prepared
These are only the preferred embodiment of the present invention, is not intended to restrict the invention, for those skilled in the art For member, the invention may be variously modified and varied.All within the spirits and principles of the present invention, it is made it is any modification, Equivalent replacement, improvement etc., should all be included in the protection scope of the present invention.

Claims (7)

1. a kind of shock resistance type vehicle glass, which is characterized in that the shock resistance type vehicle glass from the outside to the core by anti-impacting layer, Toughened glass layer, glued layer and glass-base composition；Wherein the anti-impacting layer is formed by wearing layer and tough layer；The tempering Glassy layer is formed by float glass tempering；The glued layer is formed by heat curing type transparent resin；The glass-base is by silicate Type float glass is formed；The wearing layer adds titanium dioxide and magnesia is prepared using polyurethane as substrate；It is described tough Layer adds filament carbon fibre and aluminium polyester fiber is prepared using polyethylene terephthalate as substrate；The shock resistance The preparation method of type vehicle glass, comprising the following steps:
Step S1, anti-impacting layer preparation: by melt polyurethane, being added titanium dioxide and magnesia be uniformly mixed, form paste-like, It pours into film-making machine and produces wear-resisting layer film；Filament carbon fibre is added into the polyethylene terephthalate of fusing and aluminium is poly- Ester fiber stirs evenly to form molten material, and tough layer is made in blow molding；Wearing layer and the pressurization of tough layer is compound to get anti- Shock ply；
The obtained anti-impacting layer of step S1 is bonded in toughened glass layer, obtains shock resistance composite layer by step S2；
Step S2 is obtained shock resistance composite layer and carries out hot-forming, glass after molding with glued layer and glass-base by step S3 Glass carries out the heat preservation heat treatment of 30min~60min, and natural cooling is to get the shock resistance type vehicle glass.
2. shock resistance type vehicle glass according to claim 1, which is characterized in that the average thickness of the toughened glass layer For 12mm~18mm, surface tension is 110MPa~230MPa.
3. shock resistance type vehicle glass according to claim 1, which is characterized in that the glued layer is by phenolic resin, ring Oxygen resin and silane resin are mixed to form.
4. shock resistance type vehicle glass according to claim 1, which is characterized in that in step S1, the thickness of the wearing layer Degree are as follows: 0.05mm~0.2mm.
5. shock resistance type vehicle glass according to claim 1, which is characterized in that in step S1, the thickness of the tough layer Degree are as follows: 0.1mm~0.5mm.
6. shock resistance type vehicle glass according to claim 1, which is characterized in that described hot-forming in step S3 Process conditions are as follows: temperature is 115 DEG C~125 DEG C, and pressure is 3.5MPa~6MPa.
7. shock resistance type vehicle glass according to claim 1, which is characterized in that in step S3, the heat preservation heat treatment When treatment temperature are as follows: 65 DEG C~85 DEG C.
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CN102602084A (en) * 2012-03-07 2012-07-25 奇瑞汽车股份有限公司 Automobile high polymer glass and preparation method thereof
CN104553207A (en) * 2014-12-12 2015-04-29 中国航空工业集团公司北京航空材料研究院 Safety glass capable of preventing splashing during breaking

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