CN106938325B - The pouring procedure of low overheat rare earth steel and Aluminum steel - Google Patents

The pouring procedure of low overheat rare earth steel and Aluminum steel Download PDF

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Publication number
CN106938325B
CN106938325B CN201710134528.1A CN201710134528A CN106938325B CN 106938325 B CN106938325 B CN 106938325B CN 201710134528 A CN201710134528 A CN 201710134528A CN 106938325 B CN106938325 B CN 106938325B
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steel
rare earth
pipe end
filling pipe
pouring procedure
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CN106938325A (en
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李峰
吴章忠
何建中
智建国
宋海
马利
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Baotou Iron and Steel Group Co Ltd
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Baotou Iron and Steel Group Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/16Controlling or regulating processes or operations
    • B22D11/18Controlling or regulating processes or operations for pouring

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Continuous Casting (AREA)

Abstract

It is that time one heat steel Metal in Tundish degree of superheat is each poured in continuous casting process is 15-25 DEG C, each pouring time non-one heat steel Metal in Tundish degree of superheat is 5-15 DEG C the present invention relates to the pouring procedure of a kind of low overheat rare earth steel and Aluminum steel;And the inner wall of molten steel and collector nozzle is not directly contacted with, filling pipe end bottom is equal with the inside radius of collector nozzle the top, and the angle that the lower half portion outer surface of filling pipe end and vertical direction are formed is α, and α ≠ 0.Pouring procedure provided by the invention realizes the cast cold technology of rare earth steel and Aluminum steel, and sequence casting may be implemented, and does not block the mouth of a river.In addition, realizing permanent pulling rate casting production, this is highly beneficial to the quality of steel, and also brings very big benefit to organization of production since rare earth steel and Aluminum steel do not block the mouth of a river.

Description

The pouring procedure of low overheat rare earth steel and Aluminum steel
Technical field
The present invention relates to field of iron and steel smelting, in particular to the pouring procedure of a kind of low overheat rare earth steel and Aluminum steel.
Background technique
In the continuous casting process of metallurgical industry, realize that the low overheat technology of molten steel is highly beneficial to grid electricity fee cost is reduced, but Since the degree of superheat of molten steel is low, nozzle blocking will lead to, therefore, continuous casting process is industrially generally required often to pour in time one heat steel Between Baogang's water the degree of superheat >=25 DEG C (being poured smoothly to guarantee to open), often pour the degree of superheat >=15 of time non-one heat steel Metal in Tundish ℃。
Multiple studies have shown that: the raising of RE Elements on Steel material performance is advantageous.Rare earth can reduce the grain size of steel, mention The toughness and low temperature impact properties of high steel improve the anti-lamellar tearing ability etc. in slab thickness direction.But it is dilute due to being limited by Block continuous casting sprue in native steel production process and interfere steel-making this key problem of continuous production, the exploitation of rare earth steel and using by Greatly limitation, is nearly at dead state at present.
Aluminum steel is also common steel grade, but since Aluminum steel is also easy blocking continuous casting sprue, influences the normal production of continuous casting, Therefore it is forced to pour time production (the furnace number that company pours is few) using small, therefore increases the cost of steel-making.
Patent " the compound water mouth for casting rare-earth steel " (number of patent application applied according to Shanghai No.3 Iron &. Steel Plant Zhao Suochen et al. For CN86200556U) introduction, which provides a kind of Compound Water that can prevent nozzle clogging for steel smelting Mouthful, its main feature is that mouth of a river inner wall is equipped with > 95%SiO2Vitreous silica is the bushing pipe of material.In rare earth steel casting process, by In the change of mouth of a river refractory material material, nozzle clogging physical property matter is changed, and improves re inclusion and mouth of a river inner wall The interface energy of storeroom, so as to avoid the stagnant knot of re inclusion, it is therefore prevented that the generation of dross.
But due to the SiO in the above-mentioned mouth of a river2Be easy to be washed off by steel fall into molten steel formed field trash and it is not extensive It uses.
Patent " the conticasting technology for feeding rare-earth wires into tundish " (number of patent application applied according to Institutes Of Technology Of Nanjing Zhang Xuesong et al. 01127004.7) to introduce, which is the method for avoiding rare earth steel water blocking mouthh from using tundish feeding rare-earth wires, but due to the party Content of rare earth is uneven in the molten steel of method and influences the normal production of continuous casting without being widely adopted.
According to patent " continuous casting pouring basket rare earth adding technology " (patent application for appointing newly-built et al. application of Baotou Iron and Steel Company Number for 200510053297.9) introduce, the patent also use tundish feeding rare earth technique, there is also content of rare earth for the patent Non-uniform problem.
Patent " the anti-blocking immersion of special steel continuous casting applied according to Sinosteel Luoyang Institute of Refractories Liu Guoqi et al. The mouth of a river " (number of patent application 200410060355.6) is introduced, which is made of the resistance to material of multilayer various material, but practical The nozzle blocking problem containing rare earth steel and Aluminum steel is not can solve still in.
According to patent " a method of prevent continuous-casting of steel billet nozzle blocking " (patent of Northeastern University Yu Jingkun et al. application Application No. is 201510110081.5) introducing, which is zero by mouth of a river outer surface and the earth or current potential using conductive material Position connection, makes the current potential zero of mouth of a river inner surface, reduces or eliminates migration and adherency of the steel inclusion to mouth of a river inner surface, Preventing nozzle blocking, " present invention is migrated from field trash to mouth of a river inner surface and the mechanism of adherency, fundamentally the company of solving Cast the blockage problem at the mouth of a river.
But the patent does not have been widely adopted due to operating at the scene upper difficult.
According to the utility model patent for being permitted Rongchang County et al. application of Laiwu Iron Co., Ltd., " one kind prevents Al2O3 attached The continuous casting tundish apparatus of mouth of a river wall " (number of patent application 200820016118.3) introduce, which thinks that " filling pipe end is first Dross sequentially extends downwardly into collector nozzle ... ", therefore its groundwork is placed on: ' tundish apparatus is that stopper can rotate 0- 10 °, filling pipe end inner cavity is inverted tubaeform structure ' ";And require the inner wall roughness of filling pipe end inner cavity at 0-10 microns.
Firstly, the patent is utility model, it is desirable that protection is a kind of tundish apparatus, is not involved with collector nozzle, more It is not directed to the improvement of continuous casting process;In addition, on nozzle blocking producing cause and caused by influence also to analyze it is not thorough.The patent Think " filling pipe end elder generation dross sequentially extends downwardly into collector nozzle ... (in summary of the invention chapters and sections) ", therefore main attention is put On continuous casting tundish apparatus and filling pipe end.
In fact, in the production accident that nozzle blocking occurs, the overwhelming majority is that collector nozzle blocks, the reason for this is that around collector nozzle For air, even if environment temperature is also 35 DEG C or so, and the liquid steel temperature in the mouth of a river is about 1450-1550 DEG C, therefore in summer When molten steel flows through collector nozzle, liquid steel temperature necessarily declines, and the Al in steel2O3、REAlO3The high-melting-points object such as (rare earth aluminate) Matter is adhered to collector nozzle inner surface since temperature reduces, and with the progress of production, the more poly- these substances the more, eventually cause water Mouth blocking.Such case is more obvious in winter.After collector nozzle blocking, if to change the mouth of a river, casting stream is first closed, then again will The mouth of a river of preprepared baked (generally to toast 2 hours, and temperature reaches 1000 DEG C or more) is changed, then again Open casting stream.Very big inconvenience is brought due to the uncertainty that the blocking mouth of a river occurs, thus to organization of production.Therefore replacement collector nozzle It is influenced to production bring very big.And filling pipe end generally blocks several since in tundish, heat-retaining condition is good Rate is very small.Therefore, the blocking for studying the mouth of a river should be then counter again to shift filling pipe end, and filling pipe end onto using collector nozzle as break-through point Also different establish a capital is inverted tubaeform structure for inner cavity, and which increase the difficulty of mouth of a river production.
Therefore, for reduce molten steel the degree of superheat and prevent nozzle blocking, collector nozzle should be made not contact directly with molten steel first, Then filling pipe end carries out corresponding change again.
In addition, that it is desirable to mouth of a river inner walls is more more smooth better, but it is limited by refractory nozzle itself and requires have certain gas Cell size is difficult to realize in actual production to improve mouth of a river thermal shock resistance.
Summary of the invention
In view of this, the present invention provides the pouring procedure of a kind of low overheat rare earth steel and Aluminum steel.
The present invention provides the pouring procedure of a kind of low overheat rare earth steel and Aluminum steel, each pours in continuous casting process time The one heat steel Metal in Tundish degree of superheat is 15-25 DEG C, and each pouring time non-one heat steel Metal in Tundish degree of superheat is 5-15 DEG C; And the inner wall of molten steel and collector nozzle is not directly contacted with, filling pipe end bottom is equal with the inside radius of collector nozzle the top, filling pipe end Lower half portion outer surface and the angle that is formed of vertical direction be α, and α ≠ 0.
Further, the value range of the α is 0~90 °, does not include 90 °.
Further, suitable for being poured steel in the steel grade and steel of content of rare earth 0~10%, aluminium contains the pouring procedure The steel grade of amount 0~25%.
Further, the pouring procedure is suitable for pouring for small billet, bloom, round billet, Hot Metal in Beam Blank and slab section Note.
Further, it specifically includes: the molten steel that the degree of superheat is 5~25 DEG C being poured since tundish, rare earth in steel Content 0~10%, aluminium content 0~25% in steel;The angle that the lower half portion outer surface of steel filling pipe end is formed with vertical direction is The inner wall of α, and α ≠ 0, molten steel and collector nozzle is not directly contacted with, and molten steel is not and in the inner wall and collector nozzle of filling pipe end lower half portion Wall is directly contacted into continuous cast mold, and continuous casting even pours 20 furnaces with filling pipe end non-nodulating.
Pouring procedure provided by the invention realizes the cast cold technology of rare earth steel and Aluminum steel, and more furnaces may be implemented Company pours, and does not block the mouth of a river.It averagely being reduced in terms of 5 DEG C by the ton steel degree of superheat, then the electricity charge of steel saving per ton are about 1.1 yuan/ton, 100 The electricity charge that ten thousand tons of steel are saved are 1,100,000 yuan, meet the requirement of national energy conservation and emission reduction.In addition, since rare earth steel and Aluminum steel do not block up Fill in the mouth of a river, realize the casting production of permanent pulling rate, this is highly beneficial to the quality of steel, and organization of production is also brought it is very big good Place.
Detailed description of the invention
In order to more clearly explain the embodiment of the invention or the technical proposal in the existing technology, to embodiment or will show below There is attached drawing needed in technical description to be briefly described.
Fig. 1 is the structural representation of the continuous casting sprue and its attachment of cast cold rare earth steel and Aluminum steel in the embodiment of the present invention Figure.
Description of symbols:
1- stopper 21- bakie working lining 22- tundish permanent layer 2- tundish
3- brick cup 4- filling pipe end 5- slide plate 6- collector nozzle 7- molten steel
Specific embodiment
The invention discloses the pouring procedure of a kind of low overheat rare earth steel and Aluminum steel, those skilled in the art can be borrowed Reflect present disclosure, is suitably modified realization of process parameters.In particular, it should be pointed out that all similar substitutions and modifications are to this field It is it will be apparent that they are considered as being included in the present invention for technical staff.Method and application of the invention has passed through Preferred embodiment is described, related personnel obviously can not depart from the content of present invention, in spirit and scope to described herein Methods and applications be modified or appropriate changes and combinations, carry out implementation and application the technology of the present invention.
The present invention provides the pouring procedure of a kind of low overheat rare earth steel and Aluminum steel, is: each pouring in continuous casting process The secondary one heat steel Metal in Tundish degree of superheat is 15-25 DEG C, and each pouring time non-one heat steel Metal in Tundish degree of superheat is 5-15 ℃;And the inner wall of molten steel and collector nozzle is not directly contacted with, filling pipe end bottom is equal with the inside radius of collector nozzle the top, upper water Mouthful the angle that is formed of lower half portion outer surface and vertical direction be α, and α ≠ 0.
Referring to Figure 1, which is the structural representation of the continuous casting sprue and its attachment for cast cold rare earth steel and Aluminum steel Figure, include: in above-mentioned attachment stopper 1, bakie working lining 21, tundish permanent layer 22, tundish 2, brick cup 3, filling pipe end 4, Slide plate 5, collector nozzle 6 and molten steel 7.
4 lower end of filling pipe end is equal with the inside radius of 6 upper end of collector nozzle, and 7 collector nozzle of molten steel, 6 inner wall is not directly contacted with, upper water The angle that mouthful 4 lower half portion outer surfaces and vertical direction are formed is α, and α ≠ 0.
Preferably, the value range of the α is 0~90 °, does not include 90 °.
Above-mentioned pouring procedure provided by the invention is suitable for being poured steel in the steel grade and steel of content of rare earth 0~10% The steel grade of aluminium content 0~25%.The pouring procedure is suitable for pouring for small billet, bloom, round billet, Hot Metal in Beam Blank and slab section Note.
Invention is directly contacted due to making molten steel not be particularly easy to reduced collector nozzle with temperature, and connects molten steel with filling pipe end The area of touching minimizes, to realize the cast cold of rare earth steel and Aluminum steel, and continuous casting is even poured 20 furnaces and do not tied with filling pipe end Tumor, improves that (mouth of a river does not block, and is advantageously implemented the permanent pulling rate of continuous casting, and permanent pulling rate is to mentioning to the steel of rare earth steel and Aluminum steel The quality of high slab is very necessary), cost reduce and continuous production it is highly beneficial.
Specifically, above-mentioned pouring procedure includes the following steps:
The molten steel that the degree of superheat is 5~25 DEG C is poured since tundish, content of rare earth 0~10% in steel, aluminium contains in steel Amount 0~25%;The angle that the lower half portion outer surface of steel filling pipe end and vertical direction are formed is α, and α ≠ 0, molten steel and collector nozzle Inner wall be not directly contacted with, molten steel does not contact directly with the inner wall of filling pipe end lower half portion and collector nozzle inner wall into continuous casting crystallining Device, continuous casting even pour 20 furnaces with filling pipe end non-nodulating.
Pouring procedure provided by the invention realizes the cast cold technology of rare earth steel and Aluminum steel, and more furnaces may be implemented Company pours, and does not block the mouth of a river.It averagely being reduced in terms of 5 DEG C by the ton steel degree of superheat, then the electricity charge of steel saving per ton are about 1.1 yuan/ton, 100 The electricity charge that ten thousand tons of steel are saved are 1,100,000 yuan, meet the requirement of national energy conservation and emission reduction.In addition, since rare earth steel and Aluminum steel do not block up Fill in the mouth of a river, realize the casting production of permanent pulling rate, this is highly beneficial to the quality of steel, and organization of production is also brought it is very big good Place.
Below with reference to embodiment, the present invention is further explained:
Embodiment 1
(1) by the degree of superheat the be 5-13 DEG C ML08Al (non-one heat steel) of (degree of superheat average value is 9.3 DEG C), molten steel is therefrom Between packet start to be poured;
(2) content of rare earth 0.1% in steel, aluminium content 0.05% in steel,
(3) angle that the lower half portion outer surface of filling pipe end and vertical direction are formed is 20 °.
(4) molten steel directly contacts not with the inner wall of filling pipe end lower half portion and collector nozzle inner wall enters continuous small-billet casting crystallization Device.
(5) continuous casting even pours 28 furnaces with filling pipe end non-nodulating.
Embodiment 2
(1) by the degree of superheat the be 6-11 DEG C 50W600 (non-one heat steel) of (degree of superheat average value is 9.6 DEG C), molten steel is therefrom Between packet start to be poured;
(2) content of rare earth 0.6% in steel, aluminium content 0.3% in steel,
(3) angle that the lower half portion outer surface of filling pipe end and vertical direction are formed is 25 °.
(4) molten steel directly contacts not with the inner wall of filling pipe end lower half portion and collector nozzle inner wall enters sheet billet continuous casting crystallization Device.
(5) continuous casting even pours 22 furnaces with filling pipe end non-nodulating.
Embodiment 3
(1) by the degree of superheat the be 6-13 DEG C Q355NH (non-one heat steel) of (degree of superheat average value is 9.1 DEG C), molten steel is therefrom Between packet start to be poured;
(2) content of rare earth 0.08% in steel, aluminium content 0.03% in steel,
(3) angle that the lower half portion outer surface of filling pipe end and vertical direction are formed is 25 °.
(4) molten steel directly contacts not with the inner wall of filling pipe end lower half portion and collector nozzle inner wall enters casting for shaped blank continuous crystallization Device.
(5) continuous casting even pours 21 furnaces with filling pipe end non-nodulating.
Embodiment 4
(1) by the degree of superheat be 7-13 DEG C (degree of superheat average value is 9.4 DEG C) 20G (non-one heat steel) molten steel from centre Packet starts to be poured;
(2) content of rare earth 0.12% in steel, aluminium content is 0% in steel,
(3) angle that the lower half portion outer surface of filling pipe end and vertical direction are formed is 30 °.
(4) molten steel directly contacts not with the inner wall of filling pipe end lower half portion and collector nozzle inner wall enters round billet continuous casting crystallization Device.
(5) continuous casting even pours 25 furnaces with filling pipe end non-nodulating.
Embodiment 5
(1) by the degree of superheat be 6-12 DEG C (degree of superheat average value is 9.1 DEG C) U71Mn (non-one heat steel) molten steel from centre Packet starts to be poured;
(2) content of rare earth 0.06% in steel, aluminium content is 0% in steel,
(3) angle that the lower half portion outer surface of filling pipe end and vertical direction are formed is 30 °.
(4) molten steel directly contacts not with the inner wall of filling pipe end lower half portion and collector nozzle inner wall enters bloom continuous casting crystallization Device.
(5) continuous casting even pours 23 furnaces with filling pipe end non-nodulating.
Embodiment 6
(1) U71Mn (one heat steel) molten steel that the degree of superheat is 19 DEG C is poured since tundish;
(2) content of rare earth 0.06% in steel, aluminium content is 0% in steel,
(3) angle that the lower half portion outer surface of filling pipe end and vertical direction are formed is 30 °.
(4) molten steel directly contacts not with the inner wall of filling pipe end lower half portion and collector nozzle inner wall enters bloom continuous casting crystallization Device.
(5) molten steel is smoothly opened and is poured, and subsequent molten steel is normally poured.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also answered It is considered as protection scope of the present invention.

Claims (5)

1. the pouring procedure of a kind of low overheat rare earth steel and Aluminum steel, which is characterized in that each pour secondary first in continuous casting process The furnace steel Metal in Tundish degree of superheat is 15-25 DEG C, and each pouring time non-one heat steel Metal in Tundish degree of superheat is 5-15 DEG C;And steel The inner wall of water and collector nozzle is not directly contacted with, and filling pipe end bottom is equal with the inside radius of collector nozzle the top, under filling pipe end The angle that half part outer surface and vertical direction are formed is α, and α ≠ 0.
2. pouring procedure according to claim 1, which is characterized in that the value range of the α is 0~90 °, is not included 90°。
3. pouring procedure according to claim 1, which is characterized in that pouring procedure rare earth suitable for casting steel contains The steel grade of aluminium content 0~25% in the steel grade and steel of amount 0~10%.
4. pouring procedure according to claim 1, which is characterized in that the pouring procedure be suitable for small billet, bloom, The casting of round billet, Hot Metal in Beam Blank and slab section.
5. pouring procedure according to any one of claims 1 to 4, which is characterized in that it is specifically included: being by the degree of superheat 5~25 DEG C of molten steel is poured since tundish, content of rare earth 0~10% in steel, aluminium content 0~25% in steel;Steel filling pipe end Lower half portion outer surface and the angle that is formed of vertical direction be α, the inner wall of and α ≠ 0, molten steel and collector nozzle is not directly contacted with, Molten steel is not contacted directly with the inner wall of filling pipe end lower half portion and collector nozzle inner wall into continuous cast mold, and continuous casting even pours 20 furnaces or more Mouth of a river non-nodulating.
CN201710134528.1A 2017-03-08 2017-03-08 The pouring procedure of low overheat rare earth steel and Aluminum steel Active CN106938325B (en)

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Publication number Priority date Publication date Assignee Title
CN108296463B (en) * 2017-10-26 2021-01-01 新疆八一钢铁股份有限公司 Method for controlling superheat degree of continuous casting tundish

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CN201136051Y (en) * 2008-01-04 2008-10-22 莱芜钢铁股份有限公司 Continuous casting tundish apparatus for preventing Al2O3 from adhering on downspout wall
CN201913239U (en) * 2010-12-24 2011-08-03 莱芜钢铁股份有限公司 Submersed nozzles with novel structures
CN203992363U (en) * 2014-08-14 2014-12-10 沈阳金纳新材料股份有限公司 Nickel and the closed middle water containing opening of nickel alloy vacuum melting horizontal continuous casting

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JP2008126258A (en) * 2006-11-20 2008-06-05 Tokyo Yogyo Co Ltd Casting nozzle for molten metal provided with heat insulation sleeve
JP2011110561A (en) * 2009-11-25 2011-06-09 Jfe Steel Corp Method for continuously casting steel

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Publication number Priority date Publication date Assignee Title
CN2366206Y (en) * 1999-01-26 2000-03-01 修昌珉 Sliding runner device for intermediate ladle
CN201136051Y (en) * 2008-01-04 2008-10-22 莱芜钢铁股份有限公司 Continuous casting tundish apparatus for preventing Al2O3 from adhering on downspout wall
CN201913239U (en) * 2010-12-24 2011-08-03 莱芜钢铁股份有限公司 Submersed nozzles with novel structures
CN203992363U (en) * 2014-08-14 2014-12-10 沈阳金纳新材料股份有限公司 Nickel and the closed middle water containing opening of nickel alloy vacuum melting horizontal continuous casting

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