CN106935416A - A kind of starfish shape δ MnO2The preparation method of nanometer sheet/carbon fiber paper combination electrode material - Google Patents
A kind of starfish shape δ MnO2The preparation method of nanometer sheet/carbon fiber paper combination electrode material Download PDFInfo
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- CN106935416A CN106935416A CN201710013930.4A CN201710013930A CN106935416A CN 106935416 A CN106935416 A CN 106935416A CN 201710013930 A CN201710013930 A CN 201710013930A CN 106935416 A CN106935416 A CN 106935416A
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- carbon fiber
- electrode material
- fiber paper
- combination electrode
- nanometer sheet
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- 229920000049 Carbon (fiber) Polymers 0.000 title claims abstract description 35
- 239000004917 carbon fiber Substances 0.000 title claims abstract description 35
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 35
- 241000258957 Asteroidea Species 0.000 title claims abstract description 31
- 239000007772 electrode material Substances 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 238000001035 drying Methods 0.000 claims abstract description 14
- 238000000034 method Methods 0.000 claims abstract description 9
- 238000001027 hydrothermal synthesis Methods 0.000 claims abstract description 7
- 239000011259 mixed solution Substances 0.000 claims abstract description 7
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 claims abstract description 7
- 238000005406 washing Methods 0.000 claims abstract description 7
- 239000000047 product Substances 0.000 claims description 14
- 239000012286 potassium permanganate Substances 0.000 claims description 8
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 6
- BHZRJJOHZFYXTO-UHFFFAOYSA-L potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 claims description 4
- 235000019252 potassium sulphite Nutrition 0.000 claims description 4
- 235000010265 sodium sulphite Nutrition 0.000 claims description 4
- 229910006364 δ-MnO2 Inorganic materials 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 230000035484 reaction time Effects 0.000 claims description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Inorganic materials O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 abstract description 33
- 239000000463 material Substances 0.000 abstract description 7
- 230000015572 biosynthetic process Effects 0.000 abstract description 4
- 239000002994 raw material Substances 0.000 abstract description 3
- 238000003786 synthesis reaction Methods 0.000 abstract description 3
- 239000003792 electrolyte Substances 0.000 abstract description 2
- 239000007769 metal material Substances 0.000 abstract description 2
- 239000000835 fiber Substances 0.000 abstract 1
- 150000002696 manganese Chemical class 0.000 abstract 1
- 239000002055 nanoplate Substances 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 8
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 230000005611 electricity Effects 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 238000013019 agitation Methods 0.000 description 4
- 239000008367 deionised water Substances 0.000 description 4
- 229910021641 deionized water Inorganic materials 0.000 description 4
- 239000012153 distilled water Substances 0.000 description 4
- 238000000634 powder X-ray diffraction Methods 0.000 description 4
- 239000003990 capacitor Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000013078 crystal Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- 239000004285 Potassium sulphite Substances 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000002322 conducting polymer Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 239000000696 magnetic material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/84—Processes for the manufacture of hybrid or EDL capacitors, or components thereof
- H01G11/86—Processes for the manufacture of hybrid or EDL capacitors, or components thereof specially adapted for electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/24—Electrodes characterised by structural features of the materials making up or comprised in the electrodes, e.g. form, surface area or porosity; characterised by the structural features of powders or particles used therefor
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/32—Carbon-based
- H01G11/40—Fibres
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/46—Metal oxides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
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- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
The invention belongs to Inorganic Non-metallic Materials preparation field, more particularly to a kind of starfish shape δ MnO2The preparation method of nanometer sheet/carbon fiber paper combination electrode material.It is sufficiently mixed dissolving in aqueous with the sulphite of soluble manganese salt and solubility, will clean and dried carbon fiber paper immerses above-mentioned mixed solution, and by hydro-thermal reaction, washing obtains starfish shape δ MnO after drying2Nanometer sheet/carbon fiber paper combination electrode material.The raw material of preparation method of the present invention is cheap and easy to get, synthesis technique is simple and easy to apply, preparation cost is low, contamination-free is produced, products therefrom novel in shape, and is closely grown on the fiber rod of carbon fiber paper.Synthesized manganese dioxide, the diameter of its extra large star topology between 300~500nm, the thickness of starfish shape nanometer sheet between 10~30nm, and synthesized material be uniformly dispersed, pattern it is homogeneous, the electrode material of ultracapacitor can be directly used as.In 1mol/L NaSO4In electrolyte, when current density is 1A/g, the specific capacitance value of gained combination electrode material is up to 336F/g.
Description
Technical field
The invention belongs to Inorganic Non-metallic Materials preparation field, more particularly to a kind of starfish shape δ-MnO2Nanometer sheet/carbon fiber
The preparation method of paper combination electrode material.
Background technology
Ultracapacitor is due to its power density high, fast charge-discharge velocity, the cycle life of length and more traditional electricity
Container energy density higher and as very important energy storage device of future generation, increasingly paid close attention to by people.Super electricity
The performance of container depends primarily on electrode material, and report mainly includes carbon material, metal as electrode material for super capacitor
Oxide/hydroxide and conducting polymer materials, among various materials, manganese dioxide is due to its unique physical chemistry
Matter should widely be made catalyst, magnetic material, lithium ion battery and ultracapacitor.Particularly, manganese dioxide is because its valency
Lattice are cheap, raw material resources are abundant, environment-friendly and up to 1370F/g theoretical specific volume and be considered as very promising super
The electrode material of level capacitor.
The chemical property of electrode material largely be subject to themselves crystal structure, size, dimension, especially
It is the influence of appearance structure, because these factors can largely influence the electric conductivity and structural stability of electrode material
And electrolyte ion is in the diffusion rate of electrode material surface.In the manganese dioxide of different-shape, three-dimensional sheet structure
Manganese dioxide is received significant attention because it is generally configured with preferable chemical property.
But, material of the synthesis with three-dimensional appearance is difficult in the case of without any template or surfactant
Material.At present, prepare the manganese dioxide of starfish shape nanometer sheet pattern using a step Hydrothermal Synthesiss there is not been reported.
The content of the invention
The present invention prepares starfish shape δ-MnO by a step hydrothermal synthesis method2Nanometer sheet/carbon fiber paper combination electrode material
Material.
The present invention provides a kind of starfish shape δ-MnO2The preparation method of nanometer sheet/carbon fiber paper combination electrode material, it is special
Levy and be：Soluble potassium permanganate and sulphite are fully dissolved in aqueous；To clean and dried carbon fiber
Paper carries out hydro-thermal reaction in being immersed in above-mentioned mixed solution, after question response is complete, will obtain final product purpose after products therefrom washing, drying
Product.
Above-mentioned sulphite is one or two mixture of potassium sulfite or sodium sulfite.
Above-mentioned soluble potassium permanganate and the mol ratio of soluble sulphite are 1:1.5.
Above-mentioned hydrothermal temperature is 100~160 DEG C, and the hydro-thermal reaction time is 18~36h.
Above-mentioned drying temperature is 70 DEG C, and drying time is 12h.
The present invention possesses following beneficial effect：
(1) raw material of preparation method provided by the present invention is cheap and easy to get, aboundresources, and synthesis technique is simple and easy to apply, closes
Into product quality stabilization and good process repeatability.
(2) the starfish shape manganese dioxide nano-plates array structure for having prepared novelty of the invention, and synthesized material
Size is more homogeneous, be uniformly dispersed, and any template or surfactant need not be added in building-up process.
(3) when the starfish shape manganese dioxide nano-plates prepared by the present invention do electrode of super capacitor, in 1A/g electric currents
Its specific capacitance value is up to 336F/g under density.
Brief description of the drawings
Fig. 1 is that the X-ray of the starfish shape manganese dioxide nano-plates/carbon fiber paper combination electrode material prepared by the present invention is spread out
Penetrate figure.
Fig. 2 is the scanning electricity of the starfish shape manganese dioxide nano-plates/carbon fiber paper combination electrode material prepared by the present invention
Mirror figure.
Fig. 3 is the scanning electricity of the starfish shape manganese dioxide nano-plates/carbon fiber paper combination electrode material prepared by the present invention
Mirror figure.
Fig. 4 is the scanning electricity of the starfish shape manganese dioxide nano-plates/carbon fiber paper combination electrode material prepared by the present invention
Mirror figure.
Fig. 5 is the scanning electricity of the starfish shape manganese dioxide nano-plates/carbon fiber paper combination electrode material prepared by the present invention
Mirror figure.
Fig. 6 is the circulation volt of the starfish shape manganese dioxide nano-plates/carbon fiber paper combination electrode material prepared by the present invention
Peace performance diagram.
Fig. 7 is the constant current of the starfish shape manganese dioxide nano-plates/carbon fiber paper combination electrode material prepared by the present invention
Charging and discharging curve figure.
Specific embodiment
The present invention is illustrated in detail with reference to the accompanying drawings and examples.
Used reagent in following embodiments, unless otherwise specified, is the pure level of analysis.
Embodiment 1
1mmol potassium permanganate, 1.5mmol potassium sulfites are dissolved in 30ml distilled water first, magnetic agitation is extremely at room temperature
It is completely dissolved；Then, the mixed solution is transferred in the autoclave of 50mL polytetrafluoroethyllining linings, takes and a piece of wash in advance
Net and dried carbon fiber paper, is dipped in aforesaid reaction vessel；Finally, reactor is placed in 120 DEG C of thermostatic drying chambers
Reaction 24h.After question response terminates, room temperature is naturally cooled to, the carbon fiber paper in reactor is taken out, with deionized water and anhydrous second
Alcohol intersection supersound washing is dried in putting it into 70 DEG C of drying boxes for several times, finally, obtains the two of the starfish shape nanometer chip architecture
Manganese oxide/carbon fiber combination electrode material.Products therefrom crystal formation is δ-MnO by X-ray powder diffraction analysis result2, X-ray
Diffraction patterns are as shown in Figure 1；Products therefrom pattern can be understood as shown in Fig. 2, Fig. 3, Fig. 4, Fig. 5, in figure and be seen by electronic microscope photos
Observe the manganese dioxide of finely dispersed starfish shape nanometer chip architecture；The chemical property of products therefrom leads under three-electrode system
Electrochemistry heart performance evaluation is crossed, under 1A/g current densities, its specific capacitance value is up to 336F/g.
Embodiment 2
1mmol potassium permanganate, 1.5mmol potassium sulfites are dissolved in 30ml distilled water first, magnetic agitation is extremely at room temperature
It is completely dissolved；Then, the mixed solution is transferred in the autoclave of 50mL polytetrafluoroethyllining linings, takes and a piece of wash in advance
Net and dried carbon fiber paper, is dipped in aforesaid reaction vessel；Finally, reactor is placed in 140 DEG C of thermostatic drying chambers
Reaction 18h.After question response terminates, room temperature is naturally cooled to, the carbon fiber paper in reactor is taken out, with deionized water and anhydrous second
Alcohol intersection supersound washing is dried in putting it into 70 DEG C of drying boxes for several times, finally, obtains the two of the starfish shape nanometer chip architecture
Manganese oxide/carbon fiber combination electrode material.Products therefrom understands that it is starfish shape through X-ray powder diffraction, scanning electron microscope analysis
δ-the MnO of nanometer chip architecture2, specific capacitance of the product under 1A/g current densities is 310F/g.
Embodiment 3
1mmol potassium permanganate, 1.5mmol sodium sulfites are dissolved in 30ml distilled water first, magnetic agitation is extremely at room temperature
It is completely dissolved；Then, the mixed solution is transferred in the autoclave of 50mL polytetrafluoroethyllining linings, takes and a piece of wash in advance
Net and dried carbon fiber paper, is dipped in aforesaid reaction vessel；Finally, reactor is placed in 120 DEG C of thermostatic drying chambers
Reaction 24h.After question response terminates, room temperature is naturally cooled to, the carbon fiber paper in reactor is taken out, with deionized water and anhydrous second
Alcohol intersection supersound washing is dried in putting it into 70 DEG C of drying boxes for several times, finally, obtains the two of the starfish shape nanometer chip architecture
Manganese oxide/carbon fiber combination electrode material.Products therefrom understands that it is starfish shape through X-ray powder diffraction, scanning electron microscope analysis
δ-the MnO of nanometer chip architecture2, specific capacitance of the product under 1A/g current densities is 333F/g.
Embodiment 4
1mmol potassium permanganate, 1.5mmol sodium sulfites are dissolved in 30ml distilled water first, magnetic agitation is extremely at room temperature
It is completely dissolved；Then, the mixed solution is transferred in the autoclave of 50mL polytetrafluoroethyllining linings, takes and a piece of wash in advance
Net and dried carbon fiber paper, is dipped in aforesaid reaction vessel；Finally, reactor is placed in 120 DEG C of thermostatic drying chambers
Reaction 24h.After question response terminates, room temperature is naturally cooled to, the carbon fiber paper in reactor is taken out, with deionized water and anhydrous second
Alcohol intersection supersound washing is dried in putting it into 70 DEG C of drying boxes for several times, finally, obtains the two of the starfish shape nanometer chip architecture
Manganese oxide/carbon fiber combination electrode material.Products therefrom understands that it is starfish shape through X-ray powder diffraction, scanning electron microscope analysis
δ-the MnO of nanometer chip architecture2, specific capacitance of the product under 1A/g current densities is 305F/g.
Embodiment described above only expresses several embodiments of the invention, and its description is more specific and detailed, but simultaneously
Therefore the limitation to the scope of the claims of the present invention can not be interpreted as, as long as being obtained in the form of equal replacement or equivalent transformation
Technical scheme, all should fall within the scope and spirit of the invention.
Claims (5)
1. a kind of starfish shape δ-MnO2The preparation method of nanometer sheet/carbon fiber paper combination electrode material, it is characterised in that：Will be solvable
Property potassium permanganate and solubility sulphite be sufficiently mixed dissolving in aqueous；To clean and dried carbon fiber paper
Being immersed in above-mentioned mixed solution carries out hydro-thermal reaction, after question response is complete, will products therefrom washing, dry after obtain final product purpose product
Thing.
2. a kind of starfish shape δ-MnO according to claim 12The preparation side of nanometer sheet/carbon fiber paper combination electrode material
Method, it is characterised in that：The soluble sulphite is one or two mixture of potassium sulfite or sodium sulfite.
3. a kind of starfish shape δ-MnO according to claim 22The preparation side of nanometer sheet/carbon fiber paper combination electrode material
Method, it is characterised in that：The mol ratio of the soluble potassium permanganate and soluble sulphite is 1:1.5.
4. a kind of starfish shape δ-MnO according to claim 32The preparation side of nanometer sheet/carbon fiber paper combination electrode material
Method, it is characterised in that：The hydrothermal temperature is 100~160 DEG C, and the hydro-thermal reaction time is 18~36h.
5. a kind of starfish shape δ-MnO according to claim 42The preparation side of nanometer sheet/carbon fiber paper combination electrode material
Method, it is characterised in that：The drying temperature is 70 DEG C, and drying time is 12h.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710013930.4A CN106935416B (en) | 2017-01-09 | 2017-01-09 | A kind of starfish shape δ-MnO2Nanometer sheet/carbon fiber paper combination electrode material preparation method |
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| CN201710013930.4A CN106935416B (en) | 2017-01-09 | 2017-01-09 | A kind of starfish shape δ-MnO2Nanometer sheet/carbon fiber paper combination electrode material preparation method |
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| CN106935416A true CN106935416A (en) | 2017-07-07 |
| CN106935416B CN106935416B (en) | 2019-08-23 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111986931A (en) * | 2020-07-24 | 2020-11-24 | 华南理工大学 | Manganese oxide nano-structure electrode material and preparation method and application thereof |
| CN112599764A (en) * | 2020-12-28 | 2021-04-02 | 上海纳米技术及应用国家工程研究中心有限公司 | Preparation method, product and application of ternary nanowire array @ carbon fiber |
| CN112981454A (en) * | 2021-02-03 | 2021-06-18 | 山东大学 | Manganese dioxide ultra-long nanowire catalyst with oxygen vacancy as well as preparation method and application thereof |
| CN114031125A (en) * | 2021-11-05 | 2022-02-11 | 上海纳米技术及应用国家工程研究中心有限公司 | Preparation method of ternary nanosheet @ carbon nanotube positive electrode material, product and application thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101402471A (en) * | 2008-10-24 | 2009-04-08 | 中国科学院电工研究所 | Process for producing layered delta-MnO2 nano-particle |
| CN101597086A (en) * | 2009-06-26 | 2009-12-09 | 海南大学 | Method for preparing nano manganese dioxide with different crystal forms in low-temperature acid solution |
| CN101698512A (en) * | 2009-10-23 | 2010-04-28 | 济南大学 | Method for preparing nano manganese dioxide of different crystal forms and appearances by adopting microwave hydrothermal method |
| WO2013066474A2 (en) * | 2011-08-15 | 2013-05-10 | Purdue Research Foundation | Methods and apparatus for the fabrication and use of graphene petal nanosheet structures |
| CN105013322A (en) * | 2015-06-25 | 2015-11-04 | 中国科学院生态环境研究中心 | Use of manganite catalyst in catalytic oxidation of formaldehyde |
| CN106098403A (en) * | 2016-08-17 | 2016-11-09 | 华中科技大学 | A kind of ultracapacitor, negative pole and preparation method thereof |
-
2017
- 2017-01-09 CN CN201710013930.4A patent/CN106935416B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101402471A (en) * | 2008-10-24 | 2009-04-08 | 中国科学院电工研究所 | Process for producing layered delta-MnO2 nano-particle |
| CN101597086A (en) * | 2009-06-26 | 2009-12-09 | 海南大学 | Method for preparing nano manganese dioxide with different crystal forms in low-temperature acid solution |
| CN101698512A (en) * | 2009-10-23 | 2010-04-28 | 济南大学 | Method for preparing nano manganese dioxide of different crystal forms and appearances by adopting microwave hydrothermal method |
| WO2013066474A2 (en) * | 2011-08-15 | 2013-05-10 | Purdue Research Foundation | Methods and apparatus for the fabrication and use of graphene petal nanosheet structures |
| CN105013322A (en) * | 2015-06-25 | 2015-11-04 | 中国科学院生态环境研究中心 | Use of manganite catalyst in catalytic oxidation of formaldehyde |
| CN106098403A (en) * | 2016-08-17 | 2016-11-09 | 华中科技大学 | A kind of ultracapacitor, negative pole and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 王珏: "超级电容器电极材料二氧化锰的制备、改性及其电容性能", 《中国优秀硕士学位论文全文数据库 工程科技II辑》 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111986931A (en) * | 2020-07-24 | 2020-11-24 | 华南理工大学 | Manganese oxide nano-structure electrode material and preparation method and application thereof |
| CN112599764A (en) * | 2020-12-28 | 2021-04-02 | 上海纳米技术及应用国家工程研究中心有限公司 | Preparation method, product and application of ternary nanowire array @ carbon fiber |
| CN112981454A (en) * | 2021-02-03 | 2021-06-18 | 山东大学 | Manganese dioxide ultra-long nanowire catalyst with oxygen vacancy as well as preparation method and application thereof |
| CN114031125A (en) * | 2021-11-05 | 2022-02-11 | 上海纳米技术及应用国家工程研究中心有限公司 | Preparation method of ternary nanosheet @ carbon nanotube positive electrode material, product and application thereof |
| CN114031125B (en) * | 2021-11-05 | 2023-11-28 | 上海纳米技术及应用国家工程研究中心有限公司 | Preparation method of ternary nano sheet@carbon nano tube anode material, product and application thereof |
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| CN106935416B (en) | 2019-08-23 |
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