CN106929412A - A kind of equipment for improving enzyme process depickling esterifying efficiency - Google Patents
A kind of equipment for improving enzyme process depickling esterifying efficiency Download PDFInfo
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- CN106929412A CN106929412A CN201511022051.5A CN201511022051A CN106929412A CN 106929412 A CN106929412 A CN 106929412A CN 201511022051 A CN201511022051 A CN 201511022051A CN 106929412 A CN106929412 A CN 106929412A
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- reactor
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- coil
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- 238000000034 method Methods 0.000 title claims abstract description 46
- 102000004190 Enzymes Human genes 0.000 title claims abstract description 19
- 108090000790 Enzymes Proteins 0.000 title claims abstract description 19
- 239000007789 gas Substances 0.000 claims description 23
- 238000006243 chemical reaction Methods 0.000 claims description 20
- 239000012528 membrane Substances 0.000 claims description 10
- 241000826860 Trapezium Species 0.000 claims description 9
- 239000011261 inert gas Substances 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 6
- 238000009423 ventilation Methods 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 230000018044 dehydration Effects 0.000 claims description 3
- 238000006297 dehydration reaction Methods 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 37
- 230000032050 esterification Effects 0.000 description 20
- 238000005886 esterification reaction Methods 0.000 description 20
- 229910052757 nitrogen Inorganic materials 0.000 description 18
- 239000003921 oil Substances 0.000 description 13
- 235000019198 oils Nutrition 0.000 description 13
- 239000002253 acid Substances 0.000 description 12
- 239000004519 grease Substances 0.000 description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 8
- 241000209094 Oryza Species 0.000 description 8
- 235000007164 Oryza sativa Nutrition 0.000 description 8
- 235000019774 Rice Bran oil Nutrition 0.000 description 8
- 235000009566 rice Nutrition 0.000 description 8
- 239000008165 rice bran oil Substances 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 235000021323 fish oil Nutrition 0.000 description 6
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 5
- 239000003925 fat Substances 0.000 description 5
- 239000012535 impurity Substances 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- 102000004882 Lipase Human genes 0.000 description 4
- 108090001060 Lipase Proteins 0.000 description 4
- 238000006555 catalytic reaction Methods 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 3
- 239000004367 Lipase Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 125000004494 ethyl ester group Chemical group 0.000 description 3
- 235000021588 free fatty acids Nutrition 0.000 description 3
- 235000019421 lipase Nutrition 0.000 description 3
- 150000004965 peroxy acids Chemical class 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- 102100021851 Calbindin Human genes 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 101000898082 Homo sapiens Calbindin Proteins 0.000 description 2
- 101001021643 Pseudozyma antarctica Lipase B Proteins 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical class CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 description 2
- 229960004424 carbon dioxide Drugs 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 230000001276 controlling effect Effects 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000001307 helium Substances 0.000 description 2
- 229910052734 helium Inorganic materials 0.000 description 2
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 238000005070 sampling Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- 239000002028 Biomass Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000009874 alkali refining Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000006837 decompression Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000008157 edible vegetable oil Substances 0.000 description 1
- 230000002255 enzymatic effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 229910052743 krypton Inorganic materials 0.000 description 1
- DNNSSWSSYDEUBZ-UHFFFAOYSA-N krypton atom Chemical compound [Kr] DNNSSWSSYDEUBZ-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229940126680 traditional chinese medicines Drugs 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M21/00—Bioreactors or fermenters specially adapted for specific uses
- C12M21/18—Apparatus specially designed for the use of free, immobilized or carrier-bound enzymes
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M23/00—Constructional details, e.g. recesses, hinges
- C12M23/02—Form or structure of the vessel
- C12M23/06—Tubular
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M27/00—Means for mixing, agitating or circulating fluids in the vessel
- C12M27/02—Stirrer or mobile mixing elements
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M29/00—Means for introduction, extraction or recirculation of materials, e.g. pumps
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M29/00—Means for introduction, extraction or recirculation of materials, e.g. pumps
- C12M29/04—Filters; Permeable or porous membranes or plates, e.g. dialysis
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Zoology (AREA)
- Engineering & Computer Science (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Wood Science & Technology (AREA)
- Genetics & Genomics (AREA)
- Biomedical Technology (AREA)
- Sustainable Development (AREA)
- Biochemistry (AREA)
- General Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Microbiology (AREA)
- Biotechnology (AREA)
- Clinical Laboratory Science (AREA)
- Molecular Biology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The present invention provides a kind of equipment for improving enzyme process depickling esterifying efficiency.Specifically, the present invention provides a kind of reactor, it is characterised in that the reactor includes:Reactor tank body and porous coil pipe;Wherein, the porous coil pipe is included in the pipe coiled in horizontal direction, i.e. plane curved tube, and/or the pipe of coiled coil, i.e. spiral coil in vertical direction, or be made up of the plane curved tube and/or spiral coil, wherein, it is distributed hole on the pipe, described hole is downwards and/or horizontal opening.
Description
Technical field
The invention belongs to edible oil and fat manufacture field, and in particular to a kind of raising enzyme process depickling esterifying efficiency sets
It is standby.
Background technology
For enzyme process deacidifying process, many scientific research personnel study and deliver achieving suitable achievement,
For example:
(D.K.Bhattacharyya, Deacidification of high~acid such as D.K.Bhattacharyya
Rice bran oil by reesterification with monoglycerides [J], Journal of the American
Oil Chemists ' Society, 1999,76 (10):1243~1246) report in 210 DEG C of reaction temperature and
Under vacuum condition 10mm Hg, free fatty in Rice oil can be contained by controlling monoglyceride addition
Amount drops to 0.5 ± 0.10 to 3.5 ± 0.19% (w/w) by 9.5~35.0% (w/w).But turned using the method
There is substantial amounts of monoglyceride in grease after change, easily spumed when using.
(Sengupta R, Bhattacharyya D K, the Effect of monoglycerides on such as Sengupta
Enzymatic deacidification of rice bran oil [J], Journal~Oil technologists association
Of India, 1996,28:125~130) using free in lipase (M.meihei) catalysis Rice oil
Aliphatic acid and monoglyceride react, by controlling the monoglyceride addition can be by free fatty acid content in Rice oil
2%~4% is dropped to by 8.6%~16.9%.However it is necessary that adding a certain amount of monoglyceride could reduce free fat
The content of fat acid.
Li Guihua etc. (Li Guihua etc., learn by the research [J] of high-acid value rice bran oil esterification depickling, Zhengzhou Engineering College
Report, 2002 (1):36~38) report the method that chemical esterification reduces Rice oil acid value.But due to useization
Esterification is learned, causes that the method needs hot conditions and catalyst is easily remained.
(Wang Shirang etc., the research [J] of high-acid value grease esterification deacidification new technology, food industry section such as Wang Shirang
Skill, 2010 (3):252~pre-esterification 255) is carried out to peracid value rice bran oil in the reactor of 2MPa nitrogen charging
Process, 180 DEG C of pre-esterification temperature, time 4h, the FFA of rice bran oil is dropped to from 20.5% with this understanding
13.8%;Then the optimal bar of immobilized lipase enzyme process esterification deacidification reaction under the conditions of 2MPa nitrogen charging is drawn
Part:55 DEG C of esterification temperature, glycerine addition is 0.31g, esterification time 8h, immobilized lipase addition
It is oily weight 5%, drier addition weighs 1.5% for oil, and the FFA of rice bran oil is by 13.18% with this understanding
It is down to 2.12%.The document provides a kind of pretreating process of raw material, but the method passes through high-temperature pressurizing reality
Existing, pretreatment condition requirement is high, and efficiency is relatively low.
US4698186 discloses a kind of method for reducing free fatty acid content in grease.The method is with acidity
Cation-exchanger catalysis reduces the free fatty acid content in grease.But methyl alcohol is the method use, sun
The auxiliary materials such as ion exchange resin, are not suitable for fats and oils processing and industrialized production.
WO2004/043894A1 discloses a kind of method that enzyme law catalysis are esterified fish oil.The method passes through enzyme process
Carried out after esterification fish oil molecule arrange it is separate to rich in EPA (C20:5) with DHA (from C22:6) ester
Method.But sweet three ester of fish oil is directly destroyed and obtains ethyl ester by the method, to Rice oil enzyme process esterification technique
There is no application value.
CN101319167A discloses a kind of technique of high-acid value rice bran oil esterification depickling.The method is mainly led to
Cross carries out esterification by degumming, decolouring grease under the catalysis of zinc oxide or zinc, obtain acid number for 5~
The low acid value rice bran oil of 7mgKOH/g.But the method reaction temperature is high, and there is the risk of metallic pollution.
CN101824364A discloses a kind of enzyme process method for acid stripping and refining of peracid value fish oil.The method passes through
Methyl alcohol, ethanol etc. are added in peracid value fish oil by immobilization packed bed enzyme reactor, will be dissociated in fish oil
Aliphatic acid changes into ethyl ester, the technique for then carrying out alkali refining washing and drying.But the enzyme preparation of the technique is easily lost
It is living, and ethyl ester can be lost during follow-up refining, it is necessary to individually treatment.
Although there is the technique for some patents disclosing chemical esterification depickling and enzyme process esterification deacidification at present, these
Method is that the exploration of acid value grease raising yield high serves positive effect.But, these methods such as chemistry
Method influences larger to oil quality, and enzyme process still then is limited to laboratory's rank, and it is long to there is the reaction time, turns
The low problem of rate.
The content of the invention
First aspect present invention provides a kind of porous coil pipe, and the porous coil pipe is included in what is coiled in horizontal direction
Pipe, i.e. plane curved tube, and/or the pipe of coiled coil, i.e. spiral coil in vertical direction, or by the plane
Coil pipe and/or spiral coil are constituted, wherein, hole is distributed on the pipe, described hole is downwards and/or level is opened
Mouthful.
In certain embodiments, the pipe for often enclosing coiling separates each other.
In certain embodiments, the plane curved tube is ring-type.
In certain embodiments, the porous coil pipe is made up of wherein the plane curved tube and the spiral coil,
The pipe of the spiral coil is upwardly extended in bottom on the inside of coil pipe, and 1-5 is formed in the inner side of spiral coil
Plane curved tube.
In certain embodiments, the plane curved tube from top to bottom coils to form 1-5 plane curved tube, and from
The plane curved tube of the bottom is outwards and spiral is upwardly extended, and forms the spiral coil for surrounding the plane curved tube.
In certain embodiments, the quantity of plane curved tube is 1~5, for example, 1~3.
In certain embodiments, described hole has the opening of downward opening and level simultaneously.
In certain embodiments, described hole is uniformly distributed on the coil pipe.
In certain embodiments, narrow outer trapezium structure wide in hole formation.
In certain embodiments, the outside attachment filter membrane of hole.
In certain embodiments, hole outer rim is to protrude and/or flush in coil pipe and/or agitating paddle outer surface.
In certain embodiments, hole outer rim protrudes from coil pipe and/or agitating paddle outer surface.
In certain embodiments, the hole of coil pipe and/or agitating paddle outer surface is protruded from, its overhang is coil pipe
And/or 0.05~1 times of diameter of stirring paddle, preferably 0.1~0.5 times;Further preferred 0.2~0.4 times;Most preferably
0.25~0.3 times.
Second aspect present invention provides a kind of reactor, and the reactor includes reactor tank body and of the invention
Porous coil pipe.
In certain embodiments, the porous coil pipe is fixed (for example weld) to reaction by coil pipe itself
On the inwall of device tank body.
In certain embodiments, the porous coil pipe is consolidated via support prominent in reactor inner tank wall
Determine onto reactor inner tank wall.
In certain embodiments, spiral coil is completely fixed (as welded) to the inwall of reactor tank body,
It is i.e. seamless between coil pipe outside and reactor inner tank wall.
In certain embodiments, reactor also includes agitator.
In certain embodiments, agitator includes drive motor, agitating paddle and connection motor and agitating paddle
Agitating shaft.
In certain embodiments, there is hole, described hole is downwardly open on agitating paddle.
In certain embodiments, narrow outer trapezium structure wide in the hole formation on agitating paddle.
In certain embodiments, the outside of hole adheres to filter membrane on agitating paddle.
In certain embodiments, the coil pipe is seamless is attached on reactor wall, forms helical form protrusion,
In the bottom of helical form protrusion, ventilation coil pipe is drawn, the coil pipe is scattered in plane, three layer planes are constituted altogether to coil
Coil pipe.
In certain embodiments, narrow outer width in hole, in horn-like, section is in isosceles trapezoid, hypotenuse slope
It is 1.1~8, preferably 1.5~6, further preferred 2~4, most preferably 2.5~3.
In certain embodiments, hole outer rim is to protrude and/or flush in coil pipe and/or agitating paddle outer surface.
In certain embodiments, hole outer rim protrudes from coil pipe and/or agitating paddle outer surface.
In certain embodiments, the hole of coil pipe and/or agitating paddle outer surface is protruded from, its overhang is coil pipe
And/or 0.05~1 times of diameter of stirring paddle, preferably 0.1~0.5 times;Further preferred 0.2~0.4 times;Most preferably
0.25~0.3 times.
In certain embodiments, the reactor includes:
Reactor tank body;
Porous coil pipe;With
Agitator;
Wherein, the porous coil pipe is included in the pipe of coiled coil in vertical direction, i.e. spiral coil, and optionally
The pipe for coiling in the horizontal direction, i.e. plane curved tube, wherein, be distributed hole on the pipe, described hole to
Lower and/or horizontal opening, described hole protrudes from coil pipe;
The spiral coil is completely fixed on the inwall of reactor tank body, i.e. coil pipe outside and reactor tank body
It is seamless between inwall;
The agitator includes the agitating shaft of drive motor, agitating paddle and connection motor and agitating paddle;Wherein,
There is hole, described hole is downwardly open, and described hole protrudes from agitating paddle on the agitating paddle;
Wherein, on porous coil pipe and agitating paddle hole in narrow outer width, in horn-like, section is in isosceles trapezoid,
Hypotenuse slope is 1.1~8, preferably 1.5~6, further preferred 2~4, most preferably 2.5~3.
In certain embodiments, the reactor includes:
Reactor tank body;
Porous coil pipe;With
Agitator;
Wherein, the porous coil pipe is included in the pipe of coiled coil in vertical direction, i.e. spiral coil, and in water
Square upward pipe of coiling, i.e. plane curved tube, wherein, be distributed hole on the pipe, described hole downwards and/
Or horizontal opening, described hole protrudes from coil pipe;
The coil pipe is seamless to be attached on reactor wall, forms helical form protrusion, in the bottom of helical form protrusion,
Ventilation coil pipe is drawn, the coil pipe is scattered in plane, three layer plane coil pipes are constituted altogether to coil;
The spiral coil is completely fixed on the inwall of reactor tank body, i.e. coil pipe outside and reactor tank body
It is seamless between inwall;
The agitator includes the agitating shaft of drive motor, agitating paddle and connection motor and agitating paddle;Wherein,
There is hole, described hole is downwardly open, and described hole protrudes from agitating paddle on the agitating paddle;
Wherein, on porous coil pipe and agitating paddle hole in narrow outer width, in horn-like, section is in isosceles trapezoid,
Hypotenuse slope is 1.1~8, preferably 1.5~6, further preferred 2~4, most preferably 2.5~3.
Third aspect present invention provides a kind of consersion unit, and the equipment includes gas generator and of the invention anti-
Answer device.
In certain embodiments, the consersion unit also includes gas concentration unit.
In certain embodiments, the gas generator is inert gas generator, including but not limited to nitrogen
The inert gases such as gas, helium, carbon dioxide, argon gas, Krypton, xenon.
In certain embodiments, the consersion unit also includes being located between gas generator and reactor
Buffer pressure-reducing device.
In certain embodiments, the gas concentration unit also includes clarifier and vavuum pump.
In certain embodiments, in the case of having hole on agitating paddle, the consersion unit also includes
The pipeline of gas is provided to the agitator.
Fourth aspect present invention provides a kind of method for improving enzyme process depickling esterifying efficiency, and the method is included using this
The reactor or consersion unit of invention carry out enzyme process depickling esterification.
Brief description of the drawings
The structure of reactor in Fig. 1 display certain embodiments of the invention.
The structure of reactor in another some embodiments of Fig. 2 display present invention.
The structure of reactor in another some embodiments of Fig. 3 display present invention.
The top view of Fig. 4 display present invention ventilation coil pipes and the schematic diagram of void shape, wherein, the 1st width
Figure is the perspective view for reacting nitrogen charging hole on tank skin helical structure, and the 2nd width figure is nitrogen tube shown in Fig. 3 (6)
In the perspective view of horizontal plane, the 3rd width figure is hole perspective view in the horizontal plane, and the 4th width figure shows this hair
One example of bright hole.
Fig. 5 shows the schematic diagram that reactor of the present invention is used in enzyme process depickling esterification system.
Fig. 6 shows existing structure of reactor figure.
Fig. 7 displays are tested and obtained using reactor of the invention (" design equipment ") and existing equipment
Result.
Fig. 8 shows a schematic diagram for porous coil pipe embodiment of the invention.
Specific embodiment
The equipment used during the present invention relates to being reacted in an inert atmosphere, more particularly, to enzyme process depickling
Esterification, dehydration and need equipment of the inert gas as being used in the reaction of mixer meanses.The equipment bag
Include but be not limited to porous coil pipe, the reactor containing the porous coil pipe and the consersion unit containing the reactor.
Porous coil pipe
In the present invention, porous coil pipe mean to coil in the horizontal direction (referred to herein as " plane curved tube ") or
The tube of coiled coil (referred to herein as " spiral coil ") in vertical direction.Preferably, the pipe of each coiling
It is separated by a distance each other, this distance is had no specifically limited.For example, for plane curved tube, each circle
The distance between pipe is 0.1~5cm, such as 0.5~4cm, 1~3cm.In addition, it is generally the case that planar disk
It is ring-type to manage, i.e. pipe of the core without coiling, and the agitating shaft in order to agitator passes through.In some embodiments
In, the coiled structure of the porous coil pipe can be as shown in Figure 8.
In certain embodiments, the pipe of spiral coil of the invention is upwardly extended in bottom on the inside of coil pipe,
And form plane curved tube.In this porous coil arrangement, the quantity of plane curved tube is not limited, usually 1~5 plane
Coil pipe, for example, 1~3.It is separated by a distance between plane curved tube and plane curved tube, the distance can basis
The factors such as the volume of reactor determine.Fig. 3 shows an example for porous coil pipe having a structure in which, its
In, the porous coil pipe includes spiral coil 3 and 3 plane curved tubes 6 extended out from spiral coil bottom up.
In other embodiments, pipe from top to bottom coils to form 1-5 plane curved tube, and from most bottom
The plane curved tube of layer is outwards and spiral is upwardly extended, and forms the spiral coil for surrounding the plane curved tube.
It is distributed hole on porous coil pipe, described hole is downwards and/or horizontal opening.In other words, hole is in level
There is a downward angle with porous coil pipe on direction, (calculating of angle is with hole for 0~180 ° of angular range
On the basis of the side in portion).
Hole can be cylinder;Or interior (near porous disc inside pipe wall) is narrow outer (near porous disc pipe outer wall)
Width, in horn-like, section is trapezoidal, preferably isosceles trapezoid, and hypotenuse slope is 1.1~8, preferably 1.5~6,
Further preferred 2~4, most preferably 2.5~3.
Preferably, the porous coil pipe has downwardly open and horizontal opening hole simultaneously.It is furthermore preferred that institute
Hole is stated to be uniformly distributed on the coil pipe.
In certain embodiments, hole outer rim is protruded and/or flushes in coil pipe and/or agitating paddle outer surface, preferably
Ground, hole outer rim protrudes from coil pipe and/or agitating paddle outer surface.Protrude from the hole of coil pipe and/or agitating paddle outer surface
Hole, its overhang is 0.05~1 times, preferably 0.1~0.5 times of coil pipe and/or diameter of stirring paddle;Further preferably
0.2~0.4 times;Most preferably 0.25~0.3 times.
The size of the distance between hole and hole and each hole is had no specifically limited.For example, be open to
Under the distance between hole and hole can be 0.5~10cm, more preferably preferably 0.5~5cm, 0.5~3cm
.The distance between hole of horizontal opening and hole can be 0.5~10cm, preferably 0.5~5cm, more excellent
Select 0.5~3cm.The hole of horizontal opening may be on same vertical line with downwardly open hole,
Can stagger in vertical direction, i.e. both distances in the horizontal direction can be 0~5cm, such as 0~3cm,
It is even more small, such as 0~1cm.
Porous disc pipe has certain thickness, generally in the range of 0.1~1.5cm, such as 0.1~1.0cm,
0.1~0.5cm.It is preferred, therefore, that narrow outer trapezium structure wide in hole formation, such as Fig. 4 last
Shown in width figure.The trapezium structure helps to prevent impurity into coil pipe or avoiding hole from blocking.It is furthermore preferred that
The outside attachment filter membrane of hole, for preventing impurity from entering in coil pipe.
The material of filter membrane include but is not limited to polyamide, PP filter paper, glass fibre, compound PP PET filter paper,
The membrane materials such as terylene non-woven fabric.
The inner or outer side of spiral coil can also have the pillar (figure for the spiral coil to be placed in reactor
In do not show).Generally, the quantity of pillar is at least 3.Pillar can be located only within the bottom of spiral coil, use
In by helical disk pipe support on the bottom of the reactor.Preferably, pillar can fix spiral coil, so that reaction
When spiral coil be unlikely to be rocked with reacting fluid.
Porous coil pipe is generally made of high temperature resistant, corrosion-resistant material, including but not limited to stainless steel, high score
Sub- polymer etc..
To the height and diameter of porous coil pipe also without specifically limited, can be given really according to the inside dimension of reactor
It is fixed, typically less than or equal to the internal diameter of (referring to the overall external diameter of porous coil pipe) reactor.
Fig. 8 shows the schematic diagram of porous coil pipe of the invention.Wherein, left figure is shown flat shown in Fig. 3
A part for face pipe 6;Right figure shows a part for the spiral coil 3 shown in Fig. 3.It should be understood that Fig. 8
What shown porous coil pipe was merely exemplary, whole holes and coil arrangement are not shown.
Reactor
Reactor of the invention includes reactor tank body and porous coil pipe.
Reactor tank body can have the arbitrary shape and size of this area conventional reactor, and can use this area
Known material is made.
Porous coil pipe can be fixed (for example weld) onto the inwall of reactor tank body by coil pipe itself, also may be used
It is as mentioned before to be removably mounted in reactor (via the pillar on coil pipe).Preferably, spiral shell
Capstan pipe is completely fixed (as welded) to the inwall of reactor tank body, i.e. coil pipe outside and reactor tank body
It is seamless between inwall.In certain embodiments, the porous coil pipe is dashed forward via in reactor inner tank wall
The support that goes out and be fixed in reactor inner tank wall.
Fig. 1 shows an example of reactor of the present invention.As shown in figure 1, shown agitator 11 includes
Reactor tank body 2 and spiral coil 3.Gas enters coil pipe according to shown in arrow from left side, and from reactor tank
Opening outflow on body.
Reactor generally also includes agitator.The material of agitator can be conventionally used for preparing this kind of agitator
Material.Agitator generally includes the agitating shaft of drive motor, agitating paddle and connection motor and agitating paddle.It is excellent
Choosing, also has hole on agitating paddle, described hole is downwardly open, and the distance between hole and hole can
To be 0.5~10cm, preferably 0.5~5cm, more preferably 0.5~3cm.It is also preferred that hole type
Into interior narrow outer trapezium structure wide, as shown in Fig. 4 last width figure.The trapezium structure contributes to entry deterrence coil pipe
It is interior.It is furthermore preferred that the outside attachment filter membrane of hole, for preventing impurity from entering in coil pipe.
Fig. 2 shows the reactor example comprising agitator.As shown in Fig. 2 reactor 12 includes reaction
Device tank body 2, spiral coil 3 and agitator 4.Agitator 4 includes agitating paddle 5.Agitator 4 is shown in figure
Including 2 agitating paddles.But the agitating paddle of usable varying number in practice, such as 1~5, preferably 1~
3.
The structural representation of Fig. 3 displays another reactor example of the invention.Specifically, reactor 13
Including reactor tank body 2, spiral coil 3, plane curved tube 6 and agitator 4.Agitator 4 includes agitating paddle
5.Similarly, the quantity of agitating paddle is not limited to 2, can be such as 1~5, preferably 1~3.
It should be understood that reactor also includes other components, such as, for the reaction lid for sealing, reaction is covered also can
With various openings, for running reactant turnover etc..These are all the conventional structures in this area.
Consersion unit
The present invention also provides a set of consersion unit, including gas generator and reactor of the invention.Preferably,
The consersion unit may also include gas concentration unit.
Gas goes for the various inert gases of reaction, such as nitrogen, nitrogen, helium, argon gas, two
Various inert gases such as carbonoxide.
Gas generator and retracting device can be various devices commonly used in the art.
Between gas generator and reactor, buffer pressure-reducing device is may also include.For the gas discharged,
Purification utensil is it is also possible to use, gas generator is passed back via vavuum pump, to recycle.
In the case of having hole on agitating paddle, the gas of buffered decompression is removed and directly fed to spiral coil
Outward, also agitating paddle can be supplied to via agitating shaft.
Fig. 5 shows one embodiment of consersion unit of the present invention.The consersion unit include nitrogen gas generator,
Buffering pressure regulating equipment, agitator, reactor of the invention, clarifier and vavuum pump.Produced by nitrogen gas generator
Raw nitrogen, the nitrogen is supplied to spiral coil and agitator after being depressurized via buffer pressure-reducing device, from reactor
The nitrogen of discharge is supplied to vavuum pump after can first passing through purification utensil, then is supplied to nitrogen to send out via vavuum pump
Raw device.
The purposes of reactor/consersion unit
Reactor of the invention can be used to reacting situation about need to carry out in an inert atmosphere, these situations include but
It is not limited to enzyme process depickling esterification, dehydration and needs inert gas as the reaction of mixer meanses.
Advantages of the present invention
Reactor wall attachment helical form protrusion of the present invention, can increase liquid fat in agitating paddle whipping process
Flowing, expand mass transfer;
Attachment breather line in reactor helical ripple, breather line adheres to equally distributed hole, in reaction
Process Hole fills plus nitrogen, increases mass transfer and the speed with water outlet;
In the bottom of helical form protrusion, ventilation coil pipe is drawn, the coil pipe is spirally scattered in plane, altogether composition
Three layer plane coil pipes, contribute to being evenly distributed for nitrogen;
This hole is uniformly distributed on coil pipe, contributes to being evenly distributed for nitrogen;
Hole is uniformly distributed on agitating paddle, contributes to nitrogen to be evenly distributed;
Hole goes out into interior narrow outer trapezium structure wide in outside face expanded letter, adheres to filter membrane, effectively prevents
Impurity enters, and trapezium structure also contributes to prevent impurity from entering.
Because reaction system is variant, the effect of nitrogen is not only propulsion mass transfer, while also serve as water entrainer depositing
.Because system viscosity is higher in grease system, gas dispersion effect is bad, therefore uses widely distributed spiral shell
Coil is designed, and prevents the dead angle of gas-liquid contact.
The present invention will be described in the way of specific embodiment below.It should be understood that these embodiments are only illustrative
, not limit the scope of the invention.Used method, raw material and reagent in embodiment, unless otherwise
Illustrate, be otherwise the conventional method in this area, raw material and reagent.
Agents useful for same in embodiment:
Dewaxing Rice oil:From Qinhuangdao Jin Hai Food Co., Ltd.
Glycerine:Purchase from traditional Chinese medicines.
CalB lipase:Purchase from Novozymes
White carbon:From beneficial sea (Jiamusi) biomass power generation Co., Ltd
Embodiment 1
Reacted using design equipment (equipment i.e. of the invention), specific course of reaction and the following institute of condition
State:
1st, by 175g glycerine, 1.5kg CALB, 1.5kg white carbon and 50kg raw materials dewaxing Rice oil
(AV=20.56) in injection retort;
2nd, nitrogen valve is opened, nitrogen is passed through, while by grease temperature control at 80 DEG C;
3rd, vavuum pump is opened, by vacuum degree control in > 940mbar.
4th, timing is started when vacuum reaches setting value, while recording temperature and vacuum;
5th, the sampling detection AV per 2h.
Reacted using conventional equipment (equipment i.e. shown in Fig. 6), reaction condition and step are as follows:
1st, by 175g glycerine, 1.5kg CALB, 1.5kg white carbon and 50 raw materials dewaxing Rice oil (AV=20.56)
In injection retort;By grease temperature control at 80 DEG C.
2nd, open vavuum pump, start timing when vacuum reaches setting value > 940mbar, while recording temperature
And vacuum;
3rd, the sampling detection AV per 2h.
The reaction result of two kinds of equipment is as shown in Figure 7.From figure 7 it can be seen that using testing equipment of the invention,
The esterifying efficiency of reaction will reach conventional equipment 16h apparently higher than conventional equipment, the esterification effect in 6~8h
Degree.
Claims (10)
1. a kind of reactor, it is characterised in that the reactor includes:
Reactor tank body;With
Porous coil pipe;
Wherein, the porous coil pipe is included in the pipe coiled in horizontal direction, i.e. plane curved tube, and/or vertical
The pipe of coiled coil, i.e. spiral coil on direction, or be made up of the plane curved tube and/or spiral coil, wherein,
It is distributed hole on the pipe, described hole is downwards and/or horizontal opening.
2. reactor as claimed in claim 1, it is characterised in that the porous coil pipe is by coil pipe itself
It is fixed on the inwall of reactor tank body, and/or is fixed on the support protruded in reactor inner tank wall.
3. reactor as claimed in claim 1 or 2, it is characterised in that
The spiral coil of the porous coil pipe is completely fixed on the inwall of reactor tank body, i.e., outside porous coil pipe
It is seamless between side and reactor inner tank wall;And/or
The reactor also includes agitator.
4. reactor as claimed in claim 3, it is characterised in that the agitator include drive motor,
The agitating shaft of agitating paddle and connection motor and agitating paddle, it is preferable that there is hole, described hole on agitating paddle
It is downwardly open.
5. the reactor as any one of Claims 1 to 4, it is characterised in that the reactor bag
Containing following one or more features:
1) section of the hole on the porous coil pipe and agitating paddle is interior narrow outer trapezium structure wide, preferably
Isosceles trapezoid, hypotenuse slope is 1.1~8, preferably 1.5~6, further preferred 2~4, most preferably 2.5~3;
2) described hole outer rim is protruded and/or flushes in coil pipe and/or agitating paddle outer surface, preferably protrudes from coil pipe
And/or agitating paddle outer surface;
3) described hole outer rim protrudes from the hole of coil pipe and/or agitating paddle outer surface, overhang be coil pipe and/or
0.05~1 times of diameter of stirring paddle, preferably 0.1~0.5 times;Further preferred 0.2~0.4 times;Most preferably 0.25~
0.3 times;With
4) filter membrane is attached with outside described hole.
6. the reactor as any one of Claims 1 to 5, it is characterised in that the porous coil pipe without
Seam is attached on reactor wall, forms helical form protrusion, in the bottom of helical form protrusion, draws ventilation coil pipe,
Coil pipe coiling is scattered in plane, and the plane curved tube is 1~5 layer, preferably 2~4 layers.
7. reactor as claimed in claim 1, it is characterised in that the reactor includes:
Reactor tank body;
Porous coil pipe;With
Agitator;
Wherein, the porous coil pipe is included in the pipe of coiled coil in vertical direction, i.e. spiral coil, and optionally
The pipe for coiling in the horizontal direction, i.e. plane curved tube, wherein, be distributed hole on the pipe, described hole to
Lower and/or horizontal opening, described hole protrudes from coil pipe outer surface;
The spiral coil is completely fixed on the inwall of reactor tank body, i.e. coil pipe outside and reactor tank body
It is seamless between inwall;
The agitator includes the agitating shaft of drive motor, agitating paddle and connection motor and agitating paddle;Wherein,
There is hole, described hole is downwardly open, and described hole protrudes from agitating paddle outer surface on the agitating paddle;
Hole on porous coil pipe and agitating paddle in narrow outer width, in horn-like, section is in isosceles trapezoid, hypotenuse
Slope is 1.1~8, preferably 1.5~6, further preferred 2~4, most preferably 2.5~3;
Described hole outer rim protrudes from the hole of coil pipe and/or agitating paddle outer surface, and overhang is coil pipe and/or stirring
0.05~1 times of oar diameter, preferably 0.1~0.5 times;Further preferred 0.2~0.4 times;Most preferably 0.25~0.3
Times;With
Optionally, described hole outside attachment filter membrane;
Or, the reactor includes:
Reactor tank body;
Porous coil pipe;With
Agitator;
Wherein, the porous coil pipe is included in the pipe of coiled coil in vertical direction, i.e. spiral coil, and in water
Square upward pipe of coiling, i.e. plane curved tube, wherein, be distributed hole on the pipe, described hole downwards and/
Or horizontal opening, described hole protrudes from coil pipe outer surface;
The coil pipe is seamless to be attached on reactor wall, forms helical form protrusion, in the bottom of helical form protrusion,
Ventilation coil pipe is drawn, the coil pipe is scattered in plane, three layer plane coil pipes are constituted altogether to coil;
The spiral coil is completely fixed on the inwall of reactor tank body, i.e. coil pipe outside and reactor tank body
It is seamless between inwall;
The agitator includes the agitating shaft of drive motor, agitating paddle and connection motor and agitating paddle;Wherein,
There is hole, described hole is downwardly open, and described hole protrudes from agitating paddle outer surface on the agitating paddle;
Hole on the porous coil pipe and agitating paddle in narrow outer width, in horn-like, section is in isosceles trapezoid,
Hypotenuse slope is 1.1~8, preferably 1.5~6, further preferred 2~4, most preferably 2.5~3;
Described hole outer rim protrudes from the hole of coil pipe and/or agitating paddle outer surface, and overhang is coil pipe and/or stirring
0.05~1 times of oar diameter, preferably 0.1~0.5 times;Further preferred 0.2~0.4 times;Most preferably 0.25~0.3
Times;With
Described hole outside attachment filter membrane.
8. a kind of consersion unit, the equipment includes:
Gas generator;With
Reactor any one of claim 1~7.
9. consersion unit as claimed in claim 8, it is characterised in that the consersion unit also includes gas
Body retracting device, the buffer pressure-reducing device between gas generator and reactor and optional to this
Agitator provides the pipeline of gas.
10. any one of the reactor or claim 8~9 any one of claim 1~7
The reaction that is carried out in using inert atmosphere of consersion unit in application, the reaction includes enzyme process depickling ester
Change, dehydration and use inert gas as the reaction of mixer meanses.
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US4521349A (en) * | 1983-01-20 | 1985-06-04 | A. R. Wilfley And Sons, Inc. | Fluid diffuser for gases and liquids |
CN202730136U (en) * | 2012-08-31 | 2013-02-13 | 北京清大天一科技有限公司 | Bioreactor |
CN103194378A (en) * | 2013-04-10 | 2013-07-10 | 黑龙江八一农垦大学 | Three-dimensional liquid-phase fermentation helical stirring device |
CN203653563U (en) * | 2014-01-07 | 2014-06-18 | 南阳医学高等专科学校 | Medical intelligent bioreactor |
CN204448023U (en) * | 2014-12-22 | 2015-07-08 | 浙江原野化工有限公司 | A kind of from stirring-type reactor |
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2015
- 2015-12-30 CN CN201511022051.5A patent/CN106929412A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4521349A (en) * | 1983-01-20 | 1985-06-04 | A. R. Wilfley And Sons, Inc. | Fluid diffuser for gases and liquids |
CN202730136U (en) * | 2012-08-31 | 2013-02-13 | 北京清大天一科技有限公司 | Bioreactor |
CN103194378A (en) * | 2013-04-10 | 2013-07-10 | 黑龙江八一农垦大学 | Three-dimensional liquid-phase fermentation helical stirring device |
CN203653563U (en) * | 2014-01-07 | 2014-06-18 | 南阳医学高等专科学校 | Medical intelligent bioreactor |
CN204448023U (en) * | 2014-12-22 | 2015-07-08 | 浙江原野化工有限公司 | A kind of from stirring-type reactor |
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