CN106929165A - A kind of cleaning agent and cleaning method for being applied to hot rolling sewage circulating high rate filter - Google Patents

A kind of cleaning agent and cleaning method for being applied to hot rolling sewage circulating high rate filter Download PDF

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Publication number
CN106929165A
CN106929165A CN201710124095.1A CN201710124095A CN106929165A CN 106929165 A CN106929165 A CN 106929165A CN 201710124095 A CN201710124095 A CN 201710124095A CN 106929165 A CN106929165 A CN 106929165A
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CN
China
Prior art keywords
high rate
filter
cleaning
backwash
hot rolling
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710124095.1A
Other languages
Chinese (zh)
Inventor
董进
方辉
彭定三
张长生
夏勇军
胡笳
陈俊
王君
嵇然
张萌
谢相圣
潘莉
张雪萍
葛萍
朱安云
王文兴
征卫军
李宝磊
臧建
李慧
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI XINCHUANG ENERGY-SAVING ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
Original Assignee
ANHUI XINCHUANG ENERGY-SAVING ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ANHUI XINCHUANG ENERGY-SAVING ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd filed Critical ANHUI XINCHUANG ENERGY-SAVING ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
Priority to CN201710124095.1A priority Critical patent/CN106929165A/en
Publication of CN106929165A publication Critical patent/CN106929165A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/04Carboxylic acids or salts thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D29/00Filters with filtering elements stationary during filtration, e.g. pressure or suction filters, not covered by groups B01D24/00 - B01D27/00; Filtering elements therefor
    • B01D29/62Regenerating the filter material in the filter
    • B01D29/66Regenerating the filter material in the filter by flushing, e.g. counter-current air-bumps
    • B01D29/68Regenerating the filter material in the filter by flushing, e.g. counter-current air-bumps with backwash arms, shoes or nozzles
    • B01D29/688Regenerating the filter material in the filter by flushing, e.g. counter-current air-bumps with backwash arms, shoes or nozzles with backwash arms or shoes acting on the cake side
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D33/00Filters with filtering elements which move during the filtering operation
    • B01D33/44Regenerating the filter material in the filter
    • B01D33/48Regenerating the filter material in the filter by flushing, e.g. counter-current air-bumps
    • B01D33/50Regenerating the filter material in the filter by flushing, e.g. counter-current air-bumps with backwash arms, shoes or nozzles
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/08Silicates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/10Carbonates ; Bicarbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2068Ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/30Amines; Substituted amines ; Quaternized amines

Abstract

The present invention discloses a kind of cleaning agent and cleaning method for being applied to hot rolling sewage circulating high rate filter, and the cleaning agent weight percent content is:Na2CO39%~11%, waterglass 0.8%~1.2%, triethanolamine 3.6%~4.1%, butyl cellosolve 1.5%~1.8%, laurate 4.5%~5.0%, balance of water;Under high rate filter stoppage in transit state, filter backwash emptying valve is opened, manhole in opening after ventilation, is goed deep into mud layer with feeler lever, checks filtrate situation and greasy filth thickness;Close lower draining and leach penstock, open filter influent or backwash inlet valve, control liquid level;Sequentially add piece alkali and cleaning agent;Ventilation is soaked more than 12 hours, and adjustment backwash turnover water balance, ventilation carries out steam and combines flushing, and observation backwash water outlet is untill backwash water outlet becomes clear.The cleaning agent provided in the present invention under high pH conditions, there is good demulsification peptizaiton;This cleaning method can effectively decompose greasy filth and emulsified fat in filter, loose filtrate, it is ensured that high rate filter filter effect.

Description

A kind of cleaning agent and cleaning method for being applied to hot rolling sewage circulating high rate filter
Technical field
The present invention relates to a kind of hot rolling system high rate filter, specifically a kind of hot rolling sewage circulating high rate filter that is applied to Strong osmotic cleaning agent and its cleaning method.
Background technology
Hot rolling sewage circulating system is mainly for the users such as heating furnace water sealed tank, operation roll of mill cooling, milling train and roller-way cooling, machine Frame kink is cooled down and de-scaling pump house supplement water, rushes between iron scale, grinding roller etc. with water etc..Removed with water supply water temperature and rush iron scale With being required to outside water less than 35 DEG C, backwater temperature rise≤8 DEG C.Rush iron scale water and the supply of iron scale pump group rushed by Whirlwind tank, Operation roll of mill cooling, milling train and roller-way cooling, machine frame loop cooling and de-scaling pump house supplement water by two in circulating pump room Group pump is supplied water to different users respectively, and individually water supplying pump is set between grinding roller.Contain substantial amounts of iron scale and oil in above-mentioned backwater, Rotational flow settling pond is flowed automatically to by iron sheet ditch, in the iron scale of Whirlwind tank removal about 90%, water outlet is lifted with pump after treatment To advective separation of oil sedimentation basin, oil removing is further precipitated.Advective separation of oil sedimentation basin is provided with Oil and slag scraping machine and skimming plant.Primary water Absorbing well, absorption well is flowed to, lifting pump group by horizontal flow basin is all sent to high rate filter filtering, lowers the temperature using cooling tower in overbottom pressure, cools down Water afterwards is pressurizeed by water supply pump group and is recycled for rolling line user, to prevent the blocking of rolling line equipment, in pump group outlet header Upper setting Full-automatic self-cleaning piping filter.
Existing hot rolling system high rate filter takes the greasy dirt and impurity in physics backwash mode removal filtrate substantially, instead Developing result is poor, it is difficult to meet effluent quality requirement, filter material replacement cycle is short, general 2-3 needs all to change, costly, Artificial intensity is big.Specifically, have the drawbacks of current hot rolling system high rate filter existing cleaning technique:
1st, the difficult control of backwash hydraulic pressure, higher than 0.15MPa, filtrate is easily rushed out and enters concentration basin, influences follow-up sludge pressure Squeeze, poor filtration effect after filtrate leakage, while filtrate is largely lost in needs being augmented, consumes manpower and materials.Less than 0.15MPa Single tank backwash water underfed can be caused, not washed clean clearly, cause filtrate it is hardened, hardening, cause filtering water decline, water quality become Difference, causes vicious circle.
2nd, high rate filter uses long, easy hardened, the mixed layer of its filtrate, and substantial amounts of suspended impurity and oil are mixed in filtrate Mud, filtration cycle Effects of Water Quality is poor.Depending on system for use in carrying water quality condition, change within general 3 years a filtrate, separate unit filter replacement into This is 70,000 yuan, is converted into 2.33 ten thousand yuan/platform, is overhauled costly.
3rd, can not realize that Full-automatic backwashing is operated, single manual backwash labour intensity of tank is big.
Therefore the chemical cleaning method of high rate filter is developed and is promoted, filtrate service life can be extended, reduce manpower Material resources put into, and reduce waste discharge, further support energy-conserving and environment-protective cause, are the inexorable trends of enterprise's production.
The content of the invention
It is main it is an object of the invention to provide a kind of cleaning agent and cleaning method for being applied to hot rolling sewage circulating high rate filter The pollution of steel mill hot rolling system high rate filter filtrate and hardened influence filter effect are solved the problems, such as, using in the present invention Strong osmotic cleaning agent and cleaning method, can efficiently solve hot rolling sewage circulating system high-speed filter oily pollution and filtrate is hardened Problem, it is ensured that effluent quality meets water supply requirement.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of cleaning agent for being applied to hot rolling sewage circulating high rate filter, the cleaning agent weight percent content is: Na2CO39%~11%, waterglass 0.8%~1.2%, triethanolamine 3.6%~4.1%, butyl cellosolve 1.5%~ 1.8%th, laurate 4.5%~5.0%, balance of water.
A kind of cleaning method for being applied to hot rolling sewage circulating high rate filter, the cleaning step is:
1), under high rate filter stoppage in transit state, filter backwash emptying valve is opened, manhole in opening after ventilation, is used Feeler lever gos deep into mud layer, checks filtrate situation and greasy filth thickness;
2), close lower draining and leach penstock, open filter influent or backwash inlet valve, control liquid level;
3) piece alkali and cleaning agent, are sequentially added;
4), ventilation is soaked more than 12 hours, and adjustment backwash turnover water balance, ventilation carries out steam and combines flushing, and observation is anti- Wash-off water is untill backwash water outlet becomes clear.
Step 1) in, the filtrate carries out filter chemistry when having hardened situation or greasy filth average thickness more than 2mm is clear Wash work.
Step 2) in, the Liquid level is flooding 50-100 centimetres of upper strata filtrate.
Step 3) in, a 760m3The high rate filter of/h adds 100-200 kilograms of the cleaning agent, piece alkali 50-100 Kilogram.
The method step is additionally included in step 4) after cleaning, repeat step 1) to 4) cleaning repeatedly, until filtrate is loose, It is terminal without greasy filth attachment.
Beneficial effects of the present invention:The cleaning agent provided in the present invention is mainly the compounding of basic agent and organic reagent Agent, under high pH conditions, there is good demulsification peptizaiton;This cleaning method can effectively decompose greasy filth and oil emulsion in filter Fat, loose filtrate, it is ensured that high rate filter filter effect, water after filter matter is up to standard, the filter reduced caused by filter clogging are anti- Number of times is washed, human input is reduced, filter service life is effectively increased, is that enterprise's drop originally contributes.
Brief description of the drawings
For the ease of it will be appreciated by those skilled in the art that the present invention is further illustrated below in conjunction with the accompanying drawings.
Fig. 1 is applied to hot rolling sewage circulating high rate filter cleaning method flow chart for one kind of the present invention;
Fig. 2 is greasy filth situation schematic diagram in hot rolling sewage circulating high rate filter;
Fig. 3 is filtrate schematic diagram before the cleaning of hot rolling sewage circulating high rate filter;
Fig. 4 is filtrate schematic diagram after the cleaning of hot rolling sewage circulating high rate filter.
Specific embodiment
Technical scheme is clearly and completely described below in conjunction with embodiment, it is clear that described reality It is only a part of embodiment of the invention to apply example, rather than whole embodiments.Based on the embodiment in the present invention, this area is general All other embodiment that logical technical staff is obtained under the premise of creative work is not made, belongs to present invention protection Scope.
A kind of strong osmotic cleaning agent for being applied to hot rolling sewage circulating high rate filter, the cleaning agent is a kind of prescription medicament, Mainly Na2CO3, the infiltration cleaning formulation that compounds according to a certain percentage of waterglass, triethanolamine, butyl cellosolve and laurate, Filter sand effect is significant to cleaning sludge containing, is filtered using the strong osmotic cleaning agent assisted cleaning process technical scheme to separate unit Device is cleaned offline, can effectively remove oil removal and greasy dirt;
Specifically, the cleaning agent percentage of weight formula is:Na2CO39%~11%, waterglass 0.8%~1.2%, three Monoethanolamine 3.6%~4.1%, butyl cellosolve 1.5%~1.8%, laurate 4.5%~5.0%, balance of water, are matched somebody with somebody with this The filter sand effect that greasy filth high is cleaned under Fang Gao pH conditions is more notable;
Na in the cleaning agent formula2CO3Act as regulation pH value and dissolving grease, Na2CO3It is dissolved in water and forms carbonate Ion, carbanion hydrolyzes to form bicarbonate ion and hydroxide ion, and the aobvious alkalescence of solution, hydroxide ion promotes grease Hydrolysis, formation is dissolved in the polyalcohol and aliphatic acid of water;
Waterglass Na2O·nSiO2Effect:Wetting emulsification in the basic conditions, can promote the breast of oil and cleaning agent Change is acted on, and is conducive to greasy filth to be stripped out from filtrate, prevents secondary pollution;
Triethanolamine N (CH2CH2OH)3Effect:Surfactant, adds triethanolamine in formula, can promote oily dirt Removed from attachment, meanwhile, detergency ability can be improved by improving alkalescence, and have its fabulous compatibility;
Butyl cellosolve is acted on:Have improvement emulsifiability and the auxiliary by mineral dissolution in soap lye molten in formula Agent;
Lauric effect:Surfactant, promotes grease to be separated with attachment, has in formula and changes oil emulsion The effect of property, can squeeze the emulsifying agent of two-phase interface, promote water-oil separating.
The above-mentioned strong osmotic cleaning agent with compoundings such as highly basic and surfactants, coordinates science cleaning program to carry out at a high speed Cleaning filter, can be widely applied to the cleaning of steel-making continuous casting and hot rolling sewage circulating system oily waste water filter;Referring to Fig. 1, on Stating cleaning step is:
1st, under high rate filter stoppage in transit state, filter backwash emptying valve is opened, manhole in opening after ventilation, is used Feeler lever gos deep into mud layer, checks filtrate situation and greasy filth thickness, referring to Fig. 2, when discovery filtrate has hardened situation or greasy filth average The Chemical cleaning work of filter is carried out when thickness is more than 2mm;
2nd, close lower draining and leach penstock, open filter influent or backwash inlet valve, Liquid level is flooding upper strata 50-100 centimetres of filtrate;
3rd, strong osmotic cleaning agent, a general 760m are added according to the hardened situation of filtrate3The high rate filter of/h is added 50-100 kilograms of 100-200 kilograms of cleaning agent and piece alkali.Lid inspection situation is taken off according to filter, such as greasy filth is thicker or filtrate plate Knot situation is serious, can in right amount increase the consumption of piece alkali and bleeding agent.
4th, ventilation is soaked 12-14 hours, and adjustment backwash turnover water balance, ventilation carries out steam and combines flushing, observes backwash Water outlet is untill backwash water outlet becomes clear.
After cleaning, filter is opened, filtrate oil-containing situation is checked again, to determine cleaning performance.If filtrate greasy filth is still It is clearly present or filtrate still has hardened situation, then repeats above-mentioned cleaning method and clean repeatedly, until filtrate is loose, without greasy filth attachment It is terminal, referring to Fig. 3-4.
Strong osmotic cleaning agent in the present invention is a kind of prescription medicament, mainly the compounding of basic agent and organic reagent Agent, under the conditions of high ph-values (>=12), there is good demulsification peptizaiton;This infiltration cleaning method is not strict to hydraulic demand, energy Effectively alleviate the filterins media run-off problem that hydraulic pressure control is not easily caused, extend filter material service life;This cleaning method can have Effect decomposes greasy filth and emulsified fat, loose filtrate in filter, it is ensured that high rate filter filter effect, water after filter matter is up to standard, drop The low filter backwash number of times caused by filter clogging, reduces human input, effectively increases filter service life, is enterprise Drop originally contributes.
The like product of the object of the invention can be realized at present to be had with bodied ferric sulfate, aluminium chloride and PAFC It is the series of degreaser.The present invention has the oil removing permeance property more more efficient than like product, while solving their dosing Amount is big, and cost performance is low and the problems such as not thorough cleaning performance.
Present invention disclosed above preferred embodiment is only intended to help and illustrates the present invention.Preferred embodiment is not detailed All of details is described, it is only described specific embodiment that the invention is not limited yet.Obviously, according to the content of this specification, Can make many modifications and variations.This specification is chosen and specifically describes these embodiments, is to preferably explain the present invention Principle and practical application so that skilled artisan can be best understood by and utilize the present invention.The present invention is only Limited by claims and its four corner and equivalent.

Claims (6)

1. a kind of cleaning agent for being applied to hot rolling sewage circulating high rate filter, it is characterised in that the cleaning agent weight percent content For:Na2CO39%~11%, waterglass 0.8%~1.2%, triethanolamine 3.6%~4.1%, butyl cellosolve 1.5%~ 1.8%th, laurate 4.5%~5.0%, balance of water.
2. a kind of cleaning method for being applied to hot rolling sewage circulating high rate filter, it is characterised in that the cleaning step is:
1), under high rate filter stoppage in transit state, filter backwash emptying valve is opened, manhole in opening after ventilation, uses feeler lever Go deep into mud layer, check filtrate situation and greasy filth thickness;
2), close lower draining and leach penstock, open filter influent or backwash inlet valve, control liquid level;
3) piece alkali and cleaning agent, are sequentially added;
4), ventilation is soaked more than 12 hours, and adjustment backwash turnover water balance, ventilation carries out steam and combines flushing, and observation backwash goes out Water is untill backwash water outlet becomes clear.
3. a kind of cleaning method for being applied to hot rolling sewage circulating high rate filter according to claim 2, it is characterised in that step It is rapid 1) in, the filtrate carried out when having hardened situation or greasy filth average thickness more than 2mm filter Chemical cleaning work.
4. a kind of cleaning method for being applied to hot rolling sewage circulating high rate filter according to claim 2, it is characterised in that step It is rapid 2) in, the Liquid level is flooding 50-100 centimetres of upper strata filtrate.
5. a kind of cleaning method for being applied to hot rolling sewage circulating high rate filter according to claim 2, it is characterised in that step It is rapid 3) in, a 760m3The high rate filter of/h adds 100-200 kilograms of the cleaning agent, 50-100 kilograms of piece alkali.
6. a kind of cleaning method for being applied to hot rolling sewage circulating high rate filter according to claim 2, it is characterised in that should Method and step is additionally included in step 4) after cleaning, repeat step 1) to 4) cleaning repeatedly, until filtrate is loose, without greasy filth attachment It is terminal.
CN201710124095.1A 2017-03-03 2017-03-03 A kind of cleaning agent and cleaning method for being applied to hot rolling sewage circulating high rate filter Pending CN106929165A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710124095.1A CN106929165A (en) 2017-03-03 2017-03-03 A kind of cleaning agent and cleaning method for being applied to hot rolling sewage circulating high rate filter

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710124095.1A CN106929165A (en) 2017-03-03 2017-03-03 A kind of cleaning agent and cleaning method for being applied to hot rolling sewage circulating high rate filter

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CN106929165A true CN106929165A (en) 2017-07-07

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102978022A (en) * 2012-12-12 2013-03-20 辽宁科技大学 Phosphorus-free foam-free low-temperature steel plate surface cleaning agent and preparation method thereof
CN103466908A (en) * 2013-09-07 2013-12-25 鞍钢股份有限公司 Steel rolling oil sludge clearing agent and clearing method
CN103710161A (en) * 2013-12-31 2014-04-09 上海交通大学 Cleaning agent for removing heavy dirt and greasy dirt
CN103820232A (en) * 2014-01-22 2014-05-28 天津清正然化工科技有限公司 Filtering material cleaning agent for oilfield sewage filtering system
CN104307241A (en) * 2014-11-14 2015-01-28 黄石市浩运矿山设备节能开发有限公司 Cleaning method of ceramic filter
CN104357251A (en) * 2014-10-27 2015-02-18 东北大学 Mechanical filter oil stain cleaning agent and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102978022A (en) * 2012-12-12 2013-03-20 辽宁科技大学 Phosphorus-free foam-free low-temperature steel plate surface cleaning agent and preparation method thereof
CN103466908A (en) * 2013-09-07 2013-12-25 鞍钢股份有限公司 Steel rolling oil sludge clearing agent and clearing method
CN103710161A (en) * 2013-12-31 2014-04-09 上海交通大学 Cleaning agent for removing heavy dirt and greasy dirt
CN103820232A (en) * 2014-01-22 2014-05-28 天津清正然化工科技有限公司 Filtering material cleaning agent for oilfield sewage filtering system
CN104357251A (en) * 2014-10-27 2015-02-18 东北大学 Mechanical filter oil stain cleaning agent and preparation method thereof
CN104307241A (en) * 2014-11-14 2015-01-28 黄石市浩运矿山设备节能开发有限公司 Cleaning method of ceramic filter

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Application publication date: 20170707