CN106929055A - A kind of moulded coal raw material for being coated with low-order coal and granulated garbage - Google Patents

A kind of moulded coal raw material for being coated with low-order coal and granulated garbage Download PDF

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Publication number
CN106929055A
CN106929055A CN201511019972.6A CN201511019972A CN106929055A CN 106929055 A CN106929055 A CN 106929055A CN 201511019972 A CN201511019972 A CN 201511019972A CN 106929055 A CN106929055 A CN 106929055A
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China
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coal
low
order
moulded
moulded coal
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林科
杜明来
赵文涛
马芳
白洪彬
刘彦芳
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Beijing SJ Environmental Protection and New Material Co Ltd
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Beijing SJ Environmental Protection and New Material Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/08Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form in the form of briquettes, lumps and the like
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B57/00Other carbonising or coking processes; Features of destructive distillation processes in general
    • C10B57/04Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition
    • C10B57/06Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition containing additives

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Coke Industry (AREA)

Abstract

The invention provides a kind of moulded coal raw material for being coated with low-order coal and granulated garbage, including low-order coal moulded coal body and the non-low-order coal moulded coal layer for being coated on the low-order coal moulded coal body exterior, the low-order coal moulded coal body includes granulated garbage, low-order coal and organic binder bond, and the organic binder bond is weightless less than 50% in 850 DEG C of destructive distillation completely cut off under air conditionses;The quality of the low-order coal moulded coal body is the 40-70% of the moulded coal material quality, and the addition of the granulated garbage is the 20-50% of this weight of the low-order coal moulded coal.Moulded coal raw material of the invention not only solves prior art because making low-order coal and the limited problem of spam application in the absence of large-scale industrialization equipment, also effectively overcome that existing tamping coke furnace availability is low, coking industry production capacity surplus problem so that the existing considerable economic benefit of moulded coal raw material of the invention has certain social benefit again.

Description

A kind of moulded coal raw material for being coated with low-order coal and granulated garbage
Technical field
It is former the present invention relates to a kind of moulded coal for being coated with low-order coal and granulated garbage suitable for tamping coke furnace Material, belongs to low-order coal upgrading transformation technology field.
Background technology
Since 18th century, coal has turned into one of widely used energy of human world, with regard to China Energy consumption structure for, current coal occupies 70% or so, is the national main energy sources depended on for existence. According to the difference of structure and composition, coal is divided into lignite, bituminous coal and anthracite three major types, its metabituminous coal It is divided into lower-grade metamorphic bituminous and mesometamorphism bituminous coal again, lower-grade metamorphic bituminous also referred to as ub-bituminous coal, itself and lignite one Rise and be referred to as " low-order coal ".According to statistics, the reserves of China's low-order coal account for national explored coal reserves More than 55%, up to 561,200,000,000 tons, but because low-order coal is used as the product at incoalation initial stage, With phosphorus content it is low, moisture is high, easy efflorescence, easy spontaneous combustion, fugitive constituent high, immersion intensity difference, anti-dropping The features such as intensity difference, thus the serious direct exploitation for limiting low-order coal, this undoubtedly causes huge The big wasting of resources.In addition, increasingly increase and high-quality coal stock number with domestic energy demand Fall sharply, the upgrading conversion of low-order coal already turns into current China's energy research with comprehensive utilization with exploitation Major fields.
So far, the Upgrading Processes both at home and abroad for low-order coal are broadly divided into pyrolysis upgrading skill Art, non-evaporating dehydrolysis upgrading technology and shaping upgrading technology three major types, wherein, for shaping upgrading skill For art, in forming process, the physical action such as high pressure or shearing is to its gel structure and hole for low-order coal Slot sytem generates irreversible destruction, it is thus possible to inherently lifts the coal rank of low-order coal, makes it Degree of coalification is also improved therewith, so as to the dust for solving drying low-order coal is big, easily water suction, easily again In deficiencies such as spontaneous combustions.But current low-order coal upgrading technology is in experimental study and engineering initially should With the stage, the equipment in the absence of its heavy industrialization application is made thus limit the exploitation of low-order coal Utilize.
China has the garbage compost work of current implementation for the recycling mode of house refuse at this stage Skill and the garbage derivatived fuel technology studied, wherein for garbage derivatived fuel technology, though The right technology has obtained commercial application in day, moral, Mei Deng developed countries, but because China is current Do not possess the separate waste collection system of specification still, so foreign countries are for the sorting rubbish of component stabilization Fuel manufacturing technology cannot be applied to the high humidity composting of China, therefore, the rubbish of China should be directed to Rubbish reclaims present situation, and design research and development are adapted to the process for treating garbage as resource of China's national situation.
Tamping coke furnace be coal coking process in the maximization equipment that uses, its floor space is wide, investment Capital cost is big.Coking of coal is to produce coke through high-temperature retorting by raw material of coal, while acquisition coal gas, Coal tar simultaneously reclaims a kind of coal conversion process of other chemical products, and its coke product is mainly metallurgical coke Or chemical industry is burnt.Because the quality requirements industrially to this kind of coke are very high so that production metallurgy is burnt or changes The coal raw material that work Jiao is used is mainly coking coal, 1/3 coking coal, bottle coal, rich coal, lean coal, meager lean coal Etc. coal, belong to mesometamorphism bituminous coal, but the shortage of coal resources in recent years, particularly for coking The reduction of the middle high-quality coal raw material of industry so that the cost of material of coking industry is growing day by day, in addition Steel, metallurgy etc. largely needed the decline of metallurgical coke or the burnt industry of chemical industry in recent years, caused coke to produce The demand of product is reduced, price declines, so as to force coke-oven plant drastically to reduce coke output, thus band Come consequence be tamping coke furnace out of service, once and coke oven disable will scrap, then in order to protect Furnish a huge amount of money for the tamping coke furnace equipment invested to build, would have to be maintained in minimum level the operation of coke oven, this Sample not only reduces the availability of tamping coke furnace, can also cause the production capacity surplus of coking industry.Therefore, The coking industry for being on the verge of negative growth how is saved, the availability of tamping coke furnace is improved, coking industry is solved The problem of production capacity surplus has turned into the bottleneck of current containment coking industry development.
In sum, how tamping coke furnace is applied to low-order coal and rubbish under current situation Recycling field so that above mentioned problem is all readily solved, be puzzlement those skilled in the art A technical barrier.
The content of the invention
Present invention solves the technical problem that being to overcome the prior art cannot to realize low-order coal and waste resources Change the defect and the low problem of existing tamping coke furnace availability for utilizing, and then one kind is provided and be suitable to make firm by ramming The moulded coal raw material containing low-order coal and granulated garbage of coke oven.
Therefore, the present invention realizes that the technical scheme of above-mentioned purpose is:
A kind of moulded coal raw material for being coated with low-order coal and granulated garbage, including,
Low-order coal moulded coal body and the non-low-order coal moulded coal for being coated on the low-order coal moulded coal body exterior Layer, the non-low-order coal moulded coal layer is by one or more systems in scala media coal, high-order coal or middle high-order coal Into;It is characterized in that:
The low-order coal moulded coal body includes granulated garbage, low-order coal and organic binder bond, described organic Binding agent is weightless less than 50% in 850 DEG C of destructive distillation completely cut off under air conditionses;
The quality of the low-order coal moulded coal body is the 40-70% of the moulded coal material quality;With quality Meter, the addition of the granulated garbage is the 20-50% of this weight of the low-order coal moulded coal.
The granulated garbage is by combustiblerefuse and/or Compostable through drying, crushing and in 5-40MPa Lower compacting is formed;
The moisture content of the granulated garbage is below 17wt%, and the density of the granulated garbage is 1.0-1.2g/cm3
In mass, the addition of the organic binder bond is the 5-40% of the low-order coal quality.
The organic binder bond is asphalitine of the softening point more than 100 DEG C;
It is preferred that the asphalitine is coal asphalt or petroleum asphalt of the softening point not less than 120 DEG C.
The asphalitine is hard pitch, and in mass, the fixed carbon content of the hard pitch is 25% More than, C/Hratio is 8-11.
The G values of the low-order coal are more than 40% less than 50, volatile matter content.
The quality of the low-order coal moulded coal body is the 40-50% of the moulded coal material quality.
The addition of the granulated garbage is the 20-35% of this weight of the low-order coal moulded coal.
The low-order coal moulded coal body is cuboid or inverted ladder-shaped body, and the granulated garbage is embedded at described The inside and surface of cuboid or the inverted ladder-shaped body.
The moulded coal raw material is cuboid or inverted ladder-shaped body, and the non-low-order coal moulded coal layer is arranged at described The upper surface of low-order coal moulded coal body, lower surface and the relative two sides of the low-order coal moulded coal body one.
The granulated garbage contained in moulded coal raw material of the present invention can be arbitrary shape, its volume With no more than 25cm3It is advisable.
Above-mentioned technical proposal of the invention has the following advantages that:
1st, the moulded coal raw material for being coated with low-order coal and granulated garbage that the present invention is provided, by being added in The weightless organic binder bond less than 50% of destructive distillation under 850 DEG C of isolation air conditionses, will be low using its caking property Rank coal and granulated garbage molding bonded, on the one hand can enable low-order coal and granulated garbage push stamp-charging coke Upgrading treatment is carried out in stove, on the other hand also causes low-order coal and granulated garbage through consolidating after the completion of coking Body product is not pulverized easily, it is easy to the coke pushing of tamping coke furnace, it is often more important that above-mentioned organic binder bond with it is low After rank coal and granulated garbage mixing, the active ingredient in organic binder bond can promote in low-order coal and rubbish High molecular polymer degraded at high temperature, so as to be favorably improved the oil of low-order coal and garbage raw material Gas yield, makes oil gas total amount increase production more than 10%.
Also, moulded coal raw material of the invention is arranged on low-order coal moulded coal sheet by by non-low-order coal moulded coal layer The outside of body so that the liquid that low-order coal moulded coal body is produced in high temperature grading process is penetrated into non-low In rank coal type coal seam, the quality of the coke of low-order coal moulded coal body generation is favorably improved.Thus, originally It is low because making in the absence of large-scale industrialization equipment that the moulded coal raw material of invention not only solves prior art The limited problem of rank coal and spam application, also effectively overcomes that existing tamping coke furnace availability is low, Jiao Change the problem of industry production capacity surplus.
Moulded coal raw material of the invention is made full use of during high-temperature retorting can make combustiblerefuse, Compostable Organic matter changes olefiant gas and residue can be used as the burnt characteristic of chemical industry, by low-order coal moulded coal sheet The appropriate granulated garbage of insertion in body, not only contributes under conditions of moulded coal raw material production cost is reduced Oil gas and coke yield higher is still ensured that, the recycling to rubbish can be also effectively realized, made Obtain the existing considerable economic benefit of moulded coal raw material of the invention has certain social benefit again.
2nd, the moulded coal raw material for being coated with low-order coal and granulated garbage that the present invention is provided, preferably organic adhesive Agent is coal asphalt or petroleum asphalt of the softening point not less than 120 DEG C, can so improve low-order coal and rubbish is former The quality of the solid product-coke after material upgrading so that the volatile matter in coke is not more than 3-4%, So as to can be used to generating electricity, gas making and other chemical industry purposes.
Specific embodiment
Technical scheme will be clearly and completely described below, it is clear that described Embodiment is a part of embodiment of the invention, rather than whole embodiments.Based in the present invention Embodiment, it is all that those of ordinary skill in the art are obtained under the premise of creative work is not made Other embodiment, belongs to the scope of protection of the invention.Additionally, invention described below is different As long as involved technical characteristic does not constitute conflict and can just be combined with each other each other in implementation method.
Coal composition in moulded coal raw material of the present invention is applied to all of low-order coal, scala media coal, high-order Coal or middle high-order coal raw material.For purposes of illustration only, the low-order coal in following embodiments is with ub-bituminous coal or lignite As a example by, the coal raw material of non-low-order coal is by taking 1/3 coking coal or coking coal as an example.For ease of comparing and illustrating, with In lower embodiment, wt% represents weight/mass percentage composition, quality=(quality × 75% of low-order coal of dry coal The quality of the quality × 90%+ organic binder bonds of the non-low-order coals of quality × 85%+ of+granulated garbage), " kg/t dry coals " refers to kilogram number, " Nm of the product that dry coal per ton is obtained3/ t dry coals " refer to dry coal per ton The volume of the raw gas for obtaining is converted into 25 DEG C, the 1 cubic meter numbers of normal atmosphere pressure.
Embodiment 1
(1) it is below 17wt% by combustiblerefuse drying to moisture content, crushes and be pressed under 5MPa Density is 1.0g/cm3Particulate matter, it is standby;
(2) particulate matter after crushing ub-bituminous coal and organic binder bond jointly again with step (1) is mixed, Low-order coal bulk stock is formed, it is standby;
Wherein, the G values of ub-bituminous coal are 45, and volatile content is more than 40%;Organic binder bond be Destructive distillation weightlessness under 850 DEG C of isolation air conditionses is 45% coal tar pitch, and its softening point is 105 DEG C; In low order coal bulk stock, in mass, the addition of particulate matter is low-order coal bulk stock quality 20wt%, the addition of organic binder bond is the 40wt% of ub-bituminous coal quality;
(3) 1/3 coking coal crushed is carried out using tamping machine making shaping firm by ramming, forms non-low-order coal Moulded coal bottom, and the low-order coal of 1/3 coking coal and step (2) is added on the non-low-order coal moulded coal bottom Bulk stock, in this course 1/3 coking coal along coaling case two ends add, i.e., 1/3 coking coal encloses Around low-order coal bulk stock coaling the process of powder, and continuation is entered using tamping machine to above-mentioned coal raw material Row makes shaping firm by ramming, forms moulded coal middle level, and finally continuously adding 1/3 coking coal on the moulded coal middle level is carried out Make shaping firm by ramming, form non-low-order coal moulded coal top layer, so as to obtain final moulded coal raw material, that is to say, The middle part of moulded coal raw material is low-order coal moulded coal body, the upper and lower, left and right side of low-order coal moulded coal body It is coated with 1/3 coking coal layer;
In mass, the addition of low-order coal bulk stock is the 40wt% of moulded coal material quality;
(4) upgrading treatment will be carried out in the moulded coal raw material push-in coke oven of step (3), controls upgrading temperature It is 850 DEG C to spend, and the upgrading time is 16 hours, collects raw gas, tar, the mixing of crude benzol overflowed Thing, while obtaining byproduct coke;Using the isolated raw gas of common process, tar, one is gone forward side by side Step isolates crude benzol from coal gas, and the amount of the raw gas is 395Nm3/ t dry coals, the amount of the tar It is 55kg/t dry coals, the amount of the crude benzol is 14kg/t dry coals, and the amount of the coke is 675kg/t Dry coal, the solids carbon content in coke is not more than 5%, coke-screening arrangement not less than 80%, volatile matter content Particle diameter is the 75% of coke gross mass in the particle gross mass of more than 40mm after point, and particle diameter is in 25mm Particle gross mass above is the 90% of coke gross mass.
Embodiment 2
(1) it is below 17wt% by Compostable drying to moisture content, crushes and under 22.5MPa Density is pressed into for 1.2g/cm3Particulate matter, it is standby;
(2) particulate matter after crushing ub-bituminous coal and organic binder bond jointly with step (1) is mixed, Low-order coal bulk stock is formed, it is standby;
Wherein, the G values of ub-bituminous coal are 40, and volatile content is 50%;Organic binder bond is at 850 DEG C Destructive distillation weightlessness under isolation air conditionses is 40% asphalt, and its softening point is 120 DEG C;At this In low-order coal bulk stock, in mass, the addition of particulate matter is low-order coal bulk stock quality 35wt%, the addition of organic binder bond is the 5wt% of ub-bituminous coal quality;
(3) coking coal crushed is carried out using tamping machine making shaping firm by ramming, forms non-low-order coal moulded coal bottom Layer, and the low-order coal bulk stock of coking coal and step (2) is added on the non-low-order coal moulded coal bottom, Coking coal is added along the two ends of case of coalingging in this course, i.e., coking coal is carried out around low-order coal bulk stock Coaling the process of powder, continue above-mentioned coal raw material to be carried out using tamping machine make shaping, formation moulded coal firm by ramming Middle level, coking coal is finally continuously added on the moulded coal middle level to carry out making shaping firm by ramming, forms non-low order coal type Coal top layer, so as to obtain final moulded coal raw material, the i.e. middle part of moulded coal raw material for low-order coal moulded coal body, The upper and lower, left and right side of low-order coal moulded coal body is coated with coking coal layer;
In mass, the addition of low-order coal bulk stock is the 47.5wt% of moulded coal material quality;
(4) upgrading treatment will be carried out in the moulded coal raw material push-in coke oven of step (3), controls upgrading temperature It is 850 DEG C to spend, and the upgrading time is 16 hours, collects raw gas, tar, the mixing of crude benzol overflowed Thing, while obtaining byproduct coke;Using the isolated raw gas of common process, tar, one is gone forward side by side Step isolates crude benzol from coal gas, and the amount of the raw gas is 430Nm3/ t dry coals, the amount of the tar It is 60kg/t dry coals, the amount of the crude benzol is 14kg/t dry coals, and the amount of the coke is 660kg/t Dry coal, the solids carbon content in coke is not more than 5%, coke-screening arrangement not less than 80%, volatile matter content Particle diameter is the 40% of coke gross mass in the particle gross mass of more than 40mm after point, and particle diameter is in 25mm Particle gross mass above is the 55% of coke gross mass.
Embodiment 3
(1) it is below 17wt% by Compostable drying to moisture content, crushes and pushed in 40MPa Density is made for 1.1g/cm3Particulate matter, it is standby;
(2) particulate matter after crushing lignite and organic binder bond jointly with step (1) is mixed, shape It is standby into low-order coal bulk stock;
Wherein, the G values of lignite are 0, and volatile content is 60%;Organic binder bond is at 850 DEG C Destructive distillation weightlessness under isolation air conditionses is 42% high temperature asphalt, and its softening point is 125 DEG C, The fixed carbon content in the high temperature asphalt is 30% in mass, and C/Hratio is 8;In low order In coal bulk stock, in mass, the addition of particulate matter is low-order coal bulk stock quality 30wt%, the addition of organic binder bond is the 22.5wt% of lignite quality;
(3) 1/3 coking coal crushed is carried out using tamping machine making shaping firm by ramming, forms non-low order coal type Coal bottom, and the low-order coal sheet of 1/3 coking coal and step (2) is added on the non-low-order coal moulded coal bottom Body raw material, in this course coking coal along coaling case two ends add, i.e., coking coal is around low-order coal body Raw material coaling the process of powder, and continuation carries out making shaping firm by ramming using tamping machine to above-mentioned coal raw material, Moulded coal middle level is formed, 1/3 coking coal is finally continuously added on the moulded coal middle level carries out making shaping, shape firm by ramming It is low so as to obtain final moulded coal raw material, the i.e. middle part of moulded coal raw material into non-low-order coal moulded coal top layer Rank coal type coal body, the upper and lower, left and right side of low-order coal moulded coal body is coated with 1/3 coking coal layer;
In mass, the addition of low-order coal bulk stock is the 45wt% of moulded coal material quality;
(4) upgrading treatment will be carried out in the moulded coal raw material push-in coke oven of step (3), controls upgrading temperature It is 850 DEG C to spend, and the upgrading time is 16 hours, collects raw gas, tar, the mixing of crude benzol overflowed Thing, while obtaining byproduct coke;Using the isolated raw gas of common process, tar, one is gone forward side by side Step isolates crude benzol from coal gas, and the amount of the raw gas is 460Nm3/ t dry coals, the amount of the tar It is 65kg/t dry coals, the amount of the crude benzol is 14kg/t dry coals, and the amount of the coke is 615kg/t Dry coal, the solids carbon content in coke is not more than 5%, coke-screening arrangement not less than 80%, volatile matter content Particle diameter is the 40% of coke gross mass in the particle gross mass of more than 40mm after point, and particle diameter is in 25mm Particle gross mass above is the 60% of coke gross mass.
Embodiment 4
(1) it is below 17wt% by combustiblerefuse drying to moisture content, crushes and in compacting under 10MPa It is 1.1g/cm into density3Particulate matter, it is standby;
(2) particulate matter after crushing lignite and organic binder bond jointly with step (1) is mixed, shape It is standby into low-order coal bulk stock;
Wherein, the G values of lignite are 0, and volatile content is 55%;Organic binder bond is at 850 DEG C Destructive distillation weightlessness under isolation air conditionses is 47% coal tar pitch, and its softening point is 130 DEG C, with Fixed carbon content in the quality meter coal tar pitch is 35%, and C/Hratio is 11;In low order coal sheet In body raw material, in mass, the addition of particulate matter is the 25wt% of low-order coal bulk stock quality, is had The addition of machine binding agent is the 15wt% of lignite quality;
(3) coking coal crushed is carried out using tamping machine making shaping firm by ramming, forms non-low-order coal moulded coal bottom Layer, and the low-order coal bulk stock of coking coal and step (2) is added on the non-low-order coal moulded coal bottom, Coking coal is added along the two ends of case of coalingging in this course, i.e., coking coal is carried out around low-order coal bulk stock Coaling the process of powder, continue above-mentioned coal raw material to be carried out using tamping machine make shaping, formation moulded coal firm by ramming Middle level, coking coal is finally continuously added on the moulded coal middle level to carry out making shaping firm by ramming, forms non-low order coal type Coal top layer, so as to obtain final moulded coal raw material, the i.e. middle part of moulded coal raw material for low-order coal moulded coal body, The upper and lower, left and right side of low-order coal moulded coal body is coated with coking coal layer;
In mass, the addition of low-order coal bulk stock is the 50wt% of moulded coal material quality;
(4) upgrading treatment will be carried out in the moulded coal raw material push-in coke oven of step (3), controls upgrading temperature It is 850 DEG C to spend, and the upgrading time is 16 hours, collects raw gas, tar, the mixing of crude benzol overflowed Thing, while obtaining byproduct coke;Using the isolated raw gas of common process, tar, one is gone forward side by side Step isolates crude benzol from coal gas, and the amount of the raw gas is 470Nm3/ t dry coals, the amount of the tar It is 65kg/t dry coals, the amount of the crude benzol is 12kg/t dry coals, and the amount of the coke is 610kg/t Dry coal, the solids carbon content in coke is not more than 5%, coke-screening arrangement not less than 80%, volatile matter content Particle diameter is the 40% of coke gross mass in the particle gross mass of more than 40mm after point, and particle diameter is in 25mm Particle gross mass above is the 50% of coke gross mass.
Obviously, above-described embodiment is only intended to clearly illustrate example, and not to embodiment party The restriction of formula.For those of ordinary skill in the field, may be used also on the basis of the above description To make other changes in different forms.There is no need and unable to give all of implementation method With exhaustion.And the obvious change thus extended out or change guarantor still in the invention Among shield scope.

Claims (10)

1. a kind of moulded coal raw material for being coated with low-order coal and granulated garbage, including,
Low-order coal moulded coal body and the non-low-order coal moulded coal for being coated on the low-order coal moulded coal body exterior Layer, the non-low-order coal moulded coal layer is by one or more systems in scala media coal, high-order coal or middle high-order coal Into;It is characterized in that:
The low-order coal moulded coal body includes granulated garbage, low-order coal and organic binder bond, described organic Binding agent is weightless less than 50% in 850 DEG C of destructive distillation completely cut off under air conditionses;
The quality of the low-order coal moulded coal body is the 40-70% of the moulded coal material quality;With quality Meter, the addition of the granulated garbage is the 20-50% of this weight of the low-order coal moulded coal.
2. moulded coal raw material according to claim 1, it is characterised in that the granulated garbage is by can Combustion rubbish and/or Compostable are formed through drying, crushing and in compacting under 5-40MPa;
The moisture content of the granulated garbage is below 17wt%, and the density of the granulated garbage is 1.0-1.2g/cm3
3. moulded coal raw material according to claim 1 and 2, it is characterised in that in mass, institute The addition for stating organic binder bond is the 5-40% of the low-order coal quality.
4. the moulded coal raw material according to claim any one of 1-3, it is characterised in that described organic Binding agent is asphalitine of the softening point more than 100 DEG C;
It is preferred that the asphalitine is coal asphalt or petroleum asphalt of the softening point not less than 120 DEG C.
5. moulded coal raw material according to claim 4, it is characterised in that the asphalitine is high temperature Pitch, in mass, more than 25%, C/Hratio is 8-11 to the fixed carbon content of the hard pitch.
6. the moulded coal raw material according to claim any one of 1-5, it is characterised in that the low order The G values of coal are more than 40% less than 50, volatile matter content.
7. the moulded coal raw material according to claim any one of 1-6, it is characterised in that the low order The quality of coal type coal body is the 40-50% of the moulded coal material quality.
8. the moulded coal raw material according to claim any one of 1-7, it is characterised in that the rubbish The addition of particle is the 20-35% of this weight of the low-order coal moulded coal.
9. the moulded coal raw material according to claim any one of 1-8, it is characterised in that the low order Coal type coal body is cuboid or inverted ladder-shaped body, and the granulated garbage is embedded at the cuboid or described The inside and surface of inverted ladder-shaped body.
10. moulded coal raw material according to claim 9, it is characterised in that the moulded coal raw material is length Cube or inverted ladder-shaped body, the non-low-order coal moulded coal layer are arranged at the upper table of the low-order coal moulded coal body Face, lower surface and the relative two sides of the low-order coal moulded coal body one.
CN201511019972.6A 2015-12-30 2015-12-30 A kind of moulded coal raw material for being coated with low-order coal and granulated garbage Pending CN106929055A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1465656A (en) * 2002-07-04 2004-01-07 首钢总公司 Waste plastics and coal cocoaking treatment method
CN104479709A (en) * 2014-11-14 2015-04-01 北京三聚环保新材料股份有限公司 Moulded coal raw material suitable for low rank coal upgrading technology
CN106929058A (en) * 2015-12-30 2017-07-07 北京三聚环保新材料股份有限公司 A kind of coking process of the molding mass containing low-order coal and rubbish
CN106929056A (en) * 2015-12-30 2017-07-07 北京三聚环保新材料股份有限公司 A kind of coking process of rubbish

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1465656A (en) * 2002-07-04 2004-01-07 首钢总公司 Waste plastics and coal cocoaking treatment method
CN104479709A (en) * 2014-11-14 2015-04-01 北京三聚环保新材料股份有限公司 Moulded coal raw material suitable for low rank coal upgrading technology
CN106929058A (en) * 2015-12-30 2017-07-07 北京三聚环保新材料股份有限公司 A kind of coking process of the molding mass containing low-order coal and rubbish
CN106929056A (en) * 2015-12-30 2017-07-07 北京三聚环保新材料股份有限公司 A kind of coking process of rubbish

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Application publication date: 20170707