CN106928702A - A kind of high temperature resistant nylon/polyphenylene oxide composite material and preparation method thereof - Google Patents
A kind of high temperature resistant nylon/polyphenylene oxide composite material and preparation method thereof Download PDFInfo
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- CN106928702A CN106928702A CN201511026604.4A CN201511026604A CN106928702A CN 106928702 A CN106928702 A CN 106928702A CN 201511026604 A CN201511026604 A CN 201511026604A CN 106928702 A CN106928702 A CN 106928702A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
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- B29C2948/9259—Angular velocity
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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Abstract
The invention provides a kind of high temperature resistant nylon/polyphenylene oxide composite material and preparation method thereof, composite contains：30-50 parts of high temperature resistant nylon, 10-40 parts of polyphenylene oxide, 5-40 parts of mineral filler, 3-5 parts of compatilizer, 0.5-1 parts of coupling agent, 0.5-1 parts of antioxidant and 0.5-1 parts of lubricant；Preparation method includes：30-50 parts of high temperature resistant nylon, 10-40 parts of polyphenylene oxide, 5-25 parts of mineral filler, 3-5 parts of compatilizer, 0.5-1 parts of coupling agent, 0.5-1 parts of antioxidant, 0.5-1 parts of mix lubricant is uniform, obtain mixture；Mixture is added in double screw extruder from main spout, 0-15 parts of mineral filler is added in the double screw extruder from side spout, by obtaining high temperature resistant nylon/polyphenylene oxide composite material after tie rod, cooling, pelletizing and drying；High temperature resistant nylon/polyphenylene oxide composite material of the invention has the advantages that excellent heat resistance, high rigidity, good apparent mass, preferable mobility, easy-formation are processed.
Description
Technical field
The invention belongs to technical field of polymer composite materials, it is related to a kind of nylon/polyphenylene oxide composite material and preparation method thereof.
Background technology
High temperature resistant nylon product mainly including 6T, 6I, 9T, 9I, 10T, 10I, the 12T in semiaromatic polyamide composition etc., be by
Dicarboxylic acids and aliphatic diamine with aromatic ring are through prepared by melt polycondensation, it in polyamide molecule main chain due to introducing fragrance
Ring, so as to improve heat resistance and mechanical property, reduces water absorption rate, is between general engineering plastic nylon and high temperature resistant engineering
Heat resistance between plastics PEEK resin high.Because semi-aromatic nylon is compared with nylon66 fiber, its maximum advantage is heat-resisting
The excellent and relatively low water absorption rate of property；Meanwhile, compared with all aromatic nylon, it has processing fluidity good, the spy being easily worked
Property.Therefore, as the need for the developing rapidly with environmental protection cause of new and high technology, its market demand is in rising trend, its application is opened
Hair also has new progress.
Polyphenylene oxide (abbreviation PPE or PPO) have good mechanical property, chemical stability, dielectric properties, heat resistance and
Anti-flammability, is a kind of high performance thermoplastic engineering plastic.First generation modified polyphenyl ether product is released since GE companies within 1966
Afterwards, polyphenylene oxide industry is developed rapidly, has become the fourth-largest engineering plastics after PA, PC, POM.Non-modified polyphenylene oxide
With good mechanical property, heat resistance, dimensional stability, chemical stability, hydrolytic resistance, high rigidity and anti-flammability etc.,
But PPO molecule chain rigiditys are larger, and notch shock is very sensitive, simultaneously because its melt viscosity higher, prevents it from being molded
Shaping, therefore significantly limit its application.
Because polyphenylene oxide is armorphous and nonpolar resin, nylon is crystal type and polar resin, while the two has breach
Sensitivity, the poor defect of impact property, therefore, how to produce one kind can either comprehensive polyphenylene oxide and semi-aromatic nylon each
Advantage can overcome the alloy material of the poor defect of the shock resistance of the two just to turn into problem demanding prompt solution again.
The content of the invention
First purpose of the invention is to provide a kind of high temperature resistant nylon/polyphenylene oxide composite material.
Second object of the present invention is to provide a kind of preparation method of above-mentioned high temperature resistant nylon/polyphenylene oxide composite material.
To reach above-mentioned purpose, solution of the invention is：
A kind of high temperature resistant nylon/polyphenylene oxide composite material, it is characterised in that：Weight portion containing following components and every kind of component is such as
Under：
Wherein, above-mentioned high temperature resistant nylon can be semi-aromatic nylon, can be further selected from PA6T, PA6I, PA9T, PA9I,
Any one or a few in PA10T, PA12T and PA13T.
Above-mentioned polyphenylene oxide can be the homopolymers (such as LXR038) containing 2,6- dimethyl benzene ether units, or be to contain 2,6-
The copolymer of dimethyl benzene ether unit and 2,3,6- trimethyl -1,4- phenylene ether units.The weight portion of polyphenylene oxide can also be preferably 10-25
Part.
Above-mentioned compatilizer can be selected from maleic acid, maleic anhydride, fumaric acid, itaconic acid, glycidyl acrylate and lemon
Any one or a few in acid.
Above-mentioned coupling agent can be selected from VTES, gamma-aminopropyl-triethoxy-silane, γ-aminopropyl trimethoxy
Silane, γ-propyl methacrylate base silane, γ-glycidyl ether oxygen propyl trimethoxy silicane, positive tetraisopropyl titanate and isopropyl
Any one or a few in the different 18 acyl titanate esters of base three.
Above-mentioned mineral filler can be inorganic mineral filler, can be further selected from mica, wollastonite, talcum powder, calcium carbonate,
Any one or a few in barium sulfate or kaolin.The weight portion of mineral filler can also be preferably 20-40 parts.
Above-mentioned antioxidant can be phenolic antioxidant, can be further selected from four [β-(3,5- di-tert-butyl-hydroxy phenyl) third
Acid] pentaerythritol ester, β-positive octadecanol ester of (3,5- di-tert-butyl-hydroxy phenyls) propionic acid and the (the 4- tert-butyl groups -3- of 1,3,5- tri-
Hydroxyl -2,6- dimethyl benzyls) any one or a few in -1,3,5- triazines -2,4,6- (1H, 3H, 5H)-triketone.
Above-mentioned lubricant can be fatty acid amide series lubricant agent, can be further selected from N, N '-bis- ethylene hard fatty acids acid amides,
Any one or a few in stearic amide, oleamide, zinc stearate and calcium stearate.
A kind of preparation method of above-mentioned high temperature resistant nylon/polyphenylene oxide composite material, it comprises the following steps：
(1), by 30-50 parts of dry high temperature resistant nylon, 10-40 parts of dry polyphenylene oxide, 5-25 parts of dry mineral filler,
3-5 parts of compatilizer, 0.5-1 parts of coupling agent, 0.5-1 parts of antioxidant, 0.5-1 parts of lubricant are well mixed in high-speed mixer, obtain
To mixture；
(2), mixture is added in the double screw extruder from the main spout of double screw extruder, it is dry by 0-15 parts
Mineral filler is added in the double screw extruder from the side spout of double screw extruder, by tie rod, cooling, pelletizing and dry
High temperature resistant nylon/polyphenylene oxide composite material is obtained after dry.
Wherein, in step (1), the forced air drying 6-8 at 100-120 DEG C is small by high temperature resistant nylon for dry high temperature resistant nylon
When gained；Dry polyphenylene oxide is polyphenylene oxide at 100-110 DEG C obtained by forced air drying 6-8 hours；Dry mineral filler is ore deposit
Thing filler is at 110-130 DEG C obtained by forced air drying 6-8 hours.
In step (1), the rotating speed of high-speed mixer can be 600-800r/min, and the time of mixing can be 5-10min.
In step (2), double screw extruder is 295 ± 10 DEG C using zone temperature control, area's temperature, and two area's temperature are
295 ± 10 DEG C, three area's temperature are 300 ± 10 DEG C, and four area's temperature are 305 ± 10 DEG C, and five area's temperature are 315 ± 10 DEG C, and six area's temperature are
315 ± 10 DEG C, seven area's temperature are 315 ± 10 DEG C, and eight area's temperature are 310 ± 10 DEG C, and nine area's temperature are 305 ± 10 DEG C, and ten area's temperature are
305 ± 10 DEG C, head temperature is 305 ± 10 DEG C, 250-350 revs/min of screw speed.
In the preparation method of high temperature resistant nylon/polyphenylene oxide composite material of the invention, mineral filler can be added at twice, every time
The species of the mineral filler of addition can be with identical, it is also possible to different.Because the particle diameter of mineral filler is smaller, bulk density is higher,
In with other component Blending Processes, if too high levels, mineral filler is easily deposited on feed hopper bottom, causes feeding uneven；
If all entered from side spout, because side spout is closer to the distance apart from die head, mineral filler is blended with other component melts
Time shortens, and is easily caused mixing heterogeneity, and properties of product are deteriorated, so consider preferably adding in two steps.
Due to using such scheme, the beneficial effects of the invention are as follows：
Firstth, the mineral filler that the present invention is used selects the inorganic rigid particle of acid-fast alkali-proof, water insoluble and organic solvent, tool
There is fabulous photostability and weatherability, there is the fabulous rheological equationm of state in height filling, hardly wear and tear gold in process
Category, therefore, coming filling-modified high temperature resistant nylon and polyphenylene oxide double substrate material using the mineral filler can improve its intensity, firm
Property, improve the crystalline rate and crystallinity of product, so as to improve heat resistance and dimensional stability.
Secondth, high temperature resistant nylon of the invention/polyphenylene oxide composite material adds the preferable high temperature resistant nylon of mobility, improves polyphenyl
The mobility of ether, so that product has the advantages that to have good apparent mass, good processability and is molded fast.3rd, this hair
High temperature resistant nylon strand mutually interts with the strand of polyphenylene oxide and tangles in bright high temperature resistant nylon/polyphenylene oxide composite material so that
Product has preferable toughness and notched impact properties.
Specific embodiment
The present invention relates to a kind of high temperature resistant nylon/polyphenylene oxide composite material and its preparation method and application.
<High temperature resistant nylon/polyphenylene oxide composite material>
High temperature resistant nylon/polyphenylene oxide composite material of the invention contains following components and the weight portion of every kind of component is as follows：
Wherein, high temperature resistant nylon of the invention can be semi-aromatic nylon, and the semi-aromatic nylon can be more preferably
Any one or a few in PA6T, PA6I, PA9T, PA9I, PA10T, PA12T and PA13T.Different semi-aromatic nylons
1.8MPa under heat distortion temperature between 260-290 DEG C.
Polyphenylene oxide can be selected from and contain the homopolymers of 2,6- dimethyl benzene ether units, or selected from contain 2,6- dimethyl benzenes ether unit and
The copolymer of 2,3,6- trimethyl -1,4- phenylene ether units.Polyphenylene oxide can be preferably to be produced by China LanXing Chemical Group and provide, board
Number be PPO LXR038.
Compatilizer can be selected from maleic acid, maleic anhydride, fumaric acid, itaconic acid, glycidyl acrylate and citric acid
Any one or a few.
Coupling agent can selected from for VTES, gamma-aminopropyl-triethoxy-silane, γ-aminopropyltrimethoxysilane,
γ-propyl methacrylate base silane, γ-glycidyl ether oxygen propyl trimethoxy silicane, positive tetraisopropyl titanate and isopropyl three are different
Any one or a few in 18 acyl titanate esters.
Mineral filler can be inorganic mineral filler, and the inorganic mineral filler can be preferably mica, wollastonite, talcum powder, carbon
Any one or a few in sour calcium, barium sulfate or kaolin.The average grain diameter of inorganic mineral filler is 0.4-20 μm.Antioxidant
Can be phenolic antioxidant, the phenolic antioxidant can be preferably four [β-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid] Ji Wusi
Alcohol ester, β-positive octadecanol ester of (3,5- di-tert-butyl-hydroxy phenyls) propionic acid and the (the 4- tert-butyl group -3- hydroxyls -2,6- two of 1,3,5- tri-
Methyl-benzyl) any one or a few in -1,3,5- triazines -2,4,6- (1H, 3H, 5H)-triketone.
Lubricant can be fatty acid amide series lubricant agent, and the fatty acid amide series lubricant agent can be preferably N, and N '-bis- ethylenes are hard
Any one or a few in fatty acid amide, stearic amide, oleamide, zinc stearate and calcium stearate.
<The preparation method of high temperature resistant nylon/polyphenylene oxide composite material>
The preparation method of high temperature resistant nylon/polyphenylene oxide composite material of the invention comprises the following steps：
(1), by 30-50 parts of dry high temperature resistant nylon, 10-40 parts of dry polyphenylene oxide, 5-25 parts of dry mineral filler,
3-5 parts of compatilizer, 0.5-1 parts of coupling agent, 0.5-1 parts of antioxidant and 0.5-1 parts of lubricant are well mixed in high-speed mixer,
Obtain mixture；
(2), mixture is added in the double screw extruder from the main spout of double screw extruder, it is dry by 0-15 parts
Mineral filler is added in double screw extruder from the side spout of double screw extruder, by tie rod, cooling, pelletizing and drying
Deng obtaining high temperature resistant nylon/polyphenylene oxide composite material after post-processing step.
Wherein, in step (1), dry high temperature resistant nylon is by high temperature resistant nylon forced air drying 6-8 hours at 100-120 DEG C
Gained；Dry polyphenylene oxide is polyphenylene oxide at 100-110 DEG C obtained by forced air drying 6-8 hours；Dry mineral filler is mineral
Filler is at 110-130 DEG C obtained by forced air drying 6-8 hours.
In step (1), the rotating speed of high-speed mixer can be 600-800r/min, and the time of mixing can be 5-10min.
In step (2), double screw extruder is 295 ± 10 DEG C using zone temperature control, area's temperature, and two area's temperature are
295 ± 10 DEG C, three area's temperature are 300 ± 10 DEG C, and four area's temperature are 305 ± 10 DEG C, and five area's temperature are 315 ± 10 DEG C, six area's temperature
It it is 315 ± 10 DEG C, seven area's temperature are 315 ± 10 DEG C, eight area's temperature are 310 ± 10 DEG C, nine area's temperature are 305 ± 10 DEG C, ten area's temperature
It is 305 ± 10 DEG C to spend, and head temperature is 305 ± 10 DEG C, 250-350 revs/min of screw speed.
One area's temperature is equal to two area's temperature.Three area's temperature, four area's temperature and five area's temperature then gradually rise, i.e. five area's temperature>4th area
Temperature>Three area's temperature, it is preferable that five+10 DEG C of temperature=tetra- area of area temperature, four+10 DEG C of temperature=tri- area of area temperature.Five area's temperature,
Six area's temperature and seven area's temperature are equal.Seven area's temperature, eight area's temperature and nine area's temperature are gradually reduced again, i.e. seven area's temperature>Eight area's temperature
Degree>Nine area's temperature, it is preferable that seven+5 DEG C of temperature=eight area of area temperature, eight+5 DEG C of temperature=nine area of area temperature.Nine area's temperature, tenth area
Temperature and head temperature are equal, i.e. nine temperature=ten area of area temperature=head temperature.Above each area's temperature gradually rises, and can make
Temperature of charge progressivelyes reach suitable processing temperature, behind cause that temperature of charge continues to raise due to screw rod shearing, so reducing each
Area's temperature avoids that temperature of charge is too high to cause material to thermally decompose.
In the preparation method of high temperature resistant nylon/polyphenylene oxide composite material of the invention, mineral filler can be added at twice, every time
The species of the mineral filler of addition can be with identical, it is also possible to different.The weight portion of the second dry mineral filler for adding can be with
Preferably 1-15 parts.
<The application of high temperature resistant nylon/polyphenylene oxide composite material>
High temperature resistant nylon/polyphenylene oxide composite material of the invention can be applied in electronic apparatus industry (such as auto industry),
Such as it is used to prepare the high temperature resistant component in automobile.
<Embodiment>
Embodiment one
The constituent content of the high temperature resistant nylon/polyphenylene oxide composite material of the present embodiment is as shown in table 1 below：
The constituent content table of the high temperature resistant nylon/polyphenylene oxide composite material of the embodiment one of table 1
The preparation method of the high temperature resistant nylon/polyphenylene oxide composite material of the present embodiment comprises the following steps：
(1), by high temperature resistant nylon, polyphenylene oxide and mineral filler respectively at air blast in 110 DEG C, 105 DEG C and 120 DEG C of drying box
6h is dried, dry high temperature resistant nylon, dry polyphenylene oxide and dry mineral filler is obtained；
(2), by 40 parts of dry high temperature resistant nylons, 20 parts of dry polyphenylene oxide, 25 parts of dry mineral fillers, 4 parts of phases
Hold agent, 0.5 part of coupling agent, 0.5 part of antioxidant and 0.5 part of lubricant to be well mixed in high-speed mixer, the high-speed mixer
Rotating speed be 650r/min, incorporation time is 8min, obtains mixture；
(3), mixture is added in the double screw extruder from the main spout of double screw extruder, by 15 parts of dry ore deposits
Thing filler is added in double screw extruder from the side spout of double screw extruder, by tie rod, cooling, pelletizing and drying etc.
High temperature resistant nylon/polyphenylene oxide composite material is obtained after post-processing step.
Wherein, in step (3), double screw extruder is respectively using zone temperature control, each area's temperature：One area's temperature is
295 ± 10 DEG C, two area's temperature are 295 ± 10 DEG C, and three area's temperature are 300 ± 10 DEG C, and four area's temperature are 305 ± 10 DEG C, five area's temperature
It it is 315 ± 10 DEG C, six area's temperature are 315 ± 10 DEG C, seven area's temperature are 315 ± 10 DEG C, eight area's temperature are 310 ± 10 DEG C, nine area's temperature
It is 305 ± 10 DEG C to spend, and ten area's temperature are 305 ± 10 DEG C, and head temperature is 305 ± 10 DEG C, 250-350 revs/min of screw speed.
Embodiment two
The constituent content of the high temperature resistant nylon/polyphenylene oxide composite material of the present embodiment is as shown in table 2 below：
The constituent content table of the high temperature resistant nylon/polyphenylene oxide composite material of the embodiment two of table 2
The preparation method of the high temperature resistant nylon/polyphenylene oxide composite material of the present embodiment comprises the following steps：
(1), by high temperature resistant nylon, polyphenylene oxide and mineral filler respectively at air blast in 110 DEG C, 105 DEG C and 120 DEG C of drying box
6h is dried, dry high temperature resistant nylon, dry polyphenylene oxide and dry mineral filler is obtained；
(2), by 40 parts of dry high temperature resistant nylons, 30 parts of dry polyphenylene oxide, 20 parts of dry mineral fillers, 4 parts of phases
Hold agent, 0.5 part of coupling agent, 0.5 part of antioxidant and 0.5 part of lubricant to be well mixed in high-speed mixer, the high-speed mixer
Rotating speed be 650r/min, incorporation time is 8min, obtains mixture；
(3), mixture is added in the double screw extruder from the main spout of double screw extruder, by 10 parts of dry ore deposits
Thing filler is added in double screw extruder from the side spout of double screw extruder, by tie rod, cooling, pelletizing and drying etc.
High temperature resistant nylon/polyphenylene oxide composite material is obtained after post-processing step.
Wherein, in step (3), double screw extruder is respectively using zone temperature control, each area's temperature：One area's temperature is
295 ± 10 DEG C, two area's temperature are 295 ± 10 DEG C, and three area's temperature are 300 ± 10 DEG C, and four area's temperature are 305 ± 10 DEG C, five area's temperature
It it is 315 ± 10 DEG C, six area's temperature are 315 ± 10 DEG C, seven area's temperature are 315 ± 10 DEG C, eight area's temperature are 310 ± 10 DEG C, nine area's temperature
It is 305 ± 10 DEG C to spend, and ten area's temperature are 305 ± 10 DEG C, and head temperature is 305 ± 10 DEG C, 250-350 revs/min of screw speed.
Embodiment three
The constituent content of the high temperature resistant nylon/polyphenylene oxide composite material of the present embodiment is as shown in table 3 below：
The constituent content table of the high temperature resistant nylon/polyphenylene oxide composite material of the embodiment three of table 3
The preparation method of the high temperature resistant nylon/polyphenylene oxide composite material of the present embodiment comprises the following steps：
(1), by high temperature resistant nylon, polyphenylene oxide and mineral filler respectively at air blast in 110 DEG C, 105 DEG C and 120 DEG C of drying box
6h is dried, dry high temperature resistant nylon, dry polyphenylene oxide and dry mineral filler is obtained；
(2), by 40 parts of dry high temperature resistant nylons, 30 parts of dry polyphenylene oxide, 20 parts of dry mineral fillers, 4 parts of phases
Hold agent, 0.5 part of coupling agent, 0.5 part of antioxidant and 0.5 part of lubricant to be well mixed in high-speed mixer, the high-speed mixer
Rotating speed be 650r/min, incorporation time is 8min, obtains mixture；
(3), by mixture from the main spout of double screw extruder be added to the double screw extruder in (double screw extruder
Mineral filler is added without in side spout), by obtaining high temperature resistant nylon after the post-processing steps such as tie rod, cooling, pelletizing and drying
/ polyphenylene oxide composite material.
Wherein, in step (3), double screw extruder is respectively using zone temperature control, each area's temperature：One area's temperature is
295 ± 10 DEG C, two area's temperature are 295 ± 10 DEG C, and three area's temperature are 300 ± 10 DEG C, and four area's temperature are 305 ± 10 DEG C, five area's temperature
It it is 315 ± 10 DEG C, six area's temperature are 315 ± 10 DEG C, seven area's temperature are 315 ± 10 DEG C, eight area's temperature are 310 ± 10 DEG C, nine area's temperature
It is 305 ± 10 DEG C to spend, and ten area's temperature are 305 ± 10 DEG C, and head temperature is 305 ± 10 DEG C, 250-350 revs/min of screw speed.
Example IV
The constituent content of the high temperature resistant nylon/polyphenylene oxide composite material of the present embodiment is as shown in table 4 below：
The constituent content table of the high temperature resistant nylon/polyphenylene oxide composite material of the example IV of table 4
The preparation method of the high temperature resistant nylon/polyphenylene oxide composite material of the present embodiment comprises the following steps：
(1), by high temperature resistant nylon, polyphenylene oxide and mineral filler respectively at air blast in 110 DEG C, 105 DEG C and 120 DEG C of drying box
6h is dried, dry high temperature resistant nylon, dry polyphenylene oxide and dry mineral filler is obtained；
(2), by 50 parts of dry high temperature resistant nylons, 10 parts of dry polyphenylene oxide, 25 parts of dry mineral fillers, 5 parts of phases
Hold agent, 1 part of coupling agent, 1 part of antioxidant and 1 part of lubricant to be well mixed in high-speed mixer, the rotating speed of the high-speed mixer
It is 650r/min, incorporation time is 8min, obtains mixture；
(3), mixture is added in the double screw extruder from the main spout of double screw extruder, by 15 parts of dry ore deposits
Thing filler is added in double screw extruder from the side spout of double screw extruder, by tie rod, cooling, pelletizing and drying etc.
High temperature resistant nylon/polyphenylene oxide composite material is obtained after post-processing step.
Wherein, in step (3), double screw extruder is respectively using zone temperature control, each area's temperature：One area's temperature is
295 ± 10 DEG C, two area's temperature are 295 ± 10 DEG C, and three area's temperature are 300 ± 10 DEG C, and four area's temperature are 305 ± 10 DEG C, five area's temperature
It it is 315 ± 10 DEG C, six area's temperature are 315 ± 10 DEG C, seven area's temperature are 315 ± 10 DEG C, eight area's temperature are 310 ± 10 DEG C, nine area's temperature
It is 305 ± 10 DEG C to spend, and ten area's temperature are 305 ± 10 DEG C, and head temperature is 305 ± 10 DEG C, 250-350 revs/min of screw speed.
Embodiment five
The constituent content of the high temperature resistant nylon/polyphenylene oxide composite material of the present embodiment is as shown in table 5 below：
The constituent content table of the high temperature resistant nylon/polyphenylene oxide composite material of the embodiment five of table 5
The preparation method of the high temperature resistant nylon/polyphenylene oxide composite material of the present embodiment comprises the following steps：
(1), by high temperature resistant nylon, polyphenylene oxide and mineral filler respectively at air blast in 110 DEG C, 105 DEG C and 120 DEG C of drying box
8h is dried, dry high temperature resistant nylon, dry polyphenylene oxide and dry mineral filler is obtained；
(2), by 30 parts of dry high temperature resistant nylons, 30 parts of dry polyphenylene oxide, 25 parts of dry mineral fillers, 5 parts of phases
Hold agent, 1 part of coupling agent, 1 part of antioxidant and 1 part of lubricant to be well mixed in high-speed mixer, the rotating speed of the high-speed mixer
It is 650r/min, incorporation time is 8min, obtains mixture；
(3), mixture is added in the double screw extruder from the main spout of double screw extruder, by 15 parts of dry ore deposits
Thing filler is added in double screw extruder from the side spout of double screw extruder, by tie rod, cooling, pelletizing and drying etc.
High temperature resistant nylon/polyphenylene oxide composite material is obtained after post-processing step.
Wherein, in step (3), double screw extruder is respectively using zone temperature control, each area's temperature：One area's temperature is
295 ± 10 DEG C, two area's temperature are 295 ± 10 DEG C, and three area's temperature are 300 ± 10 DEG C, and four area's temperature are 305 ± 10 DEG C, five area's temperature
It it is 315 ± 10 DEG C, six area's temperature are 315 ± 10 DEG C, seven area's temperature are 315 ± 10 DEG C, eight area's temperature are 310 ± 10 DEG C, nine area's temperature
It is 305 ± 10 DEG C to spend, and ten area's temperature are 305 ± 10 DEG C, and head temperature is 305 ± 10 DEG C, 250-350 revs/min of screw speed.
Embodiment six
The constituent content of the high temperature resistant nylon/polyphenylene oxide composite material of the present embodiment is as shown in table 6 below：
The constituent content table of the high temperature resistant nylon/polyphenylene oxide composite material of the embodiment six of table 6
The preparation method of the high temperature resistant nylon/polyphenylene oxide composite material of the present embodiment comprises the following steps：
(1), by high temperature resistant nylon, polyphenylene oxide and mineral filler respectively at air blast in 110 DEG C, 105 DEG C and 120 DEG C of drying box
6h is dried, dry high temperature resistant nylon, dry polyphenylene oxide and dry mineral filler is obtained；
(2), by 40 parts of dry high temperature resistant nylons, 20 parts of dry polyphenylene oxide, 25 parts of dry mineral fillers, 4 parts of phases
Hold agent, 0.5 part of coupling agent, 0.5 part of antioxidant and 0.5 part of lubricant to be well mixed in high-speed mixer, the high-speed mixer
Rotating speed be 650r/min, incorporation time is 8min, obtains mixture；
(3), mixture is added in the double screw extruder from the main spout of double screw extruder, by 15 parts of dry ore deposits
Thing filler is added in double screw extruder from the side spout of double screw extruder, by tie rod, cooling, pelletizing and drying etc.
High temperature resistant nylon/polyphenylene oxide composite material is obtained after post-processing step.
Wherein, in step (3), double screw extruder is respectively using zone temperature control, each area's temperature：One area's temperature is
295 ± 10 DEG C, two area's temperature are 295 ± 10 DEG C, and three area's temperature are 300 ± 10 DEG C, and four area's temperature are 305 ± 10 DEG C, five area's temperature
It it is 315 ± 10 DEG C, six area's temperature are 315 ± 10 DEG C, seven area's temperature are 315 ± 10 DEG C, eight area's temperature are 310 ± 10 DEG C, nine area's temperature
It is 305 ± 10 DEG C to spend, and ten area's temperature are 305 ± 10 DEG C, and head temperature is 305 ± 10 DEG C, 250-350 revs/min of screw speed.
Embodiment seven
The constituent content of the high temperature resistant nylon/polyphenylene oxide composite material of the present embodiment is as shown in table 7 below：
The constituent content table of the high temperature resistant nylon/polyphenylene oxide composite material of the embodiment seven of table 7
The preparation method of the high temperature resistant nylon/polyphenylene oxide composite material of the present embodiment comprises the following steps：
(1), by high temperature resistant nylon, polyphenylene oxide and mineral filler respectively at air blast in 110 DEG C, 105 DEG C and 120 DEG C of drying box
6h is dried, dry high temperature resistant nylon, dry polyphenylene oxide and dry mineral filler is obtained；
(2), by 40 parts of dry high temperature resistant nylons, 30 parts of dry polyphenylene oxide, 20 parts of dry mineral fillers, 4 parts of phases
Hold agent, 0.5 part of coupling agent, 0.5 part of antioxidant and 0.5 part of lubricant to be well mixed in high-speed mixer, the high-speed mixer
Rotating speed be 650r/min, incorporation time is 8min, obtains mixture；
(3), mixture is added in the double screw extruder from the main spout of double screw extruder, by 10 parts of dry ore deposits
Thing filler is added in double screw extruder from the side spout of double screw extruder, by tie rod, cooling, pelletizing and drying etc.
High temperature resistant nylon/polyphenylene oxide composite material is obtained after post-processing step.
Wherein, in step (3), double screw extruder is respectively using zone temperature control, each area's temperature：One area's temperature is
295 ± 10 DEG C, two area's temperature are 295 ± 10 DEG C, and three area's temperature are 300 ± 10 DEG C, and four area's temperature are 305 ± 10 DEG C, five area's temperature
It it is 315 ± 10 DEG C, six area's temperature are 315 ± 10 DEG C, seven area's temperature are 315 ± 10 DEG C, eight area's temperature are 310 ± 10 DEG C, nine area's temperature
It is 305 ± 10 DEG C to spend, and ten area's temperature are 305 ± 10 DEG C, and head temperature is 305 ± 10 DEG C, 250-350 revs/min of screw speed.
Embodiment eight
The constituent content of the high temperature resistant nylon/polyphenylene oxide composite material of the present embodiment is as shown in table 8 below：
The constituent content table of the high temperature resistant nylon/polyphenylene oxide composite material of the embodiment eight of table 8
The preparation method of the high temperature resistant nylon/polyphenylene oxide composite material of the present embodiment comprises the following steps：
(1), by high temperature resistant nylon, polyphenylene oxide and mineral filler respectively at air blast in 110 DEG C, 105 DEG C and 120 DEG C of drying box
6h is dried, dry high temperature resistant nylon, dry polyphenylene oxide and dry mineral filler is obtained；
(2), by 40 parts of dry high temperature resistant nylons, 30 parts of dry polyphenylene oxide, 20 parts of dry mineral fillers, 4 parts of phases
Hold agent, 0.5 part of coupling agent, 0.5 part of antioxidant and 0.5 part of lubricant to be well mixed in high-speed mixer, the high-speed mixer
Rotating speed be 650r/min, incorporation time is 8min, obtains mixture；
(3), by mixture from the main spout of double screw extruder be added to the double screw extruder in ((double screw extruder
Mineral filler is added without in side spout)), by obtaining high temperature resistant Buddhist nun after the post-processing steps such as tie rod, cooling, pelletizing and drying
Dragon/polyphenylene oxide composite material.
Wherein, in step (3), double screw extruder is respectively using zone temperature control, each area's temperature：One area's temperature is
295 ± 10 DEG C, two area's temperature are 295 ± 10 DEG C, and three area's temperature are 300 ± 10 DEG C, and four area's temperature are 305 ± 10 DEG C, five area's temperature
It it is 315 ± 10 DEG C, six area's temperature are 315 ± 10 DEG C, seven area's temperature are 315 ± 10 DEG C, eight area's temperature are 310 ± 10 DEG C, nine area's temperature
It is 305 ± 10 DEG C to spend, and ten area's temperature are 305 ± 10 DEG C, and head temperature is 305 ± 10 DEG C, 250-350 revs/min of screw speed.
High temperature resistant nylon/polyphenylene oxide composite material to embodiment one to embodiment eight carries out property measure, as a result as shown in table 9.
The embodiment one of table 9 to the property of the high temperature resistant nylon/polyphenylene oxide composite material of embodiment eight determines table
| Performance | Tensile strength | Bending strength | Bending modulus | Izod notch impact strengths | HDT |
| Method of testing | ASTM D638 | ASTM D790 | ASTM D790 | ASTM D256 | ISO 75‐2 |
| Unit | MPa | MPa | MPa | KJ/m2 | ℃ |
| Embodiment one | 142 | 258 | 11431 | 17 | 281 |
| Embodiment two | 135 | 251 | 10078 | 15 | 278 |
| Embodiment three | 130 | 246 | 9878 | 12 | 272 |
| Example IV | 85 | 257 | 11628 | 18 | 285 |
| Embodiment five | 126 | 263 | 11342 | 15 | 281 |
| Embodiment six | 109 | 251 | 11453 | 17 | 274 |
| Embodiment seven | 123 | 248 | 10827 | 15 | 277 |
| Embodiment eight | 138 | 233 | 9724 | 12 | 262 |
The above-mentioned description to embodiment is to be understood that and use the present invention for ease of those skilled in the art.It is familiar with
The personnel of art technology obviously can easily make various modifications to these embodiments, and should General Principle described herein
Use in other embodiment without by performing creative labour.Therefore, the invention is not restricted to above-described embodiment, art technology
Personnel's announcement of the invention, does not depart from improvement that scope made and modification all should be in protection scope of the present invention
Within.
Claims (10)
1. a kind of high temperature resistant nylon/polyphenylene oxide composite material, it is characterised in that：Weight portion containing following components and every kind of component
It is as follows：
2. high temperature resistant nylon/polyphenylene oxide composite material according to claim 1, it is characterised in that：The high temperature resistant nylon is
Semi-aromatic nylon；
Preferably, the semi-aromatic nylon is selected from appointing in PA6T, PA6I, PA9T, PA9I, PA10T, PA12T and PA13T
Anticipate one or more.
3. high temperature resistant nylon/polyphenylene oxide composite material according to claim 1, it is characterised in that：The polyphenylene oxide be containing
The homopolymers of 2,6- dimethyl benzene ether units, or be to contain 2,6- dimethyl benzenes ether unit and 2,3,6- trimethyls-Isosorbide-5-Nitrae-phenylene ether units
Copolymer；And/or,
The compatilizer is selected from appointing in maleic acid, maleic anhydride, fumaric acid, itaconic acid, glycidyl acrylate and citric acid
Anticipate one or more；And/or,
Described coupling agent be selected from VTES, gamma-aminopropyl-triethoxy-silane, γ-aminopropyltrimethoxysilane,
γ-propyl methacrylate base silane, γ-glycidyl ether oxygen propyl trimethoxy silicane, positive tetraisopropyl titanate and isopropyl three are different
Any one or a few in 18 acyl titanate esters.
4. high temperature resistant nylon/polyphenylene oxide composite material according to claim 1, it is characterised in that：The mineral filler is nothing
Machine mineral filler；
Preferably, the mineral filler is selected from any one in mica, wollastonite, talcum powder, calcium carbonate, barium sulfate or kaolin
Plant or several.
5. high temperature resistant nylon/polyphenylene oxide composite material according to claim 1, it is characterised in that：The antioxidant is phenols
Antioxidant；
Preferably, the antioxidant is selected from four [β-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol esters, β-(3,5-
Di-tert-butyl-hydroxy phenyl) the positive octadecanol ester of propionic acid and 1,3,5- tri- (the 4- tert-butyl group -3- hydroxyl -2,6- dimethyl benzyls) -1,3,5-
Any one or a few in triazine -2,4,6- (1H, 3H, 5H)-triketone.
6. high temperature resistant nylon/polyphenylene oxide composite material according to claim 1, it is characterised in that：The lubricant is fat
Sour acid amides series lubricant agent；
Preferably, the lubricant is selected from N, N '-bis- ethylene hard fatty acids acid amides, stearic amide, oleamide, zinc stearate
With any one or a few in calcium stearate.
7. a kind of preparation method of high temperature resistant nylon/polyphenylene oxide composite material as described in any in claim 1 to 6, its feature
It is：Comprise the following steps：
(1), by 30-50 parts of dry high temperature resistant nylon, 10-40 parts of dry polyphenylene oxide, 5-25 parts of dry mineral filler,
3-5 parts of compatilizer, 0.5-1 parts of coupling agent, 0.5-1 parts of antioxidant, 0.5-1 parts of lubricant are well mixed in high-speed mixer, obtain
To mixture；
(2), the mixture is added in the double screw extruder from the main spout of double screw extruder, it is dry by 0-15 parts
Dry mineral filler is added in the double screw extruder from the side spout of double screw extruder, by tie rod, cooling, pelletizing and
High temperature resistant nylon/polyphenylene oxide composite material is obtained after drying.
8. preparation method according to claim 7, it is characterised in that：The dry high temperature resistant nylon is by high temperature resistant nylon
At 100-120 DEG C obtained by forced air drying 6-8 hours；And/or,
The dry polyphenylene oxide is polyphenylene oxide at 100-110 DEG C obtained by forced air drying 6-8 hours；And/or,
The dry mineral filler is mineral filler at 110-130 DEG C obtained by forced air drying 6-8 hours.
9. preparation method according to claim 7, it is characterised in that：In step (1), the high-speed mixer turn
Speed is 600-800r/min；And/or,
In step (1), the time of the high-speed mixer mixing is 5-10min.
10. preparation method according to claim 7, it is characterised in that：In step (2), the double screw extruder is adopted
Zone temperature control is used, area's temperature is 295 ± 10 DEG C, and two area's temperature are 295 ± 10 DEG C, and three area's temperature are 300 ± 10 DEG C, 4th area
Temperature is 305 ± 10 DEG C, and five area's temperature are 315 ± 10 DEG C, and six area's temperature are 315 ± 10 DEG C, and seven area's temperature are 315 ± 10 DEG C, 8th area
Temperature is 310 ± 10 DEG C, and nine area's temperature are 305 ± 10 DEG C, and ten area's temperature are 305 ± 10 DEG C, and head temperature is 305 ± 10 DEG C, screw rod
250-350 revs/min of rotating speed.
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