CN106927112A - A kind of transparent sealed membrane for Easy tearing lid, preparation method and transparent Easy tearing lid - Google Patents
A kind of transparent sealed membrane for Easy tearing lid, preparation method and transparent Easy tearing lid Download PDFInfo
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- CN106927112A CN106927112A CN201710119538.8A CN201710119538A CN106927112A CN 106927112 A CN106927112 A CN 106927112A CN 201710119538 A CN201710119538 A CN 201710119538A CN 106927112 A CN106927112 A CN 106927112A
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- easy tearing
- sealed membrane
- tearing lid
- layer
- transparent sealed
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D17/00—Rigid or semi-rigid containers specially constructed to be opened by cutting or piercing, or by tearing of frangible members or portions
- B65D17/02—Rigid or semi-rigid containers specially constructed to be opened by cutting or piercing, or by tearing of frangible members or portions of curved cross-section, e.g. cans of circular or elliptical cross-section
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
- C09J7/25—Plastics; Metallised plastics based on macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/255—Polyesters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
- C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/385—Acrylic polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D2517/00—Containers specially constructed to be opened by cutting, piercing or tearing of wall portions, e.g. preserving cans or tins
- B65D2517/0001—Details
- B65D2517/0002—Location of opening
- B65D2517/0007—Location of opening in a separate cover
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Laminated Bodies (AREA)
Abstract
A kind of transparent sealed membrane for Easy tearing lid, preparation method and transparent Easy tearing lid, transparent sealed membrane include the pet film layer being brought into close contact and hot sealing layer, and two-layer is combined by compound or gluing mode in preparation process.Than traditional easy open cover and the canned packaging of sled lid combination cover form, hyaline membrane Easy tearing lid does not have tiny coating bits and metal fillings to fall into the secondary pollution caused in tank to food when uncapping, metal decorative cover after treatment does not have sharp edge, the potential danger of scratching fingers is prevented, so that there is provided a kind of packaging selection of new hommization.The use of hyaline membrane, makes consumer can directly be seen that the food situation in packaging, it is to avoid corrupt expired food is purchased, and enhances the sense of security of consumer.Meanwhile, the visualization of delicacy is also by the desire to buy for stimulating consumer.Can be widely applied to the drysaltery packaging of the leisure food such as nut, candy, and sterilized and hot fill product the packaging such as fruit, fish, soup.
Description
Technical field
The present invention relates to packing technique field, and in particular to a kind of transparent sealed membrane for Easy tearing lid, preparation method and
Transparent Easy tearing lid.
Background technology
Drawing lid and lid for the pop can of packaging for foodstuff are generally that metal is made, and draw fix tightly between lid and lid
Gu so that draw lid to open difficult.In addition, if after being pulled open from La Gai, lid mouth is sharp due to metal edges after can opening, it is also possible to can draw
Broken user's skin.Develop later and pull open the Easy tearing lid product easy open cover to be replaced that part is made up of aluminium foil.Aluminium foil Easy tearing lid
It is full metal sealing with easy open cover, does not possess perspectivity, limited to understanding of the consumer to product in tank, consumption is reduced sometimes
The desire to buy of person and the trust to product.And aluminium foil is replaced using common packaging for foodstuff hyaline membrane, there is difficult processing, anti-corrosion again
Property it is poor, seal it is unstable the problems such as.
The content of the invention
The present invention is regarding to the issue above, there is provided a kind of transparent sealed membrane for Easy tearing lid, preparation method and transparent easily tear
Lid.
The technical solution used in the present invention is as follows:A kind of transparent sealed membrane for Easy tearing lid, including be brought into close contact
Pet film layer and hot sealing layer.
Pet film has the features such as intensity is high, rigidity is good, transparent, glossiness is high;Odorless, nothing
Taste, colourless, nontoxic, prominent obdurability;Its tensile strength is PC(Makrolon)3 times of film, nylon membrane, impact strength is
BOPP film(Bidirectional stretching polypropylene film)3-5 times, have fabulous wearability, folding resistance, pinhole resistance and tear resistance
Deng;Heat-shrinkable is minimum, so as to improve the adhesive force of its heat sealability, barrier and printing;Polyethylene terephthalate is also
With good heat resistance, excellent boiling resistance, low temperature resistant freezing, good oil resistivity and chemical-resistant etc..It is poly- right
In addition to nitrobenzene, chloroform, phenmethylol, most of chemicals all can not dissolve it for PET film.It is poly- right
PET film water absorption rate is low, water-tolerant, proper packing water content food high.
Preferred scheme one, the hot sealing layer is modified poly ethylene film or cast polypropylene film.
The modified poly ethylene film, it is composed of the following components:
10 ~ 20wt% of polybutene;
20 ~ 40wt% of ethylene-propylene copolymer;
50 ~ 70wt% of high density polyethylene (HDPE).
Preferred scheme two, the hot sealing layer is heat-seal adhesive.
The heat-seal adhesive, it is composed of the following components:
Acroleic acid resin 30-55wt%;
Polypropylene 10-25wt%;
Ethyl acetate 20-50wt%.
Word and/or pattern can be printed with the pet film layer.
Transparent sealed membrane in preferred scheme one, its preparation process is as follows:The pet film
Layer and hot sealing layer are combined by dry type or solvent-free compound mode adds binder to be brought into close contact, followed by aging.Preferably, institute
Pet film layer is stated to be combined by dry type for two-layer pet film or without molten
The compound mode of agent adds binder to be brought into close contact to be formed.The combination of two-layer pet film can strengthen envelope
Mouth film strength, deflection.The hot sealing layer formed by modified poly ethylene film or cast polypropylene film, its thickness is 20 μm -100
μm.Modified poly ethylene film and polypropylene film have excellent heat sealability.With decorative cover heat-sealing, function admirable, with easily taking off
The property opened.
Transparent sealed membrane in preferred scheme two, its preparation process is as follows:By glue spreader in poly terephthalic acid second two
Alcohol ester thin-film surface adds heat-seal adhesive to form hot sealing layer, it is preferable that the pet film layer is two
Layer pet film is combined by dry type or solvent-free compound mode adds binder to be brought into close contact shape
Into followed by aging.Heat-seal adhesive has excellent heat sealability.With decorative cover heat-sealing, function admirable, with the easy property opened.
Gluing process can be completed by glue spreader, and the control parameter of gluing process is as follows:
Application rate:50-100 ms/min;
Drying temperature:Using three sections of drying, drying tunnel dries actual temp:
One section:80-130 DEG C, two sections:100-150 DEG C, three sections:100-130℃;
Heat-seal adhesive coating weight:4.0-10.0g/m2;
The hot sealing layer thickness of formation is 1-10 μm.
It refers to just that adhesive carries out a kind of compound method in a dry state that dry type is compound, is first to apply on a substrate
Good binder, is dried by drying tunnel, and the solvent in binder is all dried, then another base material is fitted therewith, Ran Houjing
Supercooling, produces the process of the composite with premium properties after maturation process, can be completed by dry compound machine.
The compound control parameter of dry type is as follows:
Speed:Less than or equal to 200 ms/min;
Drying tunnel drying temperature:Using three sections of drying, one section:50-65 DEG C, two sections:60-75 DEG C three sections:70-90℃;
Hot drum binding temperature:50-70℃;
Spread:2.0-5.0g/m2/ layer.
It is solvent-free compound, it is using the solventless adhesive of 100% solid, by two kinds of base materials on solvent-free composite machine
A kind of method being combined with each other, it is compound also known as response type.Solvent-free compound control parameter is as follows:
Speed:Less than or equal to 400 ms/min;
Metering roll temperature is 35-50 DEG C, and gluing roll temperature is 40-55 DEG C;
Hot drum binding temperature:40-60℃;
Spread:1.0-4.0g/m2/ layer.
Preferably, the thickness of binder is 1-5 μm.
Preferably, the thickness per strata ethylene glycol terephthalate is 6 μm -150 μm.That is individual layer poly terephthalic acid second
The pet film thickness degree that terephthalate films are formed is 6 μm -150 μm, two-layer poly terephthalic acid second
The pet film thickness degree that terephthalate films are formed is 13-305 μm.
Preferably, the condition of curing is as follows:At 35-60 DEG C, the curing time is more than or equal to 48 h.
A kind of transparent Easy tearing lid, including lid, sealed membrane, the lid are provided with and take thing hole, and the ParafilmTM takes
Thing hole, the sealed membrane is above-mentioned transparent sealed membrane.
Beneficial effects of the present invention are as follows:Hyaline membrane Easy tearing lid has had both the advantage of Easy tearing lid and plastic, transparent film.It is transparent
Film Easy tearing lid is made bezel ring, by aluminium or iron material, is fitted under conditions of HTHP with transparent polymer composite membrane and formed.Open
Qi Shi, need to only tear hyaline membrane.Than traditional easy open cover and the canned packaging of sled lid combination cover form, hyaline membrane is easy
Tear to cover does not have tiny coating bits and metal fillings to fall into the secondary pollution caused in tank to food when uncapping, the metal after treatment
Decorative cover does not have sharp edge, has prevented the potential danger of scratching fingers, so that there is provided a kind of packaging of new hommization
Selection.The use of hyaline membrane, makes consumer can directly be seen that the food situation in packaging, it is to avoid corrupt expired food is purchased
Buy, enhance the sense of security of consumer.Meanwhile, the visualization of delicacy is also by the desire to buy for stimulating consumer.In addition, transparent
Can be presented on various graph text informations in packaging using technologies such as intaglio printings by film, make product more attractive in appearance.In sum,
It can be seen that hyaline membrane Easy tearing lid have it is convenient open, safe and reliable, texture is slim and graceful, good appearance and it is rich and changeful the advantages of.Can be wide
The general drysaltery packaging for being applied to the leisure food such as nut, candy, can also be applied to the sterilized and hot filling such as fruit, fish, soup
Fill the packaging of product.
Specific embodiment
Embodiment 1
1) modified PE is prepared
Film is obtained after being blended by following components:
Polybutene 10wt%;
Ethylene-propylene copolymer 40wt%;
High density polyethylene (HDPE) 50wt%;
The thickness of obtained modified poly ethylene film is 20 μm -100 μm.
2) print(When needing pattern, word)
Pattern, word, key control parameter are stamped on pet film by intaglio press:
Speed:Wound roll material prints, speed 100-300m/ points;
Drying temperature:50-80℃;
The space of a whole page is errorless, and without obvious aberration, chromatography is accurate, and ink is uniform.
3) pet film and step 1)Obtained modified poly ethylene Film laminated
With dry compound machine by pet film and step 1)Obtained modified poly ethylene Film laminated, gathers
The thickness of ethylene glycol terephthalate film is 6 μm -150 μm, key control parameter:
Speed:Less than or equal to 200 ms/min;
Drying tunnel drying temperature:Using three sections of drying, one section:50-65 DEG C, two sections:60-75 DEG C three sections:70-90℃;
Hot drum binding temperature:50-70℃;
Spread(Butt):2.0-5.0g/m2/ layer.
4) cure
At 35-60 DEG C, the curing time is more than or equal to 48 h.
5) cutting forms the transparent sealed membrane for Easy tearing lid.
Embodiment 2
1) modified PE is prepared
Film is obtained after being blended by following components:
Polybutene 20wt%;
Ethylene-propylene copolymer 20wt%;
High density polyethylene (HDPE) 60wt%;
The thickness of obtained modified poly ethylene film is 20 μm -100 μm.
2) print(When needing pattern, word)
Pattern, word, key control parameter are stamped on pet film by intaglio press:
Speed:Wound roll material prints, speed 100-300m/ points;
Drying temperature:50-80℃;
The space of a whole page is errorless, and without obvious aberration, chromatography is accurate, and ink is uniform.
3) pet film and step 1)Obtained modified poly ethylene Film laminated
With solvent-free composite machine by pet film and step 1)Obtained modified poly ethylene Film laminated,
The thickness of pet film is 6 μm -150 μm, key control parameter:
Speed:Less than or equal to 400 ms/min;
Metering roll temperature is 35-50 DEG C, and gluing roll temperature is 40-55 DEG C;
Hot drum binding temperature:40-60℃;
Spread(Butt):1.0-4.0g/m2/ layer.
4) cure
At 35-60 DEG C, the curing time is more than or equal to 48 h.
5) cutting forms the transparent sealed membrane for Easy tearing lid.
Embodiment 3
1) modified PE is prepared
Film is obtained after being blended by following components:
Polybutene 10wt%;
Ethylene-propylene copolymer 20wt%;
High density polyethylene (HDPE) 70wt%;
The thickness of obtained modified poly ethylene film is 20 μm -100 μm.
2) print(When needing pattern, word)
Pattern, word, key control parameter are stamped on pet film by intaglio press:
Speed:Wound roll material prints, speed 100-300m/ points;
Drying temperature:50-80℃;
The space of a whole page is errorless, and without obvious aberration, chromatography is accurate, and ink is uniform.
3) two-layer pet film is combined
Two-layer pet film is combined with solvent-free composite machine is made polyethylene terephthalate
Film layer, key control parameter:
Speed:Less than or equal to 400 ms/min;
Metering roll temperature is 35-50 DEG C, and gluing roll temperature is 40-55 DEG C;
Hot drum binding temperature:40-60℃;
Spread(Butt):1.0-4.0g/m2/ layer;
Every layer of thickness of pet film is 6 μm -150 μm.
4) step 3)Obtained pet film layer and step 1)Obtained modified poly ethylene film
It is compound(
With solvent-free composite machine by step 3)Obtained pet film layer and step 1)It is obtained modified
Polyethylene film is combined, key control parameter:
Speed:Less than or equal to 400 ms/min;
Metering roll temperature is 35-50 DEG C, and gluing roll temperature is 40-55 DEG C;
Hot drum binding temperature:40-60℃;
Spread(Butt):1.0-4.0g/m2/ layer.
5) cure
At 35-60 DEG C, the curing time is more than or equal to 48 h.
6) cutting forms the transparent sealed membrane for Easy tearing lid.
Embodiment 4
1) print(When needing pattern, word)
Pattern, word, key control parameter are stamped on pet film by intaglio press:
Speed:Wound roll material prints, speed 100-300m/ points;
Drying temperature:50-80℃;
The space of a whole page is errorless, and without obvious aberration, chromatography is accurate, and ink is uniform.
2) pet film is combined with cast polypropylene film
Pet film and cast polypropylene film are combined with solvent-free composite machine, poly terephthalic acid
The thickness of glycol ester film is 6 μm -150 μm, and the thickness of cast polypropylene film is 20 μm -100 μm, key control parameter:
Speed:Less than or equal to 200 ms/min;
Drying tunnel drying temperature:Using three sections of drying, one section:50-65 DEG C, two sections:60-75 DEG C three sections:70-90℃;
Hot drum binding temperature:50-70℃;
Spread(Butt):2.0-5.0g/m2/ layer.
3) cure
At 35-60 DEG C, the curing time is more than or equal to 48 h.
4) cutting forms the transparent sealed membrane for Easy tearing lid.
Embodiment 5
1) print(When needing pattern, word)
Pattern, word, key control parameter are stamped on pet film by intaglio press:
Speed:Wound roll material prints, speed 100-300m/ points;
Drying temperature:50-80℃;
The space of a whole page is errorless, and without obvious aberration, chromatography is accurate, and ink is uniform.
2) two-layer pet film is combined
With dry compound machine, by two-layer pet film, compound to be made polyethylene terephthalate thin
Film layer, key control parameter:
Speed:Less than or equal to 200 ms/min;
Drying tunnel drying temperature:Using three sections of drying, one section:50-65 DEG C, two sections:60-75 DEG C three sections:70-90℃;
Hot drum binding temperature:50-70℃;
Spread(Butt):2.0-5.0g/m2/ layer;
Every layer of thickness of pet film is 6 μm -150 μm.
3) step 3)Obtained pet film layer is combined with cast polypropylene film
With dry compound machine by step 3)Obtained pet film layer and cast polypropylene film are combined,
The thickness of cast polypropylene film is 20 μm -100 μm, key control parameter:
Speed:Less than or equal to 200 ms/min;
Drying tunnel drying temperature:Using three sections of drying, one section:50-65 DEG C, two sections:60-75 DEG C three sections:70-90℃;
Hot drum binding temperature:50-70℃;
Spread:2.0-5.0g/m2/ layers.
4) cure
At 35-60 DEG C, the curing time is more than or equal to 48 h.
5) cutting forms the transparent sealed membrane for Easy tearing lid.
Embodiment 6
1) heat-seal adhesive is prepared
Heat-seal adhesive is obtained after being blended by following components:
Acroleic acid resin 30wt%;
Polypropylene 20wt%;
Ethyl acetate 50wt%.
2) print(When needing pattern, word)
Pattern, word, key control parameter are stamped on pet film by intaglio press:
Speed:Wound roll material prints, speed 100-300m/ points;
Drying temperature:50-80℃;
The space of a whole page is errorless, and without obvious aberration, chromatography is accurate, and ink is uniform.
3) gluing
With glue spreader on pet film uniform application heat-seal adhesive, polyethylene terephthalate is thin
The thickness of film is 6 μm -150 μm, key control parameter:
Application rate:50-100 ms/min;
Drying temperature:Using three sections of drying, drying tunnel dries actual temp:
One section:80-130 DEG C, two sections:100-150 DEG C, three sections:100-130℃;
Heat-seal adhesive coating weight:4.0-10.0g/m2;
The hot sealing layer thickness of formation is 1-10 μm.
4) cutting forms the transparent sealed membrane for Easy tearing lid.
Embodiment 7
1) heat-seal adhesive is prepared
Heat-seal adhesive is obtained after being blended by following components:
Acroleic acid resin 55wt%;
Polypropylene 10wt%;
Ethyl acetate 35wt%.
2) print(When needing pattern, word)
Pattern, word, key control parameter are stamped on pet film by intaglio press:
Speed:Wound roll material prints, speed 100-300m/ points;
Drying temperature:50-80℃;
The space of a whole page is errorless, and without obvious aberration, chromatography is accurate, and ink is uniform.
3) two-layer pet film is combined
With dry compound machine, by two-layer pet film, compound to be made polyethylene terephthalate thin
Film layer, key control parameter:
Speed:Less than or equal to 200 ms/min;
Drying tunnel drying temperature:Using three sections of drying, one section:50-65 DEG C, two sections:60-75 DEG C three sections:70-90℃;
Hot drum binding temperature:50-70℃;
Spread(Butt):2.0-5.0g/m2/ layer.
4) cure
At 35-60 DEG C, the curing time is more than or equal to 48 h.
5) gluing
With glue spreader on pet film uniform application heat-seal adhesive, polyethylene terephthalate is thin
The thickness of film is 6 μm -150 μm, key control parameter:
Application rate:50-100 ms/min;
Drying temperature:Using three sections of drying, drying tunnel dries actual temp:
One section:80-130 DEG C, two sections:100-150 DEG C, three sections:100-130℃;
Heat-seal adhesive coating weight:4.0-10.0g/m2;
The hot sealing layer thickness of formation is 1-10 μm.
6) cutting forms the transparent sealed membrane for Easy tearing lid.
Embodiment 8
1) heat-seal adhesive is prepared
Heat-seal adhesive is obtained after being blended by following components:
Acroleic acid resin 55wt%;
Polipropene 25 wt%;
Ethyl acetate 20wt%.
2) print(When needing pattern, word)
Pattern, word, key control parameter are stamped on pet film by intaglio press:
Speed:Wound roll material prints, speed 100-300m/ points;
Drying temperature:50-80℃;
The space of a whole page is errorless, and without obvious aberration, chromatography is accurate, and ink is uniform.
3) two-layer pet film is combined
Two-layer pet film is combined with solvent-free composite machine is made polyethylene terephthalate
Film layer, key control parameter:
Speed:Less than or equal to 400 ms/min;
Metering roll temperature is 35-50 DEG C, and gluing roll temperature is 40-55 DEG C;
Hot drum binding temperature:40-60℃;
Spread(Butt):1.0-4.0g/m2/ layer;
Every layer of thickness of pet film is 6 μm -150 μm.
4) cure
At 35-60 DEG C, the curing time is more than or equal to 48 h.
5) gluing
With glue spreader on pet film uniform application heat-seal adhesive, polyethylene terephthalate is thin
The thickness of film is 6 μm -150 μm, key control parameter:
Application rate:50-100 ms/min;
Drying temperature:Using three sections of drying, drying tunnel dries actual temp:
One section:80-130 DEG C, two sections:100-150 DEG C, three sections:100-130℃;
Heat-seal adhesive coating weight:4.0-10.0g/m2;
The hot sealing layer thickness of formation is 1-10 μm.
6) cutting forms the transparent sealed membrane for Easy tearing lid.
Embodiment 9
1) coating is set in the outer surface of metal sheet and/or outer surface, or is not provided with, coating can be coloured, also may be used
To be colourless, metal sheet is tinplate or aluminium sheet, and the tinplate can be tin plate, or chrome plating;
2) metal cap body is made by punch forming.
3) by being stamped and formed out taking thing hole, the thing hole that takes can be " O " shape, " D " shape, or other shapes;
4) crimping treatment is carried out to the thing hole that takes, plays anti-scratch effect;
5) the transparent sealed membrane formed after embodiment 1-8 is cut carries out heat-sealing sealing with lid by heat seal die, obtains
Bright Easy tearing lid.
Test
By hyaline membrane Easy tearing lid obtained in embodiment 9 according to professional standard《BB/T 0069-2014 packing container aluminium foil Easy tearing lids》
Specified in the 8th article of test method, carry out opening force and performing leak test.Measure and open brokenly power for 18-23N, opening force is 10-
15N, meets in standard 7.3 requirements that power and opening force are opened brokenly on Easy tearing lid(≤25N).Hyaline membrane Easy tearing lid is existed simultaneously
Under 98kpa air pressure, pressurize 1min does not have found leakage phenomenon.Therefore through test, it is found that obtained transparent Easy tearing lid, its combination
Ability and opening force function admirable, meet Easy tearing lid product standard demand.
Embodiments of the invention are the foregoing is only, not for limiting the scope of the invention;Protection scope of the present invention
Limited by the claim in claims, and it is every according to made equivalence changes and modification is invented, all of the invention special
Within the protection domain of profit.
Claims (18)
1. a kind of transparent sealed membrane for Easy tearing lid, it is characterised in that:Including the polyethylene terephthalate being brought into close contact
Ester film layer and hot sealing layer.
2. the transparent sealed membrane for Easy tearing lid according to claim 1, it is characterised in that:The hot sealing layer is modified poly-
Vinyl film or cast polypropylene film.
3. the transparent sealed membrane for Easy tearing lid according to claim 2, it is characterised in that:The modified poly ethylene is thin
Film, it is composed of the following components:
10 ~ 20wt% of polybutene;
20 ~ 40wt% of ethylene-propylene copolymer;
50 ~ 70wt% of high density polyethylene (HDPE).
4. the transparent sealed membrane for Easy tearing lid according to claim 1, it is characterised in that:The hot sealing layer is heat-sealing
Glue.
5. the transparent sealed membrane for Easy tearing lid according to claim 4, it is characterised in that:The heat-seal adhesive, by following
Component is constituted:
Acroleic acid resin 30-55wt%;
Polypropylene 10-25wt%;
Ethyl acetate 20-50wt%.
6. the transparent sealed membrane for Easy tearing lid according to claim 1, it is characterised in that:The poly terephthalic acid second
Word and/or pattern are printed with terephthalate films layer.
7. the preparation method of the transparent sealed membrane for Easy tearing lid described in a kind of claim 2, it is characterised in that process is such as
Under:Pet film layer and hot sealing layer by dry type is compound or solvent-free compound mode add it is glutinous
Mixture is brought into close contact, followed by aging.
8. the preparation method of the transparent sealed membrane for Easy tearing lid according to claim 7, it is characterised in that:It is described poly- right
PET film layer is two-layer pet film compound or solvent-free compound by dry type
Mode add binder to be brought into close contact to be formed.
9. the preparation method of the transparent sealed membrane for Easy tearing lid according to claim 7, it is characterised in that:The heat-sealing
The thickness of layer is 20 μm -100 μm.
10. the preparation method of the transparent sealed membrane for Easy tearing lid described in a kind of claim 4, it is characterised in that process is such as
Under:Heat-seal adhesive is added to form hot sealing layer in pet film layer surface by glue spreader.
The preparation method of the 11. transparent sealed membranes for Easy tearing lid according to claim 10, it is characterised in that:It is described poly-
Ethylene glycol terephthalate film layer is two-layer pet film compound or solvent-free multiple by dry type
The mode of conjunction adds binder to be brought into close contact to be formed, followed by aging.
The preparation method of the 12. transparent sealed membranes for Easy tearing lid according to claim 10, it is characterised in that:Gluing mistake
The control parameter of journey is as follows:
Application rate:50-100 ms/min;
Drying temperature:Using three sections of drying, drying tunnel dries actual temp:
One section:80-130 DEG C, two sections:100-150 DEG C, three sections:100-130℃;
Heat-seal adhesive coating weight:4.0-10.0g/m2;
The hot sealing layer thickness of formation is 1-10 μm.
The preparation method of the 13. transparent sealed membrane for Easy tearing lid according to any one of claim 7,8,10,11, it is special
Levy and be:The compound control parameter of the dry type is as follows:
Speed:Less than or equal to 200 ms/min;
Drying tunnel drying temperature:Using three sections of drying, one section:50-65 DEG C, two sections:60-75 DEG C three sections:70-90℃;
Hot drum binding temperature:50-70℃;
Spread:2.0-5.0g/m2/ layer.
The preparation method of the 14. transparent sealed membrane for Easy tearing lid according to any one of claim 7,8,10,11, it is special
Levy and be:The solvent-free compound control parameter is as follows:
Speed:Less than or equal to 400 ms/min;
Metering roll temperature is 35-50 DEG C, and gluing roll temperature is 40-55 DEG C;
Hot drum binding temperature:40-60℃;
Spread:1.0-4.0g/m2/ layer.
The preparation side of the 15. transparent sealed membrane for Easy tearing lid according to claims require 7,8,11 any one
Method, it is characterised in that:The thickness of binder is 1-5 μm.
The preparation of the 16. transparent sealed membrane for Easy tearing lid according to claims require 7,8,10,11 any one
Method, it is characterised in that:Thickness per strata ethylene glycol terephthalate is 6 μm -150 μm.
The preparation method of the 17. transparent sealed membrane for Easy tearing lid according to claim 7 or 11, it is characterised in that:It is ripe
The condition of change is as follows:At 35-60 DEG C, the curing time is more than or equal to 48 h.
A kind of 18. transparent Easy tearing lids, including lid, sealed membrane, the lid are provided with and take thing hole, and the ParafilmTM takes thing
Hole, it is characterised in that:The sealed membrane is the transparent sealed membrane described in any one of claim 1 ~ 6.
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CN201710119538.8A CN106927112A (en) | 2017-03-02 | 2017-03-02 | A kind of transparent sealed membrane for Easy tearing lid, preparation method and transparent Easy tearing lid |
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CN201710119538.8A CN106927112A (en) | 2017-03-02 | 2017-03-02 | A kind of transparent sealed membrane for Easy tearing lid, preparation method and transparent Easy tearing lid |
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CN201710119538.8A Pending CN106927112A (en) | 2017-03-02 | 2017-03-02 | A kind of transparent sealed membrane for Easy tearing lid, preparation method and transparent Easy tearing lid |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112373151A (en) * | 2020-10-22 | 2021-02-19 | 金石包装(嘉兴)有限公司 | Preparation method of sterilization type easy-to-tear sealing cover film |
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CN105061870A (en) * | 2015-07-17 | 2015-11-18 | 永新股份(黄山)包装有限公司 | Heat-sealing film and cover film adopting same |
CN105459539A (en) * | 2015-12-09 | 2016-04-06 | 湖州金洁实业有限公司 | Aluminum foil of easily torn cover |
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EP0230115A1 (en) * | 1985-11-29 | 1987-07-29 | American National Can Company | Polymeric compositions and films, plural layer sheet structures and packaging made from such films and structures |
JPH05305971A (en) * | 1992-04-27 | 1993-11-19 | Toyobo Co Ltd | High frequency sterilizing packaging material |
CN101142290A (en) * | 2005-06-17 | 2008-03-12 | 埃弗尼克罗姆有限公司 | Heat-sealing compound for sealing aluminium foil and polyethlene terephthalate film to polypropylene, polyvinyl chloride and polystyrene containers |
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CN112373151A (en) * | 2020-10-22 | 2021-02-19 | 金石包装(嘉兴)有限公司 | Preparation method of sterilization type easy-to-tear sealing cover film |
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Address after: 325000 No. 227 Weishi Road, Yueqing Economic Development Zone, Wenzhou City, Zhejiang Province Applicant after: Zhejiang bloomer New Material Technology Co., Ltd. Address before: 325000 No. 308 Weiwu Road, Yueqing Economic Development Zone, Wenzhou City, Zhejiang Province Applicant before: Zhejiang Bo Sheng new material Co., Ltd. |
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Application publication date: 20170707 |