CN106926391B - A kind of engineering plastics waste disposal method - Google Patents
A kind of engineering plastics waste disposal method Download PDFInfo
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- CN106926391B CN106926391B CN201710128403.8A CN201710128403A CN106926391B CN 106926391 B CN106926391 B CN 106926391B CN 201710128403 A CN201710128403 A CN 201710128403A CN 106926391 B CN106926391 B CN 106926391B
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
- B29B17/04—Disintegrating plastics, e.g. by milling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/02—Making granules by dividing preformed material
- B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
- B29B2017/001—Pretreating the materials before recovery
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
- B29B2017/001—Pretreating the materials before recovery
- B29B2017/0015—Washing, rinsing
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/52—Mechanical processing of waste for the recovery of materials, e.g. crushing, shredding, separation or disassembly
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
Abstract
The present invention discloses a kind of engineering plastics waste disposal method, including following operating procedure: (1) engineering plastics that will be cleaned up are put into bating liquor and impregnate；(2) bating liquor after softening on engineering plastics is removed, then engineering plastics are put into plastic crusher, after plastic crusher temperature is risen to 160-180 DEG C, additive A is put into thereto immediately, grinds 30-40min, wherein additive A；(3) temperature of plastic crusher is risen to 260-290 DEG C, additive B is added thereto immediately；(4) temperature of plastic crusher is down to 200-220 DEG C, addition of C is then added thereto, after reacting 40-50min, plastic grain is made in extruding pelletization.Using method of the invention, it can be achieved that large-scale, serialization processing engineering plastics rubbish, and in treatment process, do not pollute the environment, the obtained plastic grain of processing, processing performance is superior, widely used.
Description
Technical field
The invention belongs to field of environment protection, are related to a kind of waste disposal method, and in particular to a kind of engineering plastics rubbish
Processing method.
Background technique
With the development of China's plastics industry and the raising of the level of consumption, application of the plastic products in China is raw from industrial or agricultural
It is ubiquitous to produce clothing, food, lodging and transportion -- basic necessities of life, plastic refuse also attacks to us therewith.According to analysis of statistical data, extrapolate 2005
Plastics in China real consumption amount is 2 658.9 ten thousand t, and waste plastic yield is about 960.8 ten thousand t, and emission index about 36% accounts for China
15% or so of garbage emission total amount.Since nearly all plastics are all made of non-renewable petroleum, main component is hydrocarbonization
Object is closed, it can be with
Burning, it is the very high macromolecular material of calorific value that the heat ratio fuel oil such as polystyrene burns is also high, is had resistance to
The characteristic that sour, alkaline-resisting, weather-resistant etc. are corrosion-resistant, are not easily decomposed, causing can not be by natural decomposition, especially disposable modeling
Material packaging waste, plastics farm-oriented mulch arbitrarily abandoned by people and caused by visual pollution, i.e., it is so-called " white pollution ", and
Waste plastics potential hazard caused by environment has caused the common concern of relevant government department and society.The growth of plastic products
Speed is than other materials
Material is fast, and plastics are lower than the reuse ratio of metal or paper;The pass of correct treatment of waste plastics resource utilization and environment
System is rationally an urgent demand of China's economy, social sustainable development proposition using natural resources.China's main life at present
Technology of garbage disposal are as follows: Sanitary Landfill Technology, power generation by waste combustion technology, comprehensive treatment technique (composting technology).Waste plastics is in rubbish
In sanitary landfills processing not only many negative potential danger cannot will be also brought by resource utilization, and by facts have proved
Evil.Since plastics package is in the majority in waste plastics, their density are small, volume is big, and place can be filled up quickly by being not easily decomposed, and reduce landfill
The ability of place processing rubbish;And the place after landfill due to ground it is soft, the harmful substances such as bacterium, virus in rubbish
It is easily penetrated into underground, polluted underground water jeopardizes ambient enviroment.The characteristic of plastics, it is resolved that its final disposal should not fill.
And garbage loading embeading is using rubbish as waste processing, the utilization rate to waste resources is zero, does not meet national sustainable development
Principle is not the ideal method of garbage disposal.Engineering plastics can make the modeling of engineering material and replacement metal manufacture element part etc.
Material.Engineering plastics have excellent comprehensive performance, and rigidity is big, and creep is small, high mechanical strength, and heat-resist, electrical insulating property is good, can
It is used for a long time in harsher chemistry, physical environment, alternative metal is used as structural timber, due to engineering plastics
Intensity it is larger, deal with it is more difficult, therefore be badly in need of it is a kind of it is scientific and reasonable, environmental pollution is small, can be utmostly
Using abandoned project plastics be worth approach.
Summary of the invention
To solve the above-mentioned problems, the present invention is directed to the characteristics of engineering plastics, proposes a kind of scientific and reasonable, dirty to environment
Contaminate method that is small, being worth to the greatest extent using abandoned project plastics.
The present invention is achieved by the following technical solutions.
A kind of engineering plastics waste disposal method, including following operating procedure:
(1) engineering plastics that will be cleaned up are put into bating liquor and impregnate 4-6 hours, and wherein the temperature of bating liquor is 80-
90 DEG C, bating liquor is made of the component of following parts by weight: 19-26 parts of tartaric acid, 6-8 parts of ethylenediamine tetra-acetic acid, alkyl phenol polyoxy
11-16 parts of vinethene, 30-50 parts of sodium phosphate, 200-250 parts of water；
(2) bating liquor after softening on engineering plastics is removed, then engineering plastics are put into plastic crusher, by plastics
After pulverizer temperature rises to 160-180 DEG C, the additive A that 0.08-0.10 times of engineering plastics gross weight of investment weighs thereto immediately is ground
30-40min is ground, wherein additive A is made of the component of following parts by weight: 1-3 parts of methylpropene sodium sulfonate, cyanurate melamine
16-26 parts of amine ester, 10-15 parts of polyglutarimide, 3-5 parts of stabilizer；
(3) temperature of plastic crusher is risen to 260-290 DEG C, is immediately added thereto and the weight such as additive A adds
Add agent B, react 20-30min, wherein additive B is made of the component of following parts by weight: 2-4 parts of polyethylene wax, 1-3 parts of paraffin,
15-20 parts of calcium carbonate, 10-15 parts of polysiloxanes；
(4) temperature of plastic crusher is down to 200-220 DEG C, 3-5 times of weight of additive A is then added thereto
Addition of C, react 40-50min after, extruding pelletization, be made plastic grain, wherein addition of C by following parts by weight component system
At: 19-26 parts of haloflex, 15-19 parts of stearic acid, 6-10 parts of tetraethylthiuram disulfide.
Specifically, the temperature of bating liquor is 84-86 DEG C in above-mentioned steps (1), and the temperature of plastic crusher is in step (2)
165-175 DEG C, the temperature of plastic crusher is 275-285 DEG C in step (3), and the temperature of plastic crusher is in step (4)
205-215℃。
Specifically, above stabilizer is rare-earth stabilizer.
Preferably, in the present invention plastic grain obtained hard sewage pipe can be made, underground get lines crossed pipe, drain-pipe for building,
Pigment material can be added during processing in dustbin, oil drum and electric appliance, electrical plastic articles as needed.
From the above technical scheme, it can be seen that the beneficial effects of the present invention are:
Using method of the invention, it can be achieved that large-scale, serialization processing engineering plastics rubbish, and treatment process
In, it does not pollute the environment, the obtained plastic grain of processing, processing performance is superior, widely used.Wherein, in bating liquor
Tartaric acid, ethylenediamine tetra-acetic acid synergistic effect after, the intensity of engineering plastics can be effectively reduced, its rigidity is reduced, promote it
Processing performance, and then can effectively promote the grinding effect of abandoned project plastics；Alkyl phenol polyoxyethylene ether and sodium phosphate collaboration
After effect, the spot that engineering plastics are precipitated in softening process can be effectively removed, and then the purity of final products can be promoted；First
After base sodium allylsulfonate, cyanurate melamine ester, polyglutarimide synergistic effect, abandoned project plastics can be effectively promoted
Grinding effect, can accelerate the burn-off rate of engineering plastics, promote the uniformity of engineering plastics after melting；Polyethylene wax, paraffin
Addition, can effectively promote the lubricity of plastic grain obtained, and its processing performance can be promoted；Calcium carbonate and poly- silicon oxygen
Alkane can effectively reduce the exhaust gas that abandoned project plastics generate during processing, reduce the discharge amount of pernicious gas；Chlorination is poly-
After ethylene, stearic acid and tetraethylthiuram disulfide synergistic effect, the effect of extruding pelletization can be effectively promoted, and can mention
The intensity for rising plastic grain made from abandoned project plastics, greatly improves the quality of product.
Specific embodiment
In order to enable those skilled in the art to be further understood that feature and technology contents of the invention, please referring to following has
Close detailed description of the invention.
Embodiment 1
A kind of engineering plastics waste disposal method, including following operating procedure:
(1) engineering plastics that will be cleaned up are put into bating liquor and impregnate 4 hours, and wherein the temperature of bating liquor is 80 DEG C,
Bating liquor is made of the component of following parts by weight: 19 parts of tartaric acid, 6 parts of ethylenediamine tetra-acetic acid, 11 parts of alkyl phenol polyoxyethylene ether,
30 parts of sodium phosphate, 200 parts of water；
(2) bating liquor after softening on engineering plastics is removed, then engineering plastics are put into plastic crusher, by plastics
After pulverizer temperature rises to 160 DEG C, 0.08 times of heavy additive A of engineering plastics gross weight is put into thereto immediately, grind 30min,
Wherein additive A is made of the component of following parts by weight: 1 part of methylpropene sodium sulfonate, 16 parts of cyanurate melamine ester, poly- penta
10 parts of imidodicarbonic diamide, 3 parts of stabilizer；
(3) temperature of plastic crusher is risen to 260 DEG C, the additive with weight such as additive As is added thereto immediately
B, react 20min, wherein additive B is made of the component of following parts by weight: 2 parts of polyethylene wax, 1 part of paraffin, 15 parts of calcium carbonate,
10 parts of polysiloxanes；
(4) temperature of plastic crusher is down to 200 DEG C, the additive of 3 times of weight of additive A is then added thereto
C, after reacting 40min, plastic grain is made in extruding pelletization, and wherein addition of C is made of the component of following parts by weight: chlorination is poly-
19 parts of ethylene, 15 parts of stearic acid, 6 parts of tetraethylthiuram disulfide.
Specifically, above stabilizer is rare-earth stabilizer XT-1.
By grain plastic obtained in embodiment 1, continue to process, hard sewage pipe is made, grain plastic is in processing
In the process, moldability is good, hard sewage pipe obtained, and intensity is high, durable.
Embodiment 2
A kind of engineering plastics waste disposal method, including following operating procedure:
(1) engineering plastics that will be cleaned up are put into bating liquor and impregnate 5 hours, and wherein the temperature of bating liquor is 85 DEG C,
Bating liquor is made of the component of following parts by weight: 22 parts of tartaric acid, 7 parts of ethylenediamine tetra-acetic acid, 15 parts of alkyl phenol polyoxyethylene ether,
40 parts of sodium phosphate, 230 parts of water；
(2) bating liquor after softening on engineering plastics is removed, then engineering plastics are put into plastic crusher, by plastics
After pulverizer temperature rises to 170 DEG C, 0.09 times of heavy additive A of engineering plastics gross weight is put into thereto immediately, grind 35min,
Wherein additive A is made of the component of following parts by weight: 2 parts of methylpropene sodium sulfonate, 24 parts of cyanurate melamine ester, poly- penta
13 parts of imidodicarbonic diamide, 4 parts of stabilizer；
(3) temperature of plastic crusher is risen to 280 DEG C, the additive with weight such as additive As is added thereto immediately
B, react 25min, wherein additive B is made of the component of following parts by weight: 3 parts of polyethylene wax, 2 parts of paraffin, 17 parts of calcium carbonate,
13 parts of polysiloxanes；
(4) temperature of plastic crusher is down to 210 DEG C, the additive of 4 times of weight of additive A is then added thereto
C, after reacting 45min, plastic grain is made in extruding pelletization, and wherein addition of C is made of the component of following parts by weight: chlorination is poly-
23 parts of ethylene, 17 parts of stearic acid, 8 parts of tetraethylthiuram disulfide.
Specifically, above stabilizer is rare-earth stabilizer XT-2.
By grain plastic obtained in embodiment 1, continue to process, oil drum is made, the processing performance of grain plastic is excellent
More, oil drum obtained, intensity is high, not perishable, durable.
Embodiment 3
A kind of engineering plastics waste disposal method, including following operating procedure:
(1) engineering plastics that will be cleaned up are put into bating liquor and impregnate 6 hours, and wherein the temperature of bating liquor is 90 DEG C,
Bating liquor is made of the component of following parts by weight: 26 parts of tartaric acid, 8 parts of ethylenediamine tetra-acetic acid, 16 parts of alkyl phenol polyoxyethylene ether,
50 parts of sodium phosphate, 250 parts of water；
(2) bating liquor after softening on engineering plastics is removed, then engineering plastics are put into plastic crusher, by plastics
After pulverizer temperature rises to 180 DEG C, 0.10 times of heavy additive A of engineering plastics gross weight is put into thereto immediately, grind 40min,
Wherein additive A is made of the component of following parts by weight: 3 parts of methylpropene sodium sulfonate, 26 parts of cyanurate melamine ester, poly- penta
15 parts of imidodicarbonic diamide, 5 parts of stabilizer；
(3) temperature of plastic crusher is risen to 290 DEG C, the additive with weight such as additive As is added thereto immediately
B, react 30min, wherein additive B is made of the component of following parts by weight: 4 parts of polyethylene wax, 3 parts of paraffin, 20 parts of calcium carbonate,
15 parts of polysiloxanes；
(4) temperature of plastic crusher is down to 220 DEG C, the additive of 5 times of weight of additive A is then added thereto
C, after reacting 50min, plastic grain is made in extruding pelletization, and wherein addition of C is made of the component of following parts by weight: chlorination is poly-
26 parts of ethylene, 19 parts of stearic acid, 10 parts of tetraethylthiuram disulfide.
Specifically, above stabilizer is rare-earth stabilizer XT-3.
By grain plastic obtained in embodiment 3, continue to process, sealing strip used in automobile entrance door is made,
The processing performance of grain plastics is superior, and sealing strip obtained, excellent in mechanical performance, wearability is good, durable.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, for the skill of this field
For art personnel, the invention may be variously modified and varied.All within the spirits and principles of the present invention, made any to repair
Change, equivalent replacement, improvement etc., should all be included in the protection scope of the present invention.
Claims (3)
1. a kind of engineering plastics waste disposal method, which is characterized in that including following operating procedure:
(1) engineering plastics that will be cleaned up are put into bating liquor and impregnate 4-6 hours, and wherein the temperature of bating liquor is 80-90
DEG C, bating liquor is made of the component of following parts by weight: 19-26 parts of tartaric acid, 6-8 parts of ethylenediamine tetra-acetic acid, alkyl phenol polyoxy second
11-16 parts of alkene ether, 30-50 parts of sodium phosphate, 200-250 parts of water；
(2) bating liquor after softening on engineering plastics is removed, then engineering plastics are put into plastic crusher, by plastic crushing
After machine temperature rises to 160-180 DEG C, the additive A that 0.08-0.10 times of engineering plastics gross weight of investment weighs thereto immediately, grinding
30-40min, wherein additive A is made of the component of following parts by weight: 1-3 parts of methylpropene sodium sulfonate, cyanurate melamine
16-26 parts of ester, 10-15 parts of polyglutarimide, 3-5 parts of stabilizer；
(3) temperature of plastic crusher is risen to 260-290 DEG C, the additive with weight such as additive As is added thereto immediately
B reacts 20-30min, and wherein additive B is made of the component of following parts by weight: 2-4 parts of polyethylene wax, 1-3 parts of paraffin, carbonic acid
15-20 parts of calcium, 10-15 parts of polysiloxanes；
(4) temperature of plastic crusher is down to 200-220 DEG C, the addition of 3-5 times of weight of additive A is then added thereto
Agent C, after reacting 40-50min, plastic grain is made in extruding pelletization, and wherein addition of C is made of the component of following parts by weight: chlorine
Change polyethylene 19-26 parts, 15-19 parts of stearic acid, 6-10 parts of tetraethylthiuram disulfide.
2. a kind of engineering plastics waste disposal method according to claim 1, which is characterized in that in above-mentioned steps (1)
The temperature of bating liquor is 84-86 DEG C, and the temperature of plastic crusher is 165-175 DEG C in step (2), plastic crushing in step (3)
The temperature of machine is 275-285 DEG C, and the temperature of plastic crusher is 205-215 DEG C in step (4).
3. a kind of engineering plastics waste disposal method according to claim 1, which is characterized in that above stabilizer is dilute
Soil stabilizer.
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| FR2280492A1 (en) * | 1974-07-31 | 1976-02-27 | Emery Guy | PROCESS AND INSTALLATION FOR RECOVERING MIXED PLASTIC MATERIALS, FROM ALL SOURCES |
| CN102443210A (en) * | 2010-10-15 | 2012-05-09 | 郧县金龙塑业包装有限公司 | Waste plastic recycling process method |
| US20150099845A1 (en) * | 2013-10-07 | 2015-04-09 | Sabic Innovative Plastics Ip B.V. | Flame retardant thermoplastic compositions with improved properties |
| CN104629084B (en) * | 2015-02-09 | 2018-02-06 | 浙江理工大学 | A kind of cleaning method of waste and old polytetrafluoroethylene (PTFE) filter bag |
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