CN106917085B - Communication base station with automatically cleaning and anti-corrosion effects - Google Patents

Communication base station with automatically cleaning and anti-corrosion effects Download PDF

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Publication number
CN106917085B
CN106917085B CN201710184885.9A CN201710184885A CN106917085B CN 106917085 B CN106917085 B CN 106917085B CN 201710184885 A CN201710184885 A CN 201710184885A CN 106917085 B CN106917085 B CN 106917085B
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stuff
base station
substrate
automatically cleaning
hydrophobic
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CN201710184885.9A
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CN106917085A (en
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不公告发明人
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Jiangsu Yongding Communications Co ltd
Jiangsu Etern Co Ltd
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Individual
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C24/00Coating starting from inorganic powder
    • C23C24/08Coating starting from inorganic powder by application of heat or pressure and heat
    • C23C24/10Coating starting from inorganic powder by application of heat or pressure and heat with intermediate formation of a liquid phase in the layer
    • C23C24/103Coating with metallic material, i.e. metals or metal alloys, optionally comprising hard particles, e.g. oxides, carbides or nitrides

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Coating By Spraying Or Casting (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)

Abstract

This application involves a kind of communication base station with automatically cleaning and anti-corrosion effects, including base station ontology, the base station ontology includes substrate and the hydrophobic erosion resistant coating set on substrate surface, which is that stuff and other stuff is sprayed to substrate surface by cold spray technique to be formed;The base station ontology has good hydrophobic effect, shows as good automatically cleaning and antiseptic property.

Description

Communication base station with automatically cleaning and anti-corrosion effects
Technical field
This application involves communication base station field more particularly to a kind of communication base stations with automatically cleaning and anti-corrosion effects.
Background technique
With the development of information industry, communications equipment is quickly grown, and the connection between people is more and more closer, communication base station Also more and more.Communication base station is a kind of radio station, can be handed in certain radio coverage area by mobile communication Information transmitting is carried out between switching center9 and mobile telephone terminal.
General communication base station is in the exterior space, and without any protective equipment, this requires it to have antipollution, anti-corrosion etc. Function.
Summary of the invention
The present invention is intended to provide a kind of communication base station with automatically cleaning and anti-corrosion effects, to solve set forth above ask Topic.
A kind of communication base station with automatically cleaning and anti-corrosion effects, including base station sheet are provided in the embodiment of the present invention Body, the base station ontology include substrate and the hydrophobic erosion resistant coating set on substrate surface;The hydrophobic erosion resistant coating is to pass through cold spray technique Stuff and other stuff is sprayed into substrate surface formation.
The technical solution that the embodiment of the present invention provides can include the following benefits:
Base station ontology of the invention includes substrate and the hydrophobic erosion resistant coating set on substrate surface, which is to pass through Stuff and other stuff is sprayed to substrate surface formation by cold spray technique;The hydrophobic erosion resistant coating has good hydrophobic effect, improves The static contact angle of water droplet realizes that water droplet is freely rolled in hydrophobic surface, can during tumbling by dust and particle band It walks, self-cleaning effect can be played;In addition, using hydrophobic erosion resistant coating in metal surface, metal surface steam can reduce Aggregation effectively prevents the corrosion of metal surface;Also, the hydrophobic erosion resistant coating is realized by cold spraying, spraying process pair It is easy to operate in stuff and other stuff non-oxidation, it is at low cost.
The additional aspect of the application and advantage will be set forth in part in the description, and will partially become from the following description It obtains obviously, or recognized by the practice of the application.It should be understood that above general description and following detailed description are only Be it is exemplary and explanatory, the application can not be limited.
Detailed description of the invention
The present invention will be further described with reference to the accompanying drawings, but the embodiment in attached drawing is not constituted to any limit of the invention System, for those of ordinary skill in the art, without creative efforts, can also obtain according to the following drawings Other attached drawings.
Fig. 1 is the structural schematic diagram of base station ontology of the present invention.
Specific embodiment
Example embodiments are described in detail here, and the example is illustrated in the accompanying drawings.Following description is related to When attached drawing, unless otherwise indicated, the same numbers in different drawings indicate the same or similar elements.Following exemplary embodiment Described in embodiment do not represent all embodiments consistented with the present invention.On the contrary, they be only with it is such as appended The example of device and method being described in detail in claims, some aspects of the invention are consistent.
A kind of communication base station with automatically cleaning and anti-corrosion effects, including base station ontology, the base station ontology include substrate 5 And the hydrophobic erosion resistant coating 6 set on 5 surface of substrate.
Since hydrophobic surface has micro-nano coarse structure and lower surface free energy, the Static Contact of water droplet is improved Angle realizes that water droplet is freely rolled in hydrophobic surface so that water droplet is difficult to penetrate into micro-nano coarse structure, can during tumbling incite somebody to action Dust and particle are taken away, and self-cleaning effect can be played;In addition, using hydrophobic erosion resistant coating in metal surface, gold can reduce The aggregation of metal surface steam effectively prevents the corrosion of metal surface.
In the technical solution of the application, reach automatically cleaning and corrosion-resistant effect by the way that hydrophobic erosion resistant coating 6 is arranged.
Meanwhile the hydrophobic erosion resistant coating 6 is that stuff and other stuff is sprayed to 5 surface of substrate by cold spray technique to be formed.
Cold spraying is different from plasma spray technology, powder particle non-oxidation in spraying process, to powder particle structure without shadow It rings, equipment is simple, and it is at low cost, it is a kind of economic and environment-friendly spraying technology;Cold spray technique is widely used at present, on the surface of the material There is application in the fields such as modification, nano material, Biofunctional materials;In the technical program, formed using cold spray technique hydrophobic Erosion resistant coating, the hydrophobic erosion resistant coating have good hydrophobic effect.
The stuff and other stuff includes: titanium dioxide microballoon sphere, ZnO microsphere and low-melting alloy, the low-melting alloy be containing Tin, bismuth, lead, cadmium alloy, fusing point be lower than 250 DEG C.
ZnO microsphere is a kind of high function fining product, generally has fluorescence, piezoelectricity, absorbs scattering ultraviolet light Ability etc., ZnO microsphere application generally light, electricity, magnetic, in terms of it is more;Titanium dioxide microballoon sphere has very strong Shielding ultraviolet rays effect, be generally used for cosmetics, functional fibre, plastics, coating etc., used as ultraviolet light screener;Oxygen Change zinc microballoon and titanium dioxide microballoon sphere itself does not have hydrophobic performance, and utilizes ZnO microsphere, titanium dioxide in the application Microballoon and low-melting alloy constitute a kind of stuff and other stuff for having hydrophobic function, which is set to substrate by cold spraying Surface, since in cold spray process, the speed of stuff and other stuff is larger, the stuff and other stuff and substrate of high speed are hit, and pass through active force Plastic deformation is generated on the surface of the substrate, and the addition of low-melting alloy can be used as titanium dioxide microballoon sphere and ZnO microsphere Buffer;Meanwhile after cold spraying stuff and other stuff, substrate is carried out to the heat treatment process of certain time, in the heat treatment process In, which can melt, thus and titanium dioxide microballoon sphere, ZnO microsphere, substrate form closer combination, increase The wear-resisting property of the hydrophobic erosion resistant coating.
In the preferred embodiment, which have passed through hcl corrosion processing, can prepare micro-meter scale on surface Coarse structure, and then hydrophobic erosion resistant coating is prepared by cold spraying on the coarse structure surface, the hydrophobic erosion resistant coating can be enhanced Roughness, for hydrophobic effect generate positive influence.
In the preferred embodiment, above-mentioned titanium dioxide microballoon sphere, ZnO microsphere, low-melting alloy partial size be respectively 20 μm, 30 μm, 5 μm, above-mentioned titanium dioxide microballoon sphere, ZnO microsphere, low-melting alloy mass ratio be respectively 3:4:1.
In the preferred embodiment, the preparation process of the hydrophobic erosion resistant coating 6 are as follows:
Step 1, it handles substrate: substrate being cleaned up, the substrate hydrochloric acid solution of 1mol/l is then corroded into micron out The coarse structure of scale, then cleans up hydrochloric acid;
Step 2, it modifies stuff and other stuff: titanium dioxide microballoon sphere, ZnO microsphere and low-melting alloy being uniformly mixed, will be mixed Closing particle and being added in ethyl alcohol to percentage solubility is 8%, 6% polytetrafluoroethylene (PTFE) is then added in the solution, stirring is equal It is even;
Step 3, cold spraying and heat treatment: spraying above-mentioned stuff and other stuff in substrate surface using cold spray technique, control The technological parameter of spraying are as follows: working gas N2, preheating temperature is 450 DEG C, pressure 3.5MPa, spray distance 10mm, grain Sub- speed is 1100~1200m/s, and spray gun movement speed is 150~200mm/s;After cold spraying stuff and other stuff, substrate is put Enter in holding furnace, keep the temperature 10h at 270 DEG C, after low-melting alloy fusing after with substrate and titanium dioxide microballoon sphere, ZnO microsphere It sufficiently combines, takes out, Temperature fall.
The communication base station obtained after having sprayed has good ultra-hydrophobicity, and hydrophobic erosion resistant coating is well combined with substrate, The hydrophobic effect for testing the hydrophobic erosion resistant coating of different-thickness, is as follows:
Hydrophobic erosion resistant coating thickness deg micron 50 100 150 200 250 300
Static contact angle/degree 168 172 172 171 169 169
It can be seen that hydrophobic effect is good when hydrophobic erosion resistant coating 6 is with a thickness of 100~150 μm, show as automatically cleaning and Anti-corrosion effect is good.
The foregoing is merely preferred modes of the invention, are not intended to limit the invention, all in spirit and original of the invention Within then, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.

Claims (5)

1. a kind of communication base station with automatically cleaning and anti-corrosion effects, including base station ontology, which is characterized in that the base station ontology Including substrate and set on the hydrophobic erosion resistant coating of substrate surface;The hydrophobic erosion resistant coating is to be sprayed stuff and other stuff by cold spray technique It is formed to substrate surface;The stuff and other stuff includes: titanium dioxide microballoon sphere, ZnO microsphere and low-melting alloy;It is described low Melting alloy be containing tin, bismuth, lead, cadmium alloy, fusing point be lower than 250 DEG C.
2. the communication base station according to claim 1 with automatically cleaning and anti-corrosion effects, which is characterized in that substrate warp Hcl corrosion processing has been crossed, there is the coarse structure of micro-meter scale on its surface.
3. the communication base station according to claim 1 with automatically cleaning and anti-corrosion effects, which is characterized in that this is hydrophobic anti- Rotten layer is with a thickness of 100~150 μm.
4. the communication base station according to claim 1 with automatically cleaning and anti-corrosion effects, which is characterized in that the mangcorn Titanium dioxide microballoon sphere in son, ZnO microsphere, low-melting alloy partial size be respectively 20 μm, 30 μm, 5 μm, in the stuff and other stuff Titanium dioxide microballoon sphere, ZnO microsphere, low-melting alloy mass ratio be respectively 3:4:1.
5. the communication base station according to claim 4 with automatically cleaning and anti-corrosion effects, which is characterized in that this is hydrophobic anti- The preparation process of rotten layer are as follows:
Step 1, it handles substrate: substrate being cleaned up, the substrate hydrochloric acid solution of 1mol/l is then corroded into micro-meter scale out Coarse structure, then hydrochloric acid is cleaned up;
Step 2, it modifies stuff and other stuff: titanium dioxide microballoon sphere, ZnO microsphere and low-melting alloy being uniformly mixed, by mangcorn It is 8% that son, which is added in ethyl alcohol to percentage solubility, and 6% polytetrafluoroethylene (PTFE) is then added in the solution, stirs evenly;
Step 3, above-mentioned stuff and other stuff, control spraying cold spraying and heat treatment: are sprayed in substrate surface using cold spray technique Technological parameter are as follows: working gas N2, preheating temperature is 450 DEG C, pressure 3.5MPa, spray distance 10mm, particle speed Degree is 1100~1200m/s, and spray gun movement speed is 150~200mm/s;After cold spraying stuff and other stuff, substrate is put into guarantor In warm furnace, 10h is kept the temperature at 270 DEG C, it is abundant with substrate and titanium dioxide microballoon sphere, ZnO microsphere after low-melting alloy fusing In conjunction with, taking-up, Temperature fall.
CN201710184885.9A 2017-03-24 2017-03-24 Communication base station with automatically cleaning and anti-corrosion effects Active CN106917085B (en)

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CN201710184885.9A CN106917085B (en) 2017-03-24 2017-03-24 Communication base station with automatically cleaning and anti-corrosion effects

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CN106917085B true CN106917085B (en) 2018-12-25

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Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6997018B2 (en) * 2003-06-02 2006-02-14 Ferro Corporation Method of micro and nano texturing glass
JP4982859B2 (en) * 2007-06-29 2012-07-25 地方独立行政法人 岩手県工業技術センター Formation method of organic film
CN102174234B (en) * 2011-03-09 2012-11-14 南京工业大学 Base station antenna polyvinyl chloride (PVC) profile housing with surface self-cleaning function and preparation method thereof
CN105386032B (en) * 2015-10-29 2018-07-06 中国科学院宁波材料技术与工程研究所 A kind of method for preparing wear-resisting super-hydrophobic coat using cold spray technique and products thereof

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Effective date of registration: 20181029

Address after: 312400 Sanjiang Street East, Sanjiang street, Sanjiang, Shaoxing, Zhejiang 144

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Address before: 518000 B1002, 2022 Kangle tower, Nanshan Road, Nanshan District, Shenzhen, Guangdong

Applicant before: SHENZHEN ZHIDA MACHINERY TECHNOLOGY Co.,Ltd.

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Effective date of registration: 20200923

Address after: Wujiang District of Suzhou City, Jiangsu province 215200 Lili town Yuexiu Road No. 888

Patentee after: JIANGSU YONGDING COMMUNICATIONS Co.,Ltd.

Address before: 312400 No. 144 Sanjiang East Street, Sanjiang Street, Shengzhou City, Shaoxing City, Zhejiang Province

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Address after: 215000 north side of luxui section, 74k, 318 National Road, Lili Town, Wujiang District, Suzhou City, Jiangsu Province

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Patentee after: JIANGSU YONGDING COMMUNICATIONS Co.,Ltd.

Address before: 215200 Yuexiu Road 888, Lili Town, Wujiang District, Suzhou City, Jiangsu Province

Patentee before: JIANGSU YONGDING COMMUNICATIONS Co.,Ltd.

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