CN106915864A - A kind of dyeing waste water Treated sewage reusing ABP Processes and apparatus - Google Patents

A kind of dyeing waste water Treated sewage reusing ABP Processes and apparatus Download PDF

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Publication number
CN106915864A
CN106915864A CN201510986774.0A CN201510986774A CN106915864A CN 106915864 A CN106915864 A CN 106915864A CN 201510986774 A CN201510986774 A CN 201510986774A CN 106915864 A CN106915864 A CN 106915864A
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China
Prior art keywords
abp
reaction tanks
waste water
dyeing waste
hydrolysis acidification
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Pending
Application number
CN201510986774.0A
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Chinese (zh)
Inventor
刘景明
左龙
左一龙
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Suzhou Bolong Environmental Protection Technology Co ltd
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Jiangsu Bo Kai Environmental Science And Technology Co Ltd
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Priority to CN201510986774.0A priority Critical patent/CN106915864A/en
Publication of CN106915864A publication Critical patent/CN106915864A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/42Treatment of water, waste water, or sewage by ion-exchange
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/725Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/78Treatment of water, waste water, or sewage by oxidation with ozone
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes
    • C02F3/301Aerobic and anaerobic treatment in the same reactor

Abstract

The invention discloses a kind of dyeing waste water Treated sewage reusing ABP Processes and apparatus, including pretreatment system, neutralization pond, coagulative precipitation tank, hydrolysis acidification pool, A/O reaction tanks, an ABP reaction tanks, catalytic ozonation system, the 2nd ABP reaction tanks and powdered ion-exchange resin system;The pretreatment system is sequentially connected neutralization pond, coagulative precipitation tank, hydrolysis acidification pool, A/O reaction tanks, an ABP reaction tanks, catalytic ozonation system, the 2nd ABP reaction tanks and powdered ion-exchange resin system by pipeline;The dyeing waste water Treated sewage reusing equipment, it is enriched with denitrogenation filler using high-performance bio, it is arranged in biochemistry pool, using ABP techniques, cooling, coagulating sedimentation with reference to the pretreatment of dyeing waste water, and the powdered ion-exchange resin of advanced treating decolouring and except salt processing method, according to Preliminary design and determine technological process, and further set up the physical property and quality control index of high-performance bio enrichment filler;It is practical, it is easy to promote the use of.

Description

A kind of dyeing waste water Treated sewage reusing ABP Processes and apparatus
Technical field
The present invention relates to waste water treatment applications technical field, especially a kind of dyeing waste water Treated sewage reusing ABP techniques and set It is standby.
Background technology
Dyeing is water consumption rich and influential family, and wastewater discharge and the total amount of pollutant occupy the second of national industrial department respectively With the 4th, be one of China emphasis pollution industry.Dyeing waste water always with discharge capacity it is big, intractability is high and turns into waste water and controls Manage the emphasis and difficult point of technical study.
Dyeing waste water typically has following features:Wastewater flow rate is big, water quality is complicated, content of organics is high, biodegradability is poor, alkali Property the features such as big, colourity is high, the water temperature that has is higher and water quality and quantity fluctuation is big.Dyeing waste water species:Desized wastewater, water compared with Small, pollutant concentration is high;Boiled-off waste water, water is big, and pollutant concentration is high;Bleaching effluent, water is big, pollutes lighter;Mercerising gives up Water, alkalinity is high;Dyeing waste-water, water quality is changeable, noxious material during sometimes with using various dyestuffs;Colourity is very high, can give birth to The property changed is poor;Printing waste water, containing slurry, BOD, COD are high;Arranging process waste water, mainly contains Soft flocks, resin, formaldehyde, finish And slurry, water is few;Alkali decrement waste water:PH value is high (general>, and organic concentration is high 12);Dye waste water is generally above-mentioned kind The mixing of class is even more more, therefore sufficiently complex difficult.
In recent years due to the development of science fabric, the rise of Silk and the progress of finishing process in printing and dye-ing technology are new The bio-refractory organic matter such as auxiliary agent largely enters dyeing waste water, and its COD concentration, colourity, ammonia nitrogen and investment are also greatly improved.Print The outstanding problem for contaminating wastewater treatment is the removal of colourity and hardly degraded organic substance.With the continuous deterioration of human ecological environment, state Family increases the dynamics of environmental protection, improves the discharge standard of textile printing and dyeing wastewater so that the intractability of dyeing waste water enters One step increases, and traditional PROCESS FOR TREATMENT effect is low, can not meet emission request;Hence it is highly desirable to seek one kind more It is adapted to the total system and method for dyeing waste water feature.
The content of the invention
The need for prior art is difficult to people, in order to solve above-mentioned problem, it is useless that the present invention proposes a kind of printing and dyeing Water Treated sewage reusing ABP Processes and apparatus, it is enriched with denitrogenation filler, is arranged in biochemistry pool, using ABP works using high-performance bio The ozone of the raising waste water B/C to more than 0.3 at skill, cooling, coagulating sedimentation with reference to the pretreatment of dyeing waste water, and middle part is urged Change oxidation, and advanced treating powdered ion-exchange resin decolouring and except salt processing method, according to Preliminary design and determination Technological process, and further set up the physical property and quality control index of high-performance bio enrichment filler.
To realize the technical purpose, the technical solution adopted by the present invention is:A kind of dyeing waste water Treated sewage reusing ABP techniques and Equipment, including pretreatment system, neutralization pond, coagulative precipitation tank, hydrolysis acidification pool, A/O reaction tanks, an ABP reaction tanks, ozone Catalytic oxidation system, the 2nd ABP reaction tanks and powdered ion-exchange resin system;The pretreatment system is connected successively by pipeline Connect neutralization pond, coagulative precipitation tank, hydrolysis acidification pool, A/O reaction tanks, an ABP reaction tanks, catalytic ozonation system, second ABP reaction tanks and powdered ion-exchange resin system;The A/O reaction tanks include A reaction tanks and O reaction tanks, and A reaction tanks with Hydrolysis acidification pool is adjacent.
A kind of technique of dyeing waste water Treated sewage reusing ABP Processes and apparatus, comprises the following steps:Step one, dyeing waste water Into pretreatment system, pretreatment mode is selected according to waste water characteristic.
Step 2, pretreatment cooling and oil removing, water outlet enter neutralization pond, adjust PH to 7-9.
Step 3, neutralization pond water outlet enters coagulative precipitation tank, and coagulant is selected according to waste water characteristic, removes partial organic substances And inorganic matter.
Step 4, subsequently enters hydrolysis acidification pool, and high-performance bio enrichment denitrogenation filler is installed in pond, makes difficult degradation in waste water Organic matter decompose, improve biodegradability.
Step 5, hydrolysis acidification pool water outlet enters back into A/O reaction tanks, and A/O reaction tanks are respectively mounted high-performance bio enrichment denitrogenation Filler, realizes synchronous aerobic, anaerobic reaction on the whole.Organics removal and total nitrogen.
Step 6, A/O reaction tank water outlets enter the ABP technique of sedimentation basin, i.e.,.ABP techniques use new reflux type, Air- extraction is quantified, reflux ratio is adjusted according to waste water quality, optimize treatment effect.
Further, an ABP reaction tanks and the 2nd ABP reaction tanks use identical structure.
Further, it is provided with high-performance bio enrichment denitrogenation filler in the hydrolysis acidification pool and A/O reaction tanks.
Further, grid, cooling bay and oil interceptor are provided with the pretreatment system.
Compared with prior art, the invention has the advantages that:The dyeing waste water Treated sewage reusing equipment, it is using high Effect biological concentration denitrogenation filler, is arranged in biochemistry pool, using ABP techniques, cooling, coagulation with reference to the pretreatment of dyeing waste water Precipitation, and the raising waste water B/C to more than 0.3 at middle part catalytic ozonation, and advanced treating powder ion exchange The decolouring of resin and except salt processing method, according to Preliminary design and determines technological process, and further sets up high-performance bio enrichment The physical property and quality control index of filler;Grid, cooling bay and oil interceptor are provided with pretreatment system, enter pre- in sewage After processing system device can cool down and the large-scale impurity such as go to degrease;Setting neutralization pond can be adjusted to neutrality by the pH value of sewage;It is mixed Solidifying sedimentation basin can select coagulant according to waste water characteristic, remove partial organic substances and inorganic matter;It is provided with hydrolysis acidification pool High-performance bio is enriched with denitrogenation filler;The organic matter of difficult degradation in waste water is decomposed, biodegradability is improved;Set in A/O reaction tanks High-performance bio enrichment denitrogenation filler is equipped with, synchronous aerobic, anaerobic reaction, organics removal and total nitrogen are realized on the whole;Waste water enters Enter sedimentation basin, ABP techniques use new reflux type, i.e. quantitative air- extraction, reflux ratio is adjusted according to waste water quality, imitate treatment Fruit optimizes;Catalytic ozonation system, a large amount of difficult complicated organic matters for decomposing of removal, while having decolorization;In caudal end Powdered ion-exchange resin system is set, and it mainly removes the salt in sewage, reaches reuse water standard;Practicality By force, it is easy to promote the use of.
Brief description of the drawings
Fig. 1 is the process chart of structure of the present invention;
Fig. 2 is the integrated configuration figure of structure of the present invention;
Fig. 3 process chart of the invention;
In reference:1- pretreatment systems, 2- neutralization ponds, 3- coagulative precipitation tanks, 4- hydrolysis acidification pools, 5-A/O reaction tanks, 6- First ABP reaction tanks, 7- catalytic ozonations system, the ABP reaction tanks of 8- the 2nd, 9- powdered ion-exchange resins system, 10- lattice Grid, 11- cooling bays, 12- oil interceptors 12,51-A reaction tanks, 52-O reaction tanks.
Specific embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is carried out clear, complete Site preparation is described, it is clear that described embodiment is only a part of embodiment of the invention, rather than whole embodiments.It is based on Embodiment in the present invention, it is all other that those of ordinary skill in the art are obtained under the premise of creative work is not made Embodiment, belongs to the scope of protection of the invention.
Figure of description 1-2 is referred to, in embodiments of the present invention, a kind of dyeing waste water Treated sewage reusing ABP techniques and is set It is standby, including pretreatment system 1, neutralization pond 2, coagulative precipitation tank 3, hydrolysis acidification pool 4, A/O reaction tanks 5, an ABP reaction tanks 6, Catalytic ozonation system 7, the 2nd ABP reaction tanks 8 and powdered ion-exchange resin system 9;The pretreatment system 1 is by pipe Line is sequentially connected neutralization pond 2, coagulative precipitation tank 3, hydrolysis acidification pool 4, A/O reaction tanks 5, an ABP reaction tanks 6, ozone catalytic Oxidative system 7, the 2nd ABP reaction tanks 8 and powdered ion-exchange resin system 9;The A/O reaction tanks 5 include the He of A reaction tanks 51 O reaction tanks 52, and A reaction tanks 51 are adjacent with hydrolysis acidification pool 4;The first ABP reaction tanks 6 and the 2nd ABP reaction tanks 8 are used Identical structure;High-performance bio enrichment denitrogenation filler is provided with the hydrolysis acidification pool 4 and A/O reaction tanks 5;The pretreatment Grid 10, cooling bay 11 and oil interceptor 12 are provided with system 1.
The present invention using by sewage by pretreatment system 1 carries out pretreatment cooling, removal scum silica frost and bulky grain debris and Oil removing;Enter neutralization pond 2, regulation PH to neutrality after pretreatment;Into coagulative precipitation tank, plus PAC, PAM coagulating sedimentation;Into water Solution acidification pool 4, through hydrolysis acidification, makes hardly degraded organic substance be decomposed into biodegradability organic matter, and itrogenous organic substance is decomposed into Ammonia nitrogen;The water outlet of hydrolysis acidification pool 4 enters A reaction tanks 51, mainly carries out anaerobic denitrifying reaction using the organic matter in water, removes Nitrate nitrogen in water.What denitrification was produced can be used as the carbon source of the nitration reaction of O reaction tanks 52;Converge with hydrolysis acidification pool 4 Enter A reaction tanks 51 afterwards, in the denitrification of A reaction tanks 51, enter back into O reaction tanks 52, can form micro- in O reaction tanks 52, on filler The aerobic zone of type, anoxic zone and anaerobic zone, so as to realize synchronous nitration and denitrification, remove large amount of organic and total nitrogen;O reaction tanks 52 mixed liquors enter an ABP reaction tanks 6, remove oil removal and precipitation activated sludge, and excess sludge air lift enters sludge condensation Pond;Into catalytic ozonation device 7, the complicated organic matter of removal decolourizes;Enter back into the 2nd ABP reaction tanks 8;Finally enter powder Ion exchange resin system 9, removes salts substances, it is fully achieved reuse standard.
Referring to Fig. 3, a kind of technique of dyeing waste water Treated sewage reusing ABP Processes and apparatus is comprised the following steps:Step one, Dyeing waste water enters pretreatment system, and pretreatment mode is selected according to waste water characteristic.
Step 2, pretreatment cooling and oil removing, water outlet enter neutralization pond, adjust PH to 7-9.
Step 3, neutralization pond water outlet enters coagulative precipitation tank, and coagulant is selected according to waste water characteristic, removes partial organic substances And inorganic matter.
Step 4, subsequently enters hydrolysis acidification pool, and high-performance bio enrichment denitrogenation filler is installed in pond, makes difficult degradation in waste water Organic matter decompose, improve biodegradability.
Step 5, hydrolysis acidification pool water outlet enters back into A/O reaction tanks, and A/O reaction tanks are respectively mounted high-performance bio enrichment denitrogenation Filler, realizes synchronous aerobic, anaerobic reaction on the whole.Organics removal and total nitrogen.
Step 6, A/O reaction tank water outlets enter the ABP technique of sedimentation basin, i.e.,.ABP techniques use new reflux type, Air- extraction is quantified, reflux ratio is adjusted according to waste water quality, optimize treatment effect.
Water outlet enters catalytic ozonation system, a large amount of difficult complicated organic matters for decomposing of removal, while having decolorization.
Then the 2nd ABP reaction tanks are entered back into, water outlet enters powdered ion-exchange resin system, mainly removes salt.
By this whole set process, the dyeing waste water of high concentration, even up to reuse water standard can be processed.
Dyeing waste water concentration of pollution discharge limit value:PH:6-9;COD:80 mg/L;:20 mg/L;Ammonia nitrogen:10 mg/L; Colourity:50.
Treated sewage reusing standard limited value:PH:6-9;:10 mg/L;Ammonia nitrogen:10 mg/L;TDS:1000 mg/L.Colourity:30.
The above, only presently preferred embodiments of the present invention is not intended to limit the invention, every according to skill of the invention Any trickle amendment, equivalent and improvement that art is substantially made to above example, should be included in technical solution of the present invention Protection domain within.

Claims (5)

1. a kind of dyeing waste water Treated sewage reusing ABP Processes and apparatus, including pretreatment system(1), neutralization pond(2), coagulating sedimentation Pond(3), hydrolysis acidification pool(4), A/O reaction tanks(5), an ABP reaction tanks(6), catalytic ozonation system(7), the 2nd ABP Reaction tank(8)With powdered ion-exchange resin system(9);It is characterized in that:The pretreatment system(1)It is sequentially connected by pipeline Neutralization pond(2), coagulative precipitation tank(3), hydrolysis acidification pool(4), A/O reaction tanks(5), an ABP reaction tanks(6), ozone catalytic Oxidative system(7), the 2nd ABP reaction tanks(8)With powdered ion-exchange resin system(9);The A/O reaction tanks(5)It is anti-including A Ying Chi(51)With O reaction tanks(52), and A reaction tanks(51)With hydrolysis acidification pool(4)It is adjacent.
2. a kind of technique of dyeing waste water Treated sewage reusing ABP Processes and apparatus, comprises the following steps:It is characterized in that:Step one, Dyeing waste water enters pretreatment system, and pretreatment mode is selected according to waste water characteristic;
Step 2, pretreatment cooling and oil removing, water outlet enter neutralization pond, adjust PH to 7-9;
Step 3, neutralization pond water outlet enters coagulative precipitation tank, and coagulant is selected according to waste water characteristic, removes partial organic substances and nothing Machine thing;
Step 4, subsequently enters hydrolysis acidification pool, and high-performance bio enrichment denitrogenation filler is installed in pond, and make difficult degradation in waste water has Machine thing is decomposed, and improves biodegradability;
Step 5, hydrolysis acidification pool water outlet enters back into A/O reaction tanks, and A/O reaction tanks are respectively mounted high-performance bio enrichment denitrogenation filler, Synchronous aerobic, anaerobic reaction is realized on the whole;
Step 6, A/O reaction tank water outlets enter the ABP technique of sedimentation basin, i.e.,.
3. a kind of dyeing waste water Treated sewage reusing ABP Processes and apparatus according to claim 1, it is characterized in that:Described first ABP reaction tanks(6)With the 2nd ABP reaction tanks(8)Using identical structure.
4. a kind of dyeing waste water Treated sewage reusing ABP Processes and apparatus according to claim 1, it is characterized in that:The hydrolysis Acidification pool(4)With A/O reaction tanks(5)Inside it is provided with high-performance bio enrichment denitrogenation filler.
5. a kind of dyeing waste water Treated sewage reusing ABP Processes and apparatus according to claim 1, it is characterized in that:The pre- place Reason system(1)Inside it is provided with grid(10), cooling bay(11)And oil interceptor(12).
CN201510986774.0A 2015-12-26 2015-12-26 A kind of dyeing waste water Treated sewage reusing ABP Processes and apparatus Pending CN106915864A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110357352A (en) * 2019-07-09 2019-10-22 容健美 A kind of multistage printing and dyeing wastewater decolorizing process technique

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CN201232043Y (en) * 2008-04-17 2009-05-06 北京碧水泉科技开发中心 Full-automatic, high efficiency and energy-saving sewage water reuse and recycle apparatus
CN101525202A (en) * 2009-04-14 2009-09-09 东华大学 Advanced dyeing wastewater treatment and reclaimed water reuse system and method thereof
CN103058467A (en) * 2013-01-22 2013-04-24 富民宝地纸业有限公司 Water paper paper-making wastewater efficient treatment and comprehensive recycling method and device
CN103204608A (en) * 2013-04-12 2013-07-17 杭州一清环保工程有限公司 Comprehensive treatment method of dyeing wastewater
CN104045154A (en) * 2013-03-12 2014-09-17 江苏瑞盛水处理有限公司 Wastewater biological treatment system based on bio-contact oxidation process
CN104529080A (en) * 2014-12-31 2015-04-22 苏州苏净环保新材料有限公司 Technique for treating pesticide wastewater containing phosphorus
CN204779037U (en) * 2015-04-20 2015-11-18 江苏博凯环境科技有限公司 Standpipe denitrogenation filler device
CN205328804U (en) * 2015-12-26 2016-06-22 江苏博凯环境科技有限公司 Printing and dyeing wastewater reuse of reclaimed water equipment

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Publication number Priority date Publication date Assignee Title
CN201232043Y (en) * 2008-04-17 2009-05-06 北京碧水泉科技开发中心 Full-automatic, high efficiency and energy-saving sewage water reuse and recycle apparatus
CN101423314A (en) * 2008-12-03 2009-05-06 北京师范大学 High efficiency denitrification, phosphorus removal and phosphorus resource recovery composite for urban sewage
CN101525202A (en) * 2009-04-14 2009-09-09 东华大学 Advanced dyeing wastewater treatment and reclaimed water reuse system and method thereof
CN103058467A (en) * 2013-01-22 2013-04-24 富民宝地纸业有限公司 Water paper paper-making wastewater efficient treatment and comprehensive recycling method and device
CN104045154A (en) * 2013-03-12 2014-09-17 江苏瑞盛水处理有限公司 Wastewater biological treatment system based on bio-contact oxidation process
CN103204608A (en) * 2013-04-12 2013-07-17 杭州一清环保工程有限公司 Comprehensive treatment method of dyeing wastewater
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CN204779037U (en) * 2015-04-20 2015-11-18 江苏博凯环境科技有限公司 Standpipe denitrogenation filler device
CN205328804U (en) * 2015-12-26 2016-06-22 江苏博凯环境科技有限公司 Printing and dyeing wastewater reuse of reclaimed water equipment

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110357352A (en) * 2019-07-09 2019-10-22 容健美 A kind of multistage printing and dyeing wastewater decolorizing process technique

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