CN106914970A - One kind improves concurrent early strength and exempts from steam protecting method - Google Patents

One kind improves concurrent early strength and exempts from steam protecting method Download PDF

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Publication number
CN106914970A
CN106914970A CN201710128635.3A CN201710128635A CN106914970A CN 106914970 A CN106914970 A CN 106914970A CN 201710128635 A CN201710128635 A CN 201710128635A CN 106914970 A CN106914970 A CN 106914970A
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CN
China
Prior art keywords
parts
concurrent
exempts
acid
early strength
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710128635.3A
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Chinese (zh)
Inventor
郭军海
陈守智
何润
缪加胜
衡江
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHENGDU YINXIAN ELECTRIC POLE Co Ltd
Original Assignee
CHENGDU YINXIAN ELECTRIC POLE Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by CHENGDU YINXIAN ELECTRIC POLE Co Ltd filed Critical CHENGDU YINXIAN ELECTRIC POLE Co Ltd
Priority to CN201710128635.3A priority Critical patent/CN106914970A/en
Publication of CN106914970A publication Critical patent/CN106914970A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B1/00Producing shaped prefabricated articles from the material
    • B28B1/08Producing shaped prefabricated articles from the material by vibrating or jolting
    • B28B1/087Producing shaped prefabricated articles from the material by vibrating or jolting by means acting on the mould ; Fixation thereof to the mould
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/10Accelerators; Activators
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/30Water reducers, plasticisers, air-entrainers, flow improvers
    • C04B2103/302Water reducers

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The present invention provides a kind of concurrent early strength that improves and exempts from steam protecting method, and concrete vibration moulding method uses adhesion type vibration moulding, and concurrent additive is added in concrete;Concurrent additive includes high performance water reducing agent of polyocarboxy acid, super hardening additive, and a kind of concrete vibration moulding method;High performance water reducing agent of polyocarboxy acid is made up of following component:900 1200 parts of 600 700 parts of AEO, unitary unsaturated carboxylic acid and its derivative, 450 600 parts of acrylic acid, 60 80 parts of initiator, 40 50 parts of catalyst, 80 100 parts of molecular weight regulator, 100 150 parts of monoolefin carboxylic acid, 200 250 parts of allyl polyethenoxy ether, 300 400 parts of methyl alkenyl polyoxyethylene poly-oxygen propylene aether;Super hardening additive is made up of following component:1,000 1400 parts of methoxy polyethylene glycol methacrylate-styrene polymer, 200 300 parts of itaconic acid, 400 500 parts of methacrylic acid, 100 150 parts of maleic anhydride, 80 100 parts of unsaturated sulfonic acid, 60 100 parts of melamine.

Description

One kind improves concurrent early strength and exempts from steam protecting method
Background technology
Because concurrent needs mould to have enough to meet the need, electric pole is to reach demoulding strength.Steam curing side must be used before Formula is produced, especially concrete square bar due to volume it is big, concrete square amount is big, and the steam curing time is especially very long, while Because reinforcing bar is intensive, spacing is small.Plug-in type vibrating shaping causes to vibrate leakiness, and honeycomb face is more, reduces concrete strength.Institute Exempt from steam protecting method to solve this problem to be badly in need of a kind of concurrent early strength that improves.
The content of the invention
The purpose of the present invention is to solve the shortcomings of the prior art, there is provided it is non-evaporating that one kind improves concurrent early strength Vapour maintenance process, the method can solve the above problems well.
To reach above-mentioned requirements, the present invention is adopted the technical scheme that:
A kind of concurrent early strength that improves is provided and exempts from steam protecting method, concrete vibration moulding method uses adhesion type Vibration moulding, and concurrent additive is added in concrete, concurrent additive includes that concurrent is additional Agent includes high performance water reducing agent of polyocarboxy acid, super hardening additive.
The concurrent additive include high performance water reducing agent of polyocarboxy acid, super hardening additive and, calcining kaolin and Sodium tripolyphosphate;High performance water reducing agent of polyocarboxy acid is made up of following component:AEO 600-700 parts, unitary not Saturated carboxylic acid and its derivative 900-1200 parts, acrylic acid 450-600 parts, initiator 60-80 parts, catalyst 40-50 parts, molecule 80-100 parts of conditioning agent of amount, monoolefin carboxylic acid 100-150 parts, allyl polyethenoxy ether 200-250 parts, methyl alkenyl polyoxy second 300-400 parts of alkene polyethenoxy ether;Super hardening additive is made up of following component:Methoxy polyethylene glycol methacrylate-styrene polymer 1000-1400 parts, itaconic acid 200-300 parts, methacrylic acid 400-500 parts, maleic anhydride 100-150 parts, unsaturated sulfonic acid 80-100 parts, melamine 60-100 parts;Na2SO4 contents are less than 5%;The alkali number for calcining kaolin is less than or equal to 0.5, Al2O3 contents are more than or equal to 25, and fineness is tailed over less than 5%. with 45um
The concrete vibration moulding method changes former plug-in type vibrating molding mode, is changed to mould side both sides adhesion type Motor oscillating is molded.Concrete density can be significantly improved, strengthens concrete strength.
The advantage of the method is as follows:
The concurrent additive is added in concurrent production, while coordinating adhesion type vibration moulding mode, is only needed Electric pole is set to reach demoulding strength by wanting 18 hours, while each age strength of concrete is substantially increased, far beyond original Design strength value, so as to not only reduce cement consumption, while saving energy consumption is substantially, and can skip steam curing this ring Section.
Brief description of the drawings
Accompanying drawing described herein is used for providing further understanding of the present application, the part of the application is constituted, at this Same or analogous part, the schematic description and description of the application are represented using identical reference number in a little accompanying drawings For explaining the application, the improper restriction to the application is not constituted.In the accompanying drawings:
Fig. 1 schematically shows and exempts from steam curing adhesion type in the application and vibrate the production schematic diagram of shaping.
Fig. 2 schematically shows the production schematic diagram that existing use steam curing plugs and pounds formula shaping.
Specific embodiment
To make the purpose, technical scheme and advantage of the application clearer, below in conjunction with drawings and the specific embodiments, to this Application is described in further detail.
In the following description, the reference to " one embodiment ", " embodiment ", " example ", " example " etc. shows So the embodiment or example of description can include special characteristic, structure, characteristic, property, element or limit, but not each reality Applying example or example all necessarily includes special characteristic, structure, characteristic, property, element or limit.In addition, reuse phrase " according to One embodiment of the application " is not necessarily referring to identical embodiment although it is possible to refer to identical embodiment.
For the sake of simplicity, eliminated well known to a person skilled in the art some technical characteristics in below describing.
According to one embodiment of the application, as shown in Figure 1 to Figure 2, there is provided one kind improves concurrent early strength Exempt from steam protecting method, including concrete vibration moulding method uses adhesion type vibration moulding, and coagulation is added in concrete Native electric pole additive, concurrent additive includes that concurrent additive includes high performance water reducing agent of polyocarboxy acid, super early Strong additive.
According to one embodiment of the application, the high performance water reducing agent of polyocarboxy acid of the concurrent additive is by such as the following group Divide and be made:AEO 600-700 parts, unitary unsaturated carboxylic acid and its derivative 900-1200 parts, acrylic acid 450-600 parts, initiator 60-80 parts, catalyst 40-50 parts, molecular weight regulator 80-100 parts, monoolefin carboxylic acid 100-150 Part, allyl polyethenoxy ether 200-250 parts, 300-400 parts of methyl alkenyl polyoxyethylene poly-oxygen propylene aether.
According to one embodiment of the application, the super hardening additive of the concurrent additive is by following component system Into:Methoxy polyethylene glycol methacrylate-styrene polymer 1000-1400 parts, itaconic acid 200-300 parts, methacrylic acid 400-500 parts, Maleic anhydride 100-150 parts, unsaturated sulfonic acid 80-100 parts, melamine 60-100 parts.
According to one embodiment of the application, the concurrent vibration moulding mode is mould side both sides adhesion type electricity Machine vibration is molded;Vibrating motor is along punching block both sides cross-distribution
According to one embodiment of the application, the raising concurrent early strength exempts from the concrete electric in steam protecting method The pH value of the high performance water reducing agent of polyocarboxy acid of bar additive is 7.2.
According to one embodiment of the application, the raising concurrent early strength exempts from the coagulation in steam protecting method The pH value of the super hardening additive of native electric pole additive is 11.4.
According to one embodiment of the application, the raising concurrent early strength exempts from the coagulation in steam protecting method The density of the high performance water reducing agent of polyocarboxy acid of native electric pole additive is 1.028 g/cm3.
According to one embodiment of the application, the raising concurrent early strength exempts from the coagulation in steam protecting method The density of the super hardening additive of native electric pole additive is 0.942 g/cm3.
According to one embodiment of the application, the raising concurrent early strength exempts from the coagulation in steam protecting method The solid content of the high performance water reducing agent of polyocarboxy acid of native electric pole additive is 11%.
According to one embodiment of the application, the raising concurrent early strength exempts from the coagulation in steam protecting method The solid content of the super hardening additive of native electric pole additive is 7%.
According to one embodiment of the application, the raising concurrent early strength exempts from the coagulation in steam protecting method The water-reducing rate of the high performance water reducing agent of polyocarboxy acid of native electric pole additive is 27%.
Because concurrent needs mould to have enough to meet the need, electric pole is to reach demoulding strength.Steam curing side must be used before Formula is produced.Especially concrete square bar due to volume it is big, concrete square amount is big.The steam curing time is especially very long.Therewith And come be exactly energy consumption increase.Plug-in type vibrating molding mode easily causes honeycomb, pitted skin simultaneously.Vibration leakiness, reduces coagulation Native intensity.Use steam-cured square bar concrete mix for:460 parts of cement, 660 parts of middle sand, 1240 parts of rubble, outside naphthalene system Plus 10 parts of agent, 160 parts of water.It is 12.2MPa by 18 hours intensity of this match ratio, intensity is 16.6 MPa within 24 hours, and 48 is small Shi Qiangdu is 24.4 MPa, and 72 hours intensity is 30.6 MPa, and 28 days intensity is 46.8 MPa.Because demoulding strength must reach To 70%.That is 28 MPa, so must conserve the demoulding of 3 days ability using former match ratio carries out mould turnover.According to steam Maintenance, it is necessary to assure 80 DEG C of temperature maintenances can reach demoulding strength in 7 hours.Annual coal consumption is more than 2000 tons.
According to one embodiment of the application, present square bar has been carried out exempting from steam curing.Using natural curing.It coordinates Than being 420 parts of cement, 740 parts of middle sand, 1230 parts of rubble, 6 parts of high performance water reducing agent of polyocarboxy acid, 24 parts of super hardening additive, water 110 parts.18 hours intensity according to this match ratio are 31.3MPa, and intensity is 36.0 MPa within 24 hours, and intensity is within 48 hours 42.3 MPa, 72 hours intensity is 48.2 MPa, and 28 days intensity is strong for 58.4 MPa. only need to can reach the demoulding in 18 hours Degree, while each age strength of concrete substantially increases.Far beyond 40 MPa intensity levels of design.Cement consumption is not only reduced, Saving energy consumption is obvious simultaneously.Steam curing this link is just skipped.
Embodiment described above only represents several embodiments of the invention, and its description is more specific and detailed, but not It is understood that to be limitation of the scope of the invention.It should be pointed out that for the person of ordinary skill of the art, not departing from On the premise of present inventive concept, various modifications and improvements can be made, these belong to the scope of the present invention.Therefore this hair Bright protection domain should be defined by the claim.

Claims (9)

1. a kind of concurrent early strength that improves exempts from steam protecting method, it is characterised in that:Concrete vibration moulding method Using adhesion type vibration moulding, and concurrent additive is added in concrete;
The concurrent additive includes high performance water reducing agent of polyocarboxy acid and super hardening additive;
The high performance water reducing agent of polyocarboxy acid is made up of following component:AEO 600-700 parts, unitary unsaturation Carboxylic acid and its derivative 900-1200 parts, acrylic acid 450-600 parts, initiator 60-80 parts, catalyst 40-50 parts, molecular weight tune 80-100 part of agent of section, monoolefin carboxylic acid 100-150 parts, allyl polyethenoxy ether 200-250 parts, methyl alkenyl polyoxyethylene it is poly- 300-400 parts of oxypropylene ether;
The super hardening additive is made up of following component:Methoxy polyethylene glycol methacrylate-styrene polymer 1000-1400 parts, clothing health Sour 200-300 parts, methacrylic acid 400-500 parts, maleic anhydride 100-150 parts, unsaturated sulfonic acid 80-100 parts, melamine 60-100 parts;
The concrete vibration moulding method is punching block adhesion type vibration moulding.
2. raising concurrent early strength according to claim 1 exempts from steam protecting method, it is characterised in that:It is described The pH value of high performance water reducing agent of polyocarboxy acid is 7.2.
3. raising concurrent early strength according to claim 1 exempts from steam protecting method, it is characterised in that:It is described The pH value of super hardening additive is 11.4.
4. raising concurrent early strength according to claim 1 exempts from steam protecting method, it is characterised in that:It is described The density of high performance water reducing agent of polyocarboxy acid is 1.028g/cm3.
5. raising concurrent early strength according to claim 1 exempts from steam protecting method, it is characterised in that:It is described The density of super hardening additive is 0.942 g/cm3.
6. raising concurrent early strength according to claim 1 exempts from steam protecting method, it is characterised in that:It is described The solidification amount of high performance water reducing agent of polyocarboxy acid is 11%.
7. raising concurrent early strength according to claim 1 exempts from steam protecting method, it is characterised in that:It is described The solidification amount of super hardening additive is 7%.
8. raising concurrent early strength according to claim 1 exempts from steam protecting method, it is characterised in that:It is described The water-reducing rate of high performance water reducing agent of polyocarboxy acid is 27%.
9. raising concurrent early strength according to claim 1 exempts from steam protecting method, it is characterised in that:It is described Concrete vibration moulding mode is adhesion type vibration moulding, and vibrating motor is along punching block both sides cross-distribution.
CN201710128635.3A 2017-03-06 2017-03-06 One kind improves concurrent early strength and exempts from steam protecting method Pending CN106914970A (en)

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CN201710128635.3A CN106914970A (en) 2017-03-06 2017-03-06 One kind improves concurrent early strength and exempts from steam protecting method

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108569860A (en) * 2018-05-17 2018-09-25 安徽亨通外加剂有限公司 A kind of environment protection type water permeable concrete admixture and preparation method thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0080143A1 (en) * 1981-11-19 1983-06-01 Eskilstuna Invest Ab Foundation for a pole, a pillar or the like
CN2120842U (en) * 1992-04-28 1992-11-04 王海清 Adhesive vibrator
CN1072129A (en) * 1991-11-06 1993-05-19 岑武祥 Manufacturing method of pipe
CN101974135A (en) * 2010-10-15 2011-02-16 北京工业大学 Normal-temperature synthesis method for polycarboxylic acid water-reducing agent
CN102744775A (en) * 2012-07-09 2012-10-24 浙江天晟建材集团有限公司 Special forming mold for T-shaped precast beam plate
CN106146750A (en) * 2016-06-28 2016-11-23 四川宇砼建材有限公司 Collapse protective poly-carboxylic acid high-performance water reducing agent and preparation method thereof
CN106220097A (en) * 2016-07-29 2016-12-14 儋州宇顺实业有限公司 A kind of concurrent factory formula reducing energy consumption and electric pole preparation method

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0080143A1 (en) * 1981-11-19 1983-06-01 Eskilstuna Invest Ab Foundation for a pole, a pillar or the like
CN1072129A (en) * 1991-11-06 1993-05-19 岑武祥 Manufacturing method of pipe
CN2120842U (en) * 1992-04-28 1992-11-04 王海清 Adhesive vibrator
CN101974135A (en) * 2010-10-15 2011-02-16 北京工业大学 Normal-temperature synthesis method for polycarboxylic acid water-reducing agent
CN102744775A (en) * 2012-07-09 2012-10-24 浙江天晟建材集团有限公司 Special forming mold for T-shaped precast beam plate
CN106146750A (en) * 2016-06-28 2016-11-23 四川宇砼建材有限公司 Collapse protective poly-carboxylic acid high-performance water reducing agent and preparation method thereof
CN106220097A (en) * 2016-07-29 2016-12-14 儋州宇顺实业有限公司 A kind of concurrent factory formula reducing energy consumption and electric pole preparation method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108569860A (en) * 2018-05-17 2018-09-25 安徽亨通外加剂有限公司 A kind of environment protection type water permeable concrete admixture and preparation method thereof

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Application publication date: 20170704

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