CN106906662A - A kind of GSZ emulsion and preparation method thereof - Google Patents
A kind of GSZ emulsion and preparation method thereof Download PDFInfo
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- CN106906662A CN106906662A CN201710261687.8A CN201710261687A CN106906662A CN 106906662 A CN106906662 A CN 106906662A CN 201710261687 A CN201710261687 A CN 201710261687A CN 106906662 A CN106906662 A CN 106906662A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
- D06M15/3568—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing silicon
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/12—Monomers containing a branched unsaturated aliphatic radical or a ring substituted by an alkyl radical
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F218/02—Esters of monocarboxylic acids
- C08F218/04—Vinyl esters
- C08F218/08—Vinyl acetate
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
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Abstract
The invention discloses a kind of GSZ emulsion and preparation method thereof, the emulsion preparation method is comprised the following steps：The aqueous solution of the mixture of carboxylic acid monomer, vinylacetate, (methyl) styrene, silane, Ludox, emulsifying agent, initiator and aided initiating is carried out into free-radical emulsion polymerization, the reaction time is 3~10 hours at 50 DEG C~75 DEG C, product is adjusted into pH=6~9 with alkaline matter, after filtering, emulsion is obtained.Using GSZ emulsion obtained in the present invention, hence it is evident that improve the constancy and intensity of GSZ, high-performance, environmental requirement in GSZ production process are met.
Description
Technical field
Shaping glue field is used the present invention relates to GSZ, and in particular to a kind of GSZ emulsion and its preparation side
Method.
Background technology
Emulsion is used in GSZ, and the Main Function for rising is to shape and strengthen.Constituted according to raw material in the market
Difference mainly has the types such as styrene-butadiene emulsion, emulsion, pure-acrylic emulsion.
Styrene-butadiene emulsion, i.e., the usual SB emulsions, are one kind of synthetic emulsion, are based on styrene, divinylic monomer
Want Material synthesis.Emulsion, i.e. usual SA emulsions, it with styrene, acrylic acid or acrylate is main Material synthesis to be
's.Pure-acrylic emulsion, it with styrene, acrylic acid or acrylate is main Material synthesis to be.Added according to different GSZs
The requirement of work, by adjusting different monomer compositions, synthesizes different types of emulsion.Enhancing civil grille is primarily served after use
Intensity, prevent the effect of GSZ deformation.
Chinese patent CN105153565A discloses a kind of alkali-proof glass fiber mesh dip-coating high-intensity high-tenacity ring
Oxygen tree fat modified emulsion and preparation method thereof, is applied in the production of GSZ, also has certain sizing to make to GSZ
With, but intensity improves little, and civil grille is partially soft.
The content of the invention
The present invention proposes a kind of GSZ emulsion to solve above mentioned problem of the prior art, and it adds a small amount of silicon
Alkane and Ludox, compared with ordinary emulsion, GSZ emulsion applications of the invention make geotechnique in the production of GSZ
Grid has more preferable constancy and intensity.
To achieve the above object, the present invention uses following technical scheme：
The first aspect of the invention is to provide a kind of preparation method of GSZ emulsion, comprises the following steps：Will
The mixture of carboxylic acid monomer, vinylacetate, (methyl) styrene, silane, Ludox, emulsifying agent, initiator and aided initiating
The aqueous solution carry out free radical emulsion copolymerization, in 3~10 hours reaction time, product alkaline matter is adjusted to pH=6
~9, after filtering, the GSZ emulsion is obtained.
Further, in the preparation method of the GSZ emulsion, each component and parts by weight in reaction system
It is as follows：
It is further preferred that in the preparation method of the GSZ emulsion, each component and weight in reaction system
Number is as follows：
Further, in the preparation method of the GSZ emulsion, the carboxylic acid monomer is selected from acrylic acid, methyl
At least one in acrylic acid, maleic acid, fumaric acid, itaconic acid.
Further, in the preparation method of the GSZ emulsion, the emulsifying agent is anion surface active
Agent and the mixture of nonionic surfactant.
It is further preferred that the anion surfactant is selected from C10~C20 sodium alkyl benzene sulfonates, C10~C20 alkane
Base sodium naphthalene sulfonate, C10~C20 sodium alkyl sulfates, dialkyl group -2- sodium sulfosuccinates, dicyclohexyl -2- sodium sulfosuccinates,
At least one in succinic acid sodium sulfonate, enuatrol, potassium oleate, Emulphor FM.
It is further preferred that the nonionic surfactant is selected from sorbitan trioleate, anhydrous sorbitol three
Stearate (this disk 65), glycol fatty acid ester, methyl glycol fatty acid ester, anhydrous sorbitol list hard fatty acid ester (this disk
60), sorbitan monooleate (span 80), diethylene glycol fatty acid ester, sorbitan monopalmitate (this disk 40),
PPOX hard fatty acid ester, sorbitan mono-laurate (this disk 20), polyethylene glycol oxide hard fatty acid ester, laurate
Polyoxyethylene ester, polyethylene glycol oxide (4) anhydrous sorbitol list hard fatty acid ester (Tween61), polyethylene glycol oxide (5) Sorbitan
Alcohol monoleate (sorbimacrogol oleate100), polyethylene glycol oxide (20) anhydrous sorbitol tristearate (polysorbate65), polyethylene glycol oxide (20)
Sorbitan trioleate (polysorbate85), polyethylene glycol oxide monoleate, fatty alcohol amine polyethylene glycol oxide ether, alkyl phenol polyoxy
Vinethene, polyethylene glycol oxide monolaurate, polyoxyethylene castor oil, polyethylene glycol oxide (4) anhydrous sorbitol mono laurate
Ester (tween 21), polyethylene glycol oxide (20) anhydrous sorbitol list hard fatty acid ester (polysorbate60), polyethylene glycol oxide (20) dehydration mountain
Pears alcohol monoleate (Tween 80), polyethylene glycol oxide (20) sorbitan monopalmitate (polysorbate40), polyethylene glycol oxide
(20) sorbitan mono-laurate (polysorbas20), polyethers L31 (BASF system, similarly hereinafter), polyethers L61, polyethers L81, polyethers
At least one in L42, polyethers L62, polyethers L72, polyethers L63, polyethers L64, polyethers F68, polyethers F88, polyethers F108.
Further, in the preparation method of the GSZ emulsion, the silane is selected from the isopropyl oxygen of vinyl three
At least one in base silane, γ-methacryloxypropyl trimethoxy silane, VTES.
Further, in the preparation method of the GSZ emulsion, the initiator is selected from potassium peroxydisulfate, over cure
At least one in sour sodium, ammonium persulfate.
Further, in the preparation method of the GSZ emulsion, the aided initiating is selected from sodium sulfite, resists
At least one in bad hematic acid, sodium pyrosulfite.
Further, in the preparation method of the GSZ emulsion, the alkaline matter is selected from the hydrogen of alkali metal
Oxide, preferably NaOH.
Further, in the preparation method of the GSZ emulsion, the Ludox is received selected from particle diameter 10~50
Rice, weight solid content is 25~35% Ludox.
It is further preferred that in the preparation method of the GSZ emulsion, the Ludox be selected from particle diameter 20~
40 nanometers, weight solid content is 28~30% Ludox.
Further, in the preparation method of the GSZ emulsion, the reaction temperature of radical polymerization is 50 DEG C
~75 DEG C.
It is further preferred that in the preparation method of the GSZ emulsion, the reaction temperature of radical polymerization is
60 DEG C~65 DEG C.
Further, in the preparation method of the GSZ emulsion, the reaction time is 3.5~5 hours, with alkalescence
Material adjusts to pH=8~8.5 product.
The second aspect of the invention is to provide GSZ emulsion prepared by a kind of use above method.
Further, in described GSZ emulsion, the weight solid content of emulsion is 20%~40%.
It is further preferred that in described GSZ emulsion, the weight solid content of emulsion is 25%~30%.
The third aspect of the invention is to provide a kind of application of the GSZ emulsion, and it is used for GSZ life
In impregnation composition during product.
The inventors discovered that a small amount of silane and Ludox are added in GSZ emulsion of the invention, unexpectedly
, it is applied in GSZ impregnation composition, the intensity of GSZ has obvious raising；Its reason is analyzed, this is
It is a kind of nano particle, the effect with small size, it is easier to GSZ yarn, breast because the particle diameter of Ludox is smaller
The active group for changing pitch is combined, and forms cross-linked structure；Simultaneously silane there is certain crosslinked action, can strengthen pitch,
The effect each other of GSZ yarn, thermosetting is intended in GSZ impregnation composition high-temperature drying procedures, performance
For the intensity of GSZ is significantly improved, external manifestation is can be obvious using GSZ styrene-acrylic emulsion of the invention
Raising GSZ intensity；Additionally, a part of vinylacetate is used in the present invention, and it is unexpected, using this list
Body also increases to the effect of emulsion, while cost decreases.
The present invention uses above-mentioned technical proposal, compared with prior art, have the following technical effect that：
GSZ emulsion of the invention, is a kind of high-performance that can meet GSZ production, the product of environmental protection；Should
Product is used in the production of GSZ, can significantly improve the constancy and intensity of GSZ；And its preparation method letter
Single, easy to operate, low production cost.
Specific embodiment
The present invention is described in more detail below by specific embodiment, for a better understanding of the present invention,
But following embodiments are not intended to limit the scope of the invention.
The preparation of the GSZ emulsion of embodiment 1：
0.3 gram of neopelex, 0.2 gram of sorbitan monopalmitate are added in 2000ml reactors
(this disk 40), 0.5 gram of potassium peroxydisulfate and 142.5 grams of distilled water, are completely dissolved into the aqueous solution, are stirred heating, heating-up temperature
50 DEG C, carry out polymerisation；Then 100 grams of styrene, the mix monomer of 0.2 gram of vinyl silane triisopropoxide are added dropwise to,
Time for adding 6 hours；0.2 gram of sodium sulfite and 10 grams of aqueous solution of distilled water are added dropwise while mix monomer is added dropwise, are added dropwise
6 hours time；1 gram of Ludox (10 nanometers of particle diameter, weight solid content 25%) is added, continues to stir mixing 4 hours, be cooled to
25 DEG C, through 100 mesh sieve net filtrations, GSZ emulsion is obtained, solid content 39.86wt%, pH=6.08 (use PHS-3C essences
Close pH meter is measured).
The preparation of the GSZ emulsion of embodiment 2：
2 grams of dialkyl group -2- sodium sulfosuccinates, 3 grams of sorbitan mono-laurates are added in 2000ml reactors
(this disk 20), 5 grams of sodium peroxydisulfates and 1285.5 grams of distilled water, are completely dissolved into the aqueous solution, are stirred heating, heating-up temperature 75
DEG C, carry out polymerisation；It is added dropwise to 100 grams of methyl styrene, 5 grams of methacrylic acid, 200 grams of vinylacetate and γ-methyl
2 grams of mix monomers of acryloxypropyl trimethoxy silane, time for adding 2 hours；2 are added dropwise while mix monomer is added dropwise
Gram sodium pyrosulfite and 10 grams of aqueous solution of distilled water, time for adding 2 hours add 5 grams of Ludox (50 nanometers of particle diameter, weight
Amount solid content 35%), continue to stir mixing 1 hour；25 DEG C are cooled to, are neutralized with 12.5 grams of 40wt% sodium hydrate aqueous solutions,
Through 100 mesh sieve net filtrations, GSZ emulsion is obtained, solid content 20.18wt%, pH=8.92 (use PHS-3C Accurate pHs
Measure).
The preparation of the GSZ emulsion of embodiment 3：
1 gram of lauryl sodium sulfate, 2 grams of polyethylene glycol oxide (4) anhydrous sorbitol Dan Yue are added in 2000ml reactors
Cinnamic acid ester (tween 21), 2 grams of ammonium persulfates, 1 gram of itaconic acid and 483.2 grams of distilled water, are completely dissolved into the aqueous solution, are stirred
Heating, 65 DEG C of heating-up temperature carries out polymerisation；Then be added dropwise to 50 grams of styrene, 50 grams of methyl styrene, 2 grams of acrylic acid,
The mix monomer of 0.5 gram of 100 grams of vinylacetate and VTES, time for adding 4 hours；It is single mixing is added dropwise
1 gram of ascorbic acid and 10 grams of aqueous solution of distilled water are added dropwise while body, time for adding 4 hours adds 3 grams of Ludox (grains
25 nanometers of footpath, weight solid content 30%), continue to stir mixing 1 hour；25 DEG C are cooled to, with 10 grams of 30wt% NaOH water
Solution is neutralized, and through 100 mesh sieve net filtrations, obtains GSZ emulsion, and solid content 30.33wt%, pH=8.17 (use PHS-
3C Accurate pHs are measured).
The preparation of the GSZ emulsion of embodiment 4：
1 gram of dicyclohexyl -2- sodium sulfosuccinate, the dehydration of 1 gram of polyethylene glycol oxide (20) are added in 2000ml reactors
Sorbierite monopalmitate (polysorbate40), 2 grams of ammonium persulfates and 1 gram of sodium peroxydisulfate, 1 gram of fumaric acid, 1 gram of maleic acid and 280.06
Gram distilled water, is completely dissolved into the aqueous solution, is stirred heating, and 70 DEG C of heating-up temperature carries out polymerisation；Then it is added dropwise to benzene
20 grams of ethene, 80 grams of methyl styrene, 0.8 gram of mix monomer of 50 grams of vinylacetate and VTES, are added dropwise
3 hours time；0.3 gram of ascorbic acid, 0.2 gram of sodium pyrosulfite and 10 grams of distilled water are added dropwise while mix monomer is added dropwise
The aqueous solution, time for adding 3 hours；2 grams of Ludox (15 nanometers of particle diameter, weight solid content 33%) are added, continues to stir mixing 1
Hour, 25 DEG C are cooled to, neutralized with 10 grams of 20wt% sodium hydrate aqueous solutions, through 100 mesh sieve net filtrations, obtain GSZ use
Emulsion, solid content 35.09wt%, pH=7.26 (are measured) using PHS-3C Accurate pHs.The GSZ emulsion of embodiment 5
Prepare：
2 grams of Emulphor FMs, 2 grams of polyethylene glycol oxide hard fatty acid esters, 2 grams of over cures are added in 2000ml reactors
Sour ammonium, 1 gram of fumaric acid and 782.36 grams of distilled water, are completely dissolved into the aqueous solution, are stirred heating, and 60 DEG C of heating-up temperature is entered
Row polymerisation；Then 100 grams of styrene, 150 grams of vinylacetate, γ-methacryloxypropyl trimethoxy are added dropwise to
1.5 grams of base silane and 3 grams of mix monomers of acrylic acid, time for adding 5 hours；0.8 gram of Asia is added dropwise while mix monomer is added dropwise
Sodium sulphate, 0.7 gram of sodium pyrosulfite and 10 grams of aqueous solution of distilled water, time for adding 5 hours add 4 grams of Ludox (particle diameters
40 nanometers, weight solid content 28%), continue to stir mixing 1 hour；25 DEG C are cooled to, it is water-soluble with 10 grams of 25wt% NaOH
Liquid is neutralized, and through 100 mesh sieve net filtrations, obtains GSZ emulsion, and solid content 25.07wt%, pH=6.98 (use PHS-3C
Accurate pH is measured).
Comparative example：By emulsion prepared by the method for CN105153565A
With embodiment 1~5 and comparative example, operated by following techniques：
A, embodiment 1~5 and comparative example are diluted to weight solid content 20%, by emulsion：Emulsified asphalt (it is commercially available,
Weight solid content 30%)=2：5 are hybridly prepared into dipping solution；
B, the GSZ single yarn of non-impregnation is soaked in each dipping solution, according to soak time 2min, impregnation resin content
18% or so, after being dried up using hair-dryer, it is placed in 150 DEG C of baking ovens and dries 10min；
The feel soft durometer of GSZ yarn after C, observation impregnation, and detect single yarn Strength Changes after impregnation.
Criterion：Intensity shows that more greatly the enhancing effect of GSZ emulsion is better
| Intensity/N | |
| Non- impregnation | 105 |
| Comparative example | 208 |
| Embodiment 1 | 253 |
| Embodiment 2 | 263 |
| Embodiment 3 | 239 |
| Embodiment 4 | 247 |
| Embodiment 5 | 266 |
Be can be seen that from above-mentioned application result：The GSZ emulsion prepared using the embodiment of the present invention 1~5 is and right
Ratio is compared, more preferable to GSZ enhancing effect, hence it is evident that improve the constancy and intensity of GSZ.
Specific embodiment of the invention has been described in detail above, but it is intended only as example, and the present invention is not limited
It is formed on particular embodiments described above.To those skilled in the art, any equivalent modifications carried out to the present invention and
Replacement is also all among scope of the invention.Therefore, the impartial conversion made without departing from the spirit and scope of the invention and
Modification, all should be contained within the scope of the invention.
Claims (10)
1. a kind of preparation method of GSZ emulsion, it is characterised in that comprise the following steps：By carboxylic acid monomer, acetic acid second
The aqueous solution of the mixture of alkene ester, (methyl) styrene, silane, Ludox, emulsifying agent, initiator and aided initiating carries out freedom
Base emulsion copolymerization, in 3~10 hours reaction time, product alkaline matter is adjusted to pH=6~9, after filtering, is obtained
The GSZ emulsion.
2. the preparation method of GSZ emulsion according to claim 1, it is characterised in that in reaction system each component and
Parts by weight are as follows：
3. the preparation method of GSZ emulsion according to claim 1 or claim 2, it is characterised in that carboxylic acid monomer's choosing
From acrylic acid, methacrylic acid, maleic acid, fumaric acid or, at least one in itaconic acid；The emulsifying agent is anionic surface
The mixture of activating agent and nonionic surfactant, wherein, the anion surfactant is selected from C10~C20 alkylbenzenes
Sodium sulfonate, C10~C20 Negels, C10~C20 sodium alkyl sulfates, dialkyl group -2- sodium sulfosuccinates, two hexamethylenes
At least one in base -2- sodium sulfosuccinates, succinic acid sodium sulfonate, enuatrol, potassium oleate or Emulphor FM；It is described
Nonionic surfactant is selected from sorbitan trioleate, anhydrous sorbitol tristearate (this disk 65), ethylene glycol fat
Fat acid esters, methyl glycol fatty acid ester, anhydrous sorbitol list hard fatty acid ester (this disk 60), sorbitan monooleate (this disk
80), diethylene glycol fatty acid ester, sorbitan monopalmitate (this disk 40), PPOX hard fatty acid ester, dehydration mountain
Pears alcohol monolaurate (this disk 20), polyethylene glycol oxide hard fatty acid ester, laurate polyoxyethylene ester, polyethylene glycol oxide (4) lose
Water sorbierite list hard fatty acid ester (Tween61), polyethylene glycol oxide (5) sorbitan monooleate (sorbimacrogol oleate100), polyoxyethylene
Alkene (20) anhydrous sorbitol tristearate (polysorbate65), polyethylene glycol oxide (20) sorbitan trioleate (polysorbate85),
Polyethylene glycol oxide monoleate, fatty alcohol amine polyethylene glycol oxide ether, APES, polyethylene glycol oxide mono laurate
Ester, polyoxyethylene castor oil, polyethylene glycol oxide (4) sorbitan mono-laurate (tween 21), polyethylene glycol oxide (20)
Anhydrous sorbitol list hard fatty acid ester (polysorbate60), polyethylene glycol oxide (20) sorbitan monooleate (Tween 80), polyoxy
Change ethene (20) sorbitan monopalmitate (polysorbate40), polyethylene glycol oxide (20) sorbitan mono-laurate (to tell
Temperature 20), polyethers L31 (BASF system, similarly hereinafter), polyethers L61, polyethers L81, polyethers L42, polyethers L62, polyethers L72, polyethers L63,
At least one in polyethers L64, polyethers F68, polyethers F88, polyethers F108.
4. the preparation method of GSZ emulsion according to claim 1 or claim 2, it is characterised in that the silane is selected from second
In the isopropoxy silane of alkenyl three, γ-methacryloxypropyl trimethoxy silane, VTES extremely
Few one kind；The alkaline matter is selected from the hydroxide of alkali metal.
5. the preparation method of GSZ emulsion according to claim 1 or claim 2, it is characterised in that the initiator is selected from
At least one in potassium peroxydisulfate, sodium peroxydisulfate, ammonium persulfate；The aided initiating is selected from sodium sulfite, ascorbic acid, Jiao Ya
At least one in sodium sulphate.
6. the preparation method of GSZ emulsion according to claim 1 or claim 2, it is characterised in that the Ludox is selected from
10~50 nanometers of particle diameter, weight solid content is 25~35% Ludox.
7. GSZ emulsion according to claim 1 and 2, it is characterised in that the reaction temperature of radical polymerization is
50 DEG C~75 DEG C.
8. a kind of such as the GSZ emulsion of any one of claim 1~7 methods described preparation.
9. GSZ emulsion according to claim 8, it is characterised in that the weight solid content of emulsion is 20%~
40%.
10. a kind of application of the GSZ emulsion as described in claim 8 or 9, it is characterised in that for GSZ production
During impregnation composition in.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0381122A2 (en) * | 1989-02-01 | 1990-08-08 | Air Products And Chemicals, Inc. | Two stage polymerization of vinyl acetate/ethylene emulsion copolymers containing incompatible monomers |
| CN102417775A (en) * | 2011-11-18 | 2012-04-18 | 肇庆千江高新材料科技有限公司 | Silicasol-acrylate emulsion compound primer |
| CN102898044A (en) * | 2012-10-19 | 2013-01-30 | 四川航天拓鑫玄武岩实业有限公司 | Basalt fiber surface modification impregnating compound and preparation method thereof |
| CN103864976A (en) * | 2014-04-08 | 2014-06-18 | 中山职业技术学院 | Self-crosslinking styrene-acrylic emulsion for non-woven fabrics and preparation method of self-crosslinking styrene-acrylic emulsion |
| CN104448117A (en) * | 2014-11-28 | 2015-03-25 | 江门四方威凯精细化工有限公司 | Water-based organic/inorganic hybrid acrylate emulsion and preparation method thereof |
-
2017
- 2017-04-20 CN CN201710261687.8A patent/CN106906662A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0381122A2 (en) * | 1989-02-01 | 1990-08-08 | Air Products And Chemicals, Inc. | Two stage polymerization of vinyl acetate/ethylene emulsion copolymers containing incompatible monomers |
| CN102417775A (en) * | 2011-11-18 | 2012-04-18 | 肇庆千江高新材料科技有限公司 | Silicasol-acrylate emulsion compound primer |
| CN102898044A (en) * | 2012-10-19 | 2013-01-30 | 四川航天拓鑫玄武岩实业有限公司 | Basalt fiber surface modification impregnating compound and preparation method thereof |
| CN103864976A (en) * | 2014-04-08 | 2014-06-18 | 中山职业技术学院 | Self-crosslinking styrene-acrylic emulsion for non-woven fabrics and preparation method of self-crosslinking styrene-acrylic emulsion |
| CN104448117A (en) * | 2014-11-28 | 2015-03-25 | 江门四方威凯精细化工有限公司 | Water-based organic/inorganic hybrid acrylate emulsion and preparation method thereof |
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