CN106906416A - A kind of automobile 180BH cold rolling bakings harden high-strength steel - Google Patents
A kind of automobile 180BH cold rolling bakings harden high-strength steel Download PDFInfo
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- CN106906416A CN106906416A CN201510975819.4A CN201510975819A CN106906416A CN 106906416 A CN106906416 A CN 106906416A CN 201510975819 A CN201510975819 A CN 201510975819A CN 106906416 A CN106906416 A CN 106906416A
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/004—Very low carbon steels, i.e. having a carbon content of less than 0,01%
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/26—Methods of annealing
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/005—Heat treatment of ferrous alloys containing Mn
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/005—Ferrite
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Heat Treatment Of Sheet Steel (AREA)
Abstract
The present invention relates to metallurgical material field, automobile is belonged to advanced high-strength steel field, specially a kind of automobile 180BH cold rolling bakings harden high-strength steel.By mass percentage, its chemical composition is:C 0.0015~0.0025;Si≤0.05;Mn 0.15~0.30;P 0.030~0.050;S≤0.015;Als 0.02~0.06;Nb 0.008~0.020;Cr 0.05~0.10;Mo≤0.05;Remaining is Fe.It is as follows using continuous annealing process:840~860 DEG C of 60~120min of insulation;Furnace cooling is quickly cooled to 400 DEG C to 700~750 DEG C with 25~50 DEG C/sec of cooling rate, is incubated 1~3h, then cool to room temperature with the furnace.The cold rolling baking hardening high-strength steel 180BH product chemical composition stabilities of present invention production, forming property, excellent BH and resistance to room temperature ageing performance with stabilization.
Description
Technical field
The present invention relates to metallurgical material field, automobile advanced high-strength steel field, specially a kind of automobile are belonged to
High-strength steel is hardened with 180BH cold rolling bakings.
Background technology
Since two thousand, Chinese Automobile Industry ' enters fast-developing period, annual automobile production amount and sale
With two digits rapid growth, 2009, Chinese automobile volume of production and marketing breached 13,000,000 to amount, occupies generation
Boundary first;The automobile of China in 2010 is produced, sales volume continues rapid growth with surprising rapidity, and creates go through again
History new peak.Counted according to China Association for Automobile Manufacturers, automobile volume of production and marketing increases 32.44% He respectively within 2010
32.37%, reach 1826.47 ten thousand and 1806.19 ten thousand;Chinese automobile volume of production and marketing in pairs more than 18,000,000,
Continue to be sure to occupy global volume of production and marketing first.However, automobile to mankind's trip offer convenience condition while, also band
The problems such as traffic congestion, environmental pollution are carried out.Therefore, exploitation is with the low " ring being characterized less with discharge capacity of oil consumption
Border friendly automobile " has become development trend.Substantial amounts of result of study shows, is ensureing vehicle safety and making
On the premise of feature, it is to realize " environment-friendly type vehicle " to reduce body of a motor car deadweight (automotive light weight technology)
The major measure of this target.
At present in the raw material that manufacture automobile is used, the proportion maximum (about 2/3rds shared by ferrous materials
Left and right), and in ferrous materials consumption it is maximum be sheet metal.In the development process of automotive light weight technology, although one
The straight competition that there are ferrous materials and aluminium alloy, magnesium alloy, plastics and composite, but up to the present,
Substantial amounts of result of study shows, from vehicle safety, manufacturing cost, the recovery cycling and reutilization of material and light
Quantization sees that active development and use have high-performance, the ferrous materials of high intensity with the resultant effect of energy-conservation, and
Coordinate the advanced technology that shapes still has obvious advantage and wide application in many manufacture automotive materials
Prospect.
The automobile cold-rolled high-strength product made from steel of baking hardening has high intensity, good formability and preferable baking hardening
Property, while surface quality requirements high, this steel grade technology content is very high, also has very to production equipment
Requirement high, has in main science and technology:First it is that Design of Chemical Composition, hot rolling, cold rolling, annealing process are worked out,
It is crucial that rational continuous annealing process design is carried out on this component base, so as to meet the finished product sense of organization
Can require;Secondly steel making working procedure chemical composition precise control, hot rolling, cold rolling and annealing process system accurate control
System, it is ensured that the stabilization of product quality;It is finally whole process each operation stabilization, efficient production, it is ensured that high-volume
The requirement commercially produced.
Baking hardening steel plate (abbreviation BH steel) is based on mild steel or ultra-low-carbon steel, by adding micro- conjunction
Gold element Nb, Ti etc. and be made, have the novel high-quality vapour of excellent deep drawability and baking and hardening performance high concurrently
Automobile-used thin plate.The characteristics of BH steel plates is stamping preceding softer, easy forming, after stamping
Paint baking process increases yield strength, therefore is well suited for the coverings such as automobile exterior panel.Baking hardening (BH)
Yield point is low when steel feature is stamping, have excellent moldability, after punch process, height when being dried due to application
Warm short time heat treatment makes rise of yield point, so that stamping parts has intensity higher and resists in a state of use
Depression ability.Baking hardened steel is suitable for the production covering such as automobile exterior panel, its consumption also increasing year by year, into
It is the important component of Hyundai Motor steel.
The content of the invention
High-strength steel, its chemical composition are hardened it is an object of the invention to provide a kind of automobile 180BH cold rolling bakings
Stabilization, forming property, excellent BH and resistance to room temperature ageing performance with stabilization.
The technical scheme is that:
A kind of automobile 180BH cold rolling bakings harden high-strength steel, and by mass percentage, its chemical composition is:
C 0.0015~0.0025;Si≤0.05;Mn 0.15~0.30;P 0.030~0.050;S≤0.015;Als 0.02~
0.06;Nb 0.008~0.020;Cr 0.05~0.10;Mo≤0.05;Remaining is Fe.
Described automobile 180BH cold rolling bakings harden high-strength steel, and its performance indications is:Yield strength 185~
220MPa;320~350MPa of tensile strength;Elongation percentage 37~46.5%;n90Value 0.19~0.25;r90Value
1.62~3.1;BH2Value 30~60.
Described automobile 180BH cold rolling bakings harden high-strength steel, as follows using continuous annealing process:840~
860 DEG C of 60~120min of insulation;Furnace cooling to 700~750 DEG C, and with 25~50 DEG C/sec of fast quickly coolings of cooling rate
But to 400 DEG C, 1~3h is incubated, then cool to room temperature with the furnace.
Design philosophy of the invention is:
The present invention adds P, Mn to strengthen in composition design using Ultra-low carbon, while micro Nb, Cr element is added,
Using suitable continuous annealing process system, cold rolling baking hardening BH steel 180BH is successfully developed.Steel-making
Operation carries out Narrow Composition Control, and C content is controlled in the range of 0.0015%~0.0025%, and the control of Nb contents exists
In the range of 0.008%~0.020%, the technique for coordinating high annealing quickly to cool down, it is ensured that product has stablizes mechanics
Performance, within 10MPa, same specification product strength fluctuates within 30MPa the logical volume strength fluctuation of product.
Mo≤0.05% element is with the addition of on the basis of ultralow C composition designs, coordinates rational annealing process, it is ensured that produced
Product normal temperature ageing resistance can reach more than 6 months.
Advantages of the present invention and beneficial effect are:
1st, automobile cold-rolled baking hardening steel plate will have excellent press formability, plasticity, and relatively low bend
Intensity is taken, it is more suitable for vehicle exterior cladding element carries out the processing and forming of complicated shape, before general requirement baking
Close to the level of soft IF steel, high intensity and high-ductility are contradiction to performance, so ensureing that cold rolling baking hardening is high
Strong steel has high intensity while it is a big technological difficulties to have excellent deep drawability concurrently.In order to obtain good machinery
Performance, on the one hand, it is base steel (C≤0.0025%) that composition design uses Ultra-low carbon, adding appropriate Nb makes C
Fixed, extremely low phosphorus content be the preferable deep drawability (elongation percentage high and r values) that the steel grade has must
Condition is wanted, while in order to proof strength with the addition of appropriate Mn, P intensified element;On the other hand continuous
Annealing operation uses the quick cooling technique of high annealing, it is ensured that the final combination property of product.
2nd, due to the particular/special requirement of user vehicle, BH steel plates have excellent baking hardenability (abbreviation BH)
While require that there is resistance to room temperature ageing, the mechanism produced by BH understands good BH performances and Nai Chang
Warm hardening is contradiction, so ensureing that the steel grade there is good BH performances to have resistance to room temperature ageing performance concurrently and is
Very big technological difficulties.In order to reach above-mentioned target:1) steel making working procedure carries out Narrow Composition Control, precise control
C content (0.0015%~0.0025%), relatively low and precise control C content ensure that product has stabilization
BH performances and resistance to room temperature ageing;2) composition design with the addition of Mo≤0.05% element on the basis of Ultra-low carbon,
It is equipped with appropriate annealing process, it is ensured that there is product BH higher to have resistance to room temperature ageing concurrently simultaneously.3)
During product design, property indices do the stamping formabilily of product, so as to subtract higher than standard requirement
Few influence of the room temperature ageing to finished product application performance.
Brief description of the drawings
Fig. 1 is 180BH steel finished product organization charts.
Fig. 2 schemes for 180BH steel finished products ODF.
Specific embodiment
In specific implementation process, automobile cold-rolled baking hardening high-strength steel 180BH combinations automobile of the invention is used
Cold rolling baking hardens technical requirements, the actual features of production equipment and each chemical element of high-strength steel in steel
Effect, preparation process is:Conventional molten iron pretreatment → converter smelting → RH refining → continuous castings → continuous annealing.
Continuous annealing process of the invention is as follows:840~860 DEG C of 60~120min of insulation;Furnace cooling to 700~
750 DEG C, and 400 DEG C are quickly cooled to 25~50 DEG C/sec of cooling rate, 1~3h is incubated, then cool to room with the furnace
Temperature.
The chemical composition (mass fraction/%) of automobile cold-rolled baking hardening high-strength steel 180BH is:
C 0.0015~0.0025;Si≤0.05;Mn 0.15~0.30;P 0.030~0.050;S≤0.015;Als 0.02~
0.06;Nb 0.008~0.020;Cr 0.05~0.10;Mo≤0.05;Remaining is Fe.
The performance indications of automobile cold-rolled baking hardening high-strength steel 180BH are:
185~220MPa of yield strength;320~350MPa of tensile strength;Elongation percentage 37~46.5%;n90
Value 0.19~0.25;r90Value 1.62~3.1;BH2Value 30~60.
Automobile cold-rolled baking hardening high-strength steel 180BH of the invention is strong by super deep drawing quality and the solid solution of IF steel
Change mechanism is combined, and the excellent properties that super deep drawing quality and dent resistance high are combined are obtained by baking hardening,
Product is set to ensure good formability because yield strength is low in stamping process, while behind roasting
During paint again can make yield strength raise and obtain dent resistance high, thus successfully solve formability and
Contradiction between dent resistance, with the formability close with IF steel, while there is intensity higher, its composition
According to being:
Carbon (C):Carbon content decides the intensity and other performance of steel in steel, with the increase of phosphorus content in steel,
Yield point and tensile strength are raised, but plasticity and impact reduction.Research in the past shows that solid solution C contains with steel
The increase of amount so that perpendicular to { 111 } orientation texture density reduction of steel plate normal direction, the timeliness problem of steel is obvious.
For the phosphorous high-strength IF steel of Ultra-low carbon, in the case where production and product requirement is met, should drop to greatest extent
Low carbon content, to obtain high-elongation and good punching performance, reduces the volume ratio of carbide in crystal grain, protects
Card steel crystal grain during recrystallization annealing is grown up.
Silicon (Si):Silicon has stronger affinity with oxygen, is reducing agent and deoxidier in steelmaking process, and Si is with solid
Molten form is present in steel, can improve the intensity and hardness of steel.
Manganese (Mn):In steelmaking process, manganese is good deoxidier and desulfurizing agent, manganese part and iron in steel
Dissolve each other to form solid solution, have obvious effect to improving intensity.In ferrite being solid-solution in deep punching steel annealing process
Mn hinder preferential forming core { 111 } be orientated crystal grain growth.There are some researches show in cold-rolling deep-punching plate
With the increase of Mn contents, the intensity of material increases, but plasticity declines,Value is reduced, good in order to obtain
Processability, and with certain intensity, therefore should rationally control manganese content.
Phosphorus (P):Phosphorus is the main intensified element of the automobile cold-rolled high-strength steel that phosphorates, when phosphorus atoms enter iron atom
In lattice, replace to form solid solution with iron atom, because phosphorus is different with the atomic radius of iron, around phosphorus atoms
Produce into elastic deformation and strengthen steel, with the increase of P content, intensity increases, butAnd plasticity index
Reduce, therefore while intensity is improved, to ensure the deep drawability of product, should rationally control phosphorus content.
Sulphur (S):Sulphur is harmful element in steel, the complicated deep-draw of machining deformation is particularly acute with steel, sulfide
Be mingled with (mainly MnS) in the operation of rolling along rolling direction into strips or chainlike distribution so that steel plate
Transverse cold bending performance depreciation, produces anisotropy;In addition, sulphur can also cause the red brittleness of steel plate.Therefore should be most
Limits ground reduces S contents.
Aluminium (Al):Aluminium be usually as deoxidier add steel in, effect mainly removal molten steel in oxygen, separately
Outer aluminium suppresses solid solution of the nitrogen in ferrite as determining nitrogen agent, and aluminium is mainly controlled into the form of the second phase AlN
The tissue of product steel plate and the position of interstitial atom, so as to improve steel plate punched performance, eliminate strain-aging, improve
Cold plasticity simultaneously prevents from producing skid wire in punching course.
Niobium (Nb):Niobium element be mainly by with steel in C-shaped into tiny compound, make the C atoms in steel
Fixed completely and gap-free atom presence, so that favorable texture is first developed in annealing.
Below, by embodiment and accompanying drawing, the present invention is described in more detail.
Embodiment 1
The chemical composition (mass fraction/%) of the present embodiment is as follows:C 0.0019;Si 0.004;Mn 0.196;P
0.040;S 0.008;Als 0.029;Nb 0.012;Cr 0.065;Mo 0.015;Remaining is Fe.
The continuous annealing process of the present embodiment is as follows:850 DEG C of insulation 80min;Furnace cooling to 730 DEG C, and with
30 DEG C/sec of cooling rate is quickly cooled to 400 DEG C, is incubated 2h, then cool to room temperature with the furnace.
The performance indications of the present embodiment are as follows:Yield strength 190MPa;Tensile strength 330MPa;Elongation percentage
42%;n90Value 0.21;r90Value 2.4;BH2Value 55.
Embodiment 2
The chemical composition (mass fraction/%) of the present embodiment is as follows:C 0.0015;Si 0.001;Mn 0.18;P 0.035;
S 0.005;Als 0.02;Nb 0.015;Cr 0.072;Mo 0.026;Remaining is Fe.
Continuous annealing process of the invention is as follows:840 DEG C of insulation 90min;Furnace cooling to 720 DEG C, and with cold
35 DEG C/sec of speed is quickly cooled to 400 DEG C, is incubated 3h, then cool to room temperature with the furnace.
The performance indications of the present embodiment are as follows:Yield strength 205MPa;Tensile strength 325MPa;Elongation percentage
41%;n90Value 0.23;r90Value 1.88;BH2Value 35.
Embodiment 3
The chemical composition (mass fraction/%) of the present embodiment is as follows:C 0.0025;Si 0.012;Mn 0.22;P 0.045;
S 0.012;Als 0.0373;Nb 0.017;Cr 0.089;Mo 0.037;Remaining is Fe.
Continuous annealing process of the invention is as follows:860 DEG C of insulation 70min;Furnace cooling to 740 DEG C, and with cold
40 DEG C/sec of speed is quickly cooled to 400 DEG C, is incubated 2h, then cool to room temperature with the furnace.
The performance indications of the present embodiment are as follows:Yield strength 215MPa;Tensile strength 348MPa;Elongation percentage
45.5%;n90Value 0.24;r90Value 2.94;BH2Value 48.
As shown in figure 1 and table 1, cold rolling baking hardening high-strength steel 180BH finished product tissues are single ferrite,
Grain size is in the range of 8.0~10 grades.
Table 1
The trade mark | Metal structure | F grain sizes (level) |
180BH | F | 8.6 |
As shown in Fig. 2 texture determination is carried out on the X-ray diffractometer of power & light company of U.S. production,
180BH finished product Main Textures are { 111 }<110>Texture and { 111 }<112>Texture.
Application examples
(1) secondary processing brittleness
Secondary processing brittleness is one of defect of IF steel, is also that common IF steel especially to be examined by high-strength IF steel
The problem of worry.This is because multiplex P carries out solution strengthening in high-strength steel IF steel, due to C, N in IF steel
Fixed, crystal boundary cleaning, P has the tendency of cyrystal boundary segregation.In view of second deformation technique, to 180BH into
Product thickness 1.0mm products carry out the brittle transition temperature measurement of secondary processing brittleness, do not occur out at -60 DEG C
Split.
(2) room-temperature aging
The mechanism of production of the baking hardening characteristic of BH steel is due to having a certain amount of solid solution interstitial atom in steel, leading to
Overbaking diffusion couple dislocation carries out effectively pin improves intensity, and a certain amount of solid solution interstitial atom is also to produce
The reason for room temperature ageing, so BH steel is the steel grade very sensitive to timeliness.Current general cold rolling BH steel skill
Under the conditions of art standard requirement room temperature storage, drawing should not occur when being used in 3 months from being completed from production in steel band
Stretching strain trace (ensure 3 months without timeliness), but the longer the better Automobile Plate user time for wishing room temperature ageing.
Cold rolling baking hardened steel carries out timeliness detection, and sample is batched in normal finished product, after placing 1 month~6 months
Carry out performance detection.From result, product totally sees that performance change is not obvious after six months, and explanation has
Good resistance to room temperature ageing performance, it is ensured that normally used in 6 months.
Embodiment result shows that the cold rolling baking hardening high-strength steel 180BH product chemical compositions of present invention production are steady
It is fixed, forming property, excellent BH and resistance to room temperature ageing performance with stabilization.Cold rolling baking hardening is high-strength
The successful development of steel 180BH products creates good economic benefit, and the application of the product is also automobile work
The energy-saving and emission-reduction of industry, reduces cost are made that significant contribution, with huge social benefit.
Claims (3)
1. a kind of automobile 180BH cold rolling bakings harden high-strength steel, it is characterised in that by mass percentage,
Its chemical composition is:
C 0.0015~0.0025;Si≤0.05;Mn 0.15~0.30;P 0.030~0.050;S≤0.015;Als 0.02~
0.06;Nb 0.008~0.020;Cr 0.05~0.10;Mo≤0.05;Remaining is Fe.
2. high-strength steel is hardened according to the 180BH cold rolling bakings of the automobile described in claim 1, it is characterised in that
Its performance indications is:
185~220MPa of yield strength;320~350MPa of tensile strength;Elongation percentage 37~46.5%;n90
Value 0.19~0.25;r90Value 1.62~3.1;BH2Value 30~60.
3. high-strength steel is hardened according to the 180BH cold rolling bakings of the automobile described in claim 1, it is characterised in that
It is as follows using continuous annealing process:840~860 DEG C of 60~120min of insulation;Furnace cooling to 700~750 DEG C,
And 400 DEG C are quickly cooled to 25~50 DEG C/sec of cooling rate, 1~3h is incubated, then cool to room temperature with the furnace.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107400829A (en) * | 2017-08-07 | 2017-11-28 | 攀钢集团攀枝花钢铁研究院有限公司 | A kind of ultra-low carbon baking hardening cold rolled steel sheet and preparation method thereof |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103975082A (en) * | 2011-12-08 | 2014-08-06 | 杰富意钢铁株式会社 | Method for manufacturing high-strength cold-rolled steel sheet having excellent aging resistance and bake hardenability |
CN104593674A (en) * | 2015-01-21 | 2015-05-06 | 首钢总公司 | Hot-dip galvanized ultra-low carbon bake-hardening steel and production method thereof |
-
2015
- 2015-12-23 CN CN201510975819.4A patent/CN106906416A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103975082A (en) * | 2011-12-08 | 2014-08-06 | 杰富意钢铁株式会社 | Method for manufacturing high-strength cold-rolled steel sheet having excellent aging resistance and bake hardenability |
CN104593674A (en) * | 2015-01-21 | 2015-05-06 | 首钢总公司 | Hot-dip galvanized ultra-low carbon bake-hardening steel and production method thereof |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107400829A (en) * | 2017-08-07 | 2017-11-28 | 攀钢集团攀枝花钢铁研究院有限公司 | A kind of ultra-low carbon baking hardening cold rolled steel sheet and preparation method thereof |
CN107400829B (en) * | 2017-08-07 | 2019-02-01 | 攀钢集团攀枝花钢铁研究院有限公司 | A kind of ultra-low carbon baking hardening cold rolled steel sheet and preparation method thereof |
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