CN106905815A - A kind of water-based anticorrosive paint and preparation method thereof - Google Patents
A kind of water-based anticorrosive paint and preparation method thereof Download PDFInfo
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- CN106905815A CN106905815A CN201710111136.3A CN201710111136A CN106905815A CN 106905815 A CN106905815 A CN 106905815A CN 201710111136 A CN201710111136 A CN 201710111136A CN 106905815 A CN106905815 A CN 106905815A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/327—Aluminium phosphate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/328—Phosphates of heavy metals
Abstract
The present invention relates to technical field of coatings, and in particular to a kind of water-based anticorrosive paint and preparation method thereof.It has good antiseptic property, good to metal base adhesive force, and has pollution-free, environmental protection and energy saving.Water-based anticorrosive paint of the present invention is composed of the following raw materials by weight：15 ~ 20 parts of aqueous epoxy resins, 7 ~ 13 parts of deionized water, 0.25 ~ 0.5 part of defoamer, 0.15 ~ 0.2 part of levelling agent, 0.15 ~ 0.3 part of dispersant, 3 ~ 4 parts of aqueous carbon black, 6 ~ 8 parts of superfine talcum powder, 6 ~ 10 parts of barium sulfate, 4 ~ 6 parts of composite zinc phosphate, 1.5 ~ 2 parts of antirust agent, 0.3 ~ 0.5 part of drier, 0.2 ~ 0.3 part of ammoniacal liquor, 0.5 ~ 1 part of triethylamine, 3 ~ 5 parts of butyl glycol ether, 2 ~ 5 parts of aluminium triphosphate is obtained by certain preparation method.
Description
First, technical field：
The present invention relates to technical field of coatings, and in particular to a kind of water-based anticorrosive paint and preparation method thereof.
2nd, background technology：
The present invention relates to a kind of anticorrosive coating, and in particular to a kind of water-based anticorrosive paint.Recently as environment environmental protection
It is required that more and more higher, traditional solvent-borne coating is high because of its fugitive constituent, and air is polluted, and film forming is relatively low, and energy consumption is big, work(
Energy property is poor, it is impossible to meets the ground such as the requirement of environmental protection, Europe and prohibits the use of volatile paint successively.Petrochemical industry,
The fields such as coalfield mining, corrosion-resistant problem is equally protruded, and this is accomplished by a kind of new coating of environmental protection to substitute traditional coating.
Water-based anticorrosive paint, with water-base resin as matrix, water is solvent, and water-based anticorrosive paint shifts to an earlier date before requirement for anticorrosion satisfaction, ring
The aqueous solvent of border friendly causes its non-hazardous gaseous volatilization, more environment-friendly and safer.
3rd, the content of the invention
Of the invention to provide a kind of water-based anticorrosive paint and preparation method thereof, it has good antiseptic property, to metal
Base material adhesive force is good, and has pollution-free, environmental protection and energy saving.
To achieve the above object, the technical solution adopted by the present invention is：A kind of water-based anticorrosive paint, it is characterised in that：Institute
The water-based anticorrosive paint stated is composed of the following raw materials by weight：15~20 parts of aqueous epoxy resins, 7~13 parts of deionized water, disappear
0.25~0.5 part of infusion, 0.15~0.2 part of levelling agent, 0.15~0.3 part of dispersant, 3~4 parts of aqueous carbon black, superfine talcum powder
6~8 parts, 6~10 parts of barium sulfate, 4~6 parts of composite zinc phosphate, 1.5~2 parts of antirust agent, 0.3~0.5 part of drier, ammoniacal liquor 0.2
~0.3 part, 0.5~1 part of triethylamine, 3~5 parts of butyl glycol ether, 2~5 parts of aluminium triphosphate.
Described defoamer is Tego810 defoamers.
Described levelling agent is Tego130 levelling agents.
Described dispersant is Tego760W dispersants.
Described antirust agent is FA179 antirust agent.
Described drier is WY-01 drier.
A kind of preparation method of described water-based anticorrosive paint is：By butyl glycol ether, aqueous carbon black, superfine talcum powder,
Barium sulfate, aluminium triphosphate, composite zinc phosphate, Tego760W dispersants and Tego810 defoamers and aqueous epoxy resins are at a high speed
It is dispersed to uniformly, by scattered liquid horizontal sand mill fineness of grind to 20~30 microns, then by Tego130 levellings
Agent, FA179 antirust agent, WY-01 drier is mixed stirs, and then adjusts liquid pH-value with ammoniacal liquor using triethylamine
7~8, the too high addition ammoniacal liquor of acid number, the too high addition triethylamine regulation of base number is stirred after regulating, and is adjusted using deionized water
Viscosity, using 4 glasss of tested viscosities are applied, the metal after derusting by sandblasting was sprayed on after being then stirred at room temperature uniformly to 40~70 seconds
On workpiece, shelve solidification in 24 hours and dry or 80 DEG C of drying solidification in 2 hours.
Compared with prior art, the invention has the advantages that and effect：
The diluent deionized water that the present invention is added, will not pollute to air；
Water-repellent preservation material in the present invention, performance has and substantially carries in the case of moist, surface of bottom material treatment is halfway
Environmentally friendly nonstaining property fugitive constituent in height, and coating process, and anti-corrosive properties are good.
The present invention is especially suitable as coating metal surfaces with pollution-free water-repellent preservation coating material.
4th, specific embodiment
Technical scheme is further limited with reference to specific embodiment：
Embodiment one：A kind of water-based anticorrosive paint, described water-based anticorrosive paint is composed of the following raw materials by weight：It is aqueous
15 parts of epoxy resin, 7 parts of deionized water, 0.25 part of Tego810 defoamers, 0.15 part of Tego130 levelling agents, Tego760W dispersions
0.15 part of agent, 3 parts of aqueous carbon black, 6 parts of superfine talcum powder, 6 parts of barium sulfate, 4 parts of composite zinc phosphate, 1.5 parts of FA179 antirust agent,
0.3 part of WY-01 drier, 0.2 part of ammoniacal liquor, 0.5 part of triethylamine, 3 parts of butyl glycol ether, 2 parts of aluminium triphosphate.
A kind of preparation method of water-based anticorrosive paint is：By butyl glycol ether, aqueous carbon black, superfine talcum powder, barium sulfate,
Aluminium triphosphate, composite zinc phosphate, Tego760W dispersants and Tego810 defoamers and aqueous epoxy resins are dispersed at a high speed
It is even, then scattered liquid horizontal sand mill fineness of grind to 20~30 microns is prevented Tego130 levelling agents, FA179
Rust agent, WY-01 drier is mixed stirs, and then adjusts liquid pH-value in 7~8, acid using triethylamine and ammoniacal liquor
Be worth too high addition ammoniacal liquor, the too high addition triethylamine regulation of base number is stirred after regulating, using deionized water adjust viscosity to 40~
70 seconds, using 4 glasss of tested viscosities are applied, it is sprayed on the metal works after derusting by sandblasting after being then stirred at room temperature uniformly, is put
Solidification in 24 hours is put to dry or 80 DEG C of drying solidification in 2 hours.
Embodiment two：
A kind of water-based anticorrosive paint, described water-based anticorrosive paint is composed of the following raw materials by weight：Aqueous epoxy resins
18 parts, 10 parts of deionized water, 0.3 part of Tego810 defoamers, 0.15 part of Tego130 levelling agents, 0.3 part of Tego760W dispersants,
4 parts of aqueous carbon black, 7 parts of superfine talcum powder, 8 parts of barium sulfate, 5 parts of composite zinc phosphate, 1.8 parts of FA179 antirust agent, WY-01 urges dry
0.4 part of agent, 0.25 part of ammoniacal liquor, 0.8 part of triethylamine, 4 parts of butyl glycol ether, 4 parts of aluminium triphosphate.
A kind of preparation method of water-based anticorrosive paint is：By butyl glycol ether, aqueous carbon black, superfine talcum powder, barium sulfate,
Aluminium triphosphate, composite zinc phosphate, Tego760W dispersants and Tego810 defoamers and aqueous epoxy resins are dispersed at a high speed
It is even, then scattered liquid horizontal sand mill fineness of grind to 20~30 microns is prevented Tego130 levelling agents, FA179
Rust agent, WY-01 drier is mixed stirs, and then adjusts liquid pH-value in 7~8, acid using triethylamine and ammoniacal liquor
Be worth too high addition ammoniacal liquor, the too high addition triethylamine regulation of base number is stirred after regulating, using deionized water adjust viscosity to 40~
70 seconds, using 4 glasss of tested viscosities are applied, it is sprayed on the metal works after derusting by sandblasting after being then stirred at room temperature uniformly, is put
Solidification in 24 hours is put to dry or 80 DEG C of drying solidification in 2 hours.
Embodiment three：
A kind of water-based anticorrosive paint, described water-based anticorrosive paint is composed of the following raw materials by weight：Aqueous epoxy resins
20 parts, 13 parts of deionized water, 0.5 part of Tego810 defoamers, 0.2 part of Tego130 levelling agents, 0.3 part of Tego760W dispersants,
4 parts of aqueous carbon black, 8 parts of superfine talcum powder, 10 parts of barium sulfate, 6 parts of composite zinc phosphate, 2 parts of FA179 antirust agent, WY-01 drier
0.5 part, 0.3 part of ammoniacal liquor, 1 part of triethylamine, 5 parts of butyl glycol ether, 5 parts of aluminium triphosphate.
A kind of preparation method of water-based anticorrosive paint is：By butyl glycol ether, aqueous carbon black, superfine talcum powder, barium sulfate,
Aluminium triphosphate, composite zinc phosphate, Tego760W dispersants and Tego810 defoamers and aqueous epoxy resins are dispersed at a high speed
It is even, then scattered liquid horizontal sand mill fineness of grind to 20~30 microns is prevented Tego130 levelling agents, FA179
Rust agent, WY-01 drier is mixed stirs, and then adjusts liquid pH-value in 7~8, acid using triethylamine and ammoniacal liquor
Be worth too high addition ammoniacal liquor, the too high addition triethylamine regulation of base number is stirred after regulating, using deionized water adjust viscosity to 40~
70 seconds, using 4 glasss of tested viscosities are applied, it is sprayed on the metal works after derusting by sandblasting after being then stirred at room temperature uniformly, is put
Solidification in 24 hours is put to dry or 80 DEG C of drying solidification in 2 hours.
The performance of the water-based anticorrosive paint that the embodiment of the present invention 2 is produced：
Implementation environment of the invention：Fine day should be selected to construct.5-40 DEG C of environment temperature, relative ambient humidity is below 80%
It is good, application under the conditions of being not suitable for below 3 DEG C ambient humidity more than 80%, the 12 hours planted agents of paint film after application avoid drenching with rain or
Rinsed with water.
First, sample is made according to the formula and preparation method, sample is proportionally allocated preparation and brushes sample；
The detection project sample testing specification of table one
First, model status adjustment
Model after all brushing is placed in carries out status adjustment 24h under the conditions of constant temperature and humidity, impact resistance, bending are real
Test, cross cut test project can be detected, after regulation 168h, water resistance, salt fog resistance, humidity resistance, acid resistance, alkali resistance can
Tested.
2nd, performance test
3.1 impact resistances test uses impact tester and 4 times of magnifying glasses, by the good test plate (panel) of status adjustment as impact test
On device, pull-up impactor weight impacts to form recessed in the metal impact head of weight leading portion after certain altitude, release in coating surface
Groove, with amplifying whether sem observation groove has crackle, if flawless judges qualified, and calculates impulsive force with weight pull-out altitude,
Units of joules.
3.2 resist bending tests, the model that will regulate state is tested on crooked experiment device, when test plate (panel) is with certain condition
After bending, whether observation flexure plane has crackle or breakage, judges whether resistance to bend(ing) can qualified with without damaged, flawless phenomenon,
Angle of bend is set to complete the performance test results when qualified.
3.3 cross cut tests, adhesive force test is carried out by sample model using cross-cut tester, and cross-cut tester selects 1 millimeter of spacing 6
Tooth.Cross-cut tester is held, makes knife perpendicular to specimen surface
By model vertical hanging on sample plate frame, model front is not in contact 3.4 humidity resistances.It is put into and is transferred to temperature in advance
It it is 47 ± 1 DEG C, in the temperature and humidity regulator of relative humidity 96 ± 2%.When temperature, the humidity of regulation is gone back up to, start to calculate examination
Test the time.Condensation should not occur in specimen surface in experiment.Long run test is checked once for 48 hours.It is small every 72 after checking twice
When check once.After checking every time, model should shift one's position.The when number specified by standard carries out last time inspection.During regulation
Between after check coating surface, with non-foaming, do not fall off, non-corrosive, it is criterion of acceptability not ftracture.
3.3 acid resistances, configuration volume fraction is 50g/LH2SO4Solution.The good model of status adjustment is sealed with rosin and applies examination
The position that 5 millimeters of edges of boards edge, in the chemical reagent for regulating test plate (panel) entrance in advance after sealing, and records once a day immersion sample
Whether the outward appearance of plate, checks it is complete coating, if having foaming, have and come off, keep 24h, process deadline with occur foaming,
The defective mode such as come off is foundation.
3.3 acid resistances, configuration volume fraction is 50g/LNaOH solution.The good model of status adjustment is sealed with rosin and applies examination
The position that 5 millimeters of edges of boards edge, in the chemical reagent for regulating test plate (panel) entrance in advance after sealing, and records once a day immersion sample
Whether the outward appearance of plate, checks it is complete coating, if having foaming, have and come off, and keeps 168h, and process deadline is having occurred
It is foundation the defective mode such as to steep, come off.
Claims (7)
1. a kind of water-based anticorrosive paint, it is characterised in that：Described water-based anticorrosive paint is composed of the following raw materials by weight：It is aqueous
15 ~ 20 parts of epoxy resin, 7 ~ 13 parts of deionized water, 0.25 ~ 0.5 part of defoamer, 0.15 ~ 0.2 part of levelling agent, dispersant 0.15 ~
0.3 part, 3 ~ 4 parts of aqueous carbon black, 6 ~ 8 parts of superfine talcum powder, 6 ~ 10 parts of barium sulfate, 4 ~ 6 parts of composite zinc phosphate, antirust agent 1.5 ~ 2
Part, 0.3 ~ 0.5 part of drier, 0.2 ~ 0.3 part of ammoniacal liquor, 0.5 ~ 1 part of triethylamine, 3 ~ 5 parts of butyl glycol ether, aluminium triphosphate 2 ~ 5
Part.
2. a kind of water-based anticorrosive paint according to claim 1, it is characterised in that：Described defoamer disappears for Tego810
Infusion.
3. a kind of water-based anticorrosive paint according to claim 1 and 2, it is characterised in that：Described levelling agent is Tego130
Levelling agent.
4. a kind of water-based anticorrosive paint according to claim 3, it is characterised in that：Described dispersant is Tego760W points
Powder.
5. a kind of water-based anticorrosive paint according to claim 4, it is characterised in that：Described antirust agent is FA179 antirusts
Agent.
6. a kind of water-based anticorrosive paint according to claim 5, it is characterised in that：Described drier is dry for WY-01 is urged
Agent.
7. the preparation method of a kind of water-based anticorrosive paint according to claim 1, it is characterised in that：Preparation method is：Will
Butyl glycol ether, aqueous carbon black, superfine talcum powder, barium sulfate, aluminium triphosphate, composite zinc phosphate, Tego760W dispersants and
Tego810 defoamers are dispersed at a high speed uniformly, by scattered liquid horizontal sand mill fineness of grind with aqueous epoxy resins
To 20 ~ 30 microns, then by Tego130 levelling agents, FA179 antirust agent, WY-01 drier is mixed stirs, then
Liquid pH-value is adjusted 7 ~ 8 using triethylamine and ammoniacal liquor, and the too high addition ammoniacal liquor of acid number, the too high addition triethylamine of base number is adjusted,
Stirred after regulating, viscosity is adjusted to 40 ~ 70 seconds using deionized water, using 4 glasss of tested viscosities are applied, be then stirred at room temperature
It is sprayed on the metal works after derusting by sandblasting after uniform, shelves solidification in 24 hours and dry or 80 DEG C of drying solidification in 2 hours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710111136.3A CN106905815A (en) | 2017-02-28 | 2017-02-28 | A kind of water-based anticorrosive paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710111136.3A CN106905815A (en) | 2017-02-28 | 2017-02-28 | A kind of water-based anticorrosive paint and preparation method thereof |
Publications (1)
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| CN106905815A true CN106905815A (en) | 2017-06-30 |
Family
ID=59208157
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| CN201710111136.3A Pending CN106905815A (en) | 2017-02-28 | 2017-02-28 | A kind of water-based anticorrosive paint and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107418376A (en) * | 2017-07-27 | 2017-12-01 | 芜湖市三山龙城新材料有限公司 | Water-based anticorrosive paint and preparation method thereof |
| CN107446431A (en) * | 2017-08-22 | 2017-12-08 | 南通科星化工有限公司 | A kind of multi-functional antirust agent |
| CN107880719A (en) * | 2017-11-24 | 2018-04-06 | 桂林市和鑫防水装饰材料有限公司 | Water corrosion-resistant epoxy paint |
| CN108084846A (en) * | 2017-12-26 | 2018-05-29 | 肖彬 | Environment protecting water-based paint and preparation method thereof |
| CN108587391A (en) * | 2018-04-03 | 2018-09-28 | 杭州科瑞姆新材料有限公司 | The transparent anticorrosive coating of selfreparing and its self-repair method of a kind of pH induction and preparation method thereof and its application method |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107418376A (en) * | 2017-07-27 | 2017-12-01 | 芜湖市三山龙城新材料有限公司 | Water-based anticorrosive paint and preparation method thereof |
| CN107446431A (en) * | 2017-08-22 | 2017-12-08 | 南通科星化工有限公司 | A kind of multi-functional antirust agent |
| CN107880719A (en) * | 2017-11-24 | 2018-04-06 | 桂林市和鑫防水装饰材料有限公司 | Water corrosion-resistant epoxy paint |
| CN108084846A (en) * | 2017-12-26 | 2018-05-29 | 肖彬 | Environment protecting water-based paint and preparation method thereof |
| CN108084846B (en) * | 2017-12-26 | 2020-07-14 | 厦门辉腾盛科技发展有限公司 | Environment-friendly water-based paint and preparation method thereof |
| CN108587391A (en) * | 2018-04-03 | 2018-09-28 | 杭州科瑞姆新材料有限公司 | The transparent anticorrosive coating of selfreparing and its self-repair method of a kind of pH induction and preparation method thereof and its application method |
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