CN106905671A - A kind of PET water vapour locking is every master batch and preparation method thereof - Google Patents
A kind of PET water vapour locking is every master batch and preparation method thereof Download PDFInfo
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- CN106905671A CN106905671A CN201611201746.4A CN201611201746A CN106905671A CN 106905671 A CN106905671 A CN 106905671A CN 201611201746 A CN201611201746 A CN 201611201746A CN 106905671 A CN106905671 A CN 106905671A
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- master batch
- water vapour
- pet
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- pet water
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/14—Gas barrier composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
Abstract
The present invention relates to modifying plastics field, more particularly to a kind of PET water vapour locking is every master batch and preparation method thereof.Not good in order to solve the problems, such as PET water vapour barrier, the present invention provides a kind of PET water vapour locking every master batch and preparation method thereof.The master batch includes following compositions：Vector resin 46 88%, nanometer inorganic filler 10 50%, dispersant 1 2%, antioxidant 1 2%, the percentage composition is weight percentage；The vector resin is the one kind in PET (polyethylene terephthalate), PE (polyethylene), PP (polypropylene) or PS (polystyrene)；The nanometer inorganic filler is one kind or at least two mixing in nano imvite, nano silicon, mica sheet, Nano titanium nitride；The particle diameter of the nano-particle is 0.2 0.6 μm.Compared with prior art, the PET water vapour locking that the present invention is provided is good with PET compatibility every master batch, and with water vapor barrier property higher；Preparation method process is simple of the PET water vapour locking that the present invention is provided every master batch, it is adaptable to mass produce.
Description
Technical field
The present invention relates to modifying plastics field, more particularly to a kind of PET water vapour locking is every master batch and preparation method thereof.
Background technology
PET (polyethylene terephthalate) has excellent heat resistance, corrosion-resistant, obdurability, electrical insulating property etc., and
It is cheap, thus be used widely in plastic applications such as fiber, film, polyester bottles.PET is a kind of medium barrier material
Material, the barrier to steam and oxygen is poor, limits its application in some special occasions, therefore, exploitation is a kind of efficient
The water and oxygen barrier property for intercepting master batch raising PET has important realistic meaning.
The content of the invention
Not good in order to solve the problems, such as PET water vapour barrier, the present invention provides a kind of PET water vapour locking every master batch and its preparation
Method.The PET water vapour locking that the present invention is provided is good with PET compatibility every master batch, and with water vapor barrier property higher.The present invention is carried
Preparation method process is simple of the PET water vapour locking of confession every master batch, it is adaptable to mass produce.
In order to solve the above-mentioned technical problem, the present invention uses following technical proposals：
The present invention provides a kind of PET water vapour locking every master batch, and the master batch includes following compositions：Vector resin 46-88%, nanometer
Inorganic filler 10-50%, dispersant 1-2%, antioxidant 1-2%, the percentage composition is weight percentage.
The PET water vapour locking is referred to as water vapor rejection master batch every master batch.
Every master batch, no matter whether vector resin selects PET to the PET water vapour locking, and it is all to be specifically applied to improve PET materials
The water vapor barrier property of material.
Further, the PET water vapour locking includes following compositions every master batch：PET 46-88%, nanometer inorganic filler 10-
50%th, dispersant 1-2%, antioxidant 1-2%, the percentage composition are weight percentage.
Further, the vector resin is PET (polyethylene terephthalate), PE (polyethylene), PP (poly- third
Alkene) or PS (polystyrene) in one kind.
Further, the nanometer inorganic filler is nano imvite, nano silicon (SiO2), mica sheet, nanometer
One kind or at least two mixing in titanium nitride (TiN)；The particle diameter of the nano-particle is 0.2-0.6 μm.
Further, the dispersant is Tissuemat E or polypropylene wax.
Further, the antioxidant is the mixture of antioxidant 1010 and irgasfos 168；The antioxidant 1010 with it is anti-
The part by weight of oxygen agent 168 is 1:1.
Further, the dispersant is Tissuemat E, and the antioxidant is the mixing of antioxidant 1010 and irgasfos 168
Thing.
Further, the master batch includes following compositions：PET 46-68%, nanometer inorganic filler 30-50%, dispersant
1-2%, antioxidant 1-2%, the percentage composition are weight percentage.
Further, the master batch includes following compositions：PET 48-66%, nanometer inorganic filler 30-50%, dispersant
1-2%, antioxidant 1-2%, the percentage composition are weight percentage.
Further, the present invention also provides a kind of preparation method of PET water vapour locking every master batch, and the method includes following step
Suddenly：
(1) raw material prepares：Vector resin 46%-88%, nanometer inorganic filler 10%-50%, dispersant 1-2%, antioxygen
Agent 1-2%；
(2) batch mixing：Dispersant, antioxidant are mixed in proportion using high mixer, obtains mixed powder；
(3) extruding pelletization：The mixed powder for being obtained vector resin, nanometer inorganic filler and step (2) using extruder
Mixed by proportioning by Weightlessness balance, extruding pelletization.
Further, in preparation technology, in the step (3), extruder is squeezed from double screw extruder or single screw rod
Go out machine.
Further, extruder screw rotating speed is 280-300 revs/min.Further, extruder screw rotating speed is 280
Rev/min.
Further, extruder temperature is set as 200 DEG C -295 DEG C.Further, extruder temperature be set as 220 DEG C-
275℃。
Compared with prior art, the PET water vapour locking that the present invention is provided is good with PET compatibility every master batch, and with higher
Water vapor barrier property.Preparation method process is simple of the PET water vapour locking that the present invention is provided every master batch, it is adaptable to mass produce.
Specific embodiment
In order to be more readily understood technical scheme and technique effect, with reference to embodiment, the present invention is carried out in detail
Describe in detail bright.
A kind of PET water vapour locking that the present invention is provided is comprised the following steps every the preparation method of master batch：
(1) raw material prepares：Vector resin 46-88%, nanometer inorganic filler 10-50%, dispersant 1-2%, antioxidant 1-
2%；
(2) batch mixing：Dispersant is mixed in proportion with antioxidant using high mixer, obtains mixed powder；
(3) extruding pelletization：The mixed powder for being obtained vector resin, nanometer inorganic filler and step (2) using extruder
Mixed by proportioning by Weightlessness balance, extruding pelletization.Extruder screw rotating speed is 280-300 revs/min, and extruder temperature is set as
200℃-295℃。
The antioxidant used in embodiment is the mixture of antioxidant 1010 and irgasfos 168, wherein, antioxidant 1010 with
The part by weight of irgasfos 168 is 1:1.
0.2-0.6 μm of the particle diameter of nanometer inorganic filler.The pet vector resin used in embodiment gathers for the PET of sinopec
Ester is cut into slices.
Water vapor transmittance produces the type water vapor permeation rate testers of Permatran-W 3/33 and surveys using MOCON companies of the U.S.
Examination.
Tensile strength and elongation at break are tested using tensile testing machine.
Embodiment 1
The present invention provide PET water vapour locking every master batch and preparation method thereof, the PET water vapour locking every master batch include it is following into
Part：Pet vector resin 46%, nano imvite 50%, dispersant 2%, antioxidant 2%.PET water vapour locking is every agglomerate preparation method
It is that, by proportioning automatic blanking, total discharge quantity is 500kg/h by Weightlessness balance, extruder screw rotating speed is 280 revs/min, extrusion
Machine temperature is set as 220 DEG C -275 DEG C, the material strip of extrusion by water-cooled, drying, pelletizing, be packaged to be PET water vapour locking every master batch.
Embodiment 2
The present invention provide PET water vapour locking every master batch and preparation method thereof, the PET water vapour locking every master batch include it is following into
Part：Pet vector resin 48%, nano imvite 50%, dispersant 1%, antioxidant 1%.PET water vapour locking is every agglomerate preparation method
It is that, by proportioning automatic blanking, total discharge quantity is 500kg/h by Weightlessness balance, extruder screw rotating speed is 280 revs/min, extrusion
Machine temperature is set as 220 DEG C -275 DEG C, the material strip of extrusion by water-cooled, drying, pelletizing, be packaged to be PET water vapour locking every master batch.
Embodiment 3
The present invention provide PET water vapour locking every master batch and preparation method thereof, the PET water vapour locking every master batch include it is following into
Part：Pet vector resin 66%, nano imvite 30%, dispersant 2%, antioxidant 2%.PET water vapour locking is every agglomerate preparation method
It is that, by proportioning automatic blanking, total discharge quantity is 500kg/h by Weightlessness balance, extruder screw rotating speed is 280 revs/min, extrusion
Machine temperature is set as 220 DEG C -275 DEG C, the material strip of extrusion by water-cooled, drying, pelletizing, be packaged to be PET water vapour locking every master batch.
Embodiment 4
The present invention provide PET water vapour locking every master batch and preparation method thereof, the PET water vapour locking every master batch include it is following into
Part：Pet vector resin 68%, nano imvite 30%, dispersant 1%, antioxidant 1%.PET water vapour locking is every agglomerate preparation method
It is that, by proportioning automatic blanking, total discharge quantity is 500kg/h by Weightlessness balance, extruder screw rotating speed is 280 revs/min, extrusion
Machine temperature is set as 220 DEG C -275 DEG C, the material strip of extrusion by water-cooled, drying, pelletizing, be packaged to be PET water vapour locking every master batch.
Embodiment 5
The present invention provide PET water vapour locking every master batch and preparation method thereof, the PET water vapour locking every master batch include it is following into
Part：Pet vector resin 88%, nano imvite 10%, dispersant 1%, antioxidant 1%.PET water vapour locking is every agglomerate preparation method
It is that, by proportioning automatic blanking, total discharge quantity is 500kg/h by Weightlessness balance, extruder screw rotating speed is 280 revs/min, extrusion
Machine temperature is set as 220 DEG C -275 DEG C, the material strip of extrusion by water-cooled, drying, pelletizing, be packaged to be PET water vapour locking every master batch.
Embodiment 6
The present invention provide PET water vapour locking every master batch and preparation method thereof, the PET water vapour locking every master batch include it is following into
Part：Pet vector resin 46%, nano mica piece 50%, dispersant 2%, antioxidant 2%.PET water vapour locking is every agglomerate preparation method
It is that, by proportioning automatic blanking, total discharge quantity is 500kg/h by Weightlessness balance, extruder screw rotating speed is 280 revs/min, extrusion
Machine temperature is set as 220 DEG C -275 DEG C, the material strip of extrusion by water-cooled, drying, pelletizing, be packaged to be PET water vapour locking every master batch.
Embodiment 7
The present invention provide PET water vapour locking every master batch and preparation method thereof, the PET water vapour locking every master batch include it is following into
Part：Pet vector resin 46%, nano TiN 50%, dispersant 2%, antioxidant 2%.PET water vapour locking is every agglomerate preparation method
By Weightlessness balance by proportioning automatic blanking, total discharge quantity is 500kg/h, and extruder screw rotating speed is 280 revs/min, extruder
Temperature is set as 220 DEG C -275 DEG C, the material strip of extrusion by water-cooled, drying, pelletizing, be packaged to be PET water vapour locking every master batch..
Embodiment 8
The present invention provide PET water vapour locking every master batch and preparation method thereof, the PET water vapour locking every master batch include it is following into
Part：Pet vector resin 46%, Nano-meter SiO_2250%th, dispersant 2%, antioxidant 2%.PET water vapour locking is every agglomerate preparation method
By Weightlessness balance by proportioning automatic blanking, total discharge quantity is 500kg/h, and extruder screw rotating speed is 280 revs/min, extruder
Temperature is set as 220 DEG C -275 DEG C, the material strip of extrusion by water-cooled, drying, pelletizing, be packaged to be PET water vapour locking every master batch.
Embodiment 9
The present invention provide PET water vapour locking every master batch and preparation method thereof, the PET water vapour locking every master batch include it is following into
Part：PP vector resins 46%, nano imvite 50%, dispersant 2%, antioxidant 2%.PET water vapour locking is every agglomerate preparation method
It is that, by proportioning automatic blanking, total discharge quantity is 500kg/h by Weightlessness balance, extruder screw rotating speed is 280 revs/min, extrusion
Machine temperature is set as 220 DEG C -275 DEG C, the material strip of extrusion by water-cooled, drying, pelletizing, be packaged to be PET water vapour locking every master batch.
Embodiment 10
The present invention provide PET water vapour locking every master batch and preparation method thereof, the PET water vapour locking every master batch include it is following into
Part：PS vector resins 56%, nano imvite 40%, dispersant 2%, antioxidant 2%.PET water vapour locking is every agglomerate preparation method
It is that, by proportioning automatic blanking, total discharge quantity is 500kg/h by Weightlessness balance, extruder screw rotating speed is 280 revs/min, extrusion
Machine temperature is set as 220 DEG C -275 DEG C, the material strip of extrusion by water-cooled, drying, pelletizing, be packaged to be PET water vapour locking every master batch.
Embodiment 11
The present invention provide PET water vapour locking every master batch and preparation method thereof, the PET water vapour locking every master batch include it is following into
Part：PE vector resins 68%, nano imvite 30%, dispersant 1%, antioxidant 1%.PET water vapour locking is every agglomerate preparation method
It is that, by proportioning automatic blanking, total discharge quantity is 500kg/h by Weightlessness balance, extruder screw rotating speed is 280 revs/min, extrusion
Machine temperature is set as 220 DEG C -275 DEG C, the material strip of extrusion by water-cooled, drying, pelletizing, be packaged to be PET water vapour locking every master batch.
Comparative example
100% pure PET.
With PET water vapour locking obtained in embodiment and comparative example every master batch and PET polyester as primary raw material, using identical
Formula and identical technique prepare polyester film.
PET water vapour locking obtained in embodiment and comparative example is together added every master batch 6% and PET polyester slices 94% and is squeezed
Go out machine, extrude slab.Polyester film is obtained by stretch processes, the water vapor transmittance of testing film, tensile strength and disconnected
Split elongation.The water vapor transmittance numerical value of film is lower, represents that PET water vapour locking is stronger every the obstructing capacity of master batch.The drawing of film
Stretch that intensity is higher, represent that PET intercepts master batch smaller for the influence of the performance degradation of film.
The PET water vapour locking of table 1 is constituted and the prepared therefrom pair of the performance test results of drawing film every the composition of master batch
Data as shown in above-mentioned table 1 can draw, be produced every master batch using the PET water vapour locking prepared by the present invention
Double drawing polyester film water vapor transmittances are low, and preferably, combination property is preferable for barrier, the PET water vapour locking that wherein embodiment 1-4 is provided
More preferably, more preferably, the PET water vapour locking that wherein embodiment 2-3 is provided is every master batch for combination property for the barrier of the film prepared every master batch
Preferably, combination property is best for the barrier of the film of preparation.
The above, only presently preferred embodiments of the present invention is not intended to limit the scope of the present invention.It is every
The impartial change done according to present invention and modification, are encompassed by the scope of the claims of the invention.
Claims (10)
1. a kind of PET water vapour locking is every master batch, it is characterised in that the master batch includes following compositions：Vector resin 46-88%, receives
Rice inorganic filler 10-50%, dispersant 1-2%, antioxidant 1-2%, the percentage composition are weight percentage.
2. PET water vapour locking according to claim 1 is every master batch, it is characterised in that the PET water vapour locking is under master batch includes
State composition：PET 46-88%, nanometer inorganic filler 10-50%, dispersant 1-2%, antioxidant 1-2%, the percentage composition is
Weight percentage.
3. PET water vapour locking according to claim 1 is every master batch, it is characterised in that the vector resin is PET (poly- to benzene
Naphthalate), PE (polyethylene), the one kind in PP (polypropylene) or PS (polystyrene).
4. PET water vapour locking according to claim 1 is every master batch, it is characterised in that the nanometer inorganic filler is covered for nanometer
One kind or at least two mixing in de- soil, nano silicon, mica sheet, Nano titanium nitride；The grain of the nano-particle
Footpath is 0.2-0.6 μm.
5. PET water vapour locking according to claim 1 is every master batch, it is characterised in that the dispersant is Tissuemat E or poly-
Propylene wax.
6. PET water vapour locking according to claim 1 is every master batch, it is characterised in that the antioxidant be antioxidant 1010 with
The mixture of irgasfos 168；The antioxidant 1010 is 1 with the part by weight of irgasfos 168:1.
7. PET water vapour locking according to claim 1 is every master batch, it is characterised in that the dispersant is Tissuemat E, described
Antioxidant is the mixture of antioxidant 1010 and irgasfos 168.
8. PET water vapour locking according to claim 2 is every master batch, it is characterised in that the master batch includes following compositions：PET
46-68%, nanometer inorganic filler 30-50%, dispersant 1-2%, antioxidant 1-2%, the percentage composition contain for weight percent
Amount.
9. PET water vapour locking according to claim 2 is every master batch, it is characterised in that the master batch includes following compositions：PET
48-66%, nanometer inorganic filler 30-50%, dispersant 1-2%, antioxidant 1-2%, the percentage composition contain for weight percent
Amount.
10. every the preparation method of master batch, its feature exists the PET water vapour locking described in a kind of claim 1-9 any one claims
In the described method comprises the following steps：
(1) raw material prepares：Vector resin 46%-88%, nanometer inorganic filler 10%-50%, dispersant 1-2%, antioxidant 1-
2%；
(2) batch mixing：Dispersant, antioxidant are mixed in proportion using high mixer, obtains mixed powder；
(3) extruding pelletization：The mixed powder that vector resin, nanometer inorganic filler and step (2) are obtained is passed through using extruder
Weightlessness balance is mixed by proportioning, extruding pelletization.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611201746.4A CN106905671A (en) | 2016-12-23 | 2016-12-23 | A kind of PET water vapour locking is every master batch and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611201746.4A CN106905671A (en) | 2016-12-23 | 2016-12-23 | A kind of PET water vapour locking is every master batch and preparation method thereof |
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| CN106905671A true CN106905671A (en) | 2017-06-30 |
Family
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| CN201611201746.4A Pending CN106905671A (en) | 2016-12-23 | 2016-12-23 | A kind of PET water vapour locking is every master batch and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107400286A (en) * | 2017-09-08 | 2017-11-28 | 四川汇利实业有限公司 | The PE materials and its preparation technology of a kind of high barrier |
| CN110283446A (en) * | 2019-05-25 | 2019-09-27 | 招商局重工（江苏）有限公司 | The inner lining material and preparation method thereof of nonmetal flexible multiple tube |
| CN110982233A (en) * | 2019-12-27 | 2020-04-10 | 福州大学 | High-barrier RGO-SiO2PET protective film and preparation method thereof |
| CN111019305A (en) * | 2019-12-27 | 2020-04-17 | 福州大学 | High-barrier modified ZnO/PET (zinc oxide/polyethylene terephthalate) protective film and preparation method thereof |
| CN113306247A (en) * | 2021-07-29 | 2021-08-27 | 四川省维奇新材料股份有限公司 | Nano multilayer water-oxygen barrier film and preparation method and application thereof |
| CN116218163A (en) * | 2023-03-16 | 2023-06-06 | 富岭科技股份有限公司 | Barrier PET and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101260196A (en) * | 2008-04-07 | 2008-09-10 | 常州绝缘材料总厂有限公司 | White polyester solar energy battery back film and preparation method thereof |
| CN104672816A (en) * | 2013-12-03 | 2015-06-03 | 青岛佳亿阳工贸有限公司 | Toughened and strengthened antistatic smooth PET material with core-shell structure |
-
2016
- 2016-12-23 CN CN201611201746.4A patent/CN106905671A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101260196A (en) * | 2008-04-07 | 2008-09-10 | 常州绝缘材料总厂有限公司 | White polyester solar energy battery back film and preparation method thereof |
| CN104672816A (en) * | 2013-12-03 | 2015-06-03 | 青岛佳亿阳工贸有限公司 | Toughened and strengthened antistatic smooth PET material with core-shell structure |
Non-Patent Citations (1)
| Title |
|---|
| 王玉国: "高阻隔性PET纳米复合材料的研究进展", 《中国化学会第26届学术年会应用化学分会场论文集》 * |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107400286A (en) * | 2017-09-08 | 2017-11-28 | 四川汇利实业有限公司 | The PE materials and its preparation technology of a kind of high barrier |
| CN110283446A (en) * | 2019-05-25 | 2019-09-27 | 招商局重工（江苏）有限公司 | The inner lining material and preparation method thereof of nonmetal flexible multiple tube |
| CN110982233A (en) * | 2019-12-27 | 2020-04-10 | 福州大学 | High-barrier RGO-SiO2PET protective film and preparation method thereof |
| CN111019305A (en) * | 2019-12-27 | 2020-04-17 | 福州大学 | High-barrier modified ZnO/PET (zinc oxide/polyethylene terephthalate) protective film and preparation method thereof |
| CN111019305B (en) * | 2019-12-27 | 2021-06-29 | 福州大学 | High-barrier modified ZnO/PET (zinc oxide/polyethylene terephthalate) protective film and preparation method thereof |
| CN110982233B (en) * | 2019-12-27 | 2021-11-26 | 福州大学 | High-barrier RGO-SiO2PET protective film and preparation method thereof |
| CN113306247A (en) * | 2021-07-29 | 2021-08-27 | 四川省维奇新材料股份有限公司 | Nano multilayer water-oxygen barrier film and preparation method and application thereof |
| CN116218163A (en) * | 2023-03-16 | 2023-06-06 | 富岭科技股份有限公司 | Barrier PET and preparation method thereof |
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Application publication date: 20170630 |