CN106905666A - Plastic composition and fiber master batch - Google Patents
Plastic composition and fiber master batch Download PDFInfo
- Publication number
- CN106905666A CN106905666A CN201511017259.8A CN201511017259A CN106905666A CN 106905666 A CN106905666 A CN 106905666A CN 201511017259 A CN201511017259 A CN 201511017259A CN 106905666 A CN106905666 A CN 106905666A
- Authority
- CN
- China
- Prior art keywords
- substituted
- carbon atom
- plastic composition
- unsubstituted
- ionic liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 114
- 229920003023 plastic Polymers 0.000 title claims abstract description 87
- 239000004033 plastic Substances 0.000 title claims abstract description 87
- 239000004594 Masterbatch (MB) Substances 0.000 title claims abstract description 85
- 239000000203 mixture Substances 0.000 title claims abstract description 50
- 239000002608 ionic liquid Substances 0.000 claims abstract description 70
- 229910052799 carbon Inorganic materials 0.000 claims description 43
- 150000001721 carbon Chemical group 0.000 claims description 37
- 239000002033 PVDF binder Substances 0.000 claims description 20
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 20
- 125000003118 aryl group Chemical group 0.000 claims description 16
- 125000001118 alkylidene group Chemical group 0.000 claims description 15
- 239000002105 nanoparticle Substances 0.000 claims description 14
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 13
- 239000004332 silver Substances 0.000 claims description 13
- 229910052709 silver Inorganic materials 0.000 claims description 13
- 229910018828 PO3H2 Inorganic materials 0.000 claims description 12
- -1 aldehyde radical Chemical class 0.000 claims description 12
- 125000003342 alkenyl group Chemical group 0.000 claims description 12
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- 150000001450 anions Chemical class 0.000 claims description 12
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 7
- 229910017048 AsF6 Inorganic materials 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- 229910014332 N(SO2CF3)2 Inorganic materials 0.000 claims description 6
- 150000004678 hydrides Chemical class 0.000 claims description 6
- 125000003545 alkoxy group Chemical group 0.000 claims description 5
- 125000000304 alkynyl group Chemical group 0.000 claims description 5
- 125000004185 ester group Chemical group 0.000 claims description 5
- 125000001072 heteroaryl group Chemical group 0.000 claims description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 5
- 125000000468 ketone group Chemical group 0.000 claims description 5
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 5
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 claims description 5
- 125000003375 sulfoxide group Chemical group 0.000 claims description 5
- 125000003396 thiol group Chemical class [H]S* 0.000 claims description 5
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 3
- 229910006069 SO3H Inorganic materials 0.000 claims description 3
- 150000001336 alkenes Chemical class 0.000 claims description 3
- 229910001914 chlorine tetroxide Inorganic materials 0.000 claims description 3
- 125000005843 halogen group Chemical group 0.000 claims description 3
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Chemical compound [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 claims description 3
- 125000001424 substituent group Chemical group 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 150000003949 imides Chemical class 0.000 claims description 2
- 229920000570 polyether Polymers 0.000 claims description 2
- 238000006884 silylation reaction Methods 0.000 claims description 2
- 150000001735 carboxylic acids Chemical class 0.000 claims 1
- 230000009477 glass transition Effects 0.000 abstract description 14
- 230000000052 comparative effect Effects 0.000 description 32
- 230000003068 static effect Effects 0.000 description 20
- 238000012545 processing Methods 0.000 description 18
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 16
- 239000004697 Polyetherimide Substances 0.000 description 16
- 229920001601 polyetherimide Polymers 0.000 description 16
- 238000012360 testing method Methods 0.000 description 16
- 238000000034 method Methods 0.000 description 13
- 229920000139 polyethylene terephthalate Polymers 0.000 description 12
- 239000005020 polyethylene terephthalate Substances 0.000 description 12
- 238000004519 manufacturing process Methods 0.000 description 11
- 239000011521 glass Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 6
- 239000006057 Non-nutritive feed additive Substances 0.000 description 5
- 229920006351 engineering plastic Polymers 0.000 description 5
- 238000004898 kneading Methods 0.000 description 5
- 238000009987 spinning Methods 0.000 description 5
- 238000004227 thermal cracking Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- JCXJVPUVTGWSNB-UHFFFAOYSA-N Nitrogen dioxide Chemical compound O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 3
- 239000004696 Poly ether ether ketone Substances 0.000 description 3
- 239000004952 Polyamide Substances 0.000 description 3
- 229920002873 Polyethylenimine Polymers 0.000 description 3
- 239000004734 Polyphenylene sulfide Substances 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 235000013339 cereals Nutrition 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 229920002647 polyamide Polymers 0.000 description 3
- 229920002530 polyetherether ketone Polymers 0.000 description 3
- 229920000069 polyphenylene sulfide Polymers 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 229910001961 silver nitrate Inorganic materials 0.000 description 3
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 2
- 229920006370 Kynar Polymers 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 229920004738 ULTEM® Polymers 0.000 description 2
- 125000003172 aldehyde group Chemical group 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 125000001033 ether group Chemical group 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 125000001145 hydrido group Chemical group *[H] 0.000 description 2
- 238000002074 melt spinning Methods 0.000 description 2
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 2
- 229920002312 polyamide-imide Polymers 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 2
- 239000001509 sodium citrate Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000002411 thermogravimetry Methods 0.000 description 2
- WFLOTYSKFUPZQB-OWOJBTEDSA-N (e)-1,2-difluoroethene Chemical compound F\C=C\F WFLOTYSKFUPZQB-OWOJBTEDSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000004425 Makrolon Substances 0.000 description 1
- 240000002853 Nelumbo nucifera Species 0.000 description 1
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 1
- 235000006510 Nelumbo pentapetala Nutrition 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 241001494479 Pecora Species 0.000 description 1
- 239000004962 Polyamide-imide Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- ZSDJVGXBJDDOCD-UHFFFAOYSA-N benzene dioctyl benzene-1,2-dicarboxylate Chemical compound C(C=1C(C(=O)OCCCCCCCC)=CC=CC1)(=O)OCCCCCCCC.C1=CC=CC=C1 ZSDJVGXBJDDOCD-UHFFFAOYSA-N 0.000 description 1
- JUPQTSLXMOCDHR-UHFFFAOYSA-N benzene-1,4-diol;bis(4-fluorophenyl)methanone Chemical compound OC1=CC=C(O)C=C1.C1=CC(F)=CC=C1C(=O)C1=CC=C(F)C=C1 JUPQTSLXMOCDHR-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- 238000010130 dispersion processing Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000012994 photoredox catalyst Substances 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/41—Compounds containing sulfur bound to oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
- C08K5/19—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3442—Heterocyclic compounds having nitrogen in the ring having two nitrogen atoms in the ring
- C08K5/3445—Five-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0806—Silver
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention provides a plastic composition and a fiber master batch. The plastic composition comprises plastic and ionic liquid, wherein the content of the ionic liquid is 0.5 wt% to 20 wt% based on the total weight of the plastic. The fiber master batch is prepared by using the plastic composition. The plastic composition provided by the invention has low glass transition temperature, high melt index and electrostatic dissipation property, so that the plastic composition has good processability, fluidity and applicability, and is suitable for preparing fiber master batches.
Description
Technical field
The present invention relates to a kind of plastic composition and fiber master batch, more particularly to one kind is with the transfer of low glass
The plastic composition and fiber master batch of temperature and high fusion index.
Background technology
Due to the properties such as excellent heat resistance, chemical-resistant, anti-flammability, makrolon
(polycarbonate, PC), polyphenylene sulfide (polyphenylene sulfide, PPS), polyether-ether-ketone
(polyether ether ketone, PEEK), polyamide (polyamide, PA), polyamide acyl are sub-
It is amine (polyamide imide, PAI), PEI (polyetherimide, PEI), poly- to benzene
Dioctyl phthalate second diester (polyethylene terephthalate, PET), Kynoar (polyvinylidene
Fluoride, PVDF) etc. be referred to as " engineering plastics (engineering plastic) " thermoplastic resin
It is widely used in various fields.
However, engineering plastics have still been limited using upper, for example：The processing temperature of PEI
Spend at a relatively high (between 350~380 DEG C), this is not easy to reach for general board；And it is poly- inclined
When PVF carries out high-temperature molding, there is strong corrosion up to easily producing if more than 320 DEG C if processing temperature
The hydrofluoric acid of property.Therefore, the application for how lifting engineering plastics is still the important class actively studied at present
Topic.
The content of the invention
The present invention provides a kind of plastic composition and fiber master batch, and there is plastic composition low glass to shift
Temperature, melt index high and static dissipative, thus with good processability, mobility and application
Property, and suitable for making fiber master batch.
Plastic composition of the invention includes plastics and ionic liquid, wherein with the gross weight meter of plastics,
The content of ionic liquid is 0.5wt% to 20wt%.
In one embodiment of the present invention, above-mentioned plastics include PEI (polyetherimide,
PEI), PET (polyethylene terephthalate, PET) or poly- inclined difluoro
Ethene (polyvinylidene fluoride, PVDF).
In one embodiment of the present invention, above-mentioned ionic liquid includes at least in formula (a) to formula (q)
Structure shown in individual：
Wherein, R1And R2It is independently of one another-CxHySO3 -、-CxHyPO3H-、-(CxHy)(PO3H2)PO3H-、-CxHyCOO-、-CxHySO3H、-CxHyPO3H2、-(CxHy)(PO3H2)PO3H2Or-CxHyCOOH,
Wherein x is that 1 to 6, y is 2 to 12, and R3To R9Be independently of one another hydride base (hydrido),
Be substituted or be unsubstituted with 1 to 6 alkyl of carbon atom (alkyl), be substituted or without taking
Generation with 1 to 6 alkenyl of carbon atom (alkenyl), be substituted or be unsubstituted with 6 to
30 aryl of carbon atom (aryl), be substituted or be unsubstituted with 3 to 30 rings of carbon atom
Alkyl (cycloalkyl) ,-(Z1)-O-(Z2)-OH, wherein Z1And Z2Independently of one another for be substituted or without
Substitution with 1 to 6 alkylidene of carbon atom (alkylene) or-(Z3)-O-Z4, wherein Z3For
Be substituted or be unsubstituted with 1 to 6 alkylidene of carbon atom, Z4To be substituted or being unsubstituted
With 1 to 6 alkyl of carbon atom；Or
R1To R9Independently of one another for hydride base, be substituted or be unsubstituted with 1 to 6 carbon atom
Alkyl, be substituted or be unsubstituted with 1 to 6 alkenyl of carbon atom, be substituted or without taking
Generation with 6 to 30 aryl of carbon atom, be substituted or be unsubstituted with 3 to 30 carbon originals
Cycloalkyl, the-(Z of son1)-O-(Z2)-OH, wherein Z1And Z2It is substituted or is unsubstituted independently of one another
With 1 to 6 alkylidene or-(Z of carbon atom3)-O-Z4, wherein Z3And Z4It is independently of one another through taking
Generation or be unsubstituted with 1 to 6 alkylidene of carbon atom, wherein the alkyl being substituted, alkene
Base, aryl, cycloalkyl, alkylidene are replaced through substituents：Alkoxy (alkoxy), alkene
Base (alkenyl), alkynyl (alkynyl), aryl (aryl), heteroaryl (heteroaryl), aldehyde radical
(aldehyde group), amino (amino), ester group (ester group), ether (ether group),
Halogen atom, hydroxyl (hydroxyl), ketone group (ketone group), nitro (nitro), silane
Base (silyl), sulfonyl (sulfonyl), sulfoxide group (sulfoxide group), sulfate radical (sulfate)
Or mercapto (thiol group).
In one embodiment of the present invention, above-mentioned ionic liquid includes anion, the anion bag
Include F-、Cl-、Br-、I-、ClO4 -、SCN-、OCN-、BF4 -、PF6 -、AsF6 -、SbF6 -、
NO3 -、NO2 -、N(SO2CF3)2 -、SO4 2-、HSO4 -、PO4 3-、HPO4 2-、H2PO4 -、CF3CO2 -、CO3 2-, citrate or with 2 to 7 carboxylate radicals of carbon atom.
In one embodiment of the present invention, above-mentioned ionic liquid be fluoride ion liquid, and it is described from
Sub- liquid includes anion, and the anion includes BF4 -、PF6 -、AsF6 -、SbF6 -、N(SO2CF3)2 -Or CF3CO2 -。
In one embodiment of the present invention, above-mentioned ionic liquid includes the knot shown in formula (1) or formula (2)
Structure：
In one embodiment of the present invention, above-mentioned plastic composition also includes silver nano-particle, wherein
With the gross weight meter of plastic composition, the content of silver nano-particle is 9000ppm to 11000ppm.
Fiber master batch of the invention is used made by foregoing plastic composition.
Based on above-mentioned, plastic composition of the invention by including in the range of plastics and certain content from
Sub- liquid and there is low glass transition temperature, melt index high and static dissipative, and thus possess
Good processability, mobility and application.
It is that features described above of the invention and advantage can be become apparent, implementation method cited below particularly is made detailed
It is described as follows.
Specific embodiment
Herein, the scope for being represented by " numerical value to another numerical value ", is that one kind is avoided in specification
In enumerate the summary representation of all numerical value in the scope.Therefore, a certain special value model
The record enclosed, covers any number in the number range and by any number circle in the number range
The relatively fractional value scope made, as write out any number in plain text in the description and being somebody's turn to do compared with fractional value model
Enclose the same.
Herein, the structure of polymer or group is represented with key wire type (skeleton formula) sometimes.
This representation can omit carbon atom, hydrogen atom and C-H bond.Certainly, have in structural formula and clearly show
Go out atom or atomic radical, then by being defined for showing.
Constituted in order to prepare with good workability and application and suitable for making the plastics of fiber master batch
Thing, the present invention proposes a kind of plastic composition, and it can reach above-mentioned advantage.Hereinafter, especially exemplified by implementation method
As the example that the present invention can actually be implemented according to this.
The plastic composition that one embodiment of the present invention is proposed includes plastics and ionic liquid, wherein with
The gross weight meter of plastics, the content of ionic liquid is 0.5wt% to 20wt%, preferably 0.5wt% to 5
Wt%.
In the present embodiment, plastics are, for example, engineering plastics.Specifically, plastics for example include polyethers
Acid imide (polyetherimide, PEI), PET (polyethylene terephthalate,
) or polyvinylidene fluoride (polyvinylidene fluoride, PVDF) PET.
In the present embodiment, ionic liquid may include formula (a) to the shown knot of at least one of formula (q)
Structure：
Specifically, in above-mentioned formula (a) to the structure shown in formula (q), R1And R2Can be independently of one another
-CxHySO3 -、-CxHyPO3H-、-(CxHy)(PO3H2)PO3H-、-CxHyCOO-、-CxHySO3H、
-CxHyPO3H2、-(CxHy)(PO3H2)PO3H2Or-CxHyCOOH, wherein x are 2 for 1 to 6, y
To 12, and R3To R9Can be independently of one another hydride base (hydrido), be substituted or be unsubstituted
With 1 to 6 alkyl of carbon atom (alkyl), be substituted or be unsubstituted with 1 to 6
The alkenyl (alkenyl) of carbon atom, be substituted or be unsubstituted with 6 to 30 aryl of carbon atom
(aryl), be substituted or be unsubstituted with 3 to 30 cycloalkyl of carbon atom (cycloalkyl),
-(Z1)-O-(Z2)-OH, wherein Z1And Z2Can be independently of one another to be substituted or be unsubstituted with 1 to 6
The alkylidene (alkylene) of individual carbon atom or-(Z3)-O-Z4, wherein Z3Can be to be substituted or without taking
Generation with 1 to 6 alkylidene of carbon atom, Z4Can be to be substituted or be unsubstituted with 1 to 6
The alkyl of individual carbon atom；Or R1To R9Can be independently of one another hydride base, be substituted or without taking
Generation with 1 to 6 alkyl of carbon atom, be substituted or be unsubstituted with 1 to 6 carbon atom
Alkenyl, be substituted or be unsubstituted with 6 to 30 aryl of carbon atom, be substituted or without taking
Generation with 3 to 30 cycloalkyl of carbon atom ,-(Z1)-O-(Z2)-OH, wherein Z1And Z2Can be each other
Stand alone as be substituted or be unsubstituted with 1 to 6 alkylidene or-(Z of carbon atom3)-O-Z4, its
Middle Z3And Z4Can be independently of one another to be substituted or be unsubstituted with 1 to 6 alkylidene of carbon atom,
The wherein described alkyl being substituted, alkenyl, aryl, cycloalkyl, alkylidene are taken through substituents
Generation：Alkoxy (alkoxy), alkenyl (alkenyl), alkynyl (alkynyl), aryl (aryl),
Heteroaryl (heteroaryl), aldehyde radical (aldehyde group), amino (amino), ester group (ester
Group), ether (ether group), halogen atom, hydroxyl (hydroxyl), ketone group (ketone group),
Nitro (nitro), silylation (silyl), sulfonyl (sulfonyl), sulfoxide group (sulfoxide group),
Sulfate radical (sulfate) or mercapto (thiol group).
That is, structure of the above-mentioned formula (a) shown in formula (q) can have simultaneously respectively the part of positively charged with
And electronegative alkane sulfonate groups, or the respectively cation of positively charged.
Furthermore, in the present embodiment, when ionic liquid includes belonging to the cation of positively charged
During at least one of structure shown in formula (a) to formula (q), then ionic liquid also includes anion.Namely
Say, now, ionic liquid is made up of cation and anion.
Specifically, in one embodiment, the anion includes F-、Cl-、Br-、I-、ClO4 -、SCN-、OCN-、BF4 -、PF6 -、AsF6 -、SbF6 -、NO3 -、NO2 -、N(SO2CF3)2 -、
SO4 2-、HSO4 -、PO4 3-、HPO4 2-、H2PO4 -、CF3CO2 -、CO3 2-, citrate or tool
There are 2 to 7 carboxylate radicals of carbon atom.In another embodiment, the anion includes BF4 -、PF6 -、AsF6 -、SbF6 -、N(SO2CF3)2 -Or CF3CO2 -, and now, ionic liquid for it is fluorine-containing from
Sub- liquid.
Hold above-mentioned, in one embodiment, ionic liquid includes the structure shown in formula (1) or formula (2)：
In addition, in the present embodiment, ionic liquid can be single kind of ionic liquid or be more than two kinds
Ionic liquid mixture.
In addition, in the present embodiment, just the processability of lifting plastic composition and the viewpoint of mobility and
Speech, plastic composition can also include silver nano-particle, wherein with the gross weight meter of plastic composition, Yin Na
The content of rice particulate is 9000ppm to 11000ppm, preferably 9500ppm to 10500ppm.Separately
Outward, silver nano-particle can be used any method in art well known to those of ordinary skill to make
It is standby.
What deserves to be explained is, in the present embodiment, plastic composition is by including plastics and specific containing
Ionic liquid in the range of amount and there is low glass transition temperature and melt index high, be primarily due to
Ionic liquid has the characteristic of highly polar solvent, therefore, after ionic liquid is mixed with plastics, can drop
The interaction force of low molecule interchain, so reduce plastics strand degree of alignment and it is intermolecular mutually
Active force, so as to increase the machine-shaping temperature range of plastics.In addition, in the present embodiment, plastics
Constituent has static dissipative again by including the ionic liquid in the range of plastics and certain content
Property.Consequently, it is possible to the plastic composition of present embodiment possesses good processability, mobility and application
Property.It can be seen from description above, in the present embodiment, ionic liquid is to act as processing aid.
In addition, in the present embodiment, ionic liquid will not occur under the processing temperature of plastics cracking and
Volatilization.That is, in plastic composition, the species of the visual plastics used of species of ionic liquid
Adjusted with the application of plastic composition.
Further, since plastic composition has above-mentioned advantage, it can have many purposes and be applied to various
Field.For example, plastic composition can be molded processing procedure by being molded, being extruded or be blow molded etc.
And prepare film, film, coating, film or moulded parts；Or plastic composition can be used as spinning processing procedure
In raw material and prepare fiber.Hereinafter, the raw material in using plastic composition as spinning processing procedure are
Example is illustrated.
The fiber master batch that another embodiment of the present invention is provided is used in any one aforementioned embodiments
Made by plastic composition.
Specifically, the manufacture method of fiber master batch includes supplying plastic composition into extruder carrying out
Kneading and dispersion processing procedure, to form fiber master batch.Wherein, above-mentioned extruder can be single shaft extruder or double
Axle extruder.
What deserves to be explained is, as it was noted above, because plastic composition has low glass transition temperature, height
Melt index and static dissipative, therefore use the fiber master batch manufactured by it out also to be shifted with low glass
Temperature, high fusion index and static dissipative, and and then possess good processability, mobility and application
Property.
Below in reference to embodiment 1 to embodiment 12 and comparative example 1 to comparative example 3, more specifically describe
Feature of the invention.Although describing following examples, in the case of insurmountability scope,
Material therefor, its amount and ratio, treatment details and handling process etc. can suitably be changed.Therefore,
Restricting property of the present invention should not be explained by embodiments described just below.
Prepare the master that embodiment 1 is used to embodiment 12 and comparative example 1 to the fiber master batch of comparative example 3
Want the information of material and equipment as follows.
PET (plastics) (hereinafter referred to as PET)：By new light compositing fiber company
Manufacture, its intrinsic viscosity (I.V.) is 0.64 deciliter/gram (dL/g).
PEI (plastics) (hereinafter referred to as PEI)：By Saudi Basic Industries Corporation (Sabic)
The ULTEM 1010PEI of manufacture.
Polyvinylidene fluoride (plastics) (hereinafter referred to as PVDF)：The Kynar manufactured by Arkema companies
705。
Ionic liquid：The structure shown in structure or above-mentioned formula (2) shown in above-mentioned formula (1).
Silver nano-particle：
The silver nitrate of 0.1625g is taken, is added into the pure water of 25mL with as silver nitrate aqueous solution.
Then, take 0.5g sodium citrate add 25mL pure water in, to be made into sodium citrate aqueous solution.Connect
, the pure water for taking 950mL is heated to 100 DEG C, then the silver nitrate solution of foregoing 25mL is added into this
In 100 DEG C of pure water and stir.Treat that temperature reaches 100 DEG C afterwards again, add the citric acid of foregoing 25mL
Sodium water solution, and maintain 100 DEG C.After persistently stirring 1 minute, stopping is heated and can be silver-colored after cooling down
The aqueous solution of nanoparticle.
Twin shaft extruder：Manufactured by German HAAKE companies.
Embodiment 1
Using 1 kilogram of PET, the ionic liquid shown in 10 g of formulas of (1wt%) (1) of processing aid
Body and 3 liters of acetone, are stirred equably to mix dispersion at room temperature.It is to be mixed it is uniform after again
Acetone is removed using rotary evaporator, to form the plastic composition of embodiment 1.Then, by the modeling
Material constituent is supplied into twin shaft extruder and is about 250 in 260~280 DEG C of kneading temperature and screw speed
Kneaded under rpm, to form the fiber master batch of embodiment 1.
Embodiment 2
The fiber master batch of embodiment 2 is manufactured according to fabrication schedule same as Example 1, and difference is only
It is：The usage amount of the ionic liquid shown in formula (1) is differed, as shown in table 1.
Embodiment 3
The fiber master batch of embodiment 3 is manufactured according to fabrication schedule same as Example 2, and difference is only
It is：In embodiment 3, also including using silver nano-particle, its detailed usage amount is as shown in table 1.
Embodiment 4
Using 1 kilogram of PEI, the ionic liquid shown in 10 g of formulas of (1wt%) (1) of processing aid
And 3 liters of acetone, it is stirred equably to mix dispersion at room temperature.It is to be mixed it is uniform after make again
Acetone is removed with rotary evaporator, to form the plastic composition of embodiment 4.Then, by the plastics
Constituent is supplied into twin shaft extruder and is about 200 in 310~330 DEG C of kneading temperature and screw speed
Kneaded under rpm, to form the fiber master batch of embodiment 4.
Embodiment 5
The fiber master batch of embodiment 5 is manufactured according to fabrication schedule same as Example 4, and difference is only
It is：The usage amount of the ionic liquid shown in formula (1) is differed, as shown in table 1.
Embodiment 6
The fiber master batch of embodiment 6 is manufactured according to fabrication schedule same as Example 5, and difference is only
It is：In embodiment 6, also including using silver nano-particle, its detailed usage amount is as shown in table 1.
Embodiment 7
Using 1 kilogram of PVDF, the ion shown in 5 g of formulas of (0.5wt%) (1) of processing aid
Liquid and 3 liters of acetone, are stirred equably to mix dispersion at room temperature.It is to be mixed it is uniform after
Reuse rotary evaporator and remove acetone, to form the plastic composition of embodiment 7.Then, will be described
Plastic composition is supplied into twin shaft extruder and is about with screw speed in 230~250 DEG C of temperature of kneading
Carried out under 200rpm, to form the fiber master batch of embodiment 7.
Embodiment 8 and embodiment 9
The fiber master batch of embodiment 8 and embodiment 9 is manufactured according to fabrication schedule same as Example 7,
And difference is only that：The usage amount of the ionic liquid shown in formula (1) is differed, as shown in table 1.
Embodiment 10
Using 1 kilogram of PEI, the ionic liquid shown in 10 g of formulas of (1wt%) (2) of processing aid
And 3 liters of acetone, it is stirred equably to mix dispersion at room temperature.It is to be mixed it is uniform after make again
Acetone is removed with rotary evaporator, to form the plastic composition of embodiment 10.Then, by the plastics
Constituent is supplied into twin shaft extruder and is about 200 in 310~330 DEG C of kneading temperature and screw speed
Kneaded under rpm, to form the fiber master batch of embodiment 10.
Embodiment 11 and embodiment 12
The fiber that embodiment 11 and embodiment 12 are manufactured according to fabrication schedule same as in Example 10 is female
Grain, and difference is only that：The usage amount of the ionic liquid shown in formula (2) is differed, as shown in table 1.
Ratio is compared with 1
The commercially available PET master batch for directly taking 1 kilogram (is manufactured, it is consolidated by new light compositing fiber company
It is 0.64 deciliter/gram (dL/g) to have viscosity (I.V.)).
Ratio is compared with 2
The commercially available PEI plastic master batches for directly taking 1 kilogram (are made by Saudi Basic Industries Corporation (Sabic)
The ULTEM 1010PEI for making).
Ratio is compared with 3
Directly take 1 kilogram of the commercially available PVDF plastic master batches (Kynar manufactured by Arkema companies
705)。
To inquire into below the glass transition temperature (Tg) of fiber master batch of the invention, heat enthalpy value (Δ Η),
Thermal cracking temperature (Td10%), physical property and the static dissipative such as melt index (melt index, MI).
<The measure of glass transition temperature>
Respectively to embodiment 1 to embodiment 6, embodiment 10 to embodiment 12 and comparative example 1 to than
Fiber master batch compared with example 2 carries out the measure of glass transition temperature.The measure is described as follows, and determines
Result be shown in table 1.
By heat differential scanning-analysis method (differential scanning calorimetry, DSC) respectively to reality
Apply fiber of the example 1 to embodiment 6, embodiment 10 to embodiment 12 and comparative example 1 to comparative example 2
Master batch is set as being measured under conditions of 10 DEG C/min in nitrogen environment and heating rate, to obtain glass
Transition temperature (DEG C).
Other one is mentioned that, because PVDF glass transition temperatures in itself are in subzero, thus it is not right
Embodiment 7 to the fiber master batch of embodiment 9 and the fiber master batch of comparative example 3 carries out glass transition temperature
Determine.
<The measure of heat enthalpy value>
The fiber master batch to embodiment 7 to embodiment 9 and comparative example 3 carries out the measure of heat enthalpy value respectively.
The measure is described as follows, and the result for determining is shown in table 1.
Fiber by heat differential scanning-analysis method respectively to embodiment 7 to embodiment 9 and comparative example 3 is female
Grain is set as being measured under conditions of 10 DEG C/min in nitrogen environment and heating rate, to obtain heat enthalpy value
(℃)。
<The measure of thermal cracking temperature>
Heat is carried out to embodiment 1 to embodiment 12 and comparative example 1 to the fiber master batch of comparative example 3 respectively
The measure of cracking temperature.The measure is described as follows, and the result for determining is shown in table 1.
By thermogravimetry (thermogravimetric analysis, TGA) respectively to embodiment 1 to
Embodiment 12 and comparative example 1 to the fiber master batch of comparative example 3 set in nitrogen environment and programming rate
The temperature measured to be measured under conditions of 20 DEG C/min, and when fiber master batch is lost into 10% weight
Degree is used as thermal cracking temperature (DEG C).
<The measure of melt index>
Embodiment 1 to embodiment 12 and comparative example 1 to the fiber master batch of comparative example 3 are melted respectively
Melt the measure of index.The measure is described as follows, and the result for determining is shown in table 1.
Embodiment 1 to embodiment 12 and comparative example 1 is measured respectively according to the specification of ASTM D-1238
To the melt index of the fiber master batch of comparative example 3, (MVR, unit is cm3/ 10min), wherein counterweight lotus
2.16Kg is all againf, and test temperature is different according to the plastics for being used, DCO temperature please
With reference to shown in table 1.In general, melt index is higher, represent that mobility is better.
<The test of static dissipative>
Respectively to the fiber master batch of embodiment 3 after melt index determination the resin of gained, embodiment 5
Fiber master batch, the fiber master batch of embodiment 8, the fiber master batch of embodiment 11 institute after melt index determination
The resin and comparative example 1 for obtaining carry out the test of static dissipative to the fiber master batch of comparative example 3.It is described
That tests is described as follows, and the result of test is shown in table 1.
Measured respectively using resistivity tester (brand name TRACK, model MODEL-100) real
Apply resin, the fiber master batch of embodiment 5, the reality of fiber master batch gained after melt index determination of example 3
Apply fiber master batch, the fiber master batch of embodiment 11 of example 8 after melt index determination the resin of gained and
Comparative example 1 to the fiber master batch of comparative example 3 surface resistivity, wherein the surface resistivity tester
Sign：Surface resistivity is 106Ω/cm2To 1011Ω/cm2When, represent test object tool static dissipative.
In table 1, the test result of static dissipative is represented with the symbol of "○" or "×",
Meaning representated by wherein each symbol is as follows：
○：Tool static dissipative；
×：Do not have static dissipative.
In above-mentioned table 1：
* unit wt% is represented：With the gross weight meter of plastics；
* units ppm is represented：With the gross weight meter of plastic composition.
From above-mentioned table 1, compared with the fiber master batch of comparative example 1 for not containing ionic liquid, contain
There is the embodiment 1 of the ionic liquid shown in formula (1) to the fiber master batch of embodiment 2 relatively low glass to shift
Temperature, and there is melt index higher under identical test temperature (280 DEG C).This result shows,
The ionic liquid in the range of certain content is added in plastics can effectively be reduced glass transition temperature and improve molten
Melt index, under appropriate processing temperature, can thereby lift the processability and mobility of fiber master batch.
In addition, compared with the fiber master batch of comparative example 1 for not containing ionic liquid, containing shown in formula (1)
Although the fiber master batch of the embodiment 3 of ionic liquid and silver nano-particle shifts temperature with close glass
Degree, but have excellent melt index, even and if reduce test temperature to 270 DEG C still still have it is excellent
Different melt index.This result shows, adds in the range of silver nano-particle and certain content in the plastic
Ionic liquid can effectively improve melt index, thereby not only lift the processability and mobility of fiber master batch,
The processing temperature of fiber master batch can also be made to be reduced, and then lifts application.
From above-mentioned table 1, compared with the fiber master batch of comparative example 2 for not containing ionic liquid, contain
There is the embodiment 4 of the ionic liquid shown in formula (1) to the fiber master batch of embodiment 5 relatively low glass to shift
Temperature, and there is melt index higher under identical test temperature (340 DEG C), and embodiment 5
Fiber master batch still has excellent melt index under relatively low test temperature (320 DEG C).This result shows,
Adding the ionic liquid in the range of certain content in the plastic can effectively reduce glass transition temperature and raising
Melt index, thereby can not only lift the processability and mobility of fiber master batch, can also make fiber master batch
Processing temperature reduction, and then lift application.
In addition, compared with the fiber master batch of comparative example 2 for not containing ionic liquid, containing shown in formula (1)
Although the fiber master batch of the embodiment 6 of ionic liquid and silver nano-particle shifts temperature with close glass
Degree, but there is excellent melt index, even and if reducing test temperature (320 DEG C) still still with excellent
Melt index.This result shows, add in the plastic in the range of silver nano-particle and certain content from
Sub- liquid can effectively improve melt index, thereby not only lift the processability and mobility of fiber master batch,
The processing temperature of fiber master batch can also be made to be reduced, and then lifts application.
From above-mentioned table 1, compared with the fiber master batch of comparative example 2 for not containing ionic liquid, contain
The embodiment 10 of the ionic liquid shown in formula (2) to the fiber master batch of embodiment 12 all has relatively low glass
Transition temperature and melt index higher.More specifically, with the comparative example 2 for not containing ionic liquid
Fiber master batch is compared, and the fiber master batch of embodiment 10 and embodiment 12 is at identical test temperature (340 DEG C)
Under all have excellent melt index；And compared with the fiber master batch of comparative example 2 for not containing ionic liquid,
The fiber master batch of embodiment 11 and embodiment 12 still has under relatively low test temperature (300 DEG C, 320 DEG C)
Close melt index.This result shows that the ionic liquid in the range of addition certain content can in the plastic
Effectively to reduce glass transition temperature and improve melt index, the processing of fiber master batch thereby can be not only lifted
Property and mobility, can also make the processing temperature of fiber master batch reduces, so lifted application.
From above-mentioned table 1, compared with the fiber master batch of comparative example 3 for not containing ionic liquid, contain
The embodiment 7 of the ionic liquid shown in formula (1) to embodiment 9 fiber master batch in identical test temperature
All there is melt index higher under (250 DEG C).This result shown, certain content scope is added in the plastic
Raising melt index can effectively drop in interior ionic liquid, can thereby be lifted under appropriate processing temperature
The processability and mobility of fiber master batch.
In addition, compared with the fiber master batch of comparative example 3 for not containing ionic liquid, containing shown in formula (1)
The embodiment 7 of ionic liquid to the fiber master batch of embodiment 9 all has thermal cracking temperature higher.This knot
Fruit display, adds the ionic liquid in the range of certain content so that the thermal cracking of PVDF in PVDF
Temperature is risen, and uses the temperature range of the machine-shaping for increasing PVDF.Consequently, it is possible to embodiment
7 to embodiment 9 include the plastic composition of PVDF and the ionic liquid shown in formula (1) carry out high temperature into
During type, there can be larger nargin and be produced in the fabrication process with being prevented effectively from selecting appropriate reaction condition
Raw hydrofluoric acid.
In addition, compared with the fiber master batch of comparative example 3 for not containing ionic liquid, containing shown in formula (1)
The embodiment 7 of ionic liquid to the fiber master batch of embodiment 9 all has heat enthalpy value higher.This result shows
Show, the ionic liquid in the range of certain content is added in PVDF so that the heat enthalpy value of PVDF is able to
Rise, use the crystallinity for increasing PVDF.
From above-mentioned table 1, by including the ionic liquid in the range of plastics and certain content, fiber
Master batch is able to static dissipative, and then lifts its application.
Further, the physical property of the fiber as made by fiber master batch of the invention will be inquired into below.
The fiber master batch of embodiment 2 is carried out into melt spinning processing procedure respectively, to obtain the fiber of embodiment 2,
Wherein spinning temperature is 260~280 DEG C, and draw off rate is about 2000m/min.
Then, the fiber to embodiment 2 carries out static dissipative, friction belt voltage and surface resistivity
Determine to assess its antistatic behaviour.Foregoing measure is described as follows, and the result for determining is shown in table 2.
<The measure of static dissipative>
The static dissipative (sec) of the fiber of embodiment 2 is measured according to the specification of NFPA 99-2002.Also,
The grade of measurement result is assessed using the classification standard of FTTS-FA-009 institutes specification, wherein when electrostatic ease
Dissipate and be less than 0.01sec, be then grade 3；When static dissipative is more than or equal to 0.01sec and less than or equal to 0.5sec,
It is then grade 2；Then it is grade 1 when static dissipative is more than or equal to 0.5sec and less than 2sec, and series
It is higher that to represent antistatic behaviour better.
<The measure of friction belt voltage>
According to JIS L 094:1997/AMD 1:2008 specification measures the fiber of embodiment 2 to cotton and sheep
The friction belt voltage (V) of hair.Also, assess measure using the classification standard of FTTS-FA-009 institutes specification
The grade of result, wherein being then grade 3 when friction belt voltage is less than 100V；When friction belt voltage is more than
Then it is grade 2 equal to 100V and less than or equal to 500V；When friction belt voltage more than or equal to 500V and
Then it is grade 1 less than 1000V, and level Number is higher, and to represent antistatic behaviour better.
<The measure of surface resistivity>
Surface resistivity (Ω/the cm of the fiber of embodiment 2 is measured according to the specification of AATCC 76-20112)。
Also, the grade of measurement result is assessed using the classification standard of FTTS-FA-009 institutes specification, wherein when
Sheet resistance is between 104Ω to 106Ω, then be grade 3；Sheet resistance is between 106Ω to 109Ω, then
It is grade 2；Sheet resistance is between 109Ω to 1012Ω, then be grade 1, and series representative higher is anti-quiet
It is electrically better.Additionally, when sheet resistance is between 104Ω to 1011Ω or surface resistivity are between 105Ω/cm2
To 1012Ω/cm2When, represent test object tool static dissipative.
Table 2
From above-mentioned table 2, using embodiment 2 fiber master batch prepared by fiber can have it is anti-quiet
Electrically.Based on this partial content, and simultaneously it can be seen from the content according to above-mentioned table 1, by using including modeling
The fiber master batch of the ionic liquid in the range of material and certain content can be prepared with anti-as raw material
The fiber of static behaviour, thus with good application.
In addition, the fiber master batch of embodiment 6 is carried out into melt spinning processing procedure respectively, to obtain embodiment 6
Fiber, wherein spinning temperature is 310~330 DEG C, and draw off rate is about 600m/min.
Then, the fiber to embodiment 6 carries out the measure of fibre strength, fiber degree of stretching and LOI values.
Foregoing measure is described as follows, and the result for determining is shown in table 3.
<The measure of fibre strength, fiber degree of stretching>
The fiber of embodiment 6 is fixed with spacing 25cm, and utilizes fiber yarn strength and elongation instrument (equipment
Model STATIMAT C, are manufactured by TEXTECHNO companies) draw speed be per minute 125
Centimetre and tensile strength are 100 newton (N), and relative humidity is 65% and temperature is under conditions of 23 DEG C
Measure fibre strength (g/den) and fiber degree of stretching (%).
<The measure of LOI values>
The LOI values (%) of the fiber of embodiment 6 are measured according to the specification of ASTM D 2863.
Table 3
| Fibre strength (g/den) | Fiber degree of stretching (%) | LOI values (%) | |
| Measurement result | 0.87 | 42.2 | 27 |
From above-mentioned table 3, the fiber under conditions of being 330 DEG C in processing temperature using embodiment 6 is female
Grain carries out spinning, can prepare the fiber with good physical property.Based on this partial content, and simultaneously
It can be seen from content according to above-mentioned table 1, with the specification of existing commercially available PEI fibers (for example：By Ku Lalei
The KURAKISSS of Internaional, Inc (Kuraray co., ltd.) manufactureTMProcessing temperature be up to
390 DEG C) to compare, fiber master batch of the present invention including the ionic liquid in the range of PEI and certain content can
It is able to be processed under the processing temperature reached in usual board, thus with good application.
Although the present invention is disclosed as above with implementation method, so it is not limited to the present invention, Ren Hesuo
Those of ordinary skill in category technical field, it is without departing from the spirit and scope of the present invention, a little when that can make
Change and retouching, therefore protection scope of the present invention depending on appended claims confining spectrum when being defined.
Claims (9)
1. a kind of plastic composition, it is characterised in that including：
Plastics；And
Ionic liquid, wherein with the gross weight meter of the plastics, the content of the ionic liquid is 0.5wt%
To 20wt%.
2. plastic composition according to claim 1, it is characterised in that the plastics include polyethers
Acid imide, PET or polyvinylidene fluoride.
3. plastic composition according to claim 1, it is characterised in that the ionic liquid includes
Formula (a) is to the shown structure of at least one of formula (q)：
Wherein, R1And R2It is independently of one another-CxHySO3 -、-CxHyPO3H-、-(CxHy)(PO3H2)PO3H-、-CxHyCOO-、-CxHySO3H、-CxHyPO3H2、-(CxHy)(PO3H2)PO3H2Or-CxHyCOOH,
Wherein x is that 1 to 6, y is 2 to 12, and R3To R9Independently of one another for hydride base, be substituted or
Be unsubstituted with 1 to 6 alkyl of carbon atom, be substituted or be unsubstituted with 1 to 6
The alkenyl of carbon atom, be substituted or be unsubstituted with 6 to 30 aryl of carbon atom, be substituted or
Be unsubstituted with 3 to 30 cycloalkyl of carbon atom ,-(Z1)-O-(Z2)-OH, wherein Z1And Z2
It is independently of one another to be substituted or be unsubstituted with 1 to 6 alkylidene or-(Z of carbon atom3)-O-Z4,
Wherein Z3To be substituted or being unsubstituted with 1 to 6 alkylidene of carbon atom, Z4To be substituted or
Be unsubstituted with 1 to 6 alkyl of carbon atom；Or
R1To R9Independently of one another for hydride base, be substituted or be unsubstituted with 1 to 6 carbon atom
Alkyl, be substituted or be unsubstituted with 1 to 6 alkenyl of carbon atom, be substituted or without taking
Generation with 6 to 30 aryl of carbon atom, be substituted or be unsubstituted with 3 to 30 carbon originals
Cycloalkyl, the-(Z of son1)-O-(Z2)-OH, wherein Z1And Z2It is substituted or is unsubstituted independently of one another
With 1 to 6 alkylidene or-(Z of carbon atom3)-O-Z4, wherein Z3And Z4It is independently of one another through taking
Generation or be unsubstituted with 1 to 6 alkylidene of carbon atom, wherein the alkyl being substituted, alkene
Base, aryl, cycloalkyl, alkylidene are replaced through substituents：Alkoxy, alkenyl, alkynyl,
Aryl, heteroaryl, aldehyde radical, amino, ester group, ether, halogen atom, hydroxyl, ketone group, nitro,
Silylation, sulfonyl, sulfoxide group, sulfate radical or mercapto.
4. plastic composition according to claim 1, it is characterised in that the ionic liquid includes
Anion, the anion includes F-、Cl-、Br-、I-、ClO4 -、SCN-、OCN-、BF4 -、
PF6 -、AsF6 -、SbF6 -、NO3 -、NO2 -、N(SO2CF3)2 -、SO4 2-、HSO4 -、PO4 3-、
HPO4 2-、H2PO4 -、CF3CO2 -、CO3 2-, citrate or with 2 to 7 carboxylic acids of carbon atom
Root.
5. plastic composition according to claim 1, it is characterised in that the ionic liquid be containing
Fluorine ion liquid.
6. plastic composition according to claim 5, it is characterised in that the ionic liquid includes
Anion, the anion includes BF4 -、PF6 -、AsF6 -、SbF6 -、N(SO2CF3)2 -Or CF3CO2 -。
7. plastic composition according to claim 1, it is characterised in that the ionic liquid includes
Structure shown in formula (1) or formula (2)：
8. plastic composition according to claim 1, it is characterised in that also including silver nano-particle,
Wherein with the gross weight meter of the plastic composition, the content of the silver nano-particle for 9000ppm extremely
11000ppm。
9. a kind of fiber master batch, it is characterised in that the plastic composition described in usage right requirement 1 is made
Into.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW104143300 | 2015-12-23 | ||
| TW104143300A TWI571493B (en) | 2015-12-23 | 2015-12-23 | Plastic composition and fiber masterbatch |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106905666A true CN106905666A (en) | 2017-06-30 |
| CN106905666B CN106905666B (en) | 2019-05-07 |
Family
ID=58608306
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201511017259.8A Active CN106905666B (en) | 2015-12-23 | 2015-12-30 | Plastic composition and fiber master batch |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN106905666B (en) |
| TW (1) | TWI571493B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112126227A (en) * | 2019-06-25 | 2020-12-25 | 财团法人纺织产业综合研究所 | Plastic composition and fiber |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI758792B (en) * | 2020-03-31 | 2022-03-21 | 財團法人紡織產業綜合研究所 | Fiber masterbatch and melting spinning fiber |
| US11572639B2 (en) | 2020-03-31 | 2023-02-07 | Taiwan Textile Research Institute | Fiber masterbatch and melt spun fiber |
| TWI753693B (en) * | 2020-12-09 | 2022-01-21 | 財團法人紡織產業綜合研究所 | Breathable and waterproof non-woven fabric and manufacturing method thereof |
| US11952690B2 (en) | 2020-12-09 | 2024-04-09 | Taiwan Textile Research Institute | Breathable and waterproof non-woven fabric, manufacturing method of breathable and waterproof non-woven fabric, and breathable and waterproof cloth |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101312983A (en) * | 2005-12-02 | 2008-11-26 | 关东电化工业株式会社 | Ionic liquid containing phosphonium cation having P-N bond and method for producing same |
| CN103556234A (en) * | 2013-10-24 | 2014-02-05 | 杭州师范大学 | Anti-static high-beta-crystal-content polyvinylidene fluoride nanometer composite fiber film and preparation method thereof |
| CN104073910A (en) * | 2014-06-25 | 2014-10-01 | 绍兴佳华高分子材料股份有限公司 | Application of ionic liquid in polyethylene terephthalate composite fiber |
| US20150355561A1 (en) * | 2014-06-06 | 2015-12-10 | Canon Kabushiki Kaisha | Electro-conductive belt and electrophotographic apparatus |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101709116A (en) * | 2009-12-01 | 2010-05-19 | 上海新上化高分子材料有限公司 | Plastic additive mixed liquor and preparation method and application thereof |
| JP5762437B2 (en) * | 2009-12-10 | 2015-08-12 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | Antistatic thermoplastic composition |
| CN103848994A (en) * | 2012-12-05 | 2014-06-11 | 财团法人纺织产业综合研究所 | Ionic liquid and viscose composition |
-
2015
- 2015-12-23 TW TW104143300A patent/TWI571493B/en active
- 2015-12-30 CN CN201511017259.8A patent/CN106905666B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101312983A (en) * | 2005-12-02 | 2008-11-26 | 关东电化工业株式会社 | Ionic liquid containing phosphonium cation having P-N bond and method for producing same |
| CN103556234A (en) * | 2013-10-24 | 2014-02-05 | 杭州师范大学 | Anti-static high-beta-crystal-content polyvinylidene fluoride nanometer composite fiber film and preparation method thereof |
| US20150355561A1 (en) * | 2014-06-06 | 2015-12-10 | Canon Kabushiki Kaisha | Electro-conductive belt and electrophotographic apparatus |
| CN104073910A (en) * | 2014-06-25 | 2014-10-01 | 绍兴佳华高分子材料股份有限公司 | Application of ionic liquid in polyethylene terephthalate composite fiber |
Non-Patent Citations (2)
| Title |
|---|
| CHEN, Y: "Polyetherimide/Bucky Gels Nanocomposites with Superior Conductivity and Thermal Stability", 《ACS APPLIED MATERIALS & INTERFACES》 * |
| MARTINIS, EM: "On-line ionic liquid-based preconcentration system coupled to flame atomic absorption spectrometry for trace cadmium determination in plastic food packaging materials", 《TALANTA》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112126227A (en) * | 2019-06-25 | 2020-12-25 | 财团法人纺织产业综合研究所 | Plastic composition and fiber |
| CN112126227B (en) * | 2019-06-25 | 2023-03-14 | 财团法人纺织产业综合研究所 | Plastic composition and fiber |
Also Published As
| Publication number | Publication date |
|---|---|
| TWI571493B (en) | 2017-02-21 |
| CN106905666B (en) | 2019-05-07 |
| TW201723087A (en) | 2017-07-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106905666A (en) | Plastic composition and fiber master batch | |
| CN111849127A (en) | Recycled polyethylene terephthalate foam material and manufacturing method thereof | |
| CN107345053B (en) | Ultra-thin super transparent full-biodegradable film blown film grade material of one kind and preparation method thereof | |
| DE112015000662T5 (en) | Polyester resin composition and the polyester resin composition using molded article | |
| CN106633778A (en) | High-content glass fiber reinforced antistatic PC composite material and preparation method thereof | |
| CN112694708A (en) | Environment-friendly modified ABS (acrylonitrile butadiene styrene) composite plastic and preparation method thereof | |
| CN108864563A (en) | A kind of high intensity increasing tougheness MODIFIED PP plastics and preparation process | |
| CN101717578B (en) | Enhanced PA66 composite material and preparation method thereof | |
| CN114410091A (en) | High-temperature-resistant impact-resistant high-strength modified polylactic acid material and preparation method thereof | |
| CN108359194A (en) | A kind of anti-aging conductive plastics and preparation method thereof | |
| CN111393748A (en) | Silicon dioxide modified polypropylene antibacterial material and preparation method thereof | |
| CN107841105A (en) | Heat-proof combustion-resistant PLA graphene composite material and preparation method thereof | |
| CN108219427B (en) | Biological-grade transparent flame-retardant polycarbonate compound and preparation method thereof | |
| Doan et al. | Localization of nanofibers on polymer surface using interface transfer technique | |
| CN108796647A (en) | Method for producing fiber masterbatch and fiber | |
| CN109320935A (en) | Improve the production technology of Polycarbonate alloy material toner point | |
| CN108299805A (en) | A kind of high-impact, antistatic polyester class composite material and preparation method | |
| EP2247670B1 (en) | Polymer blends containing polydiorganosiloxane urea copolymers | |
| CN108503937A (en) | Polyethylene functional master batch and preparation method thereof | |
| CN112898785A (en) | Thermoplastic elastomer material and preparation method and application thereof | |
| CN112980083A (en) | Preparation method and preparation device of graphene antibacterial reinforced plastic | |
| CN103374199B (en) | A kind of Polyetheretherketonethioethere/polyphenyternary thioethere/polyphenyternary ternary alloy and preparation method thereof | |
| CN116535826B (en) | Solid-phase-tackified high-strength PBT and PET composite material and preparation method thereof | |
| CN113801459B (en) | Nano polyethylene terephthalate/polycarbonate composite material and preparation method thereof | |
| CN107163523A (en) | A kind of fused glass pellet polyhydroxyalkanoate material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |