CN106901997A - A kind of rapid shaping carving glue and preparation method thereof - Google Patents
A kind of rapid shaping carving glue and preparation method thereof Download PDFInfo
- Publication number
- CN106901997A CN106901997A CN201710168414.9A CN201710168414A CN106901997A CN 106901997 A CN106901997 A CN 106901997A CN 201710168414 A CN201710168414 A CN 201710168414A CN 106901997 A CN106901997 A CN 106901997A
- Authority
- CN
- China
- Prior art keywords
- rapid shaping
- newtrex
- methacrylic acid
- acrylic monomers
- carving glue
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8164—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers, e.g. poly (methyl vinyl ether-co-maleic anhydride)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/90—Block copolymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
- A61Q3/02—Nail coatings
Abstract
The invention discloses a kind of rapid shaping carving glue and preparation method thereof, the rapid shaping carving glue is composed of the following components：Acrylic monomers/methacrylic acid monomer, light initiator, newtrex, filler and colouring agent.The product carving aftershaping is fast and shaping after colloid adhesive force it is good and with certain hardness and toughness, so as to avoid, due to the damage of collision generation, can be used for manicure field.
Description
【Technical field】
The present invention relates to cosmetics synthesis field, more particularly to a kind of rapid shaping carving glue and preparation method thereof.
【Background technology】
In nail salon, carving product obtains the favor of many people, although these carving products can undercut better appearance
Style, but undercut style shaping it is slow, to nail poor adhesion, and careless slightly shape carve is easily broken off damage, from
And influence the whole structure of manicure.
【The content of the invention】
It is an object of the invention to provide a kind of rapid shaping carving glue and preparation method thereof, the product carving aftershaping it is fast and
Colloid adhesive force is good and with certain hardness and toughness after shaping, so as to avoid, due to the damage that collision occurs, can be used for U.S.
First field.
The present invention is achieved by the following technical solutions：A kind of rapid shaping carving glue, it is characterised in that：By with the following group
It is grouped into：Acrylic monomers/methacrylic acid monomer, light initiator, newtrex, filler and colouring agent.
Preferably, the percentage by weight of the acrylic monomers/methacrylic acid monomer is 35%~45%, and the light rises
The percentage by weight of beginning agent is 1%~5%, and the percentage by weight of the newtrex is 10%~20%, the weight of described filler
Amount percentage is 35%~45%, and the percentage by weight of the colouring agent is 1%~5%.
Preferably, the acrylic monomers/methacrylic acid monomer is free methyl hydroxypropyl acrylate (HPMA), methyl
Hydroxy-ethyl acrylate (HEMA), EMA (EMA), tetrahydrofurfuryl methacrylate (THFMA), PMDA
Two (methyl) acrylate, PMDA glyceryl dimethylacrylate, the dimethylacrylate of 1,2,4,5- benzene four,
Methylacryoyloxyethyl maleate, HEMA/succinate, 1,3- glycerine dimethacrylates
Ester/succinate adduct, the ethylmethyl acrylate of phthalic acid one, AAEM
(AAEMA) one or more in.
Preferably, the smooth initiator is ethyl -2,4,6- trimethylbenzoyl diphenylphosphinate esters, 2,4,6- front threes
One or more in base benzoyl diphenyl phosphine oxide, hydroxycyclohexylphenylketone, benzyldimethylketal.
Preferably, the newtrex is B-100 newtrexes.
Preferably, described filler is nano-calcium carbonate, nano silicon or their mixture.
Preferably, the colouring agent is pigment, dyestuff or their mixture.
A kind of preparation method of rapid shaping carving glue, it is characterised in that comprise the following steps：
A) acrylic monomers/methacrylic acid monomer of 35%~45%wt and the newtrex of 10%~20%wt are mixed
Close, to 70-90 DEG C, mechanical agitation makes the acrylic monomers/methacrylic acid monomer and the newtrex to warming-in-water
Mixture dissolving is homogeneous, stand-by；
B) to the filler and the colouring agent of 1%~5%wt that 35%~45%wt is added in the mixture described in step a),
Mechanical agitation, makes fully dispersed；
C) the light initiator of 1%~5%wt is added, mechanical agitation is well mixed to obtain final product the rapid shaping carving glue；
The no sequencing of addition of described filler and colouring agent；
The newtrex is B-100 newtrexes.
The beneficial effects of the invention are as follows：The present invention is shaped by ultraviolet light polymerization, and solidified forming time is very short, typically
More than ten seconds to tens seconds i.e. plastic；Used filler of the invention can be consolidated by way of strengthening cohesive force to shaping
Body carries out activeness and quietness, prevents from causing the shape moulded to be damaged due to accident collision.The use of other these fillers can be with
The cost of material of production process is greatly lowered；Newtrex in the present invention can both increase the attachment to referring to face, Er Qieyou
There is wetting action to pigment and dyestuff in itself in rosin, so the color of the manicure made is more bright-coloured full.
【Specific embodiment】
With reference to specific embodiment, the present invention is described in further detail：
The embodiment of the invention discloses a kind of rapid shaping carving glue, it is characterised in that：It is composed of the following components：Acrylic acid
Monomer/methacrylic acid monomer, light initiator, newtrex, filler and colouring agent.
Preferably, the percentage by weight of the acrylic monomers/methacrylic acid monomer is 35%~45%, and the light rises
The percentage by weight of beginning agent is 1%~5%, and the percentage by weight of the newtrex is 10%~20%, the weight of described filler
Amount percentage is 35%~45%, and the percentage by weight of the colouring agent is 1%~5%.
Preferably, the acrylic monomers/methacrylic acid monomer is hydroxy propyl methacrylate (HPMA), metering system
Sour hydroxyl ethyl ester (HEMA), EMA (EMA), tetrahydrofurfuryl methacrylate (THFMA), PMDA two
(methyl) acrylate, PMDA glyceryl dimethylacrylate, the dimethylacrylate of 1,2,4,5- benzene four, first
Base acrylyl oxy-ethyl maleate, HEMA/succinate, 1,3- glycerine dimethacrylates
Ester/succinate adduct, the ethylmethyl acrylate of phthalic acid one, AAEM
(AAEMA) one or more in.
Preferably, the smooth initiator is ethyl -2,4,6- trimethylbenzoyl diphenylphosphinate esters, 2,4,6- front threes
One or more in base benzoyl diphenyl phosphine oxide, hydroxycyclohexylphenylketone, benzyldimethylketal.
Preferably, the newtrex is B-100 newtrexes.
Preferably, described filler is nano-calcium carbonate, nano silicon or their mixture.
Preferably, the colouring agent is pigment, dyestuff or their mixture.
A kind of preparation method of rapid shaping carving glue, it is characterised in that comprise the following steps：
A) acrylic monomers/methacrylic acid monomer of 35%~45%wt and the newtrex of 10%~20%wt are mixed
Close, to 70-90 DEG C, mechanical agitation makes the acrylic monomers/methacrylic acid monomer and the newtrex to warming-in-water
Mixture dissolving is homogeneous, stand-by；
B) to the filler and the colouring agent of 1%~5%wt that 35%~45%wt is added in the mixture described in step a),
Mechanical agitation, makes fully dispersed；
C) the light initiator of 1%~5%wt is added, mechanical agitation is well mixed to obtain final product the rapid shaping carving glue；
The no sequencing of addition of described filler and colouring agent；
The newtrex is B-100 newtrexes.
For a further understanding of the present invention, the rapid shaping carving glue that the present invention is provided is said with reference to embodiment
Bright, protection scope of the present invention is not limited by the following examples.
Newtrex used by various embodiments of the present invention is selected from the B-100 newtrexes of the celebrating chemical company of Shanghai nine production；
The colouring agent is the mill base of the shades of colour of Clariant Corporation production, also can select toner, but is needed by treatment, can
Use；Remaining raw material is commercially available industrial goods.The mill base can suitably increase and decrease consumption when selecting according to the color of mill base.Example
Such as, black or white colorant can in right amount reduce consumption, and pink colour or yellow can in right amount increase consumption.
The application method of the rapid shaping carving glue：Bottom is coated on nail first, afterwards, is taken appropriate described quick
Shaping carving glue, carving is carried out using instruments such as professional instrument carving pen cooperation toothpicks, after carving terminates, is shone under uviol lamp
Penetrate, irradiated preferably under the ultraviolet light of 350-400nm, hardening time is shorter；Also can naturally be dried under sunshine, but required time
It is slightly long.
Specific embodiment is as follows：
Embodiment 1
The EMA of 35g is mixed with 15g newtrexes B-100 (celebrating chemical industry in Shanghai nine), warming-in-water is extremely
80 DEG C, mechanical agitation makes the EMA homogeneous with the mixture dissolving of the newtrex, stand-by；
B) to the nano-calcium carbonate and 4g mill bases, mechanical agitation that 45g is added in the mixture described in step a), make fully
Dispersion；
C) 1g hydroxycyclohexylphenylketones are added, mechanical agitation is well mixed to obtain final product the rapid shaping carving glue；
Embodiment 2
The hydroxy propyl methacrylate of 35g is mixed, warming-in-water with 20g newtrexes B-100 (celebrating chemical industry in Shanghai nine)
To 80 DEG C, mechanical agitation makes the hydroxy propyl methacrylate homogeneous with the mixture dissolving of the newtrex, stand-by；
B) to the nano-calcium carbonate and 3g mill bases, mechanical agitation that 40g is added in the mixture described in step a), make fully
Dispersion；
C) 2g hydroxycyclohexylphenylketones are added, mechanical agitation is well mixed to obtain final product the rapid shaping carving glue；
Embodiment 3
The methylacryoyloxyethyl maleate of 40g is mixed with 10g newtrexes B-100 (celebrating chemical industry in Shanghai nine),
To 80 DEG C, mechanical agitation makes the mixture of the methylacryoyloxyethyl maleate and the newtrex to warming-in-water
Dissolving is homogeneous, stand-by；
B) to the nano-calcium carbonate and 2g mill bases, mechanical agitation that 45g is added in the mixture described in step a), make fully
Dispersion；
C) 3g benzyldimethylketals are added, mechanical agitation is well mixed to obtain final product the rapid shaping carving glue；
Embodiment 4
The tetrahydrofurfuryl methacrylate of 40g is mixed, water-bath liter with 15g newtrexes B-100 (celebrating chemical industry in Shanghai nine)
To 80 DEG C, mechanical agitation makes the tetrahydrofurfuryl methacrylate homogeneous with the mixture dissolving of the newtrex to temperature, treats
With；
B) to the nano-calcium carbonate and 20g nano silicons and 2g that 20g is added in the mixture described in step a)
Mill base, mechanical agitation makes fully dispersed；
C) 3g benzyldimethylketals are added, mechanical agitation is well mixed to obtain final product the rapid shaping carving glue；
Embodiment 5
The ethylmethyl acrylate of phthalic acid one of 40g and 15g newtrexes B-100 (celebrating chemical industry in Shanghai nine) is mixed
Close, to 80 DEG C, mechanical agitation makes the ethylmethyl acrylate of the phthalic acid one with the newtrex to warming-in-water
Mixture dissolving is homogeneous, stand-by；
B) to the nano-calcium carbonate and 1g mill bases, mechanical agitation that 40g is added in the mixture described in step a), make fully
Dispersion；
C) add the trimethylbenzoyl diphenyl phosphine oxides of 4g 2,4,6-, mechanical agitation, it is well mixed obtain final product it is described fast
Rapid-result type carving glue；
Embodiment 6
The PMDA diacrylate of 45g is mixed, water with 10g newtrexes B-100 (celebrating chemical industry in Shanghai nine)
Bath is warming up to 80 DEG C, and mechanical agitation makes the PMDA diacrylate be dissolved with the mixture of the newtrex
It is homogeneous, it is stand-by；
B) to the nano-calcium carbonate and 5g mill bases, mechanical agitation that 35g is added in the mixture described in step a), make fully
Dispersion；
C) 5g ethyl -2 are added, 4,6- trimethylbenzoyl diphenylphosphinate esters, mechanical agitation is well mixed to obtain final product institute
State rapid shaping carving glue；
The performance of the rapid shaping carving glue to obtaining is tested, as a result referring to table 1：
Table 1
Performance test methods are as follows：
Hardening time：Same professional manicuristisn is allowed to use rapid shaping carving glue and city obtained by embodiment 1-6 respectively
Sell carving glue and carve identical flower pattern processed respectively, after carving system terminates, be placed on irradiation under the UV-LED lamps of 365nm, carving is touched not with hand
It is deformed into completion of cure.The time irradiated under uviol lamp is hardening time.
Glossiness is tested：According to HG/T3828-2006 standards, mapping test instrument Co., Ltd WGG-60 is praised just using Shanghai
The glossiness that formula mirror luster meter to the rapid shaping carving glue of above-mentioned gained test after its film is taken, film is as a result obtained
60 ° of mirror lusters.
Pencil hardness test：According to GB/T1730-1993 standards, using the hard instrument of QHQ film Pencil scratch, (Tianjin material is tried
Yan Ji factories) hardness of film of the rapid shaping carving glue of above-mentioned gained is tested.The index can be used to reflect described quick
The hardness of the material after shaping carving adhesive curing.
To sum up, rapid shaping carving glue disclosed in this invention has fast shaping, low cost and property relative to prior art
The good advantage of energy.
Although the present invention is described and defines with reference to the specific preferred embodiment of the present invention, such reference is not
Mean the limitation present invention, also do not infer there is such limitation.Form of the present invention and can functionally carry out suitable modification, change
And equivalent substitute, these are that person of ordinary skill in the relevant can realize.The present invention description preferred embodiment be
Illustrate rather than detailed the scope of the present invention.Therefore, the present invention is only limited by claims included below spirit and scope
System, all aspects are all assert equivalent.
Claims (8)
1. a kind of rapid shaping carving glue, it is characterised in that：It is composed of the following components：Acrylic monomers/methacrylic acid monomer,
Light initiator, newtrex, filler and colouring agent, the acrylic monomers/methacrylic acid monomer refer to acrylic monomers or
The mixture of methacrylic acid monomer or acrylic monomers and methacrylic acid monomer.
2. rapid shaping carving glue according to claim 1, it is characterised in that：Acrylic monomers/the methacrylic acid
The percentage by weight of monomer is 35%~45%, and the percentage by weight of the smooth initiator is 1%~5%, the newtrex
Percentage by weight be 10%~20%, the percentage by weight of described filler is 35%~45%, the weight hundred of the colouring agent
Divide than being 1%~5%.
3. rapid shaping carving glue according to claim 1, it is characterised in that：Acrylic monomers/the methacrylic acid
Monomer is hydroxy propyl methacrylate (HPMA), hydroxyethyl methacrylate (HEMA), EMA (EMA), methyl
Tetrahydrofurfuryl acrylate (THFMA), PMDA two (methyl) acrylate, PMDA glyceryl dimethyl propylene
Olefin(e) acid ester, the dimethylacrylate of 1,2,4,5- benzene four, methylacryoyloxyethyl maleate, 2- hydroxyethyl methacrylic acids
Ester/succinate, 1,3- glycerol dimethacrylates/succinate adduct, the ethyl-methyl propylene of phthalic acid one
One or more in acid esters, AAEM (AAEMA).
4. rapid shaping carving glue according to claim 1, it is characterised in that：The smooth initiator is ethyl -2,4,6-
Trimethylbenzoyl diphenylphosphinate esters, 2,4,6- trimethylbenzoyls diphenyl phosphine oxide, hydroxycyclohexylphenylketone,
One or more in benzyldimethylketal.
5. rapid shaping carving glue according to claim 1, it is characterised in that：The newtrex is B-100 polymerization pines
It is fragrant.
6. rapid shaping carving glue according to claim 1, it is characterised in that：Described filler is nano-calcium carbonate, nanometer
Silica or their mixture.
7. rapid shaping carving glue according to claim 1, it is characterised in that：The colouring agent is mill base.
8. a kind of preparation method of rapid shaping carving glue, it is characterised in that comprise the following steps：
A) acrylic monomers/methacrylic acid monomer of 35%~45%wt is mixed with the newtrex of 10%~20%wt,
To 70-90 DEG C, mechanical agitation makes the acrylic monomers/methacrylic acid monomer mixed with the newtrex to warming-in-water
Compound dissolving is homogeneous, stand-by；
B) to the filler and the colouring agent of 1%~5%wt that 35%~45%wt is added in the mixture described in step a), machinery
Stirring, makes fully dispersed；
C) the light initiator of 1%~5%wt is added, mechanical agitation is well mixed to obtain final product the rapid shaping carving glue；
The no sequencing of addition of described filler and colouring agent；
The newtrex is B-100 newtrexes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710168414.9A CN106901997A (en) | 2017-03-21 | 2017-03-21 | A kind of rapid shaping carving glue and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710168414.9A CN106901997A (en) | 2017-03-21 | 2017-03-21 | A kind of rapid shaping carving glue and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106901997A true CN106901997A (en) | 2017-06-30 |
Family
ID=59195131
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710168414.9A Pending CN106901997A (en) | 2017-03-21 | 2017-03-21 | A kind of rapid shaping carving glue and preparation method thereof |
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| Country | Link |
|---|---|
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110731913A (en) * | 2019-08-19 | 2020-01-31 | 金华市科维思日化有限公司 | novel carving glue for nail beauty |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102639578A (en) * | 2009-10-05 | 2012-08-15 | 创意指甲设计公司 | Removable protective topcoat for artificial nail coatings and methods therefore |
| CN103501755A (en) * | 2011-03-07 | 2014-01-08 | 创意指甲设计公司 | Compositions and methods for UV-curable cosmetic nail coatings |
| JP2016121087A (en) * | 2014-12-25 | 2016-07-07 | 株式会社ニッシン | Film-forming composition for nails |
-
2017
- 2017-03-21 CN CN201710168414.9A patent/CN106901997A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102639578A (en) * | 2009-10-05 | 2012-08-15 | 创意指甲设计公司 | Removable protective topcoat for artificial nail coatings and methods therefore |
| CN103501755A (en) * | 2011-03-07 | 2014-01-08 | 创意指甲设计公司 | Compositions and methods for UV-curable cosmetic nail coatings |
| JP2016121087A (en) * | 2014-12-25 | 2016-07-07 | 株式会社ニッシン | Film-forming composition for nails |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110731913A (en) * | 2019-08-19 | 2020-01-31 | 金华市科维思日化有限公司 | novel carving glue for nail beauty |
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Application publication date: 20170630 |