CN106900882A - Margarine and preparation method thereof - Google Patents

Margarine and preparation method thereof Download PDF

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Publication number
CN106900882A
CN106900882A CN201710088967.3A CN201710088967A CN106900882A CN 106900882 A CN106900882 A CN 106900882A CN 201710088967 A CN201710088967 A CN 201710088967A CN 106900882 A CN106900882 A CN 106900882A
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China
Prior art keywords
margarine
oil
cyclodextrin
mass
water
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Granted
Application number
CN201710088967.3A
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Chinese (zh)
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CN106900882B (en
Inventor
韩立娟
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SHANGHAI HI-ROAD FOOD TECHNOLOGY Co.,Ltd.
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Wuhan Polytechnic University
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D7/00Edible oil or fat compositions containing an aqueous phase, e.g. margarines
    • A23D7/01Other fatty acid esters, e.g. phosphatides
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D7/00Edible oil or fat compositions containing an aqueous phase, e.g. margarines
    • A23D7/005Edible oil or fat compositions containing an aqueous phase, e.g. margarines characterised by ingredients other than fatty acid triglycerides

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Edible Oils And Fats (AREA)
  • Coloring Foods And Improving Nutritive Qualities (AREA)

Abstract

The invention discloses a kind of margarine, including cyclodextrin and lecithin.The product can wholly or in part substitute commercially available synthetic cream without trans-fatty acid, steady quality in organoleptic attribute.

Description

Margarine and preparation method thereof
Technical field
The invention belongs to grease finely processed product field, specifically, the present invention relates to a kind of margarine and its preparation Method.
Background technology
Margarine has good shortening property, caseation, stability and excellent local flavor, can improve bread, cake And the quality of the baked product such as biscuit, widely, consumption figure gradually increases practical application.It is most artificial on domestic market Cream smears fat prod (ice cream, sandwich cream) etc. mainly based on the hydrogenated oil and fat of part, but trans fat in hydrogenated oil and fat Mass fraction (5%-10%) severe overweight of fat acid.There are some researches show, trans-fatty acid not only with angiocardiopathy and baby Grow in close relations, also result in women and suffer from diabetes B.Trans-fatty acid causes the probability of angiocardiopathy to be full With 3~5 times of aliphatic acid, can increase the low-density lipoprotein in blood, HDL reduce, induce vascular sclerosis, Increase heart disease, the danger of cerebrovas-cularaccident, it is very unfavorable to health.
Therefore, current margarine still has much room for improvement.
The content of the invention
It is contemplated that at least solving one of technical problem in correlation technique to a certain extent or providing a kind of useful Business selection.Therefore, it is an object of the present invention to propose a kind of novel artificial cream, without trans-fatty acid, quality is steady It is fixed, commercially available synthetic cream can be wholly or in part substituted in organoleptic attribute.It is another object of the present invention to provide one kind very Easy margarine preparation method, margarine can be efficiently prepared using the method.
In one aspect of the invention, the present invention provides a kind of margarine.Embodiments in accordance with the present invention, it is described artificial Cream includes cyclodextrin and lecithin.Inventors be surprised to learn that, cyclodextrin can form plural gel agent and for making with lecithin Standby novel artificial cream.Its cyclodextrin can be used as food additives, and lecithin is the important phosphatide cpd of a class, contains courage The physiologically active ingredients such as alkali, cholamine, biotin and organophosphor, with anti-aging, brain tonic and intelligence development, protection liver, regulation blood fat Etc. function;According to WHO Report, appropriate lecithin, the potency that can have additional nutrients summation, drop are eaten for each person every day Low blood cholesterol and it is without any side effects, have effect for health and prevention from suffering from the diseases, so as to get margarine have Special functional characteristic.The invention belongs to cyclodextrin in height containing the application in resin system, by be self-assembly of network structure from And margarine is formed, without trans-fatty acid.Margarine structure of the invention is novel, can significantly reduce consumer to full With the intake of fat.
Embodiments in accordance with the present invention, the margarine further includes water and grease.Thus, by by cyclodextrin with Lecithin Stable distritation is at the oil-water interface in margarine, so as to form two-arch tunnel structure, prevents oil phase and water phase Flowing.It is to form three-dimensional net structure by the triglycerides molecular crystalline of grease to be formed that it is totally different from traditional hydrogenation oil Margarine.
Embodiments in accordance with the present invention, the cyclodextrin is food grade cyclodextrin, including alpha-cyclodextrin, beta-schardinger dextrin, γ- The mixture of one or more in cyclodextrin.
Embodiments in accordance with the present invention, the water be selected from pure water, ultra-pure water, distilled water, ion exchange water at least It is a kind of.Food desired use can be based on, the water as solvent in the present invention is properly selected.
Embodiments in accordance with the present invention, the grease is refining vegetable oil, including soybean oil, sunflower oil, corn oil, dish At least one or several mixing in seed oil, cottonseed oil, tea oil, peanut oil, rice bran oil, palm oil, sesame oil and olive oil Thing.
Embodiments in accordance with the present invention, the cyclodextrin is the total matter of the margarine with the total addition level of the lecithin 1 mass %~20 mass % of amount.According to a particular embodiment of the invention, the cyclodextrin is with the mass ratio of the lecithin 1: 5~5: 1.Thus, products obtained therefrom can keep good water and oil balance.
Embodiments in accordance with the present invention, the addition of the water is 10 mass %~60 mass %.
Embodiments in accordance with the present invention, the addition of the grease is 20 mass %~89 of the margarine gross mass Quality %.
In another aspect of this invention, the present invention method that also proposition prepares margarine, embodiments in accordance with the present invention, The method includes:After the cyclodextrin, lecithin, water and grease are contacted and stirred, stored under constant temperature.Thus, Can be evenly distributed on by self assembly at oil-water two-phase interface in water-oil phase using cyclodextrin and lecithin, form oil The co-continuous network structure of water phase, so as to form margarine.The preparation method is easy to operate, and obtained margarine without Trans-fatty acid, can be used to substitute commercially available synthetic cream wholly or in part.
Embodiments in accordance with the present invention, the temperature of the contact is 50~80 degrees Celsius.
Embodiments in accordance with the present invention, the constant temperature is 0~30 degree Celsius.
Embodiments in accordance with the present invention, the time of the storage is 12~48 hours.
The beneficial effects of the present invention are:The present invention is merely relating to heat and cool down (be down to constant temperature bar from Contact Temperature Part is the process in cooling) technique in, can be prepared by cyclodextrin and lecithin and be prepared different from traditional hydrogenation cream The novel artificial cream of mechanism, products obtained therefrom is smooth, satiny, mouthfeel is outstanding, and formed product is good, steady quality, organoleptic attribute On can wholly or in part substitute commercially available synthetic cream, key also resides in it and is free of trans-fatty acid.Inventors be surprised to learn that, by ovum Phosphatide and cyclodextrin are used as plural gel agent, the organoleptic feature except that can obtain conventional artificial's cream, can also reduce people Cholesterol level in body blood, embodies health-nutrition value, therefore this novel artificial cream has trophism and feature concurrently. Novel artificial cream obtained by the present invention, has broken the barrier of conventional art, has been greatly facilitated scientific progress with development.
Preparation method operation of the invention is very easy, and the traditional hydrogenation equipment of breakthrough and hydrogenation process are very difficult to By the limitation of content of trans fatty acids reduction, hydrogenated without new catalyst, Electrochemical hydriding reaction or supercritical fluid anti- Should, to equipment without particular/special requirement, it is very suitable for large-scale production.
Additional aspect of the invention and advantage will be set forth in part in the description, and will partly become from the following description Obtain substantially, or recognized by practice of the invention.
Brief description of the drawings
Fig. 1 shows the margarine two-arch tunnel structure chart of embodiments in accordance with the present invention 1;
Fig. 2 shows the margarine outside drawing of embodiments in accordance with the present invention 2;
Fig. 3 shows the margarine outside drawing of embodiments in accordance with the present invention 3;
Fig. 4 shows the margarine outside drawing of embodiments in accordance with the present invention 4.
Specific embodiment
Embodiments of the invention are described below in detail.The embodiments described below is exemplary, is only used for explaining this hair It is bright, and be not considered as limiting the invention.Unreceipted particular technique or condition in embodiment, according to text in the art Offer described technology or condition or carried out according to product description.Agents useful for same or the unreceipted production firm person of instrument, For can by city available from conventional products.
Material and reagent
Beta-schardinger dextrin, cyclodextrin:Henan Zhong Taishihua Co., Ltds
Lecithin:Jia Ji Asia-Pacific food system (Beijing) Co., Ltd
Refined rapeseed oil:Hubei Olympic star's cereal and oil industry Co., Ltd
Purified soyabean oil:Good fortune near the house, Cofco Group Co., Ltd.
Embodiment 1
With lecithin in mass ratio for form plural gel agent at 1: 1, the addition of plural gel agent is 4 matter to beta-schardinger dextrin Amount %.
2g cyclodextrin, 2g lecithin, 32g water and 64g purified soyabean oils are stirred and evenly mixed at 50 DEG C, it is permanent at being placed in 5 DEG C Temperature storage 48h, thus obtains margarine.
Margarine is observed using laser confocal microscope (100 times of multiplication factor), it is two-arch tunnel structure, it is such as attached Shown in Fig. 1.
Embodiment 2
With lecithin in mass ratio for form plural gel agent at 1: 1, the addition of plural gel agent is 4 matter to beta-schardinger dextrin Amount %.
2g beta-schardinger dextrins, 2g lecithin, 32g water and 64g refined rapeseed oils are stirred and evenly mixed at 80 DEG C, is placed at 5 DEG C Constant temperature stores 14h, thus obtains margarine.
Embodiment 3
Cyclodextrin (β-and gamma-cyclodextrin mixture), in mass ratio for form plural gel agent at 1: 4, is combined solidifying with lecithin The addition of jelly is 10 mass %.
2g cyclodextrin, 8g lecithin, 16g water and 74g purified soyabean oils are stirred and evenly mixed at 70 DEG C, it is permanent at being placed in 15 DEG C Temperature storage 22h, thus obtains margarine.
Embodiment 4
Cyclodextrin (α-, β-, gamma-cyclodextrin mixture) with lecithin in mass ratio for 5: 1 formed plural gel agent, be combined The addition of gel is 12 mass %.
10g cyclodextrin, 2g lecithin, 32g water and 56g refined rapeseed oils are stirred and evenly mixed at 80 DEG C, is placed at 10 DEG C Constant temperature stores 18h, thus obtains margarine.
In the description of the invention, it is to be understood that term " first ", " second " are only used for describing purpose, and can not It is interpreted as indicating or implying relative importance or the implicit quantity for indicating indicated technical characteristic.Thus, define " the One ", one or more this feature can be expressed or be implicitly included to the feature of " second ".In the description of the invention, " multiple " is meant that two or more, unless otherwise expressly limited specifically.
In the description of this specification, reference term " one embodiment ", " some embodiments ", " example ", " specifically show The description of example " or " some examples " etc. means to combine specific features, structure, material or spy that the embodiment or example are described Point is contained at least one embodiment of the invention or example.In this manual, to the schematic representation of above-mentioned term not Identical embodiment or example must be directed to.And, the specific features of description, structure, material or feature can be with office Combined in an appropriate manner in one or more embodiments or example.Additionally, in the case of not conflicting, the skill of this area Art personnel can be tied the feature of the different embodiments or example described in this specification and different embodiments or example Close and combine.
Although embodiments of the invention have been shown and described above, it is to be understood that above-described embodiment is example Property, it is impossible to limitation of the present invention is interpreted as, one of ordinary skill in the art within the scope of the invention can be to above-mentioned Embodiment is changed, changes, replacing and modification.

Claims (9)

1. a kind of margarine, including cyclodextrin and lecithin.
2. margarine according to claim 1, it is characterised in that the margarine further includes water and grease.
3. margarine according to claim 1, it is characterised in that the cyclodextrin is food grade cyclodextrin, including α- The mixture of one or more in cyclodextrin, beta-schardinger dextrin, gamma-cyclodextrin.
4. margarine according to claim 2, it is characterised in that the water be selected from pure water, ultra-pure water, distilled water, At least one in ion exchange water.
5. margarine according to claim 2, it is characterised in that the grease is refining vegetable oil, including soybean oil, In sunflower oil, corn oil, rapeseed oil, cottonseed oil, tea oil, peanut oil, rice bran oil, palm oil, sesame oil and olive oil extremely Few mixture of one or more.
6. margarine according to claim 1, it is characterised in that the total addition level of the cyclodextrin and the lecithin It is 1 mass %~20 mass % of the margarine gross mass;
Optional, the cyclodextrin is 1: 5~5: 1 with the mass ratio of the lecithin.
7. margarine according to claim 2, it is characterised in that the addition of the water is the total matter of the margarine 10 mass %~60 mass % of amount;
Optional, the addition of the grease is 20 mass %~89 mass % of the margarine gross mass.
8. a kind of method for preparing margarine as claimed in claim 1, it is characterised in that by the cyclodextrin, lecithin, water After contacting and stir with grease, stored under constant temperature.
9. preparation method according to claim 8, it is characterised in that the temperature of the contact is 50~80 degrees Celsius;
Optional, the constant temperature is 0~30 degree Celsius;
Optional, the time of the storage is 12~48 hours.
CN201710088967.3A 2017-02-20 2017-02-20 Margarine and preparation method thereof Active CN106900882B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107439705A (en) * 2017-07-31 2017-12-08 安徽恋尚你食品有限公司 A kind of low fat animals and plants margarine
CN109645144A (en) * 2019-01-31 2019-04-19 郑州轻工业学院 Novel non-hydrogenated margarine of one kind and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090311387A1 (en) * 2008-06-11 2009-12-17 Plank David W Hydrated fat piece compositions and dough articles made therefrom
CN106172876A (en) * 2014-09-09 2016-12-07 长谷川香料株式会社 For giving powdered oil compositions and the adding method thereof of breast local flavor

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090311387A1 (en) * 2008-06-11 2009-12-17 Plank David W Hydrated fat piece compositions and dough articles made therefrom
CN106172876A (en) * 2014-09-09 2016-12-07 长谷川香料株式会社 For giving powdered oil compositions and the adding method thereof of breast local flavor

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107439705A (en) * 2017-07-31 2017-12-08 安徽恋尚你食品有限公司 A kind of low fat animals and plants margarine
CN109645144A (en) * 2019-01-31 2019-04-19 郑州轻工业学院 Novel non-hydrogenated margarine of one kind and preparation method thereof

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Inventor after: Han Lijuan

Inventor after: Qi Yutang

Inventor after: Qi Chuang

Inventor after: Liu Sheng

Inventor after: Li Nannan

Inventor after: Zhang Weinong

Inventor after: Zhang Yanpeng

Inventor before: Han Lijuan

GR01 Patent grant
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TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20211126

Address after: Room b857, 659 MaoYuan Road, Fengxian District, Shanghai, 201499

Patentee after: SHANGHAI SHANGDIE INDUSTRIAL CO.,LTD.

Address before: No.68 Xuefu South Road, Changqing Garden, Hankou, Wuhan, Hubei, 440023

Patentee before: WUHAN POLYTECHNIC University

Effective date of registration: 20211126

Address after: 201400 NO.666, JinDou Road, Jinhui Town, Fengxian District, Shanghai

Patentee after: SHANGHAI HI-ROAD FOOD TECHNOLOGY Co.,Ltd.

Address before: Room b857, 659 MaoYuan Road, Fengxian District, Shanghai, 201499

Patentee before: SHANGHAI SHANGDIE INDUSTRIAL CO.,LTD.