CN106890666A - A kind of catalyst of hydrogen chloride Efficient Conversion preparing chlorine gas - Google Patents
A kind of catalyst of hydrogen chloride Efficient Conversion preparing chlorine gas Download PDFInfo
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- CN106890666A CN106890666A CN201710071523.9A CN201710071523A CN106890666A CN 106890666 A CN106890666 A CN 106890666A CN 201710071523 A CN201710071523 A CN 201710071523A CN 106890666 A CN106890666 A CN 106890666A
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- hydrogen chloride
- chlorine gas
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
- B01J29/26—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
- B01J29/20—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing iron group metals, noble metals or copper
- B01J29/24—Iron group metals or copper
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/01—Chlorine; Hydrogen chloride
- C01B7/03—Preparation from chlorides
- C01B7/04—Preparation of chlorine from hydrogen chloride
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
Abstract
The invention discloses a kind of catalyst of hydrogen chloride Efficient Conversion preparing chlorine gas, it is characterised in that complex catalyst precursor weight percentage composition is：Component A：70%~80%；Component B：5%~10%；Component C：1%~2%；Component D：0.1%~0.3%；Balance of SiO2；Wherein component A is Na type modenites；Component B is Cu2+；Component C is Fr+Or Cs+；Component D is Re3+Or Ir3+.Heavy oil hydrogenating treatment catalyst of the present invention is applied to hydrogen chloride high conversion and generates chlorine.
Description
Technical field
The invention belongs to catalyst field, and in particular to a kind of catalyst of hydrogen chloride Efficient Conversion preparing chlorine gas.
Background technology
Chlorine is a kind of important Elementary Chemical Industry raw material, be widely used in polyurethane, organosilicon, chlorinated hydrocabon, epoxy resin,
The new material industry such as chlorinated rubber, chlorinated high polymers, is applied to the new energy industries such as polysilicon manufacture, is applied to disinfectant, washes
Wash the life Fine Chemicals such as agent, food additives, cosmetic additive, be applied to synthetic glycerine, chlorobenzene series, monoxone,
Benzyl chloride, PCl3Deng agricultural chemicals/pharmaceuticals industry, and it is applied to the industries such as papermaking, weaving, metallurgical and petrochemical industry.
In the heavy oil hydrogenating treatment catalyst reported, active component is mainly using metallic elements such as copper, chromium, rutheniums.China
Patent CN101125297 is disclosed with silica as carrier, the catalysis of the containing copper chloride, potassium chloride and cerium chloride of phosphoric acid treatment
Agent, the catalyst is 1 in hydrogen chloride and oxygen molar ratio:1, fixed bed reactors temperature is 400 DEG C, and reaction pressure is
0.1Mpa, hydrogen chloride Feed space velocities are 0.8hr-1, the yield of product chlorine is 80.1%.Chinese patent CN101559374 is disclosed
With silica gel, ReY molecular sieves as carrier, the catalyst of load copper chloride, potassium chloride, manganese nitrate and cerous nitrate, hydrogen chloride with
Oxygen flow is 200m1/min, and catalyst amount is 25g, and reaction temperature is at 380 DEG C, the conversion ratio of hydrogen chloride is
83.6%.Above-mentioned Cu-series catalyst all has that reaction temperature is high, the problem of the volatile inactivation of active low and active component.It is Chinese special
Sharp CN87101999 is disclosed and is used SiO2It is carrier, unbodied Cr in catalyst2O3Content be 20%~90%.Process
Using fluidized-bed reactor, in 370~420 DEG C of operations, O2/ HCl is 0.3~0.75, and conversion ratio is 75~80%.Chromium system is catalyzed
Agent there is also reaction temperature low problem high and active, and easily produce iron (or a small amount of nickel and titanium) poisoning, in practical application
In it is high to the requirement of the making material of reactor, it is necessary to using a kind of iron-holder 1% (weight) or lower material as anti-
Equipment material is answered, device fabrication expense is too high.Document (Zhang Jun an ancient unit of weight, catalytic oxidation of hydrogen chloride for preparing chlorine gas technical progress, Chinese chlor-alkali
[J], 2013 (5):Point out that SUMITOMO CHEMICAL chemical industry Co., Ltd. discloses one kind with RuO in 6-10)2It is the catalysis of major constituent
Agent.The catalyst is load with titanium oxide, zirconium oxide, aluminum oxide or zeolite etc., wherein, with rutile TiO2Urged when doing carrier
Change efficiency highest, ruthenium is 2%~6% relative to the quality ratio of carrier, it is also possible to add the third composition beyond ruthenium, such as
Palladium, copper compound, chromium compound, vfanadium compound, rare earth compound and alkali metal compound etc..Reaction uses fixed bed reaction
Device, reaction temperature is 200~380 DEG C, and reaction pressure is 101.33~55066.5kPa.The molar feed ratio of hydrogen chloride and oxygen is
0.05~1.25.Under atmospheric pressure and 20~1000/h space velocities, up to 95.9%, the catalyst makes the conversion ratio of hydrogen chloride
Can exceed 16000h with the life-span.The catalyst contains noble metal component, and the catalysis activity of catalyst can be with the duration of runs
Extension gradually reduce, the also easy irreversibility caused by the error in the impurity and operational process of craft in chlorination hydrogen feedstock
It is poisoned and inactivates.The problem that above-mentioned catalyst is present, the serious process of industrialization that must hinder hydrogen chloride Efficient Conversion preparing chlorine gas.
The content of the invention
For defect or deficiency that background technology is present, a kind of present invention low temperature active of offer is high, mithridatism is good, low cost
With the catalyst of the hydrogen chloride Efficient Conversion preparing chlorine gas of long lifespan.
The present invention is modified on the basis of copper-based active component by adding alkali metal and noble metal, and by fluorine
Change hydrogen and SiO2Reaction generation gas SiF4, while a large amount of low temperature active positions are produced in the catalyst, so as to improve catalyst performance
Can, so as to prepare the catalyst of hydrogen chloride Efficient Conversion preparing chlorine gas.
A kind of catalyst of hydrogen chloride Efficient Conversion preparing chlorine gas, its forerunner's weight percentage composition is：Component A：70%~
80%；Component B：5%~10%；Component C：1%~2%；Component D：0.1%~0.3%；Balance of SiO2；Wherein component A is
Na- type modenites；Component B is Cu2+；Component C is Fr+Or Cs+；Component D is Re3+Or Ir3+；Prepare by the following method：
A) by commercially available Na- type modenites, add 0.6mol/L the NaOH aqueous solution in, Na- types modenite with
The mass ratio of the NaOH aqueous solution is 1:4, it is heated to backflow, stirring reaction 2h, filtering, washing to PH=7, drying, 350 DEG C of roastings
Treatment 6h, obtains component A；
B) the component A obtained by step a) is added to and contains Cu2+The aqueous solution in, component A and Cu2+The quality of the aqueous solution
Than being 1:10, stir 15min；
C) Fr will be contained+Or Cs+The aqueous solution add the aqueous solution obtained by above-mentioned steps b), component A and Fr+Or Cs+Water
The mass ratio of solution is 1:1, stir 15min；
D) Re will be contained3+Or Ir3+The aqueous solution add the aqueous solution obtained by above-mentioned steps c), component A and Re3+Or Ir3+
The mass ratio of the aqueous solution is 1:0.5,80 DEG C of dipping 8h, filtering, washing, drying；
E) material and SiO obtained by step d)2Well mixed, particle diameter is adjusted to 12~18.5 mesh, the catalyst by granulation
Presoma under the conditions of 400 DEG C of temperature, calcination process 8h；
F) by step e) resulting materials in a nitrogen atmosphere, reacted with hydrogen fluoride, nitrogen and hydrogen fluoride mol ratio 20:
1, hydrogen fluoride and step e) resulting materials mass ratio 1:20, reaction pressure 1atm, 330 DEG C of reaction temperature, reaction time 2h obtain high
The hydrogen chloride preparing chlorine gas catalyst of conversion ratio.
The catalyst of hydrogen chloride Efficient Conversion preparing chlorine gas of the present invention is used in various types of reactors, such as fixed
Bed, the anti-device of fluid bed, trickle bed or slurry bed system etc., preferably fixed bed.
The catalyst of hydrogen chloride Efficient Conversion preparing chlorine gas of the present invention reacts for catalytic oxidation of hydrogen chloride for preparing chlorine gas,
Reacted at 80 DEG C~600 DEG C, reacted at preferably 200~250 DEG C.
Advantages of the present invention is as follows：
(1) hydrogen chloride Efficient Conversion preparing chlorine gas catalyst low-temperature activity of the invention is high, can just be reached in 220 DEG C of conversion ratios
To 99.1%.The reduction of temperature reduces equipment investment, and conversion ratio is improved and reduces operating cost so that remarkable in economical benefits is carried
It is high.
(2) hydrogen chloride Efficient Conversion preparing chlorine gas catalyst mithridatism of the invention is strong, will not iron poisoning.
(4) hydrogen chloride Efficient Conversion preparing chlorine gas catalyst of the invention is with low cost using base metals such as copper.
(5) hydrogen chloride Efficient Conversion preparing chlorine gas catalyst life of the invention was long, up to 25000 hours.
Specific embodiment
According to the technical scheme in the present invention, preparing chlorine by oxidizing hydrogen chloride catalyst activity evaluating apparatus are common fixed bed
Tubular reactor, reactor size isMaterial carbon steel.Catalyst packing is entered into reaction
Device, is heated to reaction temperature, and gas is by pressure-reducing valve and flowmeter rear feeding, sampling analysis after stabilization reaction.
Catalyst activity evaluation experimental condition：220 DEG C of reaction temperature, hydrogen chloride is 4 with the mol ratio/volume ratio of oxygen:
1, the inlet amount of hydrogen chloride is 200mL/min, and catalyst is 2g, reaction pressure normal pressure.Oxidation reactor outlet be mainly chlorine,
The mixture of oxygen, hydrogen chloride and water vapour, analyzes chlorine content therein and calculates the generation of chlorine in intervals
Amount, it is possible to calculate the conversion ratio of oxidation reaction, to investigate the activity of catalyst and the affecting laws of oxidation reaction condition.
According to the principle that chlorine is easily absorbed by liquor kalii iodide, in other words using the reproducibility of iodide ion, determining has oxygen
The amount of the chlorine of the property changed.When gas sample is passed through liquor kalii iodide, chlorine is absorbed, and displaces iodine, and the iodine of precipitation is again with thio
Sulfuric acid sodium standard solution is titrated, and this is iodimetric titration (or indirect iodometric processes, iodometry).Titration process is using starch as finger
Show agent.Because HCl is highly soluble in water, so in Cl2While absorption by KI solution, HCl is also absorbed simultaneously.Use thiosulfuric acid
After sodium solution titration terminates, the amount of HCl, the titrimetry phenolphthalein indicator can be titrated with standard solution of sodium hydroxide.
Concrete operation step is as follows：After system stable operation, a 20% KI solution is prepared at regular intervals
100ml, switching oxidation reactor outlet triple valve, mixed gas after reaction are passed into (100ml) liquor kalii iodide of constant volume
In, absorb 3 minutes, by absorbing liquid immigration conical flask after absorption, titrated with the sodium thiosulfate standard solution of 0.1mol/l, with
Starch makees indicator；Followed by, with phenolphthalein indicator, titrated with 0.1mol/l standard solution of sodium hydroxide unreacted
HC1。
HCl conversion ratios：
Conv%=b/ (b+d) * 100%
B represents that titration consumes Na2S2O3Solution milliliter number, ml
D represents that titration consumes NaOH solution milliliter number, ml
The present invention is described in further details with reference to embodiment, but is not limited to the scope of the invention.
Embodiment 1
The catalyst precursor percentage by weight of embodiment 1 is as follows：
Balance of SiO2The Na- type modenites that wherein component A is processed for the NaOH aqueous solution of 0.6mol/L；Component B is
Cu2+；Component C is Fr+；Component D is Re3+
The catalyst of the present embodiment is prepared by the following method.
A) by commercially available Na- type modenites, add 0.6mol/L the NaOH aqueous solution in, Na- types modenite with
The mass ratio of the NaOH aqueous solution is 1:4, it is heated to backflow, stirring reaction 2h, filtering, washing to PH=7, drying, 350 DEG C of roastings
Treatment 6h, obtains component A；
B) the component A obtained by step a) is added to and contains Cu2+The aqueous solution in, component A and Cu2+The quality of the aqueous solution
Than being 1:10, stir 15min；
C) Fr will be contained+The aqueous solution add the aqueous solution obtained by above-mentioned steps b), component A and Fr+The quality of the aqueous solution
Than being 1:1, stir 15min；
D) Re will be contained3+The aqueous solution add the aqueous solution obtained by above-mentioned steps c), component A and Re3+The matter of the aqueous solution
Amount is than being 1:0.5,80 DEG C of dipping 8h, filtering, washing, drying；
E) material and SiO obtained by step d)2Well mixed, particle diameter is adjusted to 12~18.5 mesh, the catalyst by granulation
Presoma under the conditions of 400 DEG C of temperature, calcination process 8h；
F) by step e) resulting materials in a nitrogen atmosphere, reacted with hydrogen fluoride, nitrogen and hydrogen fluoride mol ratio 20:
1, hydrogen fluoride and step e) resulting materials mass ratio 1:20, reaction pressure 1atm, 330 DEG C of reaction temperature, reaction time 2h obtain high
The hydrogen chloride preparing chlorine gas catalyst of conversion ratio is labeled as CatA.
Comparative example 1
The catalyst precursor percentage by weight of embodiment 1 with embodiment 1, preparation method with embodiment 1, except that
Comparative example 1 does not have step f, and obtained catalyst is labeled as CatA0.
Embodiment 2
The catalyst precursor percentage by weight of embodiment 2 is as follows：
Balance of SiO2
The Na- type modenites that wherein component A is processed for the NaOH aqueous solution of 0.6mol/L；Component B is Cu2+；Component C is
Cs+；Component D is Ir3+
The preparation method of the catalyst of the present embodiment is with embodiment 1, except that component C is Cs+；Component D is Ir3+,
Obtained catalyst is labeled as CatB.
Embodiment 3
The catalyst precursor percentage by weight of embodiment 3 is as follows：
Balance of SiO2
The Na- type modenites that wherein component A is processed for the NaOH aqueous solution of 0.6mol/L；Component B is Cu2+；Component C is
Cs+；Component D is Ir3+
The preparation method of the catalyst of the present embodiment is with embodiment 1, except that component C is Cs+；Component D is Ir3+,
Obtained catalyst is labeled as CatC.
Embodiment 4
The catalyst precursor percentage by weight of embodiment 4 is as follows：
Balance of SiO2
The Na- type modenites that wherein component A is processed for the NaOH aqueous solution of 0.6mol/L；Component B is Cu2+；Component C is
Fr+；Component D is Ir3+
The preparation method of the catalyst of the present embodiment is with embodiment 1, except that component C is Fr+；Component D is Ir3+,
Obtained catalyst is labeled as CatD.
Embodiment 5
The catalyst precursor percentage by weight of embodiment 5 is as follows：
Balance of SiO2
The Na- type modenites that wherein component A is processed for the NaOH aqueous solution of 0.6mol/L；Component B is Cu2+；Component C is
Fr+；Component D is Re3+
The preparation method of the catalyst of the present embodiment is with embodiment 1, except that component C is Fr+；Component D is Re3+,
Obtained catalyst is labeled as CatE.
Embodiment 6
The catalyst precursor percentage by weight of embodiment 6 is as follows：
Balance of SiO2
The Na- type modenites that wherein component A is processed for the NaOH aqueous solution of 0.6mol/L；Component B is Cu2+；Component C is
Cs+；Component D is Re3+
The preparation method of the catalyst of the present embodiment is with embodiment 1, except that component C is Cs+；Component D is Re3+,
Obtained catalyst is labeled as CatF.
Embodiment 7
The catalyst precursor percentage by weight of embodiment 7 is as follows：
Balance of SiO2
The Na- type modenites that wherein component A is processed for the NaOH aqueous solution of 0.6mol/L；Component B is Cu2+；Component C is
Cs+；Component D is Re3+
The preparation method of the catalyst of the present embodiment is with embodiment 1, except that component C is Cs+；Component D is Re3+,
Obtained catalyst is labeled as CatG.
The application of the catalyst of hydrogen chloride Efficient Conversion preparing chlorine gas of the invention：
By the hydrogen chloride reforming catalyst CatA of the high conversion prepared by embodiment 1~7, CatB, CatC, CatD,
CatE, CatF, CatG are loaded into fixed-bed tube reactor, are reacted, and reaction result is shown in Table 1.
The catalyst reaction result of table 1
Claims (2)
1. a kind of catalyst of hydrogen chloride Efficient Conversion preparing chlorine gas, its forerunner's weight percentage composition is：Component A：70%~
80%；Component B：5%~10%；Component C：1%~2%；Component D：0.1%~0.3%；Balance of SiO2；Wherein component A is
Na- type modenites；Component B is Cu2+；Component C is Fr+Or Cs+；Component D is Re3+Or Ir3+；It is characterized in that according to following sides
It is prepared by method：
A) by commercially available Na- type modenites, in adding the NaOH aqueous solution of 0.6mol/L, Na- types modenite and NaOH water
The mass ratio of solution is 1:4, it is heated to backflow, stirring reaction 2h, filtering, washing to PH=7, drying, 350 DEG C of calcination process
6h, obtains component A；
B) the component A obtained by step a) is added to and contains Cu2+The aqueous solution in, component A and Cu2+The mass ratio of the aqueous solution is 1:
10, stir 15min；
C) Fr will be contained+Or Cs+The aqueous solution add the aqueous solution obtained by above-mentioned steps b), component A and Fr+Or Cs+The aqueous solution
Mass ratio be 1:1, stir 15min；
D) Re will be contained3+Or Ir3+The aqueous solution add the aqueous solution obtained by above-mentioned steps c), component A and Re3+Or Ir3+It is water-soluble
The mass ratio of liquid is 1:0.5,80 DEG C of dipping 8h, filtering, washing, drying；
E) material and SiO obtained by step d)2Well mixed, particle diameter is adjusted to 12~18.5 mesh, the complex catalyst precursor by granulation
Body under the conditions of 400 DEG C of temperature, calcination process 8h；
F) by step e) resulting materials in a nitrogen atmosphere, reacted with hydrogen fluoride, nitrogen and hydrogen fluoride mol ratio 20:1, fluorine
Change hydrogen and step e) resulting materials mass ratio 1:20, reaction pressure 1atm, 330 DEG C of reaction temperature, reaction time 2h obtain conversion high
The hydrogen chloride preparing chlorine gas catalyst of rate.
2. a kind of application of the catalyst of hydrogen chloride Efficient Conversion preparing chlorine gas as claimed in claim 1, it is characterised in that for chlorine
Change hydrogen catalysis oxidation preparing chlorine gas reaction.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710071523.9A CN106890666B (en) | 2017-02-09 | 2017-02-09 | A kind of catalyst of hydrogen chloride Efficient Conversion preparing chlorine gas |
| PCT/CN2017/076452 WO2018145345A1 (en) | 2017-02-09 | 2017-03-13 | Catalyst for efficient conversion of hydrogen chloride to produce chlorine gas |
Applications Claiming Priority (1)
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| CN201710071523.9A CN106890666B (en) | 2017-02-09 | 2017-02-09 | A kind of catalyst of hydrogen chloride Efficient Conversion preparing chlorine gas |
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| CN106890666B (en) | 2019-06-28 |
| WO2018145345A1 (en) | 2018-08-16 |
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