CN106890575A - A kind of regenerated offline device of ceramic membrane - Google Patents

A kind of regenerated offline device of ceramic membrane Download PDF

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Publication number
CN106890575A
CN106890575A CN201710164811.9A CN201710164811A CN106890575A CN 106890575 A CN106890575 A CN 106890575A CN 201710164811 A CN201710164811 A CN 201710164811A CN 106890575 A CN106890575 A CN 106890575A
Authority
CN
China
Prior art keywords
ceramic membrane
ceramic
membrane
air outlet
device body
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710164811.9A
Other languages
Chinese (zh)
Inventor
朱宣
陆涛
周莉
丁恺
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nanjing Sinoma Water Co Ltd
Original Assignee
Nanjing Sinoma Water Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nanjing Sinoma Water Co Ltd filed Critical Nanjing Sinoma Water Co Ltd
Publication of CN106890575A publication Critical patent/CN106890575A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D65/00Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
    • B01D65/02Membrane cleaning or sterilisation ; Membrane regeneration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/12Activated sludge processes
    • C02F3/1236Particular type of activated sludge installations
    • C02F3/1268Membrane bioreactor systems
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/16Regeneration of sorbents, filters
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

Abstract

The invention provides a kind of regenerated offline device of ceramic membrane, including device body, hot blast heating cooking stove, blower fan and ceramic diaphragm plummer;The air inlet of the hot blast heating cooking stove air outlet connecting fan, the air outlet communication apparatus body of blower fan, and blown in device body, device body build-in cavities, open and close door is provided with, ceramic diaphragm plummer passes through open and close door in-out apparatus body, and positioned at the top of air outlet.The beneficial effects of the present invention are:Simple structure, the ceramic membrane regeneration plant has safe and reliable, operation is efficient, low-loss feature, when the device occurs decaying or cannot still recovering after on-line cleaning for membrane flux when line is runed, by the drying and dewatering to ceramic diaphragm and burning diaphragm, the pollutant of membrane removal surface attachment can effectively be removed, realize that the thorough regeneration of ceramic film component under offline mode recovers, and improve the contamination resistance of plate membrane bioreactor, avoid the structural damage and damage easily occurred under general soda acid cleaning method, and solve ceramic membrane chronicity is dirty stifled cannot Chemical cleaning thoroughly situation.

Description

A kind of regenerated offline device of ceramic membrane
Technical field
The present invention relates to a kind of regenerated offline device of ceramic membrane.
Background technology
Ceramic membrane bioreactor is that Flat Membrane is placed in reactor, and growth of microorganism need are met by being aerated keeping Will, and then remove pollutant.This treatment technology can meet various sewage treatment process.And the fouling membrane for bringing therewith can be caused The consequences such as flux depression, producing water ratio reduction.To mitigate fouling membrane degree, offline or in-site chemical cleaning, but warp is usually taken After crossing long-term use, even if long-term cleaning still occurs the decay of film energy so that system can not meet processing requirement.At this moment only Have by offline means to realize the recovery of membrane flux, it is predominantly by the chemical cleaning method of liquid medicine immersion but this clear The mode of washing is possible to damage diaphragm structure, makes diaphragm generation bulging or internal structure impaired, and consume a large amount of chemicals. How to make ceramic membrane in regenerative process, and on the premise of protecting ceramic structure, easily and reliably realize reverting to for membrane flux For the forward position research direction of ceramic membrane bioreactor.
For the cleaning and regeneration of ceramic membrane, existing patent is reported, various patent reports soda acid alternative method is to ceramics Film carries out regeneration washing, such as patent CN102847442A, patent CN202237817U, patent CN102512967A, although soda acid The composition design of liquid is different, but this kind of method has certain infringement to ceramic membrane, and individual method is primarily adapted for use in tubular porous pottery Porcelain film;Also there is a method that patent report removes impurity in ceramic membrane micropore using compressed air, such as patent CN202237817U, The validity of this kind of method can not be completely secured.Comprehensive existing Patent data is it can be found that existing ceramic membrane major part is used With the off-line cleaning method that chemical agent is carried out, these methods may be more or less to the internal capillary ceramic structure of ceramic membrane Ground produces permanent damage, and then influences the service life of ceramic membrane.Therefore, research one kind efficient, low can damage ground cleaning and put down Plate ceramic membrane bioreactor, and the method for extending the ceramic membrane Effective Operation time limit, as ceramic membrane regenerated offline engineering technology Emphasis and difficult point.
The content of the invention
The technical problem to be solved in the present invention is cleaning and regeneration in the prior art for ceramic membrane, is replaced using soda acid more Method is cleaned, and easily produces the problem of irreversible damage in itself to ceramic membrane.
In order to solve the above-mentioned technical problem, the invention provides a kind of regenerated offline device of ceramic membrane, including device sheet Body, hot blast heating cooking stove, blower fan and ceramic diaphragm plummer;The air inlet of the air outlet connecting fan of the hot blast heating cooking stove, The air outlet communication apparatus body of blower fan, and blown in device body, device body build-in cavities are provided with open and close door, ceramics Diaphragm plummer passes through open and close door in-out apparatus body, and positioned at the top of air outlet.
When the present apparatus occurs decaying or cannot still recovering after on-line cleaning for membrane flux when line is runed, by pottery The drying and dewatering of porcelain diaphragm and diaphragm is burned, can effectively remove the pollutant of membrane removal surface attachment, realize ceramic membrane under offline mode The thorough regeneration of component recovers, and improve the contamination resistance of plate membrane bioreactor, it is to avoid clear in general soda acid The structural damage and damage easily occurred under washing method, and solve ceramic membrane chronicity is dirty stifled cannot Chemical cleaning Thoroughly situation.
Further preferred scheme is that described device body interior also sets and circulating ventilation pipe, the air-out of circulating ventilation pipe The air inlet of mouth connecting fan, circulation airduct with the lingering remnants of past customs of absorption plant body, and can be followed with the blower fan formation outside device body Ring air channel, can to carry out high temperature constant temperature to ceramic diaphragm degerming with significantly more efficient;
Further preferred scheme is that the hot blast heating cooking stove further comprises stable-pressure device, self-checking device, combustion fan, Stable-pressure device controls combustion chamber operational by self-checking device;
Further preferred scheme is that the outer connected control system of the regenerating unit, control system controls hot blast heating cooking stove and wind Machine is heated and air-supply;
Further preferred scheme is that instrument board is set on described device body, the signal output part connection control system of instrument board System;
Above-mentioned control system completes Automated condtrol by PLC system control;
Further preferred scheme is that described device body is provided with more than one exhaust outlet, and exhaust is opened after end-of-job Mouthful
The beneficial effects of the present invention are:
(1)The present apparatus changes the traditional approach decontaminated by soda acid alternative method cleaning ceramic diaphragm, by the way of heating, can Effectively to remove the pollutant of ceramic diaphragm, conventional sludge adhesion membrane surface is solved, it is impossible to solve by cleaning way Block the difficulty in duct.
(2)The present apparatus removes the pollutant of diaphragm by physical means, can reduce such as Chemical cleaning, easily causes The damage of diaphragm ceramic structure, and thus may cause scrapping for diaphragm.
(3)By the application of the present apparatus, it is possible to reduce the general chemical reagent consumed using Chemical cleaning diaphragm, use It is convenient and easy, be conducive to popularization and application.
Brief description of the drawings
Fig. 1 is structural representation of the invention.
Fig. 2 is the structural representation of hot blast heating cooking stove of the invention.
Specific embodiment
As shown in Figure 1 and Figure 2, a kind of regenerated offline device of ceramic membrane, including device body 1, hot blast heating cooking stove 6, blower fan 7 and ceramic diaphragm plummer 3;The air inlet of the air outlet connecting fan 7 of the hot blast heating cooking stove 6, the air outlet connection of blower fan 7 Device body 1, and blown in device body 1, the build-in cavities of device body 1 are provided with circulating ventilation pipe 2, device sheet in cavity Body 1 is externally provided with the exhaust outlet 5 of open and close door 8 and more than 1, the air inlet of the air outlet connecting fan 7 of circulating ventilation pipe 2, pottery Porcelain diaphragm plummer 3 is additionally provided with instrument by the in-out apparatus body 1 of open and close door 8 on the top of air outlet, device body 1 Dial plate 4, hot blast heating cooking stove 6 and blower fan 7 are all connected with control system, and control system is focused on by PLC is programmable;Described hot blast Burner 6-1 is provided with the air outlet of heating cooking stove 6, stable-pressure device 6-3, self-checking device, combustion fan, voltage stabilizing dress is further comprises Put and control combustion chamber 6-2 to work by self-checking device, also through PLC system control;
The course of work of the present apparatus is:Divide following 3 stages:
First stage:Intensification drying stage
90 DEG C, and constant 1 hour or so are progressively warming up to after igniting in hot blast heating cooking stove 6, heat is delivered to ceramics by hot blast Membrane surface so that the hygroscopic water of surface and inside is evaporated and surface temperature maintains stabilization, is slowly completed moisture evaporation, this process In, it is impossible to rapidly heat up, prevent water vapour rapid evaporation, cause structural damage.
Second stage:At the uniform velocity heat up and the constant temperature stage
Transmitted by hot blast after the completion of evaporating the surface of ceramic membrane and internal moisture.Development is at the uniform velocity warming up to 200 DEG C, and permanent Temperature 2 hours or so, treats that partial contamination thing volatilizees;400 DEG C, and constant temperature 1 hour or so are at the uniform velocity warming up to again;Finally about 600 DEG C, constant temperature 1 hour or so.After constant temperature several times works, the pollutant of diaphragm is volatilized substantially and burn clean.
Phase III:The cooling and drying stage
With the carrying out of heat transfer, when membrane surface with it is internal there is no moisture and pollutant after, unnecessary heat can be by Its surface is delivered to inside by heat transfer, diaphragm is internally formed thermograde, to ensure state of the diaphragm by the rapidly temperature difference And deform and damage.After constant temperature terminates, cause that the inside and outside of diaphragm under less thermograde, is released by cooling slowly Thermal discharge, until normal temperature range, completes whole operation process.Such as occur a small amount of pollutant it is serious dirty stifled and it is incomplete The phenomenon of removing, with During Repeated Heating, and can lengthen high temperature section constant temperature time.
The beneficial effects of the present invention are:Simple structure, the ceramic membrane regeneration plant have it is safe and reliable, operation efficiently, Low-loss feature, when the device occurs decaying or cannot still recovering after on-line cleaning for membrane flux when line is runed, leads to Cross to the drying and dewatering of ceramic diaphragm and burn diaphragm, can effectively remove the pollutant of membrane removal surface attachment, under realizing offline mode The thorough regeneration of ceramic film component recovers, and improve the contamination resistance of plate membrane bioreactor, it is to avoid general The structural damage and damage easily occurred under soda acid cleaning method, and solve ceramic membrane and cannot change chronicity is dirty stifled Learn cleaning thoroughly situation.

Claims (6)

1. the regenerated offline device of a kind of ceramic membrane, it is characterised in that:Including device body, hot blast heating cooking stove, blower fan and pottery Porcelain diaphragm plummer;The air inlet of the air outlet connecting fan of the hot blast heating cooking stove, the air outlet communication apparatus body of blower fan, And blown in device body, device body build-in cavities are provided with open and close door, and ceramic diaphragm plummer is passed in and out by open and close door and filled Body is put, and positioned at the top of air outlet.
2. the regenerated offline device of ceramic membrane according to claim 1, it is characterised in that:Described device body interior also sets With circulating ventilation pipe, the air inlet of the air outlet connecting fan of circulating ventilation pipe.
3. the regenerated offline device of ceramic membrane according to claim 1 and 2, it is characterised in that:The hot blast heating cooking stove is also Stable-pressure device, self-checking device, combustion fan are included, stable-pressure device controls combustion chamber operational by self-checking device.
4. the regenerated offline device of ceramic membrane according to claim 3, it is characterised in that:The external control of regenerating unit System, control system control hot blast heating cooking stove and blower fan heating and air-supply.
5. the regenerated offline device of ceramic membrane according to claim 4, it is characterised in that:Instrument is set on described device body Dial plate, the signal output part connection control system of instrument board.
6. the regenerated offline device of the ceramic membrane according to claim 5, it is characterised in that:Described device body is provided with one Exhaust outlet more than individual.
CN201710164811.9A 2017-01-09 2017-03-20 A kind of regenerated offline device of ceramic membrane Pending CN106890575A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201710013176 2017-01-09
CN2017100131764 2017-01-09

Publications (1)

Publication Number Publication Date
CN106890575A true CN106890575A (en) 2017-06-27

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Country Status (1)

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CN (1) CN106890575A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107617339A (en) * 2017-09-28 2018-01-23 兴源环境科技股份有限公司 A kind of NEW TYPE OF COMPOSITE silicon carbide film element and its electric heating cleaning
CN113975972A (en) * 2021-11-10 2022-01-28 江苏久朗高科技股份有限公司 Regeneration method of silicon carbide film for active coke regeneration process
CN115155314A (en) * 2022-08-01 2022-10-11 重庆聚狮新材料科技有限公司 Membrane filtration equipment of polyphenylene sulfide separation device and regeneration method thereof

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CN103983011A (en) * 2014-04-14 2014-08-13 兰州泰得燃烧设备工程有限公司 Device for generating circulating hot air
CN104755155A (en) * 2012-11-01 2015-07-01 日本碍子株式会社 Zeolite membrane regeneration method
JP2015181965A (en) * 2014-03-20 2015-10-22 日本碍子株式会社 Regeneration method and regeneration apparatus
WO2016027713A1 (en) * 2014-08-21 2016-02-25 日本碍子株式会社 Separation device and regeneration method
CN205316838U (en) * 2015-12-29 2016-06-15 贵州华安堂药业有限公司 Efficient heated air circulation stoving case
CN206631443U (en) * 2017-01-09 2017-11-14 南京中材水务股份有限公司 A kind of regenerated offline device of ceramic membrane

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104755155A (en) * 2012-11-01 2015-07-01 日本碍子株式会社 Zeolite membrane regeneration method
US20150224487A1 (en) * 2012-11-01 2015-08-13 Ngk Insulators, Ltd. Zeolite membrane regeneration method
JP2015181965A (en) * 2014-03-20 2015-10-22 日本碍子株式会社 Regeneration method and regeneration apparatus
CN103983011A (en) * 2014-04-14 2014-08-13 兰州泰得燃烧设备工程有限公司 Device for generating circulating hot air
WO2016027713A1 (en) * 2014-08-21 2016-02-25 日本碍子株式会社 Separation device and regeneration method
CN205316838U (en) * 2015-12-29 2016-06-15 贵州华安堂药业有限公司 Efficient heated air circulation stoving case
CN206631443U (en) * 2017-01-09 2017-11-14 南京中材水务股份有限公司 A kind of regenerated offline device of ceramic membrane

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107617339A (en) * 2017-09-28 2018-01-23 兴源环境科技股份有限公司 A kind of NEW TYPE OF COMPOSITE silicon carbide film element and its electric heating cleaning
CN113975972A (en) * 2021-11-10 2022-01-28 江苏久朗高科技股份有限公司 Regeneration method of silicon carbide film for active coke regeneration process
CN113975972B (en) * 2021-11-10 2024-01-19 江苏久朗高科技股份有限公司 Regeneration method of silicon carbide film for active coke regeneration process
CN115155314A (en) * 2022-08-01 2022-10-11 重庆聚狮新材料科技有限公司 Membrane filtration equipment of polyphenylene sulfide separation device and regeneration method thereof

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Application publication date: 20170627