CN106883686A - A kind of preparation method of high accuracy RFID antenna electrically conductive ink - Google Patents

A kind of preparation method of high accuracy RFID antenna electrically conductive ink Download PDF

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Publication number
CN106883686A
CN106883686A CN201710287348.7A CN201710287348A CN106883686A CN 106883686 A CN106883686 A CN 106883686A CN 201710287348 A CN201710287348 A CN 201710287348A CN 106883686 A CN106883686 A CN 106883686A
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rfid antenna
nano
silver
ink
nano silver
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陈广学
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Dongguan Yong Huahao Information Technology Co Ltd
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Dongguan Yong Huahao Information Technology Co Ltd
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Priority to CN201710287348.7A priority Critical patent/CN106883686A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/101Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/52Electrically conductive inks

Abstract

A kind of preparation method of high accuracy RFID antenna electrically conductive ink, comprises the following steps:(1)It is 3 to weigh mass ratio:2:1 flake nano Argent grain, ball shaped nano Argent grain and linear nano silver, are dissolved in solvent and filter acquisition uniform solution;(2)Will(1)In obtained ethanol and ethyl acetate mixed solvent nano silver dispersion added in mixed solvent, and add 2 parts of light triggers, 0.5 part of levelling agent, 0.5 part of polymerization inhibitor;(3)Will be through with drum-type silk-screen printing(1)With(2)The UV LED Nano silver conductive inks of acquisition print RFID antenna on paper;(4)Be placed in the layer of ink after solidification in vacuum drying oven nitrogen atmosphere according to 12 minutes to solidification by the RFID antenna picture and text circuit that will be printed UV LED lamplights, and less than 50 DEG C continue 4h.Printed RFID antenna lines are fluent, and edge is bright and clean, impulse- free robustness, and high conductivity performance can be obtained after simple sintering.

Description

A kind of preparation method of high accuracy RFID antenna electrically conductive ink
Technical field
The present invention relates to RFID conductive antenna printing technologies field, more particularly to a kind of high accuracy RFID antenna conductive oil The preparation method of ink.
Background technology
RFID is being supplied as a kind of non-contact automatic identification technology received by electromagnetic conversion with transmission signal The fields such as chain are widely applied, and accelerate the information transfer of each field difference link.Antenna is used as the important of rfid system Part, its printing method receives extensive concern.Current RFID antenna manufacturing technology mainly has copper conductor coiling, electro-coppering Paper tinsel, metal aluminum foil etching, electrically conductive ink print these four technologies, and for first three antcnnas manufacturing technology, conductive oil The conductive good, good reliability of method of the RFID label antenna of ink print, the low, production capacity of pollution are big.Many countries include U.S. State, Japan, Germany and South Korea have all started the research and development tide to electrically conductive ink.
It is in the majority with electrically conductive ink for ink-jet conductive ink and silk-screen printing in the research of electrically conductive ink, conductive material Predominantly metal_based material, including gold, silver, copper, platinum etc..The Nano Silver that electric conductivity is excellent and inoxidizability is strong receives much concern simultaneously It is widely studied.Because the mode of ink-jet is restricted by shower nozzle, material therefor is typically limited to spheric granules, it is difficult to which it is right to realize The printing of the preferable sheet of electric conductivity and filamentary material.This problem has been captured using the silk-screen printing of mesh transfer ink. Conductive filler is usually the mixture of sheet and spherical Nano Silver in silk-screen printing, using face contact and the spherical particle of sheet Filling effect reaches high conduction performance requirement, is further to improve electric conductivity, adds linear nano silver to increase conductive path.
More abundant, excellent so as to the ensure that layer of ink electric conductivity of layer of ink of silk-screen printing printing, but fail instantaneous solidification The diffusion that dry thick layer of ink easily causes ink is sprawled, so as to influence the printing precision of RFID conductive antennas.
The Chinese patent of Publication No. CN106189525A discloses a kind of electrically conductive ink for RFID antenna printing, category In electrically conductive ink technical field, technical points include that the electrically conductive ink includes the raw material of following weight portion:Epoxy resin 20~ 30 parts;20~30 parts of terminal isocyanate group base polyurethane prepolymer for use as;40~60 parts of nano silver copper tungsten nickel particle;Acetylene carbon black 1 ~5 parts;10~30 parts of solvent;1~3 part of coupling agent;1~3 part of curing agent;0.5~2 part of dispersant.Practical application finds, above-mentioned Electrically conductive ink impressionability, precision, electric conductivity etc. are still poor, still need to further improvement.
The content of the invention
The purpose of the present invention, is the shortcoming and defect for overcoming prior art, and provides a kind of high accuracy RFID antenna and use The preparation method of electrically conductive ink.
In order to solve the above-mentioned technical problem, the present invention is addressed by following technical proposals:
A kind of preparation method of high accuracy RFID antenna electrically conductive ink, comprises the following steps:
(1)It is 3 to weigh mass ratio:2:1 flake nano Argent grain, ball shaped nano Argent grain and linear nano silver, and by 60 In 15 parts of ethanol and ethyl acetate mixed solvent, jitter time is 5-10 minutes to part silver powder mixture ultrasonic disperse, and filtering is obtained Obtain uniform solution;
(2)With 50g silver nitrates and 22.2g hydrazine hydrates as raw material, 9.8g polyvinylpyrrolidones (PVP) are protective agent, PVP and Ag The mol ratio 0.3 of salt:1, the dispersion liquid that chemical reduction reaction is obtained in water or alcohol system is settled three times using acetone, is discarded Layer clear liquid, adds mixed solvent ethylene glycol, isopropanol and propylene glycol monomethyl ether 20.04g to carry out redisperse, wherein mixed in lower sediment The mass ratio of bonding solvent ethylene glycol, isopropanol and propylene glycol monomethyl ether is 1:1:1, will(1)In obtained ethanol and ethyl acetate it is mixed Bonding solvent nano silver dispersion is added to wherein, and adds 2 parts of light triggers, 0.5 part of levelling agent, 0.5 part of polymerization inhibitor;
(3)Will be through with drum-type silk-screen printing(1)With(2)The UV-LED Nano silver conductive inks of acquisition print RFID on paper Antenna;
(4)The RFID antenna picture and text circuit that will be printed UV-LED light put the layer of ink after solidification according to 1-2 minutes to solidification In vacuum drying oven nitrogen atmosphere, less than 50 DEG C continue 4h.Printed RFID antenna lines are fluent, and edge is bright and clean, without hair Thorn, high conductivity performance can be obtained after simple sintering.
A kind of preparation method of high accuracy RFID antenna electrically conductive ink, comprises the following steps:
(1)It is 3 to weigh mass ratio:2:1 flake nano Argent grain, ball shaped nano Argent grain and linear nano silver, and by 65 In 12 parts of ethanol and ethyl acetate mixed solvent, jitter time is 5-10 minutes to part silver powder mixture ultrasonic disperse, and filtering is obtained Obtain uniform solution;
(2)With 50g silver nitrates and 22.2g hydrazine hydrates as raw material, 9.8g polyvinylpyrrolidones (PVP) are protective agent, PVP and Ag The mol ratio 0.3 of salt:1, the dispersion liquid that chemical reduction reaction is obtained in water or alcohol system is settled three times using acetone, is discarded Layer clear liquid, adds mixed solvent ethylene glycol, isopropanol and propylene glycol monomethyl ether 20.04g to carry out redisperse, wherein mixed in lower sediment The mass ratio of bonding solvent ethylene glycol, isopropanol and propylene glycol monomethyl ether is 1:1:1, will(1)In obtained ethanol and ethyl acetate it is mixed Bonding solvent nano silver dispersion is added to wherein, and adds 3 parts of light triggers, 1.0 parts of levelling agents, 0.5 part of polymerization inhibitor;
(3)Will be through with drum-type silk-screen printing(1)With(2)The UV-LED Nano silver conductive inks of acquisition print RFID on paper Antenna;
(4)The RFID antenna picture and text circuit that will be printed UV-LED light put the layer of ink after solidification according to 1-2 minutes to solidification In vacuum drying oven nitrogen atmosphere, less than 50 DEG C continue 4h.Printed RFID antenna lines are fluent, and edge is bright and clean, without hair Thorn, high conductivity performance can be obtained after simple sintering.
A kind of preparation method of high accuracy RFID antenna electrically conductive ink, comprises the following steps:
(1)It is 3 to weigh mass ratio:2:1 flake nano Argent grain, ball shaped nano Argent grain and linear nano silver, and by 55 In 10 parts of ethanol and ethyl acetate mixed solvent, jitter time is 5-10 minutes to part silver powder mixture ultrasonic disperse, and filtering is obtained Obtain uniform solution;
(2)With 50g silver nitrates and 22.2g hydrazine hydrates as raw material, 9.8g polyvinylpyrrolidones (PVP) are protective agent, PVP and Ag The mol ratio 0.3 of salt:1, the dispersion liquid that chemical reduction reaction is obtained in water or alcohol system is settled three times using acetone, is discarded Layer clear liquid, adds mixed solvent ethylene glycol, isopropanol and propylene glycol monomethyl ether 20.04g to carry out redisperse, wherein mixed in lower sediment The mass ratio of bonding solvent ethylene glycol, isopropanol and propylene glycol monomethyl ether is 1:1:1, will(1)In obtained ethanol and ethyl acetate it is mixed Bonding solvent nano silver dispersion is added to wherein, and adds 1 part of light trigger, 0.3 part of levelling agent, 1.0 parts of polymerization inhibitors;
(3)Will be through step with drum-type silk-screen printing(2)Obtained silver-colored electrically conductive ink prints RFID antenna on paper;
(4)The RFID antenna picture and text circuit that will be printed UV-LED light put the layer of ink after solidification according to 1-2 minutes to solidification In vacuum drying oven nitrogen atmosphere, less than 50 DEG C continue 4h.Printed RFID antenna lines are fluent, and edge is bright and clean, without hair Thorn, high conductivity performance can be obtained after simple sintering.
Compared with the prior art, the invention has the advantages that:
(1)The electrically conductive ink has preferable silk-screen printing adaptive and electric conductivity, and cost is low compared with traditional ink.
(2)Using drum-type screen printing mode, printing efficiency is high, and deformation is small, and the obtained antenna precision of print is high.
(3)Using UV-LED curing modes, ink instantaneous solidification can be made, the diffusion for reducing ink is sprawled, so as to improve print The resolution ratio of brush circuit, obtains high-precision RFID conducting channels.
Specific embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention Accompanying drawing, the technical scheme to the embodiment of the present invention is clearly and completely described.Obviously, described embodiment is this hair Bright a part of embodiment, rather than whole embodiments.Based on described embodiments of the invention, ordinary skill The every other embodiment that personnel are obtained on the premise of without creative work, belongs to the scope of protection of the invention.
Embodiment 1:
(1)It is 3 to weigh mass ratio:2:1 flake nano Argent grain, ball shaped nano Argent grain and linear nano silver, and by 60 In 15 parts of ethanol and ethyl acetate mixed solvent, jitter time is 5-10 minutes to part silver powder mixture ultrasonic disperse, and filtering is obtained Obtain uniform solution.
(2)With 50g silver nitrates and 22.2g hydrazine hydrates as raw material, 9.8g polyvinylpyrrolidones (PVP) are protective agent, PVP With the mol ratio 0.3 of Ag salt:1, the dispersion liquid that chemical reduction reaction is obtained in water or alcohol system is settled three times using acetone, is abandoned Supernatant liquor is removed, adds mixed solvent ethylene glycol, isopropanol and propylene glycol monomethyl ether 20.04g to carry out redisperse in lower sediment, its The mass ratio of middle mixed solvent ethylene glycol, isopropanol and propylene glycol monomethyl ether is 1:1:1, will(1)In obtained ethanol and acetic acid second Ester mixed solvent nano silver dispersion is added to wherein, and adds 2 parts of light triggers, 0.5 part of levelling agent, 0.5 part of polymerization inhibitor.
(3)Will be through with drum-type silk-screen printing(1)With(2)The UV-LED Nano silver conductive inks of acquisition are printed on paper RFID antenna.
(4)The RFID antenna picture and text circuit that will be printed UV-LED light according to 1-2 minute to solidification, and by the ink after solidification It is placed in vacuum drying oven nitrogen atmosphere, less than 50 DEG C continue 4h.Printed RFID antenna lines are fluent, and edge is bright and clean, nothing Burr, high conductivity performance can be obtained after simple sintering.
Embodiment 2:
(1)It is 3 to weigh mass ratio:2:1 flake nano Argent grain, ball shaped nano Argent grain and linear nano silver, and by 65 In 12 parts of ethanol and ethyl acetate mixed solvent, jitter time is 5-10 minutes to part silver powder mixture ultrasonic disperse, and filtering is obtained Obtain uniform solution.
(2)With 50g silver nitrates and 22.2g hydrazine hydrates as raw material, 9.8g polyvinylpyrrolidones (PVP) are protective agent, PVP With the mol ratio 0.3 of Ag salt:1, the dispersion liquid that chemical reduction reaction is obtained in water or alcohol system is settled three times using acetone, is abandoned Supernatant liquor is removed, adds mixed solvent ethylene glycol, isopropanol and propylene glycol monomethyl ether 20.04g to carry out redisperse in lower sediment, its The mass ratio of middle mixed solvent ethylene glycol, isopropanol and propylene glycol monomethyl ether is 1:1:1, will(1)In obtained ethanol and acetic acid second Ester mixed solvent nano silver dispersion is added to wherein, and adds 3 parts of light triggers, 1.0 parts of levelling agents, 0.5 part of polymerization inhibitor.
(3)Will be through with drum-type silk-screen printing(1)With(2)The UV-LED Nano silver conductive inks of acquisition are printed on paper RFID antenna.
(4)The RFID antenna picture and text circuit that will be printed UV-LED light according to 1-2 minute to solidification, and by the ink after solidification It is placed in vacuum drying oven nitrogen atmosphere, less than 50 DEG C continue 4h.Printed RFID antenna lines are fluent, and edge is bright and clean, nothing Burr, high conductivity performance can be obtained after simple sintering.
Embodiment 3:
(1)It is 3 to weigh mass ratio:2:1 flake nano Argent grain, ball shaped nano Argent grain and linear nano silver, and by 55 In 10 parts of ethanol and ethyl acetate mixed solvent, jitter time is 5-10 minutes to part silver powder mixture ultrasonic disperse, and filtering is obtained Obtain uniform solution.
(2)With 50g silver nitrates and 22.2g hydrazine hydrates as raw material, 9.8g polyvinylpyrrolidones (PVP) are protective agent, PVP With the mol ratio 0.3 of Ag salt:1, the dispersion liquid that chemical reduction reaction is obtained in water or alcohol system is settled three times using acetone, is abandoned Supernatant liquor is removed, adds mixed solvent ethylene glycol, isopropanol and propylene glycol monomethyl ether 20.04g to carry out redisperse in lower sediment, its The mass ratio of middle mixed solvent ethylene glycol, isopropanol and propylene glycol monomethyl ether is 1:1:1, will(1)In obtained ethanol and acetic acid second Ester mixed solvent nano silver dispersion is added to wherein, and adds 1 part of light trigger, 0.3 part of levelling agent, 1.0 parts of polymerization inhibitors.
(3)Will be through step with drum-type silk-screen printing(2)Obtained silver-colored electrically conductive ink prints RFID antenna on paper.
(4)The RFID antenna picture and text circuit that will be printed UV-LED light according to 1-2 minute to solidification, and by the ink after solidification It is placed in vacuum drying oven nitrogen atmosphere, less than 50 DEG C continue 4h.Printed RFID antenna lines are fluent, and edge is bright and clean, nothing Burr, high conductivity performance can be obtained after simple sintering.
Of the present invention to improve the method that RFID antenna circuit prints precision, the method combines nano material technology With UV-LED photocuring technologies, acrylic resin and activated monomer are added in nano-metal dispersion, using UV-LED Photocuring realizes the drying of conductive inks, and carries out low-temperature sintering to layer of ink.UV-LED photocurings can make layer of ink instantaneous solidification, Improve ink sprawls diffusion, so that the precision of RFID antenna printing is improved, while making nano ink using low-temperature sintering Reach good electric conductivity.Meanwhile, the not only energy saving of UV-LED photocurings, and solidification temperature is low, with nano metal Low-temperature sintering is combined can make the invention ink that application is realized on high temperature deformation base material.Light curing nano electrically conductive ink can use rolling Cartridge type screen printing technique, by RFID antenna pattern printing on the sheet materials such as film, obtains conductive path after solidification, it has solid Change temperature it is low, hardening time is short, good conductivity, high resolution the characteristics of, obtained conductive antenna film tack is good, pliability Good, electric conductivity is excellent.
Although it should be understood that with reference to its exemplary embodiment, particularly shown and description is carried out to the present invention, It should be understood by those skilled in the art that without departing substantially from by spirit of the invention as defined in the claims and model Under conditions of enclosing, the change of various forms and details can be wherein carried out, any combination of various embodiments can be carried out.

Claims (3)

1. a kind of preparation method of high accuracy RFID antenna electrically conductive ink, it is characterised in that comprise the following steps:
(1)It is 3 to weigh mass ratio:2:1 flake nano Argent grain, ball shaped nano Argent grain and linear nano silver, and by 60 In 15 parts of ethanol and ethyl acetate mixed solvent, jitter time is 5-10 minutes to part silver powder mixture ultrasonic disperse, and filtering is obtained Obtain uniform solution;
(2)With 50g silver nitrates and 22.2g hydrazine hydrates as raw material, 9.8g polyvinylpyrrolidones (PVP) are protective agent, PVP and Ag The mol ratio 0.3 of salt:1, the dispersion liquid that chemical reduction reaction is obtained in water or alcohol system is settled three times using acetone, is discarded Layer clear liquid, adds mixed solvent ethylene glycol, isopropanol and propylene glycol monomethyl ether 20.04g to carry out redisperse, wherein mixed in lower sediment The mass ratio of bonding solvent ethylene glycol, isopropanol and propylene glycol monomethyl ether is 1:1:1, will(1)In obtained ethanol and ethyl acetate it is mixed Bonding solvent nano silver dispersion is added to wherein, and adds 2 parts of light triggers, 0.5 part of levelling agent, 0.5 part of polymerization inhibitor;
(3)Will be through with drum-type silk-screen printing(1)With(2)The UV-LED Nano silver conductive inks of acquisition print RFID on paper Antenna;
(4)The RFID antenna picture and text circuit that will be printed UV-LED light put the layer of ink after solidification according to 1-2 minutes to solidification In vacuum drying oven nitrogen atmosphere, less than 50 DEG C continue 4h, and printed RFID antenna lines are fluent, and edge is bright and clean, without hair Thorn, high conductivity performance can be obtained after simple sintering.
2. a kind of preparation method of high accuracy RFID antenna electrically conductive ink, it is characterised in that comprise the following steps:
(1)It is 3 to weigh mass ratio:2:1 flake nano Argent grain, ball shaped nano Argent grain and linear nano silver, and by 65 In 12 parts of ethanol and ethyl acetate mixed solvent, jitter time is 5-10 minutes to part silver powder mixture ultrasonic disperse, and filtering is obtained Obtain uniform solution;
(2)With 50g silver nitrates and 22.2g hydrazine hydrates as raw material, 9.8g polyvinylpyrrolidones (PVP) are protective agent, PVP and Ag The mol ratio 0.3 of salt:1, the dispersion liquid that chemical reduction reaction is obtained in water or alcohol system is settled three times using acetone, is discarded Layer clear liquid, adds mixed solvent ethylene glycol, isopropanol and propylene glycol monomethyl ether 20.04g to carry out redisperse, wherein mixed in lower sediment The mass ratio of bonding solvent ethylene glycol, isopropanol and propylene glycol monomethyl ether is 1:1:1, will(1)In obtained ethanol and ethyl acetate it is mixed Bonding solvent nano silver dispersion is added to wherein, and adds 3 parts of light triggers, 1.0 parts of levelling agents, 0.5 part of polymerization inhibitor;
(3)Will be through with drum-type silk-screen printing(1)With(2)The UV-LED Nano silver conductive inks of acquisition print RFID on paper Antenna;
(4)The RFID antenna picture and text circuit that will be printed UV-LED light put the layer of ink after solidification according to 1-2 minutes to solidification In vacuum drying oven nitrogen atmosphere, less than 50 DEG C continue 4h, and printed RFID antenna lines are fluent, and edge is bright and clean, without hair Thorn, high conductivity performance can be obtained after simple sintering.
3. a kind of preparation method of high accuracy RFID antenna electrically conductive ink, it is characterised in that comprise the following steps:
(1)It is 3 to weigh mass ratio:2:1 flake nano Argent grain, ball shaped nano Argent grain and linear nano silver, and by 55 In 10 parts of ethanol and ethyl acetate mixed solvent, jitter time is 5-10 minutes to part silver powder mixture ultrasonic disperse, and filtering is obtained Obtain uniform solution;
(2)With 50g silver nitrates and 22.2g hydrazine hydrates as raw material, 9.8g polyvinylpyrrolidones (PVP) are protective agent, PVP and Ag The mol ratio 0.3 of salt:1, the dispersion liquid that chemical reduction reaction is obtained in water or alcohol system is settled three times using acetone, is discarded Layer clear liquid, adds mixed solvent ethylene glycol, isopropanol and propylene glycol monomethyl ether 20.04g to carry out redisperse, wherein mixed in lower sediment The mass ratio of bonding solvent ethylene glycol, isopropanol and propylene glycol monomethyl ether is 1:1:1, will(1)In obtained ethanol and ethyl acetate it is mixed Bonding solvent nano silver dispersion is added to wherein, and adds 1 part of light trigger, 0.3 part of levelling agent, 1.0 parts of polymerization inhibitors;
(3)Will be through step with drum-type silk-screen printing(2)Obtained silver-colored electrically conductive ink prints RFID antenna on paper;
(4)The RFID antenna picture and text circuit that will be printed UV-LED light put the layer of ink after solidification according to 1-2 minutes to solidification In vacuum drying oven nitrogen atmosphere, less than 50 DEG C continue 4h, and printed RFID antenna lines are fluent, and edge is bright and clean, without hair Thorn, high conductivity performance can be obtained after simple sintering.
CN201710287348.7A 2017-04-27 2017-04-27 A kind of preparation method of high accuracy RFID antenna electrically conductive ink Pending CN106883686A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102187352B1 (en) * 2019-11-26 2020-12-04 한국생산기술연구원 Conductive ink for three-dimensional in-mold molding and mathod of manufacturing the same
CN112778823A (en) * 2021-01-27 2021-05-11 九江纳维新材料科技有限公司 Ultra-high conductivity electronic grade graphene-silver composite conductive UV curing ink and preparation method and application thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102187352B1 (en) * 2019-11-26 2020-12-04 한국생산기술연구원 Conductive ink for three-dimensional in-mold molding and mathod of manufacturing the same
CN112778823A (en) * 2021-01-27 2021-05-11 九江纳维新材料科技有限公司 Ultra-high conductivity electronic grade graphene-silver composite conductive UV curing ink and preparation method and application thereof
CN112778823B (en) * 2021-01-27 2022-08-12 九江纳维新材料科技有限公司 Ultra-high conductivity electronic grade graphene-silver composite conductive UV curing ink and preparation method and application thereof

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