CN1068829C - Nickel alloy clad pate and method of mfg. such - Google Patents

Nickel alloy clad pate and method of mfg. such Download PDF

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Publication number
CN1068829C
CN1068829C CN97122110A CN97122110A CN1068829C CN 1068829 C CN1068829 C CN 1068829C CN 97122110 A CN97122110 A CN 97122110A CN 97122110 A CN97122110 A CN 97122110A CN 1068829 C CN1068829 C CN 1068829C
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CN
China
Prior art keywords
plate
nickel
steel plate
thin
steel
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Expired - Fee Related
Application number
CN97122110A
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Chinese (zh)
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CN1184734A (en
Inventor
郑珠镛
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JUNG WON ENGINEERING Co Ltd
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JUNG WON ENGINEERING Co Ltd
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Publication of CN1184734A publication Critical patent/CN1184734A/en
Application granted granted Critical
Publication of CN1068829C publication Critical patent/CN1068829C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K11/00—Resistance welding; Severing by resistance heating
    • B23K11/16—Resistance welding; Severing by resistance heating taking account of the properties of the material to be welded
    • B23K11/20—Resistance welding; Severing by resistance heating taking account of the properties of the material to be welded of different metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24—Selection of soldering or welding materials proper
    • B23K35/30—Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
    • B23K35/3033—Ni as the principal constituent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24—Selection of soldering or welding materials proper
    • B23K35/30—Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
    • B23K35/3053—Fe as the principal constituent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2103/00—Materials to be soldered, welded or cut
    • B23K2103/18—Dissimilar materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/01—Layered products comprising a layer of metal all layers being exclusively metallic
    • B32B15/013—Layered products comprising a layer of metal all layers being exclusively metallic one layer being formed of an iron alloy or steel, another layer being formed of a metal other than iron or aluminium
    • B32B15/015—Layered products comprising a layer of metal all layers being exclusively metallic one layer being formed of an iron alloy or steel, another layer being formed of a metal other than iron or aluminium the said other metal being copper or nickel or an alloy thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2311/00—Metals, their alloys or their compounds
    • B32B2311/22—Nickel or cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2311/00—Metals, their alloys or their compounds
    • B32B2311/30—Iron, e.g. steel

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Pressure Welding/Diffusion-Bonding (AREA)
  • Laminated Bodies (AREA)
  • Resistance Welding (AREA)

Abstract

The present invention discloses anickel alloy clad plate made by welding cheap steel plate, for example soft steel plate or carbon steel plate, on expensive and excellent acid-resistant corrosion-resistant nickel alloy plate. A thin bonding agent, for example a thin nickel plate, a thin stainless steel substrate plate, a nickel belt or stainless belt attach to a steel plate at first. Then a nickel alloy plate is welded on the steel plate by resistance seam welding method, the bonding agent inserts between the nickel alloy plate and the steel plate.

Description

Nickel alloy pluramelt and production method thereof
The present invention generally relates to nickel alloy pluramelt and production method thereof, and is particularly a kind of with cheap steel plate, as mild steel plate or carbon steel sheet, is soldered to a kind of nickel alloy pluramelt of producing on the expensive good acidproof corrosion-resistant nickel-base alloy plate.
Known as one's own profession personage institute, pluramelt generally is welded the different metal plate by this way, is about to cheap parent metal, has good acidproof corrosion resistant expensive metal plate as mild steel or the bottoming of carbon steel stratification and the one deck of burn-oning.This clad metal has advantages of being cheap, and has good being expected from the mechanical performance of conventional steel plate acquisition, also has good being expected from the acidproof corrosion resistance of particulate metal acquisition of costliness.Therefore, this cladding sheet is widely used for various uses, as distillation system, and freshwater system and power plant desulfurization system, the acidproof and corrosion resistance that these system requirements are good.
In the steam generator system of power plant, when using heavy oil or coal to do fuel combustion, produce a large amount of sulphur dioxides, cause environmental pollution.Therefore, the desulphurization system of collecting and removing sulphur dioxide must be installed.But in such steam generator system, the absorption tower of desulphurization system, conduit and chimney etc. are corrosion easily, because they always are exposed in the sulphur dioxide.Thereby, the lost of life of desulphurization system, force the owner with too much expense with new replacement existing systems.
In order to address the above problem, the method for this purposes steel plate of several manufacturings has been proposed.At first, have good acidproof corrosion resistant single metal plate and can be used for being exposed to part in the sulphur dioxide.The second, with a cheap steel plate with have cladding sheet that good acidproof corrosion resistant metallic plate combines and can be used for being exposed to part in the sulphur dioxide.Yet the problem that first method has is and since be expensive metal it is very expensive, and this plate is installed very difficult in system like this.For this consideration, use the cladding sheet of producing according to second method more desirable at present.
Introduce the technology of making cladding sheet according to prior art below.This cladding sheet can be by several method production.At first, cladding sheet can be produced by the explosive welding (EW) connection, and this is to utilize the force of explosion of explosive that the erosion-resisting metallic plate of height is welded on the plain steel plate.In addition, cladding sheet can be produced by the roll bonding method, and this is by means of a thermo roll anticorrosive plate and plain steel to be hardened to close.As another kind of method again, cladding sheet can be by the production of seam resistance welding method, and this is to use a kind of bond, as stainless (steel) wire, copper mesh or sheet copper in conjunction with noncorroding metal plate and plain steel plate.Though the quality of the cladding sheet of being produced by first and second kind method is good, they be costliness and also the machined difficulty, and machinability is poor.And therefore first and second kind method waste material hinders and uses them.Simultaneously, it is cheap that the seam resistance welding method is compared with other method, makes it preferentially be widely used for producing pluramelt.
But the seam resistance welding method has a bond problem, and as stainless (steel) wire, copper mesh or sheet copper can not harden corrosion resisting alloy effectively and be incorporated on the steel plate.Thereby the cladding sheet that this method is produced as low lamentedly on tensile strength, tearing strength and the shear strength, therefore can not satisfy user's requirement in mechanical performance.
Chinese invention patent communique CN1151354 discloses a kind of lining material, it comprises (iron system) substrate metal layer, corrosion-resistant metal sheet material and places the nickel between this substrate metal layer and the corrosion resistant metal sheet material is metal level (nickel foil), by the weld seam welding this three is mutually combined.This lining material has mechanical performance and good acidproof and corrosivity preferably.As everyone knows, nickel is a kind of rare precious metal.This invention covers nickel plate or net on the whole surface of base material steel plate, has increased manufacturing cost inevitably yet regrettably.
Therefore, in order to solve the problems referred to above that occur in the prior art, the purpose of this invention is to provide a kind of method of making the nickel-base alloy cladding sheet, this method can reduce the consumption of precious metal (nickel) effectively, and makes the weight saving of final products.
Another object of the present invention provides the nickel-base alloy cladding sheet that a kind of use precious metal (nickel) is less and weight is lighter.
In order to achieve the above object, the invention provides a kind of method of making the nickel alloy cladding sheet, the step of this method comprises: earlier a plurality of thin nickel straps or stainless steel band are attached on the steel plate along the predetermined operation line that stitches electric resistance welding; By the seam electric resistance welding nickel-base alloy plate is welded on the described steel plate, described a plurality of thin nickel straps or stainless steel band are inserted in and are welded between described two plates.
And, the invention provides a kind of nickel alloy cladding sheet, this plate comprises: a steel plate and a nickel-base alloy plate that is welded on the described steel plate, between described two plates, insert a bond spare, it is characterized in that described bond spare comprises a plurality of thin nickel strap or the stainless steel band that only is arranged on the seam electric resistance welding welding production line.
The present invention only attaches to many nickel straps on the steel plate along the predetermined operation line of seam electric resistance welding, rather than nickel plate or net are covered on the whole surface of base material steel plate.Thereby saved the consumption of precious metal nickel greatly, and making the weight saving of final products (cladding sheet) simultaneously, cost reduces.
Above-mentioned purpose of the present invention and further feature and advantage are from more clear below in conjunction with meeting the description of the drawings.In the accompanying drawing:
Fig. 1 is the enlarged perspective of nickel alloy cladding sheet according to a preferred embodiment of the invention.
According to the present invention, a thin bond plate, as a thin nickel plate, thin stainless steel base plate, nickel strap or stainless steel band at first attach on the steel plate.Then, by seam electric resistance welding method one nickel-base alloy plate is welded on this steel plate, this bond is inserted between nickel alloy plate and the steel plate.
The following describes the combination of steel plate and nickel alloy plate.At first, big electric current flows through between steel matrix plate and nickel alloy plate, thereby at once high resistance heat takes place.Therefore bond is melted by high resistance heat.Nickel-base alloy plate and steel plate fusion when bond melts, thus steel plate and nickel alloy plate are firmly welded.
Preferably a kind of flux is added to bond two, so that the nickel alloy plate is melted on the steel plate effectively.
Be because of its cheapness as the matrix steel plate and have the intensity that hope is wanted with carbon steel sheet.
With thin nickel plate, thin corrosion resistant plate, nickel strap or stainless steel band be as bond, be because they be by with parent metal, promptly similar the or same metal of carbon steel or nickel alloy plate is made.Because make their metal and parent metal, promptly carbon steel or nickel alloy plate are similar or identical, are easy to fusion between this two plate of welding.Thereby, obtain firm weld force.Thin nickel plate, thin corrosion resistant plate, nickel strap or stainless steel band are used as bond, compare with stainless steel or copper mesh with routine, can form a wide calmodulin binding domain CaM, therefore obtain firm weld force.
In addition, can reduce the bond quantity of material with nickel strap or stainless steel band.At this moment can reduce the weight of the nickel alloy cladding sheet of final production significantly, because these bands only are placed on the zone that will weld.
Example
As shown in Figure 1, according to example 1, the thin nickel plate 2 that has thickness and be 0.05-0.3mm at first is attached on the carbon steel sheet 1, and the thickness of carbon steel sheet is 6.0mm.By the seam resistance welding method nickel alloy plate 3 is welded on the thin nickel plate 2 then.So just, obtain cladding sheet.
According to the purposes of cladding sheet and the design strength of wanting, the seam resistance welding method can carry out at the weld interval of 10-200mm.The shape of the welding bead of producing 4 as shown in Figure 1.
As bond, make the cladding sheet of routine 2-4 equally respectively with nickel strap, thin stainless steel and stainless steel band with example 1.For relatively, make for comparing cladding sheet example 1-3 with stainless (steel) wire, copper mesh and copper coin respectively.
Mechanical performance at cladding sheet produced according to the invention shown in the table 1 and that produce according to prior art.
Table 1
Bond Mechanical performance
Tensile strength (kg/mm 2) Shear strength (KSI) Tearing strength (kg/mm 2)
Example 1 Thin nickel plate 65-68 40-42 18-20
Example 2 Nickel strap 66-67 40-42 18-22
Example 3 Thin corrosion resistant plate 56-60 35-38 15-17
Example 4 Stainless steel band 55-58 35-37 15-18
Comparative example 1 Stainless (steel) wire 40-45 28-32 11-14
Comparative example 2 Copper mesh 27-30 15-18 7-10
Comparative example 3 Copper coin 35-38 20-24 10-12
As shown in table 1, can see the feature of using different bonds to demonstrate a great difference respectively.Demonstrate during thin corrosion resistant plate particularly used according to the invention than prior art with stainless (steel) wire, copper mesh and copper coin, can obtain higher mechanical properties.Use thin nickel plate also to show than obtaining than high-mechanical property with thin corrosion resistant plate.
As mentioned above, according to the present invention, make bond with thin nickel plate and thin corrosion resistant plate and can make and have good mechanical properties, as the nickel-base alloy cladding sheet of tensile strength, shear strength and tearing strength.For bond, can suitably determine selecting for use of stainless steel or nickel strap bond according to the intensity and the service condition of hope design.Therefore, the present invention can provide a kind of reliable and cheap nickel-base alloy cladding sheet, thereby reduces the manufacturing expense of desulphurization system.
Though in order to illustrate the preferred embodiments of the present invention are introduced, the personage who understands present technique understands, does not depart from the disclosed scope of the invention of appended claim and spirit, makes various modifications, and it is possible adding and replacing.

Claims (2)

1. nickel alloy pluramelt manufacture method said method comprising the steps of:
Earlier a plurality of thin nickel straps or stainless steel band are attached on the steel plate along the predetermined operation line that stitches electric resistance welding;
By the seam electric resistance welding nickel-base alloy plate is welded on the described steel plate, described a plurality of thin nickel straps or stainless steel band are inserted in and are welded between described two plates.
2. nickel alloy cladding sheet, described plate comprises: a steel plate and a nickel-base alloy plate that is welded on the described steel plate, insert a bond spare between described two plates, it is characterized in that, described bond spare comprises a plurality of thin nickel strap or the stainless steel band that only is arranged on the seam electric resistance welding welding production line.
CN97122110A 1996-11-13 1997-11-12 Nickel alloy clad pate and method of mfg. such Expired - Fee Related CN1068829C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
KR53678/1996 1996-11-13
KR1019960053678A KR0180475B1 (en) 1996-11-13 1996-11-13 Nickel alloy cladplate and manufacture method
KR53678/96 1996-11-13

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Publication Number Publication Date
CN1184734A CN1184734A (en) 1998-06-17
CN1068829C true CN1068829C (en) 2001-07-25

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2977478B1 (en) * 2013-05-09 2019-03-06 JFE Steel Corporation Nickel alloy clad steel having excellent grain boundary corrosion resistance properties, and method for producing same
CN104742433A (en) * 2013-12-31 2015-07-01 浙江申达斯奥医疗器械有限公司 Composite material for medical operation instrument and preparation method
CN109048234B (en) * 2018-10-10 2019-08-06 福建海山重工有限公司 A kind of forklift part high-efficiency and precision processing technology

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1151354A (en) * 1995-07-06 1997-06-11 株式会社昭和铅铁 Coating material

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1151354A (en) * 1995-07-06 1997-06-11 株式会社昭和铅铁 Coating material

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KR0180475B1 (en) 1999-02-18
KR19980035350A (en) 1998-08-05
CN1184734A (en) 1998-06-17
ID18822A (en) 1998-05-14

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Granted publication date: 20010725

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