CN106876757B - Functional enhanced proton exchange membrane and preparation method thereof - Google Patents
Functional enhanced proton exchange membrane and preparation method thereof Download PDFInfo
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- CN106876757B CN106876757B CN201510925102.9A CN201510925102A CN106876757B CN 106876757 B CN106876757 B CN 106876757B CN 201510925102 A CN201510925102 A CN 201510925102A CN 106876757 B CN106876757 B CN 106876757B
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/1065—Polymeric electrolyte materials characterised by the form, e.g. perforated or wave-shaped
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M2008/1095—Fuel cells with polymeric electrolytes
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Abstract
The invention discloses a functionalized enhanced proton exchange membrane and a preparation method thereof. In a pure oxygen proton exchange membrane fuel cell, a thicker proton exchange membrane is needed to avoid hydrogen permeation, but the hydrogen-oxygen fuel cell is easy to cause serious swelling problem to the proton exchange membrane due to higher humidity of the operating environment, and the proton exchange membrane is shrunk due to the dry cell environment after the cell is stopped, so that the proton exchange membrane is seriously damaged mechanically. At present, the commercial enhanced proton exchange membrane can obviously reduce the swelling deformation rate and improve the mechanical strength of the proton membrane by introducing an enhanced framework into the membrane, but the thickness of the enhanced proton exchange membrane can only reach 20 microns at most and cannot meet the application requirement of a pure oxygen type fuel cell. Aiming at the problems, the invention provides a method for preparing a proton exchange membrane suitable for an oxyhydrogen fuel cell on the basis of the existing enhanced composite proton exchange membrane, which can obviously prolong the mechanical attenuation resistance and the service life of a membrane electrode.
Description
Technical Field
The invention belongs to the field of proton exchange membrane fuel cells, and relates to a functional enhanced proton exchange membrane suitable for running in an oxyhydrogen fuel cell and a preparation method thereof.
Background
The proton exchange membrane fuel cell is an energy conversion device, works like an internal combustion engine, can directly convert chemical energy in hydrogen fuel into electric energy to be released, and is widely applied to different fields of automobile transportation, distributed power generation, aerospace, underwater power and the like due to the advantages of low working temperature, high energy conversion efficiency, high starting speed, environmental friendliness and the like. The air can be directly used as an oxidant in the fields of automobile transportation and distributed power generation, and the air can be called a hydrogen fuel cell, while the air needs to carry pure oxygen as the oxidant in the fields of aerospace, underwater power and the like, and the air can be called a hydrogen fuel cell. There is also a large difference in system management, internal structural design, etc. of hydrogen-air and hydrogen-oxygen fuel cells depending on the oxidant.
The core component of the fuel cell, namely the membrane electrode, is the key for determining the service life and the performance of the cell, wherein the key role for the service life and the stability of the membrane electrode is the proton exchange membrane, and the most main reason for the failure of the fuel cell at present is the phenomena of perforation, rupture and the like of the membrane. In a hydrogen-air fuel cell, in order to improve the performance of the cell and reduce the ohmic resistance, the trend of a proton exchange membrane is as thin as possible, and is only a few to tens of micrometers. Meanwhile, in order to ensure the strength of the proton exchange membrane, the membrane is usually reinforced, for example, a reinforcing skeleton is added in the middle of the proton exchange membrane, or inorganic substances with reinforcing effect are doped. However, in the hydrogen-oxygen fuel cell, the problem of hydrogen permeation cannot be ignored, and the proton exchange membrane must have a certain thickness to avoid the hot spot generated by hydrogen permeation, thereby avoiding the damage to the membrane electrode.
On the other hand, in the hydrogen-air fuel cell, because the oxygen content in the air is only 21%, in order to meet the requirement of electrochemical reaction and reduce the diffusion resistance, the air intake quantity of the air is often higher than the actually required metering ratio, so that the water generated by the operation of the cell can be smoothly discharged along with the air tail gas, and the problem of flooding of the membrane electrode can not be caused. In the hydrogen-oxygen fuel cell, oxygen needs to ensure a certain utilization rate, a large amount of gas can not be supplied according to the gas inlet mode of the hydrogen-oxygen fuel cell, and liquid water can not be discharged by means of tail gas naturally after being removed. At present, liquid water in the hydrogen-oxygen fuel cell is discharged in various modes such as water diversion by a water segregator, water drainage by a water permeable plate and the like.
Because the hydrogen-oxygen fuel cell needs to adopt a thick film and has low drainage efficiency, a thick proton exchange membrane is easy to swell to a large scale under high humidity, and serious mechanical damage is easily brought to the proton exchange membrane in repeated dry-wet circulation. At present, the commercial enhanced proton exchange membrane can obviously reduce the swelling deformation rate and improve the mechanical strength of the proton membrane by introducing an enhanced framework into the membrane, but the thickness of the enhanced proton exchange membrane can only reach 20 microns at most, and the enhanced proton exchange membrane cannot meet the application requirements of direct methanol fuel cells and pure oxygen fuel cells. Therefore, how to optimize the proton exchange membrane in the hydrogen-oxygen fuel cell, the swelling property of the proton exchange membrane is reduced while the problem of hydrogen permeation is avoided, and the method has very important scientific significance.
Related patent
In order to improve the chemical stability of proton exchange membranes, the patent application No. 201510019249.1 proposes a multi-layer composite proton exchange membrane, which comprises three layers of sulfonic acid polymer membrane stacked on each other, the outer membrane on both sides is a perfluorosulfonic acid polymer layer, the middle base membrane is a non-fluorosulfonic acid polymer layer, and the outer membrane and the base membrane are connected to each other through covalent bonds.
The patent application No. 200910231125.4 proposes a free radical stable fiber reinforced multilayer fluoride ion exchange membrane consisting of 2-5 layers, at least one monolayer of the membrane having fibers added as reinforcement and at least one monolayer of the membrane having a substance that promotes free radical degradation, thereby improving the mechanical stability of the membrane and reducing hydrogen and methanol crossover.
Disclosure of Invention
The above related patent 1 is to sandwich a non-fluorine membrane between two perfluorosulfonic acid membranes, which can reduce the cost of the thick proton exchange membrane and can improve the mechanical strength of the whole proton membrane by using the non-fluorine membrane. The invention is different from the prior art, the functional enhanced proton exchange membrane prepared by the invention is still a perfluorinated membrane, and aims to prepare a thick perfluorinated proton exchange membrane with an enhanced framework and realize the purposes of free radical quenching and self-humidification by adding a functional additive into a sprayed ion exchange resin layer.
The above related patent 2 is to prepare a perfluorosulfonic acid membrane of a multilayer structure by adding different substances to a single layer for the purpose of enhancing the membrane strength and promoting radical degradation. The invention is different from the method that a thin reinforced film with a reinforced framework is adopted as a base film, functional additives with self-humidifying and free radical quenching promoting functions are sprayed on the base film to form a functionalized thickness expanding layer, and the multiple thin reinforced films are further laminated and hot pressed to form a thick functionalized reinforced film.
The invention aims to provide a thick functional enhanced proton exchange membrane capable of simultaneously solving hydrogen permeation and frequent dry and wet operations of a hydrogen-oxygen fuel cell so as to adapt to the special working environment of the hydrogen-oxygen fuel cell and further ensure the reliability and the service life of the hydrogen-oxygen fuel cell.
In order to achieve the purpose, the invention adopts the technical scheme that:
1-3 layers of thin enhanced proton exchange membranes are taken as a bottom membrane (a polytetrafluoroethylene porous membrane is taken as an enhanced framework), a solution consisting of ion exchange resin and functional additives is sprayed on the surface of the bottom membrane to form a functionalized thickness expanding layer and a bonding layer, and further, 1-3 layers of thin enhanced proton exchange membranes are laminated into a thick functionalized enhanced proton exchange membrane through hot pressing.
The basement membrane is a commercial proton exchange membrane with the thickness of 8-20 microns, any one of which contains a polytetrafluoroethylene porous membrane as a reinforcing framework, and solution consisting of ion exchange resin and functional additives is continuously sprayed on the surface of the basement membrane to form a functionalized thickness expanding layer and a functionalized bonding layer.
The spray solution, which consists of an ion exchange resin (usually Nafion) and a functional additive comprising inorganic particles (preferably MnO)2，CeO2，Ag2One or more of O, etc.), organic-treated inorganic metal oxides (preferably sulfonated CeO)2Sulfonated MnO2Sulfonated Ag2One or more of O), heteropoly acid (preferably one or more of 12-HSW, 21-HPW, cesium phosphotungstate and the like), wherein the weight ratio of the ion exchange resin to the functional additive is 100: 0-95: 5, and the particle size of the functional additive is 10-30 nm.
When the number of the basement membrane layers is 1, the enhanced proton exchange membrane with the thickness of 18-20 microns is selected as the basement membrane, the basement membrane is placed on the surface of a heating plate with the temperature of 60-80 degrees, solutions consisting of Nafion ion resin and functional additives (one or two of water absorption function and free radical resistance function) are respectively sprayed on the two sides of the basement membrane to respectively form functionalized thickness expansion layers with the thickness of 5-15 microns, the types and the proportions of the functional additives contained in the functionalized expansion layers on the two sides can be respectively adjusted according to the functionalized requirements, and then the membrane is hot-pressed for 1-5min at 140 degrees and gauge pressure of 1-5Mpa, so that the thick-layer functionalized enhanced proton exchange membrane with different functions is obtained.
When the number of the basement membrane layers is 2, the strengthening membrane with the thickness of 12-17 microns is selected as the basement membrane, the basement membrane is placed on the surface of a heating plate with the temperature of 60-80 degrees, solutions consisting of Nafion ion resin and functional additives (one or two of water absorption function and free radical resistance function) are respectively sprayed on one side of each of the two basement membranes, a functional expansion layer with the thickness of 5-15 microns is formed, and the types and the proportion of the functional additives contained in the two functional expansion layers can be respectively adjusted according to the functional requirements. And then, the spraying surfaces of the two membranes are opposite, and hot pressing is carried out for 1-5min at 140 ℃ and gauge pressure of 1-5Mpa, so as to obtain the functionalized thick-layer enhanced proton exchange membrane.
When the bottom membrane is 3 layers, the functionalized enhanced proton exchange membrane selects the enhanced membrane with the thickness of 8-11 microns as the bottom membrane, spraying solution composed of Nafion and functional additive (having one or two of water absorption function and free radical resisting function) onto two sides of 1 membrane at 60-80 deg.C to form a functionalized extension layer with thickness of 5-15 μm, spraying solution composed of Nafion and functional additive (having one or two of water absorption function and free radical resisting function) onto one side of the other two membranes to form a functionalized extension layer with thickness of 5-15 μm, the types and the proportions of the functional additives contained in the four functional extension layers can be respectively adjusted according to the functional requirements, then the spraying surfaces of the three films are opposite, hot pressing at 140 deg.C and gauge pressure of 1-5Mpa for 1-5min to obtain thick functional enhanced proton exchange membrane.
The proton conductivity of the enhanced proton exchange membrane prepared by the method is 0.05-0.09S/cm. Longitudinal/transverse tensile strength of 40-60MPa, hydrogen gas passing rate of less than 0.01ml min cm2。
The invention has the following advantages:
1. the thick functional enhanced proton exchange membrane with the thickness of 28-93 microns is prepared by using 1-3 layers of thin enhanced proton exchange membranes as a bottom membrane, and the problem of high swelling degree of the existing thick proton exchange membrane can be solved.
2. The thick functional enhanced proton exchange membrane with the thickness of 28-93 microns is prepared by using 1-3 layers of thin enhanced proton exchange membranes as a bottom membrane, and the problem that the existing enhanced proton exchange membrane is thin and is easy to permeate hydrogen can be solved.
3. By using 1-3 layers of thin enhanced proton exchange membranes as bottom membranes to prepare the thick functionalized enhanced proton exchange membrane with the thickness of 28-93 microns, the functionalization of the enhanced proton exchange membrane can be realized so as to prolong the service life of the fuel cell.
Drawings
FIG. 1 is a schematic view of an enhanced proton exchange membrane according to the present invention;
FIG. 2 is a graph comparing the ohmic resistance of the electrodes of example 1;
FIG. 3 is a graph comparing the operating life of the electrodes in example 2.
Detailed Description
Referring to fig. 1, the structure of the reinforced proton exchange membrane of the present invention is schematically illustrated in three cases, wherein case 1 has one bottom membrane, case 2 has two bottom membranes, case 3 has three bottom membranes, and in the figure, (1) is a thin reinforced bottom membrane, (2) is a sprayed ion exchange resin and functional additive layer
Example 1
First, sulfonated SiO is prepared2And CeO2Mixing 10g of nano SiO210g of 1, 3-propylsultone were reacted at 110 ℃ for 36 hours using toluene as a solvent. After the reaction is finished, repeatedly cleaning the reaction product for 3 times by using methylbenzene, and drying the reaction product to obtain sulfonated SiO2。
Preparing 0.05mol/L NaOH solution, and calibrating the NaOH solution by using the prepared potassium hydrogen phthalate solution. Sulfonated SiO2Soaking in saturated NaCl solution for 3 days to obtain sulfonated SiO with sulfonation degree of 24%2And (3) powder. Sulfonated CeO2The preparation process is the same as that of (1). The sulfonated SiO prepared by the method2And CeO2The grain diameter is between 10 and 30 nm.
A piece of a 10cm by 10cm HP membrane (20 μm thick) from DuPont was mounted on a 60 ℃ hot plate, 50g of a 5 wt% Nafion solution was weighed, and 80mg of sulfonated SiO was added2And 50mg of sulfonated CeO2Using isopropanol diluentReleasing 5 times and uniformly mixing, uniformly spraying the mixture on the surface of the HP film, controlling the thickness of the expansion layer sprayed on the surface of the HP film to be about 5 microns, and stopping spraying to form the expansion layer with the thickness of one side. The film was then turned over to be sprayed with the other side thickness extension.
Drying the film sprayed with the thickness expansion layer, placing the film in a flat plate press, setting the temperature at 140 degrees, hot-pressing the film at 1Mpa for 1min to form an integrated reinforced film with the thickness of about 30 micrometers, and testing the proton conductivity of the film to be 0.09S/cm, the longitudinal/transverse tensile strength to be about 30MPa and the hydrogen passing rate to be 0.008 ml/min/cm by using a four-probe method2。
The membrane electrode assembly is clamped between two gas diffusion electrodes with the area of 5cm multiplied by 5cm, a membrane electrode integrated assembly (1) is formed through hot pressing, and a single cell is assembled for ohmic resistance test and performance stability test.
Example 2
Taking 1 home-made reinforced membrane (the thickness is 15 microns) with the area of about 10cm multiplied by 10cm, fixing the membrane on a 80-degree hot table, weighing 50g of 5 wt% Nafion solution, diluting and uniformly mixing by 5 times of isopropanol, uniformly spraying the Nafion solution on the single-side surface of the reinforced membrane, controlling the thickness of an expansion layer sprayed on the surface of the membrane to be about 10 microns, and stopping spraying to form a single-side thickness expansion layer.
Taking 1 domestic reinforced film (thickness 15 micrometer) with area of about 10cm × 10cm, fixing it on 80 ° hot table, weighing 50g of 5 wt% Nafion solution, adding 20mg SiO2And 30mg of CeO2The particle diameters of the two are 10-30nm, the isopropyl alcohol is diluted by 5 times and uniformly mixed, the mixture is uniformly sprayed on the single-side surface of the reinforced membrane, the thickness of the expansion layer sprayed on the membrane surface is controlled to be about 10 microns, and then the spraying is stopped, so that the single-side thickness expansion layer is formed.
Drying the reinforced membrane sprayed with the expanded layer, then, bonding the expanded layers by using a flat hot press, setting the temperature at 140 degrees, hot-pressing the pressure at 3Mpa for 3min to form an integrated reinforced membrane with the thickness of about 50 microns, and testing the proton conductivity of the reinforced membrane to be 0.06S/cm, the longitudinal/transverse tensile strength to be about 50MPa and the hydrogen passing rate to be 0.005 ml/min/cm by using a four-probe method2。
The membrane electrode assembly is clamped between two gas diffusion electrodes with the area of 5cm multiplied by 5cm, a membrane electrode integrated assembly (1) is formed through hot pressing, and a single cell is assembled for ohmic resistance test and performance stability test.
Example 3
A domestic reinforced membrane (thickness 8 μm) with an area of about 10cm × 10cm was fixed on a 70 ℃ hot plate, 50g of 5 wt% Nafion solution was weighed, and 50mg of sulfonated SiO was added2The isopropyl alcohol is diluted by 5 times and uniformly mixed, then the mixture is uniformly sprayed on the surface of the reinforced membrane, and the spraying is stopped after the thickness of the expansion layer sprayed on the surface of the membrane is controlled to be about 15 micrometers, so that a single-side expansion layer is formed. The film was then turned over and the other side extension layer was sprayed on.
Two domestic reinforced membranes (8 microns in thickness) with the area of about 10cm multiplied by 10cm are respectively fixed on a 70-degree hot table, 50g of 5 wt% Nafion solution is weighed, and 50mg of sulfonated CeO is added2The isopropyl alcohol is diluted by 5 times and uniformly mixed, then the isopropyl alcohol is respectively and uniformly sprayed on the surfaces of the two reinforced membranes, the thickness of the expansion layer sprayed on the membrane surface is controlled to be about 15 micrometers, and then the spraying is stopped, so that the single-side expansion layer is formed.
Drying the reinforced membrane sprayed with the expanded layers, facing the four expanded layers, bonding the four expanded layers by using a flat hot press, setting the temperature at 140 degrees, hot-pressing the pressure at 5MPa for 5min to form an integrated reinforced membrane with the thickness of about 84 micrometers, and testing the proton conductivity of the reinforced membrane to be 0.05S/cm, the longitudinal/transverse tensile strength to be about 60MPa and the hydrogen passing rate to be 0.004 ml/min/cm by using a four-probe method2。
The membrane electrode assembly is clamped between two gas diffusion electrodes with the area of 5cm multiplied by 5cm, a membrane electrode integrated assembly (1) is formed through hot pressing, and a single cell is assembled for ohmic resistance test and performance stability test.
Figure 2 shows the ohmic resistance of the membrane electrode in the above three examples, compared to the ohmic resistance of the 115 and 212 membrane electrodes in the same case.
Fig. 3 shows the results of life tests performed on the three electrodes and the 115-film and 212-film electrodes under the same conditions, after the same pulse drainage frequency, the same humidification conditions and the same dry-wet change are performed, wherein the 212-film electrode starts to be perforated after about 500h of operation, the 115-film electrode starts to be perforated after 800h of operation, and the three film electrodes in the embodiment are operated for more than 1000h without perforation.
Claims (2)
1. A functional enhancement type proton exchange membrane is characterized in that 2 layers or 3 layers of polytetrafluoroethylene porous membranes are used as bottom membranes, and a functional extension layer with one or two of self-humidifying and anti-free radical functions is prepared between the 2 layers or 3 layers of bottom membranes to obtain the functional enhancement type proton exchange membrane; when the number of the bottom film layers is 2, the thickness of the bottom film of the polytetrafluoroethylene porous film is 12-17 micrometers, and when the number of the bottom film layers is 3, the thickness of the bottom film of the polytetrafluoroethylene porous film is 8-11 micrometers; the thickness of the functionalized extension layer is 5-15 microns, the functionalized extension layer between the base membranes is two layers, the particle size of the functional additive in the functionalized extension layer is 10-30nm, the proton conductivity range of the functionalized enhanced proton exchange membrane is 0.05-0.09S/cm, the longitudinal/transverse tensile strength is 40-60MPa, and the hydrogen passing rate is less than 0.01ml min cm2；
When the number of the bottom membrane layers is 2, selecting a polytetrafluoroethylene porous membrane with the thickness of 12-17 microns as the bottom membrane, placing the bottom membrane on the surface of a heating plate with the temperature of 60-80 ℃, respectively spraying a solution consisting of Nafion ion resin and a functional additive on one side of the two bottom membranes to form a functional expansion layer with the thickness of 5-15 microns, then enabling the spraying surfaces of the two membranes to be opposite, and carrying out hot pressing for 1-5min at the temperature of 120-140 ℃ and the gauge pressure of 1-5Mpa to obtain the functional enhanced proton exchange membrane;
or when the bottom membrane is 3 layers, selecting a polytetrafluoroethylene porous membrane with the thickness of 8-11 microns as the bottom membrane, spraying a solution consisting of Nafion and a functional additive to two sides of 1 membrane at 60-80 ℃ to form a functionalized expansion layer with the thickness of 5-15 microns, spraying a solution consisting of Nafion and a functional additive to one side of the other two membranes to form a functionalized expansion layer with the thickness of 5-15 microns, then sequentially and oppositely spraying the surfaces of the three membranes, and carrying out hot pressing at 120-140 ℃ and gauge pressure of 1-5MPa for 1-5min to obtain the functionalized enhanced proton exchange membrane;
the functional additive comprises one or more of MnO in the inorganic metal oxide2，CeO2，Ag2One or more than two of O; sulfonated CeO in organic-treated inorganic Metal oxides2Sulfonated MnO2Sulfonated Ag2One or more than two of O; one or more than two of 12-HSW, 21-HPW and cesium phosphotungstate in the heteropoly acid; the weight ratio of the ionic resin Nafion to the functional additive is 100: 0-95: 5, and the content of the functional additive is not 0.
2. The functionalized reinforced proton exchange membrane of claim 1, wherein: the total weight of the sulfonate in the inorganic metal oxide treated by the organic matter is 20-30%.
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