CN106869813A - A kind of anti-sulphur oil pipe overall structure of glazing cermet and its processing method - Google Patents

A kind of anti-sulphur oil pipe overall structure of glazing cermet and its processing method Download PDF

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Publication number
CN106869813A
CN106869813A CN201710040223.4A CN201710040223A CN106869813A CN 106869813 A CN106869813 A CN 106869813A CN 201710040223 A CN201710040223 A CN 201710040223A CN 106869813 A CN106869813 A CN 106869813A
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China
Prior art keywords
oil pipe
glazing
cermet
box cupling
glaze
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CN201710040223.4A
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Chinese (zh)
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杨永利
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Individual
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Priority to CN201710040223.4A priority Critical patent/CN106869813A/en
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    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B17/00Drilling rods or pipes; Flexible drill strings; Kellies; Drill collars; Sucker rods; Cables; Casings; Tubings
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23DENAMELLING OF, OR APPLYING A VITREOUS LAYER TO, METALS
    • C23D11/00Continuous processes; Apparatus therefor
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B17/00Drilling rods or pipes; Flexible drill strings; Kellies; Drill collars; Sucker rods; Cables; Casings; Tubings
    • E21B17/02Couplings; joints
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L58/00Protection of pipes or pipe fittings against corrosion or incrustation
    • F16L58/02Protection of pipes or pipe fittings against corrosion or incrustation by means of internal or external coatings
    • F16L58/04Coatings characterised by the materials used
    • F16L58/14Coatings characterised by the materials used by ceramic or vitreous materials
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L9/00Rigid pipes
    • F16L9/14Compound tubes, i.e. made of materials not wholly covered by any one of the preceding groups

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Mining & Mineral Resources (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Environmental & Geological Engineering (AREA)
  • Fluid Mechanics (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Materials Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)

Abstract

A kind of anti-sulphur oil pipe overall structure of glazing cermet, including oil pipe, box cupling, oil tube inner lining cermet coating, it is characterised in that:It is ceramic glaze layer above cermet coating, oil pipe port cermet coating the inside and box cupling inwall are nickel base alloy layer, are tightly connected between oil pipe port and box cupling.The present invention applies ceramic glaze using cermet composite oil pipe inwall, can effectively prevent corrosion of the sulfur-containing gas to tubing, glazing from solving the pin hole and micro-crack defect problem of surface ceramii layer, obtaining smooth tube inner wall, reduces flow resistance;Hermetic seal screw thread is employed, the bearing capacity of oil pipe is substantially increased;The nickel-base alloy part fallen by sealing surface in oil pipe port and box cupling, it is ensured that anti-sulphur effect.

Description

A kind of anti-sulphur oil pipe overall structure of glazing cermet and its processing method
Technical field
The invention belongs to chemical industry equipment manufacture technology field, a kind of glazing cermet of the natural gas well is specifically related to Anti- sulphur oil pipe overall structure and its processing method.
Background technology
During sulfur-containing gas are produced and collect defeated, because the corrosivity of sulfur-containing gas is extremely strong, oil pipe pipe can be caused The damage of material.Hydrogen sulfide corrosion causes the common form of oil pipe break to have hydrogen induced cracking (HIC) HIC, sulfide stress in sulfur-containing gas The diversified forms such as cracking SSC, stress corrosion cracking SCC, oil pipe break is often unexpected generation, it is difficult to prediction and preventing and treating, pole Easily cause great economic loss and casualties.
At present, in the world in the development process of sulfur Gas Fields, oil pipe generally uses alloy pipe, but alloy pipe price One ton of costliness, up to hundreds of thousands unit, its tubing cost reaches the 70% of Sulfurous Gas Fields Development cost, and the exploitation to sulfur Gas Fields is made Into strong influence, cause the relatively low gas field of yield because development cost is too high to employ.How to solve to develop sulfur-bearing The tubing corrosion problems of natural gas, the international, country does not propose effective solution.Tubing problem is still restriction sulfur Gas Fields The main problem of exploitation.Therefore, a kind of low cost, reliably exploitation of the anti-sulphur oil pipe for sulfur-containing gas are researched and developed With very great economic benefit and social environment benefit.
The content of the invention
There is problem for prior art, the present invention provides a kind of anti-sulphur oil pipe overall structure of glazing cermet and its adds Work method, to improve pressure-bearing, the sealability of oil pipe, it is ensured that anti-sulphur effect.
For achieving the above object, the present invention provides a kind of anti-sulphur oil pipe overall structure of glazing cermet, including oil Pipe, box cupling, oil tube inner lining cermet coating, it is characterised in that:It is ceramic glaze layer, oil pipe port metal pottery above cermet coating Enamel coating the inside and box cupling inwall are nickel base alloy layer, are tightly connected between oil pipe port and box cupling.
It is tightly connected between described oil pipe port and box cupling as hermetic seal is threadedly coupled.
Described hermetic seal screw thread uses partially trapezoidal sealing screw thread.
Described oil pipe end face is connected the position oil pipe port to form sealing surface with box cupling and box cupling is respectively machined with fillet.
A kind of anti-sulphur oil pipe overall structure processing method of glazing cermet, it is characterised in that comprise the following steps:
A, oil pipe port and box cupling are combined one layer of nickel-base alloy;
B, whole tube inner wall lining metal ceramic layer;
C, apply ceramic glaze in ceramic layer inwall;
D, oil pipe port, box cupling hermetic seal threaded connection.
The step a, oil pipe port and box cupling 3D printing nickel-base alloy.
The step c, ceramic glaze is applied in oil pipe ceramic layer inwall, and glazing at twice is for the first time to treat self-propagating reaction knot Shu Hou, first stops oil pipe and rotates, and removes oil pipe helmet, restarts centrifuge, adjustment cermet oil pipe rotating speed to 300-400 Rev/min, the temperature change of oil pipe is monitored with temperature measurer;When oil pipe temperature drop is to 500-480 degrees Celsius, to cermet oil Inside pipe wall glazing, with the reduction of cermet oil pipe temperature, glaze can first melt and solidify again;It is centrifuged after glaze solidifies completely Machine stops operating, and is taken out from centrifuge after the cooling of cermet oil pipe;Cermet oil pipe is put into 580-620 degrees Celsius of guarantor 20-40 minutes is incubated in warm stove into glaze;Cermet oil pipe is taken out, room temperature is cooled to;Second glazing is in first time glazing Glazing during rear cermet oil pipe inactive state, other techniques are with first time glazing.
Glaze is the low temperature glaze of main component silicon-boron-titanium-zinc system twice, and glaze mesh number is in 400-600 mesh.
Present invention has the advantages that:The present invention applies ceramic glaze using cermet composite oil pipe inwall, can effectively prevent Corrosion of the sulfur-containing gas to tubing, glazing solves the pin hole and micro-crack defect problem of surface ceramii layer, obtains smooth Tube inner wall, reduce flow resistance;Hermetic seal screw thread is employed, the bearing capacity of oil pipe is substantially increased;By sealing The nickel-base alloy part that face falls in oil pipe port and box cupling, it is ensured that anti-sulphur effect.
Brief description of the drawings
Fig. 1 is the schematic diagram of oil pipe port 3D printing nickel-base alloy;
Fig. 2 is the schematic diagram of box cupling 3D printing nickel-base alloy;
Fig. 3 is the schematic diagram after oil tube inner lining cermet coating;
Fig. 4 is the schematic diagram after cermet tube inner wall applies ceramic glaze;
Fig. 5 is that oil pipe processes the schematic diagram that hermetic seal is threadedly coupled after applying ceramic glaze;
Fig. 6 is the schematic diagram of box cupling processing hermetic seal threaded connection;
Fig. 7 is overall structure diagram of the present invention.
Specific embodiment
The present invention is described in more detail with reference to the accompanying drawings.
Embodiment 1
Reference picture 1, in Ф 73.02*5.51mm*9.6m, the port 3D of J55 oil pipes 2 beats 5mm nickel-base alloys ring 1, nickel-base alloy thickness It is identical with oil pipe pipe thickness.
Reference picture 2,3D printing Ф 73*8.5mm*59mm nickel-base alloys ring 4, Ni-based in the middle part of Ф 89*189mm box cupling inwalls Alloy surface is with box cupling inner surface with high.
Reference picture 3, port is printed with the inwall lining metal ceramic layer 5 of the oil pipe 2 of nickel-base alloy 1.By reaction equation 2Al+ Fe2O3=Al2O3+ 2Fe calculates reaction-ure mixture:Al powder 6.64Kg, Fe2O3 powder 19.67Kg.120 DEG C of oil pipe preheating, insulation 2 Hour, 260 mesh chemistry powder is well mixed and is put into oil pipe, oil pipe is then put into special overlength centrifuge, by 180g's Centrifugal force determines rotating speed, lights reactant, and product is according to the different layering solidifications of density.Outermost layer is the larger iron layer of density, Metallurgical binding is formed with tube inner wall;Centre is the cermet coating that aluminium oxide ceramics is not kept completely separate with metal;Innermost layer is Alumina ceramic layer.
Reference picture 4, applies ceramic glaze and forms ceramic glaze layer 6 in the inwall of oil pipe ceramic layer 5.Glazing at twice, treats for the first time After self-propagating reaction terminates, first stop oil pipe and rotate, remove oil pipe helmet, restart centrifuge, adjustment cermet oil pipe turns Speed monitors the temperature change of oil pipe with temperature measurer to 300 revs/min;When oil pipe temperature drop is to 500 degrees Celsius, in oil pipe Wall glazing, with the reduction of oil pipe temperature, glaze can first melt and solidify again;Centrifuge stops operating after glaze solidifies completely, Taken out from centrifuge after oil pipe cooling;Oil pipe is put into 620 degrees Celsius of holding furnaces and is incubated 20 minutes into glaze;Take out oil pipe, Room temperature is cooled to, first time glazing primarily serves the effect being modified to ceramic surface, improves ceramic glaze in ceramic surface Wetability;Second glazing is the glazing in the oil pipe inactive state after first time glazing, and other techniques are with first time glazing.The Secondary glazing can form smooth glaze in the glaze layer surface of first time glazing with the formal expansion of complete wetting in ceramic surface Face, reaches anti-corrosion, the purpose of antiscale.Glaze is the low temperature glaze of main component silicon-boron-titanium-zinc system twice, and glaze mesh number exists 400 mesh.
Reference picture 5, the outer wall side circumferential surface processing hermetic seal screw thread 7 of oil pipe 2, forms sealing surface 8.Ceramic layer end essence Mill, to increase sealing property, oil pipe processes fillet with box cupling junction oil pipe port, and screw thread uses partially trapezoidal sealing screw thread.
Reference picture 6, processes hermetic seal screw thread 10 on the both sides circumferential surface of 3 inside nickel-base alloy of box cupling 4, form sealing surface 9, box cupling processes fillet with oil pipe junction, and screw thread uses partially trapezoidal sealing screw thread.
Reference picture 7, oil pipe 2 and box cupling 3 tighten pressure testing, packaging and warehousing of painting.
Embodiment 2
In addition to glazing process difference, remaining is with embodiment 1.
Glazing at twice, is for the first time after self-propagating reaction terminates, first to stop oil pipe and rotate, and removes oil pipe helmet, then Start centrifuge, adjustment oil pipe rotating speed monitors the temperature change of oil pipe with temperature measurer to 350 revs/min;Treat oil pipe temperature drop extremely At 480 degrees Celsius, to tube inner wall glazing, with the reduction of oil pipe temperature, glaze can first melt and solidify again;Treat that glaze coagulates completely Gu rear centrifuge stops operating, taken out from centrifuge after oil pipe cooling;Oil pipe is put into 580 degrees Celsius of holding furnaces and is incubated 30 Minute into glaze;Oil pipe is taken out, room temperature is cooled to, first time glazing primarily serves the effect being modified to ceramic surface, improved Wetability of the ceramic glaze in ceramic surface;Second glazing is the glazing in the oil pipe inactive state after first time glazing, other Technique is with first time glazing.Second glazing can be in the glaze layer surface of first time glazing with the formal expansion of complete wetting, in pottery Porcelain surface forms smooth glaze paint, reaches anti-corrosion, the purpose of antiscale.Glaze is main component silicon-boron-titanium-zinc system twice Low temperature glaze, glaze mesh number is in 500 mesh.
Embodiment 3
In addition to glazing process difference, remaining is with embodiment 1.
Glazing at twice, is for the first time after self-propagating reaction terminates, first to stop oil pipe and rotate, and removes oil pipe helmet, then Start centrifuge, adjustment oil pipe rotating speed monitors the temperature change of oil pipe with temperature measurer to 400 revs/min;Treat oil pipe temperature drop extremely At 490 degrees Celsius, to tube inner wall glazing, with the reduction of oil pipe temperature, glaze can first melt and solidify again;Treat that glaze coagulates completely Gu rear centrifuge stops operating, taken out from centrifuge after oil pipe cooling;Oil pipe is put into 600 degrees Celsius of holding furnaces and is incubated 40 Minute into glaze;Oil pipe is taken out, room temperature is cooled to;Second glazing is the cermet oil pipe inactive state after first time glazing When glazing, other techniques are with first time glazing.

Claims (8)

1. the anti-sulphur oil pipe overall structure of a kind of glazing cermet, including oil pipe, box cupling, oil tube inner lining cermet coating, it is special Levy and be:It is ceramic glaze layer above cermet coating, oil pipe port cermet coating the inside and box cupling inwall are Ni-based conjunction Layer gold, is tightly connected between oil pipe port and box cupling.
2. the anti-sulphur oil pipe overall structure of a kind of glazing cermet according to claim 1, it is characterised in that:Described oil It is tightly connected between pipe port and box cupling as hermetic seal is threadedly coupled.
3. the anti-sulphur oil pipe overall structure of a kind of glazing cermet according to claim 2, it is characterised in that:Described gas Sealing screw thread uses partially trapezoidal sealing screw thread.
4. the anti-sulphur oil pipe overall structure of a kind of glazing cermet according to claim 1, it is characterised in that:Described oil End surfaces and box cupling are tightly connected the position oil pipe port to form sealing surface and box cupling is respectively machined with fillet.
5. a kind of anti-integrally-built processing method of sulphur oil pipe of glazing cermet according to claim 1, its feature exists In comprising the following steps:
A, oil pipe port and box cupling are combined one layer of nickel-base alloy;
B, whole tube inner wall lining metal ceramic layer;
C, apply ceramic glaze in ceramic layer inwall;
D, oil pipe port, box cupling hermetic seal threaded connection.
6. a kind of anti-integrally-built processing method of sulphur oil pipe of glazing cermet according to claim 5, its feature exists In:The step a, oil pipe port and box cupling 3D printing nickel-base alloy.
7. a kind of anti-integrally-built processing method of sulphur oil pipe of glazing cermet according to claim 5, its feature exists In:The step c, ceramic glaze is applied in oil pipe ceramic layer inwall, glazing at twice, be for the first time after self-propagating reaction terminates, First stop oil pipe rotating, remove oil pipe helmet, restart centrifuge, adjust cermet oil pipe rotating speed to 300-400 revs/min, The temperature change of oil pipe is monitored with temperature measurer;When oil pipe temperature drop is to 500-480 degrees Celsius, to cermet tube inner wall Glazing, with the reduction of cermet oil pipe temperature, glaze can first melt and solidify again;Centrifuge stops after glaze solidifies completely Rotate, taken out from centrifuge after the cooling of cermet oil pipe;Cermet oil pipe is put into 580-620 degrees Celsius of holding furnace 20-40 minutes is incubated into glaze;Cermet oil pipe is taken out, room temperature is cooled to;Second glazing is the gold after first time glazing Glazing during category ceramics oil pipe inactive state, other techniques are with first time glazing.
8. a kind of anti-integrally-built processing method of sulphur oil pipe of glazing cermet according to claim 7, its feature exists In:Glaze is the low temperature glaze of main component silicon-boron-titanium-zinc system twice, and glaze mesh number is in 400-600 mesh.
CN201710040223.4A 2017-01-20 2017-01-20 A kind of anti-sulphur oil pipe overall structure of glazing cermet and its processing method Withdrawn CN106869813A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022069366A1 (en) * 2020-10-01 2022-04-07 Vallourec Oil And Gas France Metal tubular connecting part and method for obtaining such a part by additive manufacturing

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103451647A (en) * 2013-07-22 2013-12-18 南通大学 Preparation method for centrifugal self-propagating ceramic/alloy double-compound wear-resistant tube
US8678042B2 (en) * 1995-09-28 2014-03-25 Fiberspar Corporation Composite spoolable tube
CN103967425A (en) * 2013-01-28 2014-08-06 扬州安泰威合金硬面科技有限公司 Abrasion-resistant and corrosion-resistant bimetal composite oil pipe completely coated with coating
CN104032301A (en) * 2014-06-05 2014-09-10 武汉团结点金激光制造技术有限公司 Laser-cladding coating preparation process of corrosion-resistant, sulfur-resistant and wear-resistant tubing coupling
CN203939451U (en) * 2013-10-11 2014-11-12 杨林 Nickel-base alloy oil pipe or sleeve pipe
CN105351635A (en) * 2015-08-26 2016-02-24 杨永利 Metal-ceramic composite pipe and manufacturing process thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8678042B2 (en) * 1995-09-28 2014-03-25 Fiberspar Corporation Composite spoolable tube
CN103967425A (en) * 2013-01-28 2014-08-06 扬州安泰威合金硬面科技有限公司 Abrasion-resistant and corrosion-resistant bimetal composite oil pipe completely coated with coating
CN103451647A (en) * 2013-07-22 2013-12-18 南通大学 Preparation method for centrifugal self-propagating ceramic/alloy double-compound wear-resistant tube
CN203939451U (en) * 2013-10-11 2014-11-12 杨林 Nickel-base alloy oil pipe or sleeve pipe
CN104032301A (en) * 2014-06-05 2014-09-10 武汉团结点金激光制造技术有限公司 Laser-cladding coating preparation process of corrosion-resistant, sulfur-resistant and wear-resistant tubing coupling
CN105351635A (en) * 2015-08-26 2016-02-24 杨永利 Metal-ceramic composite pipe and manufacturing process thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022069366A1 (en) * 2020-10-01 2022-04-07 Vallourec Oil And Gas France Metal tubular connecting part and method for obtaining such a part by additive manufacturing
FR3114859A1 (en) * 2020-10-01 2022-04-08 Vallourec Oil And Gas France METAL TUBULAR CONNECTING PART AND METHOD FOR OBTAINING SUCH A PART BY ADDITIVE MANUFACTURING

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Application publication date: 20170620

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