CN106867644A - A kind of stainless steel forging compounded lubricant and preparation method thereof and application method - Google Patents
A kind of stainless steel forging compounded lubricant and preparation method thereof and application method Download PDFInfo
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- CN106867644A CN106867644A CN201611214362.6A CN201611214362A CN106867644A CN 106867644 A CN106867644 A CN 106867644A CN 201611214362 A CN201611214362 A CN 201611214362A CN 106867644 A CN106867644 A CN 106867644A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/02—Water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/08—Inorganic acids or salts thereof
- C10M2201/081—Inorganic acids or salts thereof containing halogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/10—Compounds containing silicon
- C10M2201/102—Silicates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/10—Compounds containing silicon
- C10M2201/105—Silica
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/12—Glass
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/101—Condensation polymers of aldehydes or ketones and phenols, e.g. Also polyoxyalkylene ether derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/04—Groups 2 or 12
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/02—Pour-point; Viscosity index
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/08—Resistance to extreme temperature
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Forging (AREA)
- Lubricants (AREA)
Abstract
The present invention discloses a kind of stainless steel forging composite lubricant and preparation method thereof and application method, is made up of the component of following weight portion:90 100 parts of glass dust, 57 parts of calamine of forging, 68 parts of chlorite, 25 30 parts of fusion silicon powder, 47 parts of yttria, 0.2 0.6 parts of phenol-formaldehyde resin modified high-temperature agglomerant, 200 250 parts of water, 12 14 parts of calcium chloride.A kind of stainless steel forging composite lubricant and preparation method thereof and application method that the present invention is provided; can be during stainless steel be forged; for it provides good protection; oxidation and decarburization that stainless steel is caused in heating process due to high temperature can be greatly reduced, the surface quality of forging can be effectively improved.
Description
Technical field
The invention belongs to stainless steel forging field, and in particular to a kind of stainless steel forging compounded lubricant and its preparation side
Method and application method.
Background technology
Stainless steel at most, causes poor this kind of steel heat conductivility, narrow forging temperature, superheated susceptivity containing chromium, nickel element
Drag is big under strong and high temperature, the low unfavorable factor of plasticity, and many difficulties are brought to forging.Different types of stainless steel forging
Making technique also has very big difference.Therefore from industrial technology and needs are put into practice, need to use in stainless steel forging process
High-temperature lubricant come aid in forging.It is glass protecting lubricant to apply at present most, and it can be in certain heating and plasticity
In deformation temperature range, fine and close, continuous, uniform glass film is formed on metal blank surface, in metal plastic deformation process
Play good protection, lubrication and heat insulating function.But found in actual production, common glass protecting lubricant effect effect
Fruit is not that very significantly its protecting effect at high temperature to stainless steel is less desirable, and stainless steel oxidation at high temperature is still
Very serious, obtained stainless steel quality is relatively low.
The content of the invention
In order to solve the deficiencies in the prior art, the present invention provides a kind of stainless steel forging compounded lubricant and its preparation side
Method and application method.
The present invention is achieved by the following technical solutions.
A kind of stainless steel forging compounded lubricant, is made up of the component of following weight portion:Glass dust 90-100 parts, forge
Sweet stone 5-7 parts, chlorite 6-8 parts, 25-30 parts of fusion silicon powder, yttria 4-7 parts, phenol-formaldehyde resin modified high temperature glue
Knot 0.2-0.6 parts of agent, water 200-250 parts, calcium chloride 12-14 parts, above-mentioned glass dust is made up of the component of following weight portion:Dioxy
36 parts of SiClx, 2 parts of aluminum oxide, 8 parts of calcium oxide, 4 parts of magnesia, 34 parts of boron oxide, 16 parts of sodium oxide molybdena, above-mentioned forging calamine by with
The component composition of lower weight portion:94 parts of zinc oxide, 1 part of calcium oxide, 0.5 part of magnesia, iron oxide 3.5,1 part of manganese oxide are above-mentioned
Phenol-formaldehyde resin modified high-temperature agglomerant is according to 95 by phenolic resin and boron carbide:13 weight ratio is mixed.
As the further scheme of invention, a kind of preparation method of stainless steel forging compounded lubricant, including following behaviour
Make step:Glass dust, forging calamine, chlorite, fusion silicon powder, yttria are put into ball mill, mixed at high speed
Taken out after 40-50min, be added to the water, then to phenol-formaldehyde resin modified high-temperature agglomerant, calcium chloride is added in water, stir 20-
After 25min, the preparation method of stainless steel forging compounded lubricant is obtained.
As the further scheme of invention, a kind of application method of stainless steel forging compounded lubricant, by stainless steel watch
Face using dip coating by after decontamination rust cleaning oil removal treatment, stainless steel being uniformly coated in by stainless steel forging compounded lubricant
Surface, in 0.3-0.5mm, wherein stainless steel forging is with composite lubricated for the thickness of dry film control of stainless steel forging compounded lubricant
The operating temperature range of agent is 900-1300 DEG C.
Technical scheme more than, the beneficial effects of the invention are as follows:
Stainless steel forging compounded lubricant of the invention obtained, with resistance to burning, be not lost in the characteristics of, at high temperature, with compared with
Viscosity high and good mobility, can effectively make stainless steel surface and air exclusion during forging, play excellent
Oxidation-protective effect more, and the obtained lubricant of the present invention, operating temperature range are wider, can be that the stainless steel of various material exists
Protective effect is provided during forging.Wherein, glass dust in high temperature environments, can stainless steel surfaces formed one layer it is good
With the film for lubricating and completely cutting off air, then fusion silicon powder and yttria synergy, can fill up glass dust thin
The hole of film, further lifts the greasy property of film and the ability of isolation air, and it can also lift the stability of film;
Forging calamine, the addition of chlorite, can form with glass dust and act synergistically, and lift wink the melting property and viscosity of lubricant, greatly
Improve the performance of lubricant.
Specific embodiment
Following examples are used to illustrate the present invention, but can not be used for limiting the scope of the present invention.The reality used in embodiment
The condition of applying can be for further adjustments according to the condition of producer, and unaccounted implementation condition is usually conventional laboratory conditions.
Embodiment 1
A kind of stainless steel forging compounded lubricant, is made up of the component of following weight portion:90 parts of glass dust, forging 5 parts of calamine,
6 parts of chlorite, 25 parts of fusion silicon powder, 4 parts of yttria, 0.2 part of phenol-formaldehyde resin modified high-temperature agglomerant, 200 parts of water,
12 parts of calcium chloride, above-mentioned glass dust is made up of the component of following weight portion:36 parts of silica, 2 parts of aluminum oxide, 8 parts of calcium oxide,
4 parts of magnesia, 34 parts of boron oxide, 16 parts of sodium oxide molybdena, above-mentioned forging calamine are made up of the component of following weight portion:Zinc oxide 94
Part, 1 part of calcium oxide, 0.5 part of magnesia, iron oxide 3.5,1 part of manganese oxide, above-mentioned phenol-formaldehyde resin modified high-temperature agglomerant is by phenol
Urea formaldehyde and boron carbide are according to 95:13 weight ratio is mixed.
As the further scheme of invention, a kind of preparation method of stainless steel forging compounded lubricant, including following behaviour
Make step:Glass dust, forging calamine, chlorite, fusion silicon powder, yttria are put into ball mill, mixed at high speed
Taken out after 40min, be added to the water, then to phenol-formaldehyde resin modified high-temperature agglomerant, calcium chloride is added in water, after stirring 20min, made
Obtain the preparation method of stainless steel forging compounded lubricant.
As the further scheme of invention, a kind of application method of stainless steel forging compounded lubricant, by stainless steel watch
Face using dip coating by after decontamination rust cleaning oil removal treatment, stainless steel being uniformly coated in by stainless steel forging compounded lubricant
Surface, the thickness of dry film control of stainless steel forging compounded lubricant in 0.3mm, wherein stainless steel forging compounded lubricant
Operating temperature range is 900-1300 DEG C.
Embodiment 2
A kind of stainless steel forging compounded lubricant, is made up of the component of following weight portion:95 parts of glass dust, forging 6 parts of calamine,
7 parts of chlorite, 28 parts of fusion silicon powder, 5 parts of yttria, 0.4 part of phenol-formaldehyde resin modified high-temperature agglomerant, 225 parts of water,
13 parts of calcium chloride, above-mentioned glass dust is made up of the component of following weight portion:36 parts of silica, 2 parts of aluminum oxide, 8 parts of calcium oxide,
4 parts of magnesia, 34 parts of boron oxide, 16 parts of sodium oxide molybdena, above-mentioned forging calamine are made up of the component of following weight portion:Zinc oxide 94
Part, 1 part of calcium oxide, 0.5 part of magnesia, iron oxide 3.5,1 part of manganese oxide, above-mentioned phenol-formaldehyde resin modified high-temperature agglomerant is by phenol
Urea formaldehyde and boron carbide are according to 95:13 weight ratio is mixed.
As the further scheme of invention, a kind of preparation method of stainless steel forging compounded lubricant, including following behaviour
Make step:Glass dust, forging calamine, chlorite, fusion silicon powder, yttria are put into ball mill, mixed at high speed
Taken out after 45min, be added to the water, then to phenol-formaldehyde resin modified high-temperature agglomerant, calcium chloride is added in water, after stirring 23min, made
Obtain the preparation method of stainless steel forging compounded lubricant.
As the further scheme of invention, a kind of application method of stainless steel forging compounded lubricant, by stainless steel watch
Face using dip coating by after decontamination rust cleaning oil removal treatment, stainless steel being uniformly coated in by stainless steel forging compounded lubricant
Surface, the thickness of dry film control of stainless steel forging compounded lubricant in 0.4mm, wherein stainless steel forging compounded lubricant
Operating temperature range is 900-1300 DEG C.
Embodiment 3
A kind of stainless steel forging compounded lubricant, is made up of the component of following weight portion:100 parts of glass dust, forging calamine 7
Part, 8 parts of chlorite, 30 parts of fusion silicon powder, 7 parts of yttria, 0.6 part of phenol-formaldehyde resin modified high-temperature agglomerant, water 250
Part, 14 parts of calcium chloride, above-mentioned glass dust is made up of the component of following weight portion:36 parts of silica, 2 parts of aluminum oxide, calcium oxide 8
Part, 4 parts of magnesia, 34 parts of boron oxide, 16 parts of sodium oxide molybdena, above-mentioned forging calamine are made up of the component of following weight portion:Zinc oxide
94 parts, 1 part of calcium oxide, 0.5 part of magnesia, iron oxide 3.5,1 part of manganese oxide, above-mentioned phenol-formaldehyde resin modified high-temperature agglomerant be by
Phenolic resin and boron carbide are according to 95:13 weight ratio is mixed.
As the further scheme of invention, a kind of preparation method of stainless steel forging compounded lubricant, including following behaviour
Make step:Glass dust, forging calamine, chlorite, fusion silicon powder, yttria are put into ball mill, mixed at high speed
Taken out after 50min, be added to the water, then to phenol-formaldehyde resin modified high-temperature agglomerant, calcium chloride is added in water, after stirring 25min, made
Obtain the preparation method of stainless steel forging compounded lubricant.
As the further scheme of invention, a kind of application method of stainless steel forging compounded lubricant, by stainless steel watch
Face using dip coating by after decontamination rust cleaning oil removal treatment, stainless steel being uniformly coated in by stainless steel forging compounded lubricant
Surface, the thickness of dry film control of stainless steel forging compounded lubricant in 0.5mm, wherein stainless steel forging compounded lubricant
Operating temperature range is 900-1300 DEG C.
In order to verify effect of the invention, conventional technology is not for during embodiment 1,2,3 and comparative example is respectively adopted
Rust steel provides protection during forging, and test result is as shown in table 1:
A kind of compliance test result of stainless steel forging compounded lubricant of table 1
Project | Scale thickness/mm |
Embodiment 1 | 0 |
Embodiment 2 | 0 |
Embodiment 3 | 0 |
Comparative example | 0.25 |
As shown in Table 1, composite lubricant and preparation method thereof and user are used in a kind of stainless steel forging that the present invention is provided
Method, can stainless steel forge during, for it provides good protection, can greatly reduce stainless steel heating process by
In oxidation and decarburization that high temperature causes, the surface quality of forging can be effectively improved.
Certainly, described above is not limitation of the present invention, and the present invention is also not limited to the example above, the art
Those of ordinary skill, in essential scope of the invention, the change made, change, addition or replace, should all belong to the present invention
Protection domain.
Claims (3)
1. a kind of stainless steel forging compounded lubricant, it is characterised in that be made up of the component of following weight portion:Glass dust 90-
100 parts, forging 5-7 parts of calamine, chlorite 6-8 parts, 25-30 parts of fusion silicon powder, yttria 4-7 parts, modified phenolic
0.2-0.6 parts of resin high-temperature agglomerant, water 200-250 parts, calcium chloride 12-14 parts, above-mentioned glass dust by following weight portion group
It is grouped into:36 parts of silica, 2 parts of aluminum oxide, 8 parts of calcium oxide, 4 parts of magnesia, 34 parts of boron oxide, 16 parts of sodium oxide molybdena, it is above-mentioned
Forging calamine is made up of the component of following weight portion:94 parts of zinc oxide, 1 part of calcium oxide, 0.5 part of magnesia, iron oxide 3.5, oxygen
Change 1 part of manganese, above-mentioned phenol-formaldehyde resin modified high-temperature agglomerant is according to 95 by phenolic resin and boron carbide:13 weight is made than mixing
Into.
2. the preparation method of the stainless steel forging compounded lubricant described in a kind of claim 1, it is characterised in that including with
Lower operating procedure:Glass dust, forging calamine, chlorite, fusion silicon powder, yttria are put into ball mill, at a high speed
Taken out after mixing 40-50min, be added to the water, then to phenol-formaldehyde resin modified high-temperature agglomerant, calcium chloride is added in water, stir 20-
After 25min, the preparation method of stainless steel forging compounded lubricant is obtained.
3. the application method of the stainless steel forging compounded lubricant described in a kind of claim 1, it is characterised in that will be stainless
Steel surface is by after decontamination rust cleaning oil removal treatment, stainless steel forging compounded lubricant being uniformly coated in using dip coating stainless
The surface of steel, in 0.3-0.5mm, wherein stainless steel forging uses compound for the thickness of dry film control of stainless steel forging compounded lubricant
The operating temperature range of lubricant is 900-1300 DEG C.
Priority Applications (1)
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CN201611214362.6A CN106867644A (en) | 2016-12-26 | 2016-12-26 | A kind of stainless steel forging compounded lubricant and preparation method thereof and application method |
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CN201611214362.6A CN106867644A (en) | 2016-12-26 | 2016-12-26 | A kind of stainless steel forging compounded lubricant and preparation method thereof and application method |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108165359A (en) * | 2018-02-08 | 2018-06-15 | 广西厚思品牌策划顾问有限公司 | A kind of fire-resistant lubricants and preparation method thereof |
CN109797023A (en) * | 2019-01-25 | 2019-05-24 | 二重(德阳)重型装备有限公司 | Ten thousand tons of press, hundred tons of complex forging forging lubricants and its preparation method |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102277221A (en) * | 2011-04-27 | 2011-12-14 | 北京天力创玻璃科技开发有限公司 | Novel glass lubricant of stainless steel extruded tube |
CN102549282A (en) * | 2009-09-29 | 2012-07-04 | 谢夫勒科技股份两合公司 | Lubricating varnish for coating a metal component or applied to a metal component |
-
2016
- 2016-12-26 CN CN201611214362.6A patent/CN106867644A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102549282A (en) * | 2009-09-29 | 2012-07-04 | 谢夫勒科技股份两合公司 | Lubricating varnish for coating a metal component or applied to a metal component |
CN102277221A (en) * | 2011-04-27 | 2011-12-14 | 北京天力创玻璃科技开发有限公司 | Novel glass lubricant of stainless steel extruded tube |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108165359A (en) * | 2018-02-08 | 2018-06-15 | 广西厚思品牌策划顾问有限公司 | A kind of fire-resistant lubricants and preparation method thereof |
CN109797023A (en) * | 2019-01-25 | 2019-05-24 | 二重(德阳)重型装备有限公司 | Ten thousand tons of press, hundred tons of complex forging forging lubricants and its preparation method |
CN109797023B (en) * | 2019-01-25 | 2020-06-23 | 二重(德阳)重型装备有限公司 | Million-ton complex forging lubricant for ten-thousand-ton press and preparation method thereof |
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